Adsorption Mechanism and Kinetic Characterization of Bituminous Coal under High Temperatures and Pressures in the Linxing-Shenfu Area     

TAO Chuanqi  WANG Yanbin  LI Yong  NI Xiaoming  GAO Xiangdong 《《地质学报》英文版》2020,94(2):399-408

The majority of coalbed methane(CBM) in coal reservoirs is in adsorption states in coal matrix pores. To reveal the adsorption behavior of bituminous coal under high-temperature and high-pressure conditions and to discuss the microscopic control mechanism affecting the adsorption characteristics, isothermal adsorption experiments under hightemperature and high-pressure conditions, low-temperature liquid nitrogen adsorption-desorption experiments and CO2 adsorption experiments were performed on coal samples. Results show that the adsorption capacity of coal is comprehensively controlled by the maximum vitrinite reflectance(Ro, max), as well as temperature and pressure conditions. As the vitrinite reflectance increases, the adsorption capacity of coal increases. At low pressures, the pressure has a significant effect on the positive effect of adsorption, but the effect of temperature is relatively weak. As the pressure increases, the effect of temperature on the negative effect of adsorption gradually becomes apparent, and the influence of pressure gradually decreases. Considering pore volumes of pores with diameters of 1.7-100 nm, the peak volume of pores with diameters 10-100 nm is higher than that from pores with diameters 1.7-10 nm, especially for pores with diameters of 40-60 nm, indicating that pores with diameters of 10-100 nm are the main contributors to the pore volume. The pore specific surface area shows multiple peaks, and the peak value appears for pore diameters of 2-3 nm, indicating that this pore diameter is the main contributor to the specific surface area. For pore diameters of 0.489-1.083 nm, the pore size distribution is bimodal, with peak values at 0.56-0.62 nm and 0.82-0.88 nm. The adsorption capability of the coal reservoir depends on the development degree of the supermicroporous specific surface area, because the supermicroporous pores are the main contributors to the specific pore area. Additionally, the adsorption space increases as the adsorption equilibrium pressure increases. Under the same pressure, as the maximum vitrinite reflectance increases, the adsorption space increases. In addition, the cumulative reduction in the surface free energy increases as the maximum vitrinite reflectance increases. Furthermore, as the pressure increases, the surface free energy of each pressure point gradually decreases, indicating that as the pressure increases, it is increasingly difficult to adsorb methane molecules.  相似文献   

四川理塘地区二叠—三叠纪硅质岩的地球化学特征及地质意义     

严松涛  谭昌海  秦蒙  李虎  段阳海 《地球学报》2020,41(4):504-514

甘孜—理塘蛇绿混杂岩带位于西南"三江"东缘,为义敦—理塘弧盆系的重要组成部分,其内部发育大量不同时代不同类型的硅质岩。本次研究在理塘县理觉公路硅质岩夹层泥岩、泥灰岩中发现含有大量的中二叠—晚二叠世牙形石,在查日查东村附近硅质岩中采获中三叠世放射虫。通过对研究区硅质岩岩石学、地球化学特征研究,探讨硅质岩的成因类型及其沉积环境。结果表明,理塘地区硅质岩SiO_2质量分数为66.13%～85.89%, Al_2O_3质量分数为4.69%～7.85%, Al/(Al+Fe+Mn)值介于0.44～0.73之间, U/Th比值为0.10～0.19,δCe值为1.00～1.63,这些特征共同指示其为生物成因硅质岩。Al_2O_3/(Al_2O_3+Fe_2O_3)质量比为0.52～0.79, MnO/TiO_2质量比为0.05～0.27,∑REE为(49.26～165.41)×10~(–6),平均为94.37×10~(–6),(La/Yb)N比值为0.78～2.32,(La/Ce)N比值为0.72～1.26,指示其应形成于大陆边缘环境。理塘地区理觉公路和查日查东村二叠—三叠纪大陆边缘型硅质岩的厘定,不仅丰富了甘孜—理塘蛇绿混杂岩带的物质组成,也为甘孜—理塘洋盆二叠—三叠纪地质演化提供了新的证据。  相似文献   

