Surficial and Deep Earth Material Prediction from Geochemical Compositions     

Talebi  Hassan  Mueller  Ute  Tolosana-Delgado  Raimon  Grunsky  Eric C.  McKinley  Jennifer M.  Caritat  Patrice de 《Natural Resources Research》2019,28(3):869-891

Prediction of true classes of surficial and deep earth materials using multivariate spatial data is a common challenge for geoscience modelers. Most geological processes leave a footprint that can be explored by geochemical data analysis. These footprints are normally complex statistical and spatial patterns buried deep in the high-dimensional compositional space. This paper proposes a spatial predictive model for classification of surficial and deep earth materials derived from the geochemical composition of surface regolith. The model is based on a combination of geostatistical simulation and machine learning approaches. A random forest predictive model is trained, and features are ranked based on their contribution to the predictive model. To generate potential and uncertainty maps, compositional data are simulated at unsampled locations via a chain of transformations (isometric log-ratio transformation followed by the flow anamorphosis) and geostatistical simulation. The simulated results are subsequently back-transformed to the original compositional space. The trained predictive model is used to estimate the probability of classes for simulated compositions. The proposed approach is illustrated through two case studies. In the first case study, the major crustal blocks of the Australian continent are predicted from the surface regolith geochemistry of the National Geochemical Survey of Australia project. The aim of the second case study is to discover the superficial deposits (peat) from the regional-scale soil geochemical data of the Tellus Project. The accuracy of the results in these two case studies confirms the usefulness of the proposed method for geological class prediction and geological process discovery.

  相似文献   

Geochemical and geochronological characteristics of the Um Rus granite intrusion and associated gold deposit,Eastern Desert,Egypt     

Basem Zoheir  Richard Goldfarb  Astrid Holzheid  Hassan Helmy  Ahmed El Sheikh 《地学前缘(英文版)》2020,11(1):325-345

The Um Rus tonalite-granodiorite intrusion(~6 km2)occurs at the eastern end of the Neoproterozoic,ENE-trending Wadi Muba rak shear belt in the Central Eastern Desert of Egypt.Gold-bearing quartz veins hosted by the Um Rus intrusion were mined intermittently,and initially by the ancient Egyptians and until the early 1900 s.The relationship between the gold mineralization,host intrusion,and regional structures has always been unclear.We present new geochemical and geochronological data that help to define the tectonic environment and age of the Um Rus intrusion.In addition,field studies are integrated with EPMA and LA-ICP-MS data for gold-associated sulfides to better understand the formation and distribution of gold mineralization.The bulk-rock geochemical data of fresh host rocks indicate a calc-alkaline,metaluminous to mildly peraluminous,I-type granite signature.Their trace element composition reflects a tectonic setting intermediate between subduction-related and within-plate environments,presumably transitional between syn-and post-collisional stages.The crystallization age of the Um Rus intrusion was determined by in situ SHRIMP 206 Pb/238 U and 207Pb/235U measurements on accessory monazite grains.The resultant monazite U-Pb weighted mean age(643±9 Ma;MSWD 1.8)roughly overlaps existing geochronological data for similar granitic intrusions that are confined to major shear systems and are locally associated with gold mineralization in the Central Eastrn Desert(e.g.,Fawakhir and Hangaliya).This age is also consistent with magmatism recognized as concomitant to transpressional tectonics(D2:~650 Ma)during the evolution of the Wadi Mubark belt.Formation of the gold-bearing quartz veins in NNE-SSW and N-S striking fault segments was likely linked to the change from transpressional to transtensional tectonics and terrane exhumation(D3:620-580 Ma).The development of N-S throughgoing fault arrays and dike swarms(~595 Ma)led to heterogeneous deformation and recrystallization of the mineralized quartz veins.Ore minerals in the auriferous quartz veins include ubiquitous pyrite and arsenopyrite,with less abundant pyrrhotite,chalcopyrite,sphalerite,and galena.Uncommon pentlandite,gersdorffite,and cobaltite inclusions hosted in quartz veins with meladiorite slivers are interpreted as pre-ore sulfide phases.The gold-sulfide paragenesis encompasses an early pyrite-arsenopyrite±loellingite assemblage,a transitional pyrite-arsenopyrite assemblage,and a late pyrrhotite-chalcopyrite-sphalerite±galena assemblage.Free-milling gold/electrum grains(10 sμm-long)are scattered in extensively deformed vein quartz and in and adjacent to sulfide grains.Marcasite,malachite,and nodular goethite are authigenic alteration phases after pyrrhotite,chalcopyrite,and pyrite and arsenopyrite,respectively.A combined ore petrography,EPMA,and LA-ICP-MS study distinguishes morphological and compositional differences in the early and transitional pyrites(PyⅠ,PyⅡ)and arsenopyrite(ApyⅠ,ApyⅡ).Py I forms uncommon small euhedral inclusions in later PyⅡand Apy II.PyⅡforms large subhedral crystals with porous inner zones and massive outer zones,separated by narrow As-rich irregular mantles.The Fe and As contents in PyⅡare variable,and the LA-ICP-MS analysis shows erratic concentrations of Au(<1 to 177 ppm)and other trace elements(e.g.,Ag,Te,and Sb)in the porous inner zones,most likely related to discrete sub-microscopic sulfide inclusions.The outer massive zones have a rather homogenous composition,with consistently lower abundances of base metals and Au(mean 1.28 ppm).The early arsenopyrite(Apy I)forms fine-grained euhedral crystals enriched in Au(mean 17.7 ppm)and many other trace elements(i.e.,Ni,Co,Se,Ag,Sb,Te,Hg,and Bi).On the other hand,ApyⅡoccurs as coarsegrained subhedral crystals with lower and less variable concentrations of Au(mean 4 ppm).Elevated concentrations of Au(max.327 ppm)and other trace elements are measured in fragmented and aggregated pyrite and arsenopyrite grains,whereas the undeformed intact zones of the same grains are poor in all trace elements.The occurrence of gold/electrum as secondary inclusions in deformed pyrite and arsenopyrite crystals indicates that gold introduction was relatively late in the paragenesis.The LAICP-MS results are consistent with gold redistribution by the N-S though-going faults/dikes overprinted the earlier NNW-SSE quartz veins in the southeastern part of the intrusion,where the underground mining is concentrated.Formation of the Um Rus intrusion and gold-bearing quartz veins can be related to the evolution of the Wadi Mubarak shear belt,where the granitic intrusion formed during or just subsequent to D2 and provided dilatation spaces for gold-quartz vein deposition when deformed by D3 structures.  相似文献   

