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The alkali element K is moderately volatile and fluid mobile; thus, it can be influenced by both primary processes (evaporation and recondensation) in the solar nebula and secondary processes (thermal and aqueous alteration) in the parent body. Since these primary and secondary processes would induce different isotopic fractionations, K isotopes could become a potential tracer to distinguish them. Using recently developed methods with improved precision (0.05‰, 95% confidence interval), we systematically measured the K isotopic compositions and major/trace elemental compositions of chondritic components (18 chondrules, 3 CAIs, 2 matrices, and 5 bulks) in the carbonaceous chondrite fall Allende. Among all the components analyzed in this study, CAIs, which formed initially under high‐temperature conditions in the solar nebula and were dominated by nominally K‐free refractory minerals, have the highest K2O content (average 0.53 wt%) and have K isotope compositions most enriched in heavy isotopes (δ41K: ?0.30 to ?0.25‰). Such an observation is consistent with previous petrologic studies that show CAIs in Allende have undergone alkali enrichment during metasomatism. In contrast, chondrules contain lower K2O content (0.003–0.17 wt%) and generally lighter K isotope compositions (δ41K: ?0.87‰ to ?0.24‰). The matrix and bulks are nearly identical in K2O content and K isotope compositions (0.02–0.05 wt%; δ41K: ?0.62 to ? 0.46‰), which are, as expected, right in the middle of CAIs and chondrules. This strongly indicates that most of the chondritic components of Allende suffered aqueous alteration and their K isotopic compositions are the ramification of Allende parent‐body processing instead of primary nebular signatures. Nevertheless, we propose the small K isotope fractionations observed (< 1‰) among Allende components are likely similar to the overall range of K isotopic fractionation that occurred in nebular environment. Furthermore, the K isotope compositions seen in the components of Allende in this study are consistent with MC‐ICP‐MS analyses of the components in ordinary chondrites, which also show an absence of large (10‰) isotope fractionations. This is not expected as evaporation experiments in nebular conditions suggest there should be large K isotopic fractionations. Nevertheless, possible nebular processes such as chondrules back exchanging with ambient gas when they formed could explain this lack of large K isotopic variation.  相似文献   
3.
朱芳  苏勤  陶云  沈惊宏 《热带地理》2020,40(4):636-648
日常生活环境和旅游目的地环境都可以为个体提供恢复的机会,不同环境的属性特征导致不同程度的恢复。为了探究环境类型与恢复性效应之间的关系及停留时间的调节作用,文章采用问卷调查方式,利用配对样本t检验和混合设计方差分析相结合的方法,探讨游客在不同环境中的恢复性效应,并对这一现象提供心理上的解释。结果表明:1)恢复体验的4个维度(放松体验、心理脱离、掌握体验、控制体验)在旅游目的地环境中的得分均高于日常生活环境。2)掌握和控制体验维度在城市旅游目的地中的变化程度高于乡村旅游目的地,两种类型目的地的放松和心理脱离维度差异较小。3)随着在目的地停留时间的延长,乡村旅游目的地放松体验和心理脱离维度变化程度高于城市旅游目的地,两种类型目的地环境恢复性效应会相互靠近。因此,游客的环境恢复性效应不仅受到环境和目的地类型的影响,同时还与游客的适应程度有关,且受到其停留时间的调节作用。  相似文献   
4.
进入城市时代以来,居住环境与居民健康的联系愈发密切,尤其在“流动性"增强的大背景下,居住迁移对居民健康的影响问题受到广泛关注。论文结合知识图谱分析和文献研究法,系统评述居住迁移影响居民健康问题的最新进展。研究发现:① 近15 a来,该领域的文献数量逐年增多,关注度持续上升;文献空间分布主要集中在发达国家,但不同地区的研究内容存在显著差异。② 主要研究对象由“同质性群体”向“异质性群体”转变,从“一般性群体”向“特殊群体”转变;研究方法由数理统计向混合研究、综合应用转变。③ 研究视角经历“人口迁移—个体健康”“居住迁移—环境—个体健康”与“迁居轨迹—环境演变—个体健康发展”等3个演变阶段。④ 近期研究重点有:迁居行为与儿童健康,迁居时空特征与身心健康,住房生涯与身心健康,邻里环境、累积剥夺与健康发展等。结合以上分析,提出如下建议:注重“整合性”分析;关注城市内部迁居行为和多次迁居轨迹对居民健康的影响;扩大迁居引发的“环境”因素(如居住隔离、社会分异、职住空间错位等)研究;更多关注迁居对二代流动人口儿童健康的影响,侧重对非正规居住空间如“城中村”等的研究。  相似文献   
5.
