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1.
Current efforts to assess changes to the wetland hydrology caused by growing anthropogenic pressures in the Athabasca Oil Sands Region (AOSR) require well-founded spatial and temporal estimates of actual evapotranspiration (ET), which is the dominant component of the water budget in this region. This study assessed growing season (May–September) and peak growing season (July) ET variability at a treed moderate-rich fen and treed poor fen (in 2013–2018), open poor fen (in 2011–2014), and saline fen (in 2015–2018) using eddy covariance technique and a set of complementary environmental data. Seasonal fluctuations in ET were positively related to net radiation, air temperature and vapour pressure deficit and followed trends typical for the Boreal Plains (BP) and AOSR with highest rates in June–July. However, no strong effect of water table position on ET was found. Strong surface control on ET is evident from lower ET values than potential evapotranspiration (PET); the lowest ET/PET was observed at saline fen, followed by open fen, moderately treed fen, and heavily treed fen, suggesting a strong influence of vegetation on water loss. In most years PET exceeded precipitation (P), and positive relations between P/PET and ET were observed with the highest July ET rates occurring under P/PET ~1. However, during months with P/PET > 1, increased P/PET was associated with decreased July ET. With respect to 30-year mean values of air temperature and P in the area, both dry and wet, cool and warm growing seasons (GS) were observed. No clear trends between ET values and GS wetness/coldness were found, but all wet GS were characterized by peak growing seasons with high daily ET variability.  相似文献   
2.
Most source-to-sink studies typically focus on the dynamics of clastic sediments and consider erosion, transport and deposition of sediment particles as the sole contributors. Although often neglected, dissolved solids produced by weathering processes contribute significantly in the sedimentary dynamics of basins, supporting chemical and/or biological precipitation. Calcium ions are usually a major dissolved constituent of water drained through the watershed and may facilitate the precipitation of calcium carbonate when supersaturating conditions are reached. The high mobility of Ca2+ ions may cause outflow from an open system and consequently loss. In contrast, in closed basins, all dissolved (i.e. non-volatile) inputs converge at the lowest point of the basin. The endoreic Great Salt Lake basin constitutes an excellent natural laboratory to study the dynamics of calcium on a basin scale, from the erosion and transport through the watershed to the sink, including sedimentation in lake's waterbody. The current investigation focused on the Holocene epoch. Despite successive lake level fluctuations (amplitude around 10 m), the average water level seems to have not been affected by any significant long-term change (i.e. no increasing or decreasing trend, but fairly stable across the Holocene). Weathering of calcium-rich minerals in the watershed mobilizes Ca2+ ions that are transported by surface streams and subsurface flow to the Great Salt Lake (GSL). Monitoring data of these flows was corrected for recent anthropogenic activity (river management) and combined with direct precipitation (i.e. rain and snow) and atmospheric dust income into the lake, allowing estimating the amount of calcium delivered to the GSL. These values were then extrapolated through the Holocene period and compared to the estimated amount of calcium stored in GSL water column, porewater and sediments (using hydrochemical, mapping, coring and petrophysical estimates). The similar estimate of calcium delivered (4.88 Gt) and calcium stored (3.94 Gt) is consistent with the premise of the source-to-sink approach: a mass balance between eroded and transported compounds and the sinks. The amount of calcium deposited in the basin can therefore be predicted indirectly from the different inputs, which can be assessed with more confidence. When monitoring is unavailable (e.g. in the fossil record), the geodynamic context, the average lithology of the watershed and the bioclimatic classification of an endoreic basin are alternative properties that may be used to estimate the inputs. We show that this approach is sufficiently accurate to predict the amount of calcium captured in a basin and can be extended to the whole fossil record and inform on the storage of calcium.  相似文献   
3.