Carcinogenic Risk Assessment of Trihalomethanes in Major Drinking Water Sources of Baghdad City     

Salam H. Ewaid  Adel M. Rabee  Saadi K. Al-Naseri 《Water Resources》2018,45(5):803-812

Three standard methodological approaches used for carcinogenic risk assessment of the four trihalomethanes (THMs) species: Dibromochloromethane (CHClBr₂), Bromodichloromethane (CHCl₂Br), Bromoform (CHBr₃) and Chloroform (CHCl₃), in water collected from public water supplies which included main water source (raw water of the Tigris River), water treatment plants (treated water) and distribution system (tap water) in Baghdad City. The total concentration of THMs ranged between 13.78 and 63.1 μg/L in winter and summer respectively. The occurrence of THMs followed the given order: CHClBr₂ (36%) > CHCl₂Br (27%) > CHCl₃ (25%) > CHBr₃ (12%). The annual levels of THMs concentrations in the distribution networks of Baghdad City ranged between 12 and 97.3 μg/L in winter and summer, respectively, and followed the given order: CHClBr₂ (37%) > CHCl₂Br (33%) > CHCl₃ (21%) > CHBr³ (9%). The World Health Organization (WHO) index for additive toxicity approach was in compliant with the WHO guideline value, and does not pose any adverse toxic health impacts. The hazard index does not suggest any potential noncancer risk to the exposed population, whereas the total multi-pathway cancer risk analysis suggests that total cancer risk exceeds the USEPA acceptable level of 10–6.  相似文献   

Hydrothermal alteration and evolution of Zr-Th-U-REE mineralization in the microgranite of Wadi Ras Abda,North Eastern Desert,Egypt     

Amr Abdel Aty Abdel Hamid  Hassan Ismail El Sundoly  Ahmed Ali Abu Steet 《Arabian Journal of Geosciences》2018,11(11):273