摘要:目的 探讨菌株Salinivibrio sp.YH4分泌的丝氨酸蛋白酶EYHS的耐盐性及结构特征。方法 明胶底物酶谱法分析EYHS的耐盐性。应用生物信息学手段对EYHS及6种耐盐的S8家族丝氨酸蛋白酶结构特征进行分析。结果 EYHS在4 mol/L的NaCl溶液中仍具有活性,属于耐盐蛋白酶。EYHS及6种S8家族丝氨酸蛋白酶分子表面的loop区等无规则卷曲所占比例较高,α-螺旋与β-片层则主要位于酶分子内部。EYHS分子表面酸性氨基酸含量较高,且具有弱疏水内核。多序列比对发现蛋白酶的催化三联体两侧存在高度保守的基序和保守的极性氨基酸及芳香族氨基酸,并存在多个保守的Gly与Ala。同源模建和表面电荷分布显示,α螺旋和β片层围成了蛋白酶的催化腔,EYHS活性中心包含由Asp32、His65与Ser215组成的催化三联体,且催化位点区域表面静电势为负。结论 上述结构特征可能有助于耐盐丝氨酸蛋白酶EYHS在高盐环境下维持其稳定性和适度柔性,并有助于其催化功能的发挥,为深入研究耐盐丝氨酸蛋白酶的高盐环境适应性提供了一定的理论依据。  相似文献   
6.
Fang  Xiuqi  Zheng  Xue  Zhang  Xing 《地理学报(英文版)》2020,30(1):103-118
ENSO is an interannual mode which may be affected by external forcing, such as volcanic eruptions. Based on the reconstructed volcanic eruptions chronology and ENSO sequences, both 195 large volcanic eruptions(VEI≥4) and 398 ENSO(El Ni?o and La Ni?a) events were extracted from 1525 to 2000. An analysis of the correspondence between the large volcanic eruptions and ENSO events was performed by matching the large volcanic eruptions with the types and magnitudes of ENSO events present in the 0–2 years after the eruptions. The results show the following:(1) The percentages of ENSO events within the 3 years after the large eruptions had increased to 68.3% from 31.7% compared with those with no-eruptions in the previous 0–2 years. In addition, the ratio of El Ni?o to La Ni?a events turned from 2:3 to 1:1, and more El Ni?o events occurred in the 0 year after eruptions in the low-latitudes of the Northern Hemisphere and in the tropics but more La Ni?a events occurred in the 0 year after in the high-latitudes of the Northern Hemisphere and the Southern Hemisphere.(2) After the eruptions, the weak(W) El Ni?o events had increased by 8 percentage points and the very strong(VS) El Ni?o events had decreased by 10 percentage points; conversely, there was a decrease by 15 percentage points of the weak La Ni?a events and an increase by 11.4 percentage points of the very strong La Ni?a events. Specifically, the percentages of strong La Ni?a events increased to a peak at 1(+1) year after the eruptions.(3) The percentage of eruptions followed by single-year ENSO was the greatest. The percentage of ENSO events that occurred in the consecutive 2 years following an eruption was approximately equal to the percentage of events that occurred consecutively 3 years following an eruption, and both sets of ENSO magnitudes showed a decreasing trend.  相似文献   
7.