Crack nucleation has been the subject of important contributions in the last two last decades. However, it seems that few attention has been granted to the case of saturated porous media. This is the question addressed in the present paper which is devoted to nucleation in traction mode. From a physical point of view, nucleation is a sudden phenomenon, so that the material response is both adiabatic and undrained. In the spirit of the variational approach, the nucleated crack is viewed as the final state of a region of space in which the material undergoes a full damage process. In traction mode, the opening of a saturated crack in undrained condition induces a drop of fluid pressure. In case of low fluid compressibility, the presence of the fluid delays the brittle failure usually associated with nucleation, as long as the fluid pressure remains above the saturation vapor pressure. Nucleation is therefore possible only if a partial vaporization of the fluid takes place.  相似文献   
4.
This work presents new 87Sr/86Sr and δ88/86SrSRM987 isotopic values of thirteen mineral, vegetal and animal reference materials. Except for UB‐N, all our results are consistent with previously published data. Our results highlight intermediate precisions among the best presently published and a non‐significant systematic shift with the calculated δ88/86SrSRM987 mean values for the three most analysed reference materials in the literature (i.e., IAPSO, BCR‐2 and JCp‐1). By comparison with the literature and between two distinct digestions, a significant bias of δ88/86SrSRM987 values was highlighted for two reference materials (UB‐N and GS‐N). It has also been shown that digestion protocols (nitric and multi‐acid) have a moderate impact on the δ88/86SrSRM987 isotopic values for the Jls‐1 reference materials suggesting that a nitric acid digestion of carbonate can be used without significant bias from partial digestion of non‐carbonate impurities. Different δ88/86SrSRM987 values were measured after two independent Sr/matrix separations, according to the same protocol, for a fat‐rich organic reference material (BCR‐380R) and have been related to a potential post‐digestion heterogeneity. Finally, the δ88/86SrSRM987 value differences measured between animal‐vegetal and between coral‐seawater reference materials agree with the previously published results, highlighting an Sr isotopic fractionation along the trophic chain and during carbonate precipitation.  相似文献   
5.
ABSTRACT

The importance of including a contextual underpinning to the spatial analysis of social data is gaining traction in the spatial science community. The challenge, though, is how to capture these data in a rigorous manner that is translational. One method that has shown promise in achieving this aim is the spatial video geonarrative (SVG), and in this paper we pose questions that advance the science of geonarratives through a case study of criminal ex-offenders. Eleven ex-offenders provided sketch maps and SVGs identifying high-crime areas of their community. Wordmapper software was used to map and classify the SVG content; its spatial filter extension was used for hot spot mapping with statistical significance tested using Monte Carlo simulations. Then, each subject’s sketch map and SVG were compared. Results reveal that SVGs consistently produce finer spatial-scale data and more locations of relevance than the sketch maps. SVGs also provide explanation of spatial-temporal processes and causal mechanisms linked to specific places, which are not evident in the sketch maps. SVG can be a rigorous translational method for collecting data on the geographic context of many phenomena. Therefore, this paper makes an important advance in understanding how environmentally immersive methods contribute to the understanding of geographic context.  相似文献   
6.
ABSTRACT

Crime often clusters in space and time. Near-repeat patterns improve understanding of crime communicability and their space–time interactions. Near-repeat analysis requires extensive computing resources for the assessment of statistical significance of space–time interactions. A computationally intensive Monte Carlo simulation-based approach is used to evaluate the statistical significance of the space-time patterns underlying near-repeat events. Currently available software for identifying near-repeat patterns is not scalable for large crime datasets. In this paper, we show how parallel spatial programming can help to leverage spatio-temporal simulation-based analysis in large datasets. A parallel near-repeat calculator was developed and a set of experiments were conducted to compare the newly developed software with an existing implementation, assess the performance gain due to parallel computation, test the scalability of the software to handle large crime datasets and assess the utility of the new software for real-world crime data analysis. Our experimental results suggest that, efficiently designed parallel algorithms that leverage high-performance computing along with performance optimization techniques could be used to develop software that are scalable with large datasets and could provide solutions for computationally intensive statistical simulation-based approaches in crime analysis.  相似文献   
7.
