南海北部西沙海槽沉积物管状黄铁矿特征及其形成机理^*          下载免费PDF全文

石思思  吴朝东  梁金强  王熠哲  叶云涛  方允鑫  马健  翟俪娜 《古地理学报》2020,22(1):175-192

南海北部西沙海槽S1站位的岩心柱沉积物中广泛发育自生矿物黄铁矿,其形态以管状为主,且具有内部中空的圈层结构。使用扫描电镜、电子探针、LA-ICP-MS、SIMS等测试方法研究了管状黄铁矿的形态及圈层结构,结果显示: (1)管状黄铁矿发育内部中空的圈层结构,其中内圈层(I_py)由莓球状黄铁矿呈五角十二面体紧密堆积组成,外圈层(O_py)由晶形较好晶粒较大的八面体黄铁矿组成,并混有沉积碎屑及钙质生物壳体;(2)内圈层和外圈层分别呈现出贫S富Fe和富S贫Fe的特征,其成因是甲烷渗漏造成的局部还原环境使得As进入黄铁矿中导致晶格空缺或被扭曲,从而促进Ni、Co、Cu、Zn、Pb等微量元素的掺入;(3)内圈层、外圈层发生了明显的硫同位素分馏现象,内圈层中 δ³⁴S 平均为-37.8‰,外圈层中 δ³⁴S 平均为-29.3‰。研究认为,管状黄铁矿作为曾经甲烷渗漏的通道,其生长机制可分为3个阶段: (1)气水通道形成阶段: 向上运移的甲烷流体在沉积物孔隙中逐渐形成气水通道;(2)外圈层形成阶段: 当向上运移的甲烷与硫酸盐发生甲烷厌氧氧化时,逐渐形成晶体较大、晶形较好的八面体黄铁矿外圈层;(3)内圈层形成阶段: 随着甲烷浓度逐渐降低,在气水通道中的微生物作用下,剩余甲烷与向下运移的硫酸盐继续反应形成莓球状黄铁矿内圈层。因此,南海北部的泥岩中大量发育的管状黄铁矿常常与地层中甲烷水合物的存在有关。  相似文献   

Generalized stress framework for unsaturated soil: demonstration and discussion     

Duan  Xiaomeng  Zeng  Lifeng  Sun  Xiang 《Acta Geotechnica》2019,14(5):1459-1481

The long-lived debate on the principle of effective stress is rooted in the obscure physical significance of stresses. For the sakes of clarifying stress concepts and establishing a reasonable principle of effective stress, unsaturated soil is divided into six phases and the bearing structure of it, named generalized soil structure, is defined based on considering soil as a special structure. Then the essence of effective stress equation, named stress relation equation, is derived according to analysis of interphase interactions and independent-phase equilibrium. The stress relation equation indicates the corresponding relation between two series of stress variables used in mixed and multiphase continuum models, respectively. Furthermore, a reasonable concept of suction stress is redefined to describe interparticle connection properties. Then, a generalized stress framework is constructed by associating stress relation equation with suction stress. After demonstrating the concept of neutral stress, a generalized principle of effective stress is established and the total soil skeleton stress is searched out, which is the predominant stress controlling the strength and deformation of soil. Finally, the collapse phenomenon is analyzed and the time- and spatial-dependent stress frameworks are developed.

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从水体到沉积物:探寻有机质的沉积过程及其意义          下载免费PDF全文

蔡进功  曾翔  韦海伦  宋明水  王学军  刘庆 《古地理学报》2019,21(1):49-66

自然界中有机质分布广泛、类型多样且性质各异,不论在水体还是在沉积物(岩)中都扮演着重要的角色。因此,探讨各类型有机质聚集和沉积过程的差异性,对深化认识有机质沉积特征和演化规律具有重要的意义。生物体在生长过程中产生了许多有机质,包括生物体自身、生物残体、动物排泄物以及生物分泌的有机分子等,各类型有机质的性质差异极大。由于研究方法的不同,可将海洋中有机质划分为颗粒有机质(particulate organic matter,POM)和溶解有机质(dissolved organic matter,DOM),而DOM又可划分为胶体有机质(colloidal organic matter,COM)和真溶解有机质;从聚合体形式上看,又有海雪和悬浮体等存在形式。进一步分析发现有机质的形态包括生物体、生物残体、排泄物和有机质聚合体等,并且各类型有机质与无机矿物以不同的形式共存。此外,DOM与POM间存在一定的转化关系。这些性质和特征架起了不同类型有机质间聚集和沉积的桥梁。在沉积物(岩)中通过粒度或密度分级分离及孢粉相分析,也发现不同类型的有机质,如生物体、生物残体和无定形等,它们常与特定的无机矿物共生,如无定形多富集在黏粒级颗粒中,而生物体和生物残体多富集在粗颗粒中。进一步溯源发现沉积物(岩)中的各类有机质与生物有机质或海洋中有机质的类型极具相似性,这些特征展现各类型有机质在沉积过程中的差异性。综合有机质的形态、性质以及与矿物共生关系,认为有机质可通过机械沉积、化学沉积和生物沉积等3种不同的方式沉积保存,其中机械沉积的有机质以惰性的生物残体为主,化学沉积的有机质以活性极强的无定形为主,生物沉积有机质以活性较强的微生物和粘附物为主。有机质沉积方式及有机质特征、矿物—有机质间关系和保存条件的差异,决定了有机质的演化命运的不同,进而对有机质生烃以及碳循环产生重要的影响,因而应引起人们的高度关注。  相似文献   