不同顶管组合方式的管幕冻结温度场模型试验   总被引：1，自引：1，他引：0  

段寅  荣传新  程桦  蔡海兵  解德柱  丁杨龙 《冰川冻土》2020,42(2):479-490

拱北隧道作为港珠澳大桥珠海连接线的关键性工程， 在国内外首次成功运用了管幕冻结技术。以此为背景， 为更加全面地掌握饱和软土地层中管幕冻结温度场的分布特点， 开展了不同顶管组合方式下的管幕冻结温度场模型试验研究。试验结果表明： 各测点温度曲线在积极冻结期前4 h急剧下降， 随后逐渐减缓， 降至砂土冰点后趋于平稳， 三种布管方式均满足冻结设计要求； 冻结管中低温盐水提供的冷量首先传递给顶管管壁， 再以“面”的形式均匀地传递给周围土体； 积极冻结21 h后， 采用四根空顶管组合的C区冻结壁竖向范围最大， 空管管壁正上方冻结壁平均厚度约为105 mm， 在满足管幕刚度设计要求的前提下， 可采此布管方式以达到快速形成冻结帷幕的目的。限位管开启后的4 h内， 实顶管中线垂直距离100 mm范围内测点温度曲线虽有明显回升但仍维持在冻土冰点以下， 超出此范围后温度变化影响逐渐减弱， 且顶管间冻结壁稳定存在， 表明限位管在满足管间有效封水的条件下， 能在一定范围内起到定向限制地层冻胀的作用。优化后的双圆形冻结管在满足冻结设计要求的同时， 更加便于安装且经济环保。  相似文献   

Mineral Deposit Model of Cu–Fe–Au Skarn System in the Edongnan Region, Eastern China     

XIE Guiqing  MAO Jingwen  ZHU Qiaoqiao  HAN Yingxiao  LI Wei  DUAN Chao  YE Hui 《《地质学报》英文版》2020,94(6):1797-1807

Cu and Fe skarns are the world’s most abundant and largest skarn type deposits, especially in China, and Au-rich skarn deposits have received much attention in the past two decades and yet there are few papers focused on schematic mineral deposit models of Cu–Fe–Au skarn systems. Three types of Au-rich deposits are recognized in the Edongnan region, Middle–Lower Yangtze River metallogenic belt: ~140 Ma Cu–Au and Au–Cu skarn deposits and distal Au–Tl deposits; 137–148 Ma Cu–Fe; and 130–133 Ma Fe skarn deposits. The Cu–Fe skarn deposits have a greater contribution of mantle components than the Fe skarn deposits, and the hydrothermal fluids responsible for formation of the Fe skarn deposits involved a greater contribution from evaporitic sedimentary rocks compared to Cu–Fe skarn deposits. The carbonate-hosted Au–Tl deposits in the Edongnan region are interpreted as distal products of Cu–Au skarn mineralization. A new schematic mineral deposit model of the Cu–Fe–Au skarn system is proposed to illustrate the relationship between the Cu–Fe–Au skarn mineralization, the evaporitic sedimentary rocks, and distal Au–Tl deposits. This model has important implications for the exploration for carbonate–hosted Au–Tl deposits in the more distal parts of Cu–Au skarn systems, and Fe skarn deposits with the occurrence of gypsum-bearing host sedimentary rocks in the MLYRB, and possibly elsewhere.  相似文献   

