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Analytical protocols for SHRIMP‐SI oxygen isotope analysis (δ18O) of a suite of zircon reference materials (RMs) are presented. Data reduction involved a robust estimate of uncertainties associated with the individual spot as well as for groups where the spot data are combined. The repeatability of δ18O measurements is dependent on both the analytical conditions and the choice of the primary reference material. Under optimised conditions, repeatability was often better than 0.4‰ (2s) allowing sample uncertainties to be obtained to better than 0.2‰ (at 95% confidence limit). Single spot uncertainty combined the within‐spot precision with the scatter associated with repeated measurements of the primary zircon reference material during a measurement session. The uncertainty for individual spots measured under optimised conditions was between 0.3 and 0.4‰ (at 95% confidence). The analytical protocols described were used to assess a variety of zircon RMs that have been used for geochronology and for which laser fluorination oxygen isotope data are available (Temora 2, FC1, R33, QGNG and Ple?ovice), as well as zircons that have been used as RMs for trace element or other types of determination (Mud Tank, Monastery, 91500, AS57, AS3, KIM‐5, OG1, SL13, CZ3 and several other Sri Lankan zircons). Repeated analyses over nine sessions and seven different mounts show agreement within analytical uncertainty for Temora 2, FC1, R33, QGNG, Ple?ovice and 91500, when normalised to Mud Tank. For existing ion microprobe mounts with these materials, an appropriate δ18O can be determined. However, care should be taken when using zircons from the Duluth Complex (i.e., FC1, AS57 and AS3) as reference materials as our data indicated an excess scatter on δ18O values associated with low‐U zircon grains.  相似文献   
2.
Total hours of sunshine are one of the most important factors affecting climate and environment, and its long-term variation is of much concern in climate studies. Trends of temporal and spatial patterns in sunshine hours and related climatic factors over southwestern China are evaluated for the period 1961–2009 based on data from 111 standard meteorological stations. The results showed that southwestern China is experiencing a statistical decrease of sunshine hours, at the rate of 31.9 h/10a during 1961–2009. The decline was particularly strong in summer, whereas it is nonsignificant in winter. Spatially, statistically significant decreases of sunshine hours mainly occurred in lower altitude regions, especially in the Sichuan basin and Guizhou plateau. Sunshine hours have a high correlation with wind speed, relative humidity, precipitation, cloud cover, surface downwards solar radiation flux, and cloud water content, with wind speed showing the strongest relationship to sunshine hours, implicit in the close correlation (temporally and spatially) between the two variables. Changing water vapor and cloud cover influence sunshine hours in southwestern China. In addition, the increased surface downwards solar radiation flux also made some contribution to a rise of sunshine hours during 1991–2009. The larger decreasing trends of sunshine hours at urban stations than rural stations may reflect the effect of urbanization on sunshine hours. Variations are dominated by the comprehensive functions of multiple factors owing to the complex nature of effects on sunshine hours.  相似文献   
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Canonical variate analysis of living and fossil organisms, based on morphological characters, can sometimes greatly distort the biological interpretation (i.e., reification) of the coefficients of the eigenvectors forming the canonical variates through the inclusion of redundant within-group directions. Instability is associated with the smallest eigenvalues, particularly if these do not greatly differ from zero. In the present study of 46 borehole samples of the Late Cretaceous foraminifer Afrobolivina afraReyment, stability of the canonical variate coefficients is attained by removal of a near redundant direction of within-group variation. This leads to improved interpretability of the morphometric relationships in this species. on leave from Division of Mathematics and Statistics, CSIRO, Wembley, 6014, Western Australia.  相似文献   
4.