准噶尔盆地玛湖凹陷西斜坡三叠系百口泉组扇三角洲优质储集层预测          下载免费PDF全文

桑林翔  刘军  王贵文  王苏天  李全  张云龙 《古地理学报》2020,22(6):1053-1064

针对准噶尔盆地玛湖凹陷西斜坡风南地区三叠系百口泉组扇三角洲砂岩物性空间变化大、优质储集层(孔隙度大于7.4%,渗透率大于0.05×10^-3μm²)预测难的问题,在沉积岩石学、地震沉积学以及地震反演和解释理论指导下,综合利用测井、岩心和三维地震等资料开展了高精度层序地层划分、沉积微相描述和优质储集层地震反演研究。建立了风南井区四级层序地层格架,明确了扇三角洲多期水进水退的充填过程,指出SSQ3和SSQ5是优质储集层的发育层系;识别出扇三角洲平原分流河道、河道间和扇三角洲前缘水下分流水道、河口坝、席状砂等沉积微相,指出扇三角洲平原是优质储集层发育相带;通过应用高分辨层序地层纵向边界和沉积相横向边界约束,进行分层相控叠后地震波阻抗反演,提升储集层预测精度,在SSQ3和SSQ5预测5个优质储集层发育区,提出3口井的井位建议,钻探均获工业油流。  相似文献   

基于波形特征的露天钼矿微震事件的识别分析——以卓资山钼矿为例     

赵艳红  包金哲  王树波  翟浩  魏建民  杨智升  张晖  赵铁锁  苏日亚  王磊  王鑫  贾昕晔  刘芳 《震灾防御技术》2019,14(3):662-676

基于前人研究成果以及现场的实测结果，采用卓资山露天钼矿微震监测项目产出资料，提取了5类微震事件的波形特征和时频特征。波形特征显示:微地震的振幅、辐射均匀性和频率变化特征表明微地震是由于岩层受到单力偶和剪切力作用破裂而产生；爆破具有P波初动方向向上、S波不易识别的特点，包含“初震段、主震段、尾波段”三段变化形态；小型边坡滑坡波事件属楔体滑坡，是由多个“加速—缓冲—终止”构成，波形是由包络线呈“V”字形的多组脉冲波列组成；机械开采震动事件具有自振能量不变、脉冲幅度相差很大、持续时间间隔不确定的特点；运输车辆波形振幅具有形态“弱—强—弱”、等频率、包络线呈多段纺锤形的特征。时频空间分布可以分为相对独立、界限分明的两类:一类包含微地震、爆破、机械开采、小型边坡滑坡事件，另一类只包含车辆运输事件。  相似文献   

A brief review of ENSO theories and prediction     

Xianghui FANG  Ruihuang XIE 《中国科学:地球科学(英文版)》2020,63(4):476-491

Although the El Ni?o-Southern Oscillation(ENSO) originates and develops in the equatorial Pacific, it has substantial climatic impacts around the globe. Thus, the ability to effectively simulate and predict ENSO one or more seasons in advance is of great societal importance, but this remains a challenging task. The main obstacles are the diversity, complexity,irregularity, and asymmetry of ENSO. The purpose of this article is to organically integrate the understanding of ENSO based on current progress on the physical mechanisms, prediction, and connections between the interannual ENSO phenomenon and physical processes on other time and space scales, and to provide guidance for future studies by extracting specific important questions.  相似文献   

Variation in the vertical zonality of erodibility and critical shear stress of rill erosion in China's Hengduan Mountains     

Zhengan Su  Donghong Xiong  Jianhui Zhang  Tao Zhou  Hongkun Yang  Yifan Dong  Haidong Fang  Liangtao Shi 《地球表面变化过程与地形》2019,44(1):88-97