Urbanization and eco-environment coupling is a research hotspot.Dynamic simulation of urbanization and eco-environment coupling needs to be improved because the processes of coupling are complex and statistical methods are limited.Systems science and cross-scale coupling allow us to define the coupled urbanization and eco-environment system as an open complex giant system with multiple feedback loops.We review the current state of dynamic simulation of urbanization and eco-environment coupling and find that:(1)The use of dynamic simulation is an increasing trend,the relevant theory is being developed,and modeling processes are being improved;(2)Dynamic simulation technology has become diversified,refined,intelligent and integrated;(3)Simulation is mainly performed for three aspects of the coupling,multiple regions and multiple elements,local coupling and telecoupling,and regional synergy.However,we also found some shortcomings:(1)Basic theories are inadequately developed and insufficiently integrated;(2)The methods of unifying systems and sharing data are behind the times;(3)Coupling relations and the dynamic characteristics of the main driving elements are not fully understood or completely identified.Additionally,simulation of telecoupling does not quantify parameters and is not systemically unified,and therefore cannot be used to represent spatial synergy.In the future,we must promote communication between research networks,technology integration and data sharing to identify the processes governing change in coupled relations and in the main driving elements in urban agglomerations.Finally,we must build decision support systems to plan and ensure regional sustainable urbanization.  相似文献   
8.
通过改进Tessier连续提取法对贵州草海黑颈鹤栖息地不同水位梯度下沉积物汞(Hg)、砷(As)形态及生态风险进行了研究.结果表明,草海湿地沉积物中Hg含量在0.45~1.51-mg/kg之间,超过国家土壤环境质量农用地土壤风险管控标准;形态组成上,残渣态汞(Res-Hg)有机结合态汞(Org-Hg)碳酸盐结合态(Car-Hg)铁锰氧化态(Fe-O-Hg)可交换态(Ex-Hg),不同水位梯度下含量和赋存形态在不同区域不一致.As含量在16.4~23.8-mg/kg之间,形态依次为残渣态砷(Res-As)有机结合态砷(Org-As)铁锰氧化态砷(Fe-O-As)碳酸盐结合态砷(Car-As)可交换态砷(Ex-As).-As含量与贵州省土壤背景值持平,随着水位梯度的抬升,其总量呈增加趋势,残渣态占比逐步增多,性质逐渐稳定.采用地积累指数(I_(geo))、潜在生态风险指数(E_r~i)、风险评价编码法(RAC)对Hg、As的危害程度进行分析表明,基于草海较高Hg环境背景值,Hg整体污染风险较高,As处于低水平的污染风险等级且对环境影响较小.该研究揭示了不同水位梯度下Hg、As总量及形态分布特征,对草海湿地水位抬升恢复湿地提供了参考.  相似文献   
9.
分布式光纤声波传感器(Distributed Acoustic Sensing,DAS)是近年来兴起的超密集地震观测系统,具有一系列观测密度高、观测成本低、耐受恶劣环境等优势,在油气行业得到了广泛应用,也引起了天然地震学界的关注.本文简要回顾了DAS系统的测量原理、发展历程、技术方案、介绍了测量原理及其响应特性,然后围绕多个观测实验,介绍浅部结构成像、深部结构探测和地震监测三个方向的典型应用实例,最后讨论了DAS系统在天然地震学研究中应用面临的挑战和发展趋势.  相似文献   
10.
激电法是地质勘查中的一种重要方法,时、频域测量各具优势,但传统的时、频域测量实现方法相对独立.根据频域和时域可相互转换的理论,本文提出一种基于全波形采样的时频激电多参数提取的地球物理数据处理方法.采取时间域激电法的观测模式,接收机高精度同步记录整周期电压-电流全部采样点的波形数据,通过该文提出的处理方法,仅一次供电和测量即可提取多种时、频域激电参数:时域激电的视电阻率、视极化率和频域激电的多频视电阻率、视相位、视频散率、去耦后的视相位等参数.在云南保山某典型矿区开展方法的试验应用,提取了地质体大量的相关激电信息,总结了目标体的激电参数响应规律.应用结果表明,该方法便捷高效,抗干扰能力强,相较于传统的时域激电测量,多种参数组合可提升对目标地质体的认识,增强激电法的应用效果.  相似文献   
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