Ras Abda plutonic suite, North Eastern Desert of Egypt, consists predominantly of Neoproterozoic calc-alkaline older granites. Minor exposures of pink microgranite are occurring along Wadi Ras Abda within the older granites. Previous studies on this area demonstrated that the microgranite is altered in some parts and contains anomalous concentrations of rare metal elements (Zr, Th, and U). These altered and mineralized zones are re-assessed using field observations, chemical analysis, and by the application of various transmitted light and electron microscopic techniques. The rare metals exist as mineral segregation grew freely into open cavities of the microgranite and concordant with the NNE strike-slip fault movement. The mineralized zones contain an assemblage of secondary magnetite, zircon, uranothorite, columbite-(Mn), fergusonite-(Y), and allanite-(Ce). The extreme abundance of zircon in the mineralized zone, along with other evidence, indicates a hydrothermal origin of this zircon together with associated rare metals. The geochemical investigation and mass balance calculations revealed extreme enrichment of Zr, Th, U, Y, Nb, Ta, and REE. Post-magmatic hydrothermal alterations resulted in such pronounced chemical and mineralogical heterogeneity. The hydrothermal fluids are thought to be oxidizing, alkaline and of medium temperature (>?250 °C). The average contents of the elements Zr (1606 ppm), Th (1639 ppm), U (306 ppm), Nb (955 ppm), and REE (1710 ppm) in the mineralized microgranite reach sub-economic levels and could be a potential source of these elements.  相似文献   

Surface mapping of the Milh Kharwah salt diapir to better understand the subsurface petroleum system in the Sab’atayn Basin,onshore Yemen     

Gabor Tari  Leslie Jessen  Patrick Kennelly  Adel Salman  Thomas Rainer  Peter Hagedorn 《Arabian Journal of Geosciences》2018,11(15):428

  相似文献   

Short-term greenhouse emission lowering effect of biochars from solid organic municipal wastes     

Djaafar Rehrah  Rishipal R. Bansode  Osman Hassan  Mohamed Ahmedna 《International Journal of Environmental Science and Technology》2018,15(5):1093-1102

Qatar economy has been growing rapidly during the last two decades during which waste generation and greenhouse gas emissions increased exponentially making them among the main environmental challenges facing the country. Production of biochar from municipal solid organic wastes (SOWs) for soil application may offer a sustainable waste management strategy while improving crop productivity and sequestering carbon. This study was conducted to (1) investigate the physicochemical parameters of biochars for SOW, (2) select the best-performing biochars for soil fertility, and (3) evaluate the potential benefits of these biochars in lowering greenhouse gases (GHGs) during soil incubation. Biochars were produced from SOW at pyrolysis temperatures of 300–750 °C and residence times of 2–6 h. Biochars were characterized before use in soil incubation to select the best-performing treatment and evaluation of potential GHG-lowering effect using CO₂ emission as proxy. Here, soil–biochar mixtures (0–2%w/w) were incubated in greenhouse settings for 120 days at 10% soil moisture. Soil properties, such as pH, EC, TC, and WHC, were significantly improved after soil amendment with biochar. Two biochars produced from mixed materials at 300–500 °C for 2 h and used at 0.5–1% application rate performed the best in enhancing soil fertility parameters. A significant decrease in CO₂ emission was observed in vials with soil–biochar mixtures, especially for biochars produced at 500 °C compared the corresponding raw materials which exhibited an exponential increase in the CO₂ emission. Hence, application of biochar to agricultural soils could be beneficial for simultaneously improving soil fertility/crop productivity while sequestering carbon, thereby reducing anthropogenic emissions of GHGs.  相似文献   

Assessment of the reliability of supervised classifications of Landsat-7, ASTER,and SPOT-5 multispectral data in rock unit discriminations of Jabal Daf-Wadi Fatima area,Saudi Arabia     