Soil erodibility is an essential parameter used in soil erosion prediction. This study selected the Liangshan town watershed to quantify variation in the vertical zonality of rill erodibility (k_r) in China's ecologically fragile Hengduan Mountains. Soil types comprised of yellow–brown (soil A), purple (soil B), and dry-red (soil C) in a descending order of occurrence from the summit to the valley, which roughly corresponds to the vertical climate zone (i.e. cool-high mountain, warm-low mountain, and dry-hot valley sections) of the study area. With elevation, vertical soil zonality varied in both soil organic matter (SOM) content and soil particle-size fractions. A series of rill erosion-based scour experiments were conducted, using water discharge rates of 100, 200, 300, 400, 500, and 600 mL min^-1. Additionally, detachment rates (Dr) were measured under three hydrological conditions (the drainage, saturation, and seepage treatments). Results show that both Dr and flow shear stress (Ʈ) values increased as discharge increased. As elevation increased, the k_r values decreased, while the vertical zonality of critical shear stress (Ʈ_c) values showed no obvious variation. The highest k_r values were observed during the seepage treatment, followed by the saturation treatment then drainage treatment, indicating that variation in vertical hydraulic gradients could significantly alter k_r values. This study also found that land-use types could also alter k_r and Ʈ_c values. Further research, however, is necessary to better quantify the effects of subsurface hydrological conditions and land-use types on k_r under different soil zonalities in China's Hengduan Mountains. © 2018 John Wiley & Sons, Ltd.  相似文献   

基于核酸适配体功能化石墨纳米颗粒荧光探针的17β-雌二醇快速检测方法     

朴云仙  祁小丽  王湘  康博泉  史玉玺  胡慧  杨悦锁 《吉林大学学报(地球科学版)》2019,49(4):1137-1144

为构建一种能够简单、快速、特异性检测复杂环境水体中雌激素污染的方法，利用石墨纳米颗粒作为荧光淬灭剂、核酸适配体作为识别元素、1-芘丁酸N-羟基琥珀酰亚胺酯作为异型双功能交联剂，构建了一种新型纳米荧光探针；并探究了构建荧光探针时核酸适配体初始投加量和荧光探针投加量对雌二醇检测的影响及最佳实验条件下检测雌二醇的效果和特异性。实验结果表明：核酸适配体能成功修饰在石墨纳米颗粒表面形成的稳定荧光探针；构建荧光探针时核酸适配体的最佳初始投加量为1.0 μmol/L；检测雌二醇时，荧光探针的最佳投加量为4 μg/mL；最佳实验条件下，相对荧光强度与雌二醇的质量浓度在50~800 ng/mL范围内成正比，最低检测限为34.5 ng/mL，且该荧光探针能实现对雌二醇的简单、快速、特异性检测。  相似文献   

Comparisons of Salinity Adaptation in Terms of Growth,Body Composition,and Energy Budget in Juveniles of Rainbow and Steelhead Trouts (Oncorhynchus mykiss)     

XIONG Yinghuai  WANG Xin  DONG Shuanglin  WANG Fang  YANG Jingwen  ZHOU Yangen 《中国海洋大学学报(英文版)》2019,(2)

This study examined the effect of different salinities(0, 5, 10, 15, 20, 25 and 30) on the growth performance and energy budget of juveniles of two different ecotypes of Oncorhynchus mykiss, landlocked rainbow trout and anadromous steelhead trout. In the 42 d experiment, fish were cultured in three replicate tanks per salinity treatment(eight fish per tank). At the end of the experiment, the growth of rainbow and steelhead trouts was significantly higher at salinities of 5 and 10, respectively, than at all other salinities. The protein, lipid and energy content of both ecotypes declined with the increase of salinity. Based on their energy budgets, the percentage of energy consumed for growth by rainbow and steelhead trouts were significantly higher at salinities of 5(34.00% ±1.69%) and 10(43.76% ± 1.29%), respectively, than at all other salinities. The percentage of energy consumed for respiration by rainbow and steelhead trouts was lower at salinities of 5(54.90% ± 1.77%) and 10(46.73% ± 0.62%), respectively, than at all other salinities. Our results indicated that the salinity adaptation ability of juvenile steelhead trout was slightly better than that of juvenile rainbow trout, and salinities of 10 and 5, respectively, were most suitable for growth of these two fishes.  相似文献   

An Amended Chemical Mass Balance Model for Source Apportionment of PM2.5 in Typical Chinese Eastern Coastal Cities     

Qiaoli Wang  Nana Cheng  Sujing Li  Minli Dong  Xiangqian Wang  Linlin Ge  Tianjiao Guo  Wei Li  Xiang Gao 《洁净——土壤、空气、水》2019,47(2)

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