The Bonneville Basin is a continental lacustrine system accommodating extensive microbial carbonate deposits corresponding to two distinct phases: the deep Lake Bonneville (30 000 to 11 500 14C bp ) and the shallow Great Salt Lake (since 11 500 14C bp ). A characterization of these microbial deposits and their associated sediments provides insights into their spatio‐temporal distribution patterns. The Bonneville phase preferentially displays vertical distribution of the microbial deposits resulting from high‐amplitude lake level variations. Due to the basin physiography, the microbial deposits were restricted to a narrow shoreline belt following Bonneville lake level variations. Carbonate production was more efficient during intervals of relative lake level stability as recorded by the formation of successive terraces. In contrast, the Great Salt Lake microbial deposits showed a great lateral distribution, linked to the modern flat bottom configuration. A low vertical distribution of the microbial deposits was the result of the shallow water depth combined with a low amplitude of lake level fluctuations. These younger microbial deposits display a higher diversity of fabrics and sizes. They are distributed along an extensive ‘shore to lake’ transect on a flat platform in relation to local and progressive accommodation space changes. Microbial deposits are temporally discontinuous throughout the lake history showing longer hiatuses during the Bonneville phase. The main parameters controlling the rate of carbonate production are related to the interaction between physical (kinetics of the mineral precipitation, lake water temperature and runoff), chemical (Ca2+, Mg2+ and HCO3? concentrations, Mg/Ca ratio, dilution and depletion) and/or biological (trophic) factors. The contrast in evolution of Lake Bonneville and Great Salt Lake microbial deposits during their lacustrine history leads to discussions on major chemical and climatic changes during this interval as well as the role of physiography. Furthermore, it provides novel insights into the composition, structure and formation of microbialite‐rich carbonate deposits under freshwater and hypersaline conditions.  相似文献   
8.

Prediction of true classes of surficial and deep earth materials using multivariate spatial data is a common challenge for geoscience modelers. Most geological processes leave a footprint that can be explored by geochemical data analysis. These footprints are normally complex statistical and spatial patterns buried deep in the high-dimensional compositional space. This paper proposes a spatial predictive model for classification of surficial and deep earth materials derived from the geochemical composition of surface regolith. The model is based on a combination of geostatistical simulation and machine learning approaches. A random forest predictive model is trained, and features are ranked based on their contribution to the predictive model. To generate potential and uncertainty maps, compositional data are simulated at unsampled locations via a chain of transformations (isometric log-ratio transformation followed by the flow anamorphosis) and geostatistical simulation. The simulated results are subsequently back-transformed to the original compositional space. The trained predictive model is used to estimate the probability of classes for simulated compositions. The proposed approach is illustrated through two case studies. In the first case study, the major crustal blocks of the Australian continent are predicted from the surface regolith geochemistry of the National Geochemical Survey of Australia project. The aim of the second case study is to discover the superficial deposits (peat) from the regional-scale soil geochemical data of the Tellus Project. The accuracy of the results in these two case studies confirms the usefulness of the proposed method for geological class prediction and geological process discovery.

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9.
10.
Analyses (n = 525) of chloride (Cl), bromide (Br), nitrate as nitrogen (NO3-N), sodium (Na+), calcium (Ca2+) and potassium (K+) in stream water, tile-drain water and groundwater were conducted in an urban-agricultural watershed (10% urban/impervious, 87% agriculture) to explore potential differences in the signature of Cl originating from an urban source as compared with an agricultural source. Only during winter recharge events did measured Cl concentrations exceed the 230 mg/L chronic threshold. At base flow, nearly all surface water and tile water samples had Cl concentrations above the calculated background threshold of 18 mg/L. Mann–Whitney U tests revealed ratios of Cl to Br (p = .045), to NO3-N (p < .0001), to Ca2+ (p < .0001), and to Na+ (p < .0001) to be significantly different between urban and agricultural waters. While Cl ratios indicate that road salt was the dominant source of Cl in the watershed, potassium chloride fertilizer contributed as an important secondary source. Deicing in watersheds where urban land use is minimal had a profound impact on Cl dynamics; however, agricultural practices contributed Cl year-round, elevating stream base flow Cl concentrations above the background level.  相似文献   
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