西太平洋Y3海山对营养盐的影响及其生态环境效应     

马骏  宋金明  李学刚  袁华茂  李宁  段丽琴  王启栋 《地学前缘》2020,27(4):322-331

作为大洋典型地貌特征的海山,其邻近的海洋生境并不被人熟知。依据2014年冬季对热带西太平洋Y3海山及其邻近海域的综合调查,首次探讨了该海山区海水中营养盐的分布特征及其与生态环境的耦合关系。结果表明Y3海山区是典型的热带寡营养海域。在50~125 m的深度,温跃层和高盐区双重作用对底部高浓度营养盐向上输送的阻碍,是导致真光层上部营养盐浓度较低的重要原因;同时,浮游植物和异养细菌的消耗也加剧了该区域营养盐的缺乏。Y3海山突出的地形地貌对营养盐的分布产生重要的影响,海山对流经的海流产生阻碍,形成上升流,使底部高浓度的营养盐突破温跃层和高盐区的阻碍向上输送,从而使海山周围营养盐的平均浓度高于远离海山的海域。相关性分析显示,Y3海山区真光层中营养盐浓度与温度、盐度、叶绿素a浓度和异养细菌丰度分别呈负相关、正相关、负相关(除NO₂-N外)和负相关关系。海山区特殊的营养盐分布及其与生态环境的耦合是其成为一种独特的大洋生态系统的重要因素。  相似文献   

Carboniferous integrative stratigraphy and timescale of China     

Wang  Xiangdong  Hu  Keyi  Qie  Wenkun  Sheng  Qingyi  Chen  Bo  Lin  Wei  Yao  Le  Wang  Qiulai  Qi  Yuping  Chen  Jitao  Liao  Zhuoting  Song  Junjun 《中国科学:地球科学(英文版)》2019,62(1):135-153

The Carboniferous period lasted about 60 Myr, from ～358.9 Ma to ～298.9 Ma. According to the International Commission on Stratigraphy, the Carboniferous System is subdivided into two subsystems, i.e., Mississippian and Pennsylvanian, including 6 series and 7 stages. The Global Stratotype Sections and Points(GSSPs) of three stages have been ratified, the Tournaisian, Visean, and Bashkirian stages. The GSSPs of the remaining four stages(i.e., the Serpukhovian, Moscovian,Kasimovian, and Gzhelian) have not been ratified so far. This paper outlines Carboniferous stratigraphic subdivision and correlation on the basis of detailed biostratigraphy mainly from South China, and summarizes the Carboniferous chronostratigraphic framework of China. High-resolution biostratigraphic study reveals 37 conodont zones, 24 foraminiferal(including fusulinid) zones, 13 ammonoid zones, 10 brachiopod zones, and 10 rugose coral zones in the Carboniferous of China. The biostratigraphic framework based on these biozones warrants the precise correlation of regional stratigraphy of China(including2 subsystems, 4 series, and 8 stages) to that of the other regions globally. Meanwhile, the Carboniferous chemo-, sequence-,cyclo-, and event-stratigraphy of China have been intensively studied and can also be correlated worldwide. Future studies on the Carboniferous in China should focus on(1) the correlation between shallow-and deep-water facies and between marine and continental facies,(2) high-resolution astronomical cyclostratigraphy, and(3) paleoenvironment and paleoclimate analysis based on geochemical proxies such as strontium and oxygen isotopes, as well as stomatal indices of fossil plants.  相似文献   