Adel Zein Bishta 《Arabian Journal of Geosciences》2018,11(23):755

Multispectral, multiresolution remotely sensed data were processed to emphasize geological interpretation of Jabal Daf-Wadi Fatima area. The investigated area is situated in the central western part of Saudi Arabia and geologically consists of igneous and metamorphosed rocks overlain by sedimentary sequence belonging to the Arabian-Nubian Shield. Three sets of digital satellite data, Landsat-7 ETM+, ASTER, and SPOT-5, were used in this study. The application of image processing techniques enables to identify and delineate the lithologic units and the structural features of the study area. The results of this study indicate that the confusion matrix of the three maximum likelihood supervised classifications of the three datasets shows that the Landsat ETM+ bands scored the best degree of average and overall accuracy (77 and 78%, respectively). This classification distinguishes most of the rock units for mapping in the investigated area. The supervised classification of ASTER and SPOT bands has lower degrees of accuracy than the classified Landsat data. The supervised classification of SPOT bands has a degree of average and overall accuracy of 66 and 67%, respectively, but it is the best for distinguishing the spectral signatures of the different members of Fatima Formation (lower, middle, and upper members). The statistical analyses of the confusion matrices of classifications and the interpretation of the produced classified thematic maps revealed that the classification accuracy does not necessary depend on the spatial resolution of satellite data. The data of the highest spatial resolution such as SPOT data are also very useful in emphasizing and classifying the rock units of a small outcrop area. The detailed geological map of Jabal Daf-Wadi Fatima area is interpreted in this work from supervised classified images of different resolutions as well as the structure map of this area. This study shows that it is preferable to use the supervised classifications of multiresolution data for rock unit discrimination in detailed field mapping.  相似文献   

Provenance,weathering, and paleoenvironment of the Upper Cretaceous Duwi black shales,Aswan Governorate,Egypt     

Samir M. Zaid  Oussama A. EL-Badry  Adel M. Akarish  Mahmoud A. Mohamed 《Arabian Journal of Geosciences》2018,11(7):147

The mineralogy and geochemistry of the Upper Cretaceous Duwi black shales of Nile Valley district, Aswan Governorate, Egypt, have been investigated to identify the source rock characteristics, paleoweathering, and paleoenvironment of the source area. The Duwi Formation consists mainly of phosphorite and black shales and is subdivided into three members. The lower and upper members composed mainly of phosphorite beds intercalated with thin lenses of gray shales, while the middle member is mainly composed of gray shale, cracked, and filled with gypsum. Mineralogically, the Duwi black shales consist mainly of smectite and kaolinite. The non-clay minerals are dominated by quartz, calcite, phosphate, dolomite, feldspar, with little gypsum, anhydrite, iron oxides, and pyrite. Based on the CIA, PIA, and CIW values (average?=?84, 94, 95, respectively), it can be concluded that the litho-components of the studied shales were subjected to intense chemical weathering and reflect warm/humid climatic conditions in the depositional basin. The provenance discrimination diagram indicates that the nature of the source rocks probably was mainly intermediate and mafic igneous sources with subordinate recycled sedimentary rocks (Nubia Formation). Geochemical characteristics indicate that the Duwi black shales in Nile Valley district were deposited under anoxic reducing marine environments.  相似文献   

ENSO and IOD analysis on the occurrence of floods in Pakistan     

Asif Iqbal  Syed Ahmad Hassan 《Natural Hazards》2018,91(3):879-890

Different techniques have been used to discuss the existence of significant relation between the El Nino Southern Oscillation (ENSO) and Indian Ocean Dipole (IOD). Various studies present their interaction and influence on the natural disasters (i.e. drought, flood, etc.) over large parts of the globe. This study uses a Markov chain method to investigate the relation between the ENSO and IOD for the period of 62 years (1950–2011) and aggregates their influence on the occurrence of floods in Pakistan. Both data sets show similarities in the formation of transition matrices and expected number of visits from one state to another. The strong values of 2-dimensional correlation and high self-communication of the transition states confirm the existence of a possible relation between ENSO and IOD data. Moreover, significant values of dependency and stationary test endorse the applicability of the Markov chain analyses. The independent analysis shows that strong events of both data sets are co-occurred in the same flood years. During the study period maximum number of floods was observed during summer monsoon season. However, further analysis shows that after 1970, Pakistan observed the highest percentage of floods occurred per year during El Nino, Non-ENSO and positive IOD years. These observations and results demonstrate that climate variability especially ENSO and IOD should be incorporated into disaster risk analyses and policies in Pakistan.  相似文献   

The impact of land use and land cover changes on soil erosion in western Iran   总被引：1，自引：0，他引：1  

Eskandari Damaneh  Hadi  Khosravi  Hassan  Habashi  Khalil  Eskandari Damaneh  Hamed  Tiefenbacher  John P. 《Natural Hazards》2022,110(3):2185-2205

Natural Hazards - Analysis of long-term land use and land cover (LULC) changes requires up-to-date remotely sensed data to assess their effects on erosion. This is a particularly important...  相似文献