河西走廊西段戈壁灌木群落多样性及其分布格局研究          下载免费PDF全文

董雪  李永华  辛智鸣  段瑞兵  姚斌  包岩峰  黄雅茹  张正国 《干旱区地理》2020,43(6):1514-1522

通过野外样方调查河西走廊西段荒漠戈壁典型灌木群落多样性状况，研究探讨了 8 种典型 灌木群落物种多样性的空间分布格局及其与地理因子的关系，对荒漠戈壁植物群落的多样性的保 护和可持续发展具有重要意义。结果表明：(1) 8 个典型灌木群落 Shannon-Wiener 指数、Simpson 指 数、Margalef 指数和 Pielou 指数从高到低为：盐爪爪群落>麻黄群落>合头草群落>红砂群落>梭梭群 落>泡泡刺群落>多枝柽柳群落>沙拐枣群落；波动范围分别为 0.314 ~ 1.355、0.179 ~ 0.666、0.334 ~ 1.222 和 0.051 ~ 0.218，说明荒漠戈壁灌木群落物种多样性指数偏低，群落结构简单，物种组成稀 少。(2) 不同灌木群落内物种数越多，群落间 Jaccard 相似性系数越大。大部分灌木群落类型间 Jac? card 相似性在 0.20 ~ 0.60 之间，群落间相似水平较低，群落相对稳定。(3) 随着海拔的升高，Margalef 指数、Pielou 指数和 Shannon-Wiener 指数均呈先增加后降低的单峰型分布格局，最大值出现在海拔 2 000 m，且与海拔显著相关（P<0.05）；在经度梯度上，从东到西，Margalef 指数、Pielou 指数和 Shan? non-Wiener 指数呈递增格局，但与经度无显著相关性（P>0.05）；在纬度梯度上，从南到北，Margalef 指数、Pielou 指数和 Shannon-Wiener 指数呈显著递增趋势（P<0.05）。总体上，荒漠戈壁灌木群落物 种多样性呈现出明显的垂直（海拔）和纬度地带性分布格局。  相似文献   

水源钻机在超深土层绳索取心钻进中的应用          下载免费PDF全文

杨联锋  段云星 《探矿工程》2020,47(11):44-50

山西省清徐县区域地质调查项目设计800、2000、3000 m科学钻探孔，以调查填补新生界底板埋深控制空白区，各孔钻入基岩30 m完钻。要求全孔取心，岩心采取率≮85%，岩心直径≮60 mm，采用塑料保护管采取原状岩样。针对超深软土层、各组地层特性及厚度未知、钻遇基岩完钻深度未知、大直径高保真全孔取心、项目价格远低于目前市场成本等难题，经过“水源钻机+大提钻取心+长裸眼孔段”实施800 m孔、“岩心钻机+绳索取心+套管固井”实施640 m参数对比孔，创新性使用“水源钻机+绳索取心+长裸眼孔段”工艺完成了2000 m孔的施工。该工艺岩心采取率达到93%，孔径和孔斜符合地质要求，为3000 m孔顺利施工打下了坚实的基础，为同类型项目提供了经验和借鉴。  相似文献   

气举反循环钻进井壁稳定及适用性探讨          下载免费PDF全文

郑伯乐  郑秀华  段晨阳  叶宏宇 《探矿工程》2020,47(6):13-18

气举反循环工艺具有钻进效率高、携带岩屑能力强、防漏效果好以及钻头寿命长等优点，同时还可以提高流体矿产的产能。但是一般认为气举反循环钻进抽吸作用会产生负压，不利于井壁稳定，不宜在松散地层应用。本文通过计算气举反循环钻进环空水力参数，并从环空压力以及冲洗液流态、流速等方面探讨研究气举反循环钻进中井壁稳定及其适用性，指出通过选取合适的钻具组合以及调节冲洗液性能，可使气举反循环工艺对不同地层的适应性更广。  相似文献   

基于斩波轮技术的K波段接收机噪声校准研究          下载免费PDF全文

王凯  王洋  陈卯蒸  段雪峰  闫浩  马军  陈晨雨  曹亮 《天文学报》2020,61(1):1

接收机是射电天文中用于探测微弱射电信号的重要接收设备.接收机的强度校准就是将接收机对射电源的响应转换为天文意义上的流量密度.常规方法就是使用经典的冷热负载法,将接收机自身的强度响应转换为一个等效的温度值,之后再据此对射电源做进一步标定.通过搭建基于斩波轮技术的K波段接收机强度校准平台,使用斩波轮法测试K波段常温接收机的噪声温度,并与传统冷热负载法的测试结果进行比对.结果显示,在晴好天气条件下,斩波轮法在30°、90°仰角下噪声温度的最大测试误差为7.5%和8.4%,可以很好地应用于实际噪声温度测试中;但在5°仰角测试中,由于过低仰角引入了地面噪声,使得斩波轮法的测试误差上升至20%–30%之间而无法使用.希望在此基础上进一步开展K波段天空亮温度的理论计算与实测,从而完善斩波轮技术的应用,使之可以满足在不同气象条件下的噪声校准测试需求.  相似文献