Microseismic monitoring has proven invaluable for optimizing hydraulic fracturing stimulations and monitoring reservoir changes. The signal to noise ratio of the recorded microseismic data varies enormously from one dataset to another, and it can often be very low, especially for surface monitoring scenarios. Moreover, the data are often contaminated by correlated noises such as borehole waves in the downhole monitoring case. These issues pose a significant challenge for microseismic event detection. In addition, for downhole monitoring, the location of microseismic events relies on the accurate polarization analysis of the often weak P‐wave to determine the event azimuth. Therefore, enhancing the microseismic signal, especially the low signal to noise ratio P‐wave data, has become an important task. In this study, a statistical approach based on the binary hypothesis test is developed to detect the weak events embedded in high noise. The method constructs a vector space, known as the signal subspace, from previously detected events to represent similar, yet significantly variable microseismic signals from specific source regions. Empirical procedures are presented for building the signal subspace from clusters of events. The distribution of the detection statistics is analysed to determine the parameters of the subspace detector including the signal subspace dimension and detection threshold. The effect of correlated noise is corrected in the statistical analysis. The subspace design and detection approach is illustrated on a dual‐array hydrofracture monitoring dataset. The comparison between the subspace approach, array correlation method, and array short‐time average/long‐time average detector is performed on the data from the far monitoring well. It is shown that, at the same expected false alarm rate, the subspace detector gives fewer false alarms than the array short‐time average/long‐time average detector and more event detections than the array correlation detector. The additionally detected events from the subspace detector are further validated using the data from the nearby monitoring well. The comparison demonstrates the potential benefit of using the subspace approach to improve the microseismic viewing distance. Following event detection, a novel method based on subspace projection is proposed to enhance weak microseismic signals. Examples on field data are presented, indicating the effectiveness of this subspace‐projection‐based signal enhancement procedure.  相似文献   
5.
The dynamics of dissolved combined neutral sugars (DCNS) were assessed in the upper 250 m at the Bermuda Atlantic Time-series Study (BATS) site between 2001 and 2004. Our results reveal a regular annual pattern of DCNS accumulation with concentrations increasing at a rate of 0.009–0.012 μmol C L?1 d?1 in the surface 40 m from March to July and reaching maximum mean concentrations of 2.2–3.3 μmol C L?1. Winter convective mixing (between January and March) annually exported surface-accumulated DCNS to the upper mesopelagic zone (100–250 m), as concentrations increased there by 0.3–0.6 μmol C L?1. The exported DCNS was subsequently removed over a period of weeks following restratification of the water column. Vertical and temporal trends in DCNS yield (% of DOC) supported its use as a diagenetic indicator of DOM quality. Higher DCNS yields in surface waters suggested a portion of the DOM accumulated relatively recently compared to the more recalcitrant material of the upper mesopelagic that had comparably lower yields. DCNS yields and mol% neutral sugar content, together, indicated differences in the diagenetic state of the surface-accumulated and deep pools of DOM. Seasonally accumulated, recently produced DOM with higher DCNS yields was characterized by elevated mol% of galactose and mannose+xylose levels. Conversely, more recalcitrant DOM from depths >100 m had lower DCNS yields but higher mol% of glucose. Lower DCNS yields and elevated mol% glucose were also observed in the surface waters during winter convective mixing, indicating an entrainment of a diagenetically altered DOM pool into the upper 100 m. A multivariate statistical analysis confirms the use of DCNS as an index of shifts in DOM quality at this site.  相似文献   
6.
Despite growing interest in urbanization and its social and ecological impacts on formerly rural areas, empirical research remains limited. Extant studies largely focus either on issues of social exclusion and enclosure or ecological change. This article uses the case of sweetgrass basketmaking in Mt. Pleasant, South Carolina, to explore the implications of urbanization, including gentrification, for the distribution and accessibility of sweetgrass, an economically important nontimber forest product (NTFP) for historically African American communities, in this rapidly growing area. We explore the usefulness of grounded visualization for research efforts that are examining the existence of “fringe ecologies” associated with NTFP. Our findings highlight the importance of integrated qualitative and quantitative analyses for revealing the complex social and ecological changes that accompany both urbanization and rural gentrification.  相似文献   
7.
A geographic data model for representing ground water systems   总被引:4,自引:0,他引:4  
The Arc Hydro ground water data model is a geographic data model for representing spatial and temporal ground water information within a geographic information system (GIS). The data model is a standardized representation of ground water systems within a spatial database that provides a public domain template for GIS users to store, document, and analyze commonly used spatial and temporal ground water data sets. This paper describes the data model framework, a simplified version of the complete ground water data model that includes two-dimensional and three-dimensional (3D) object classes for representing aquifers, wells, and borehole data, and the 3D geospatial context in which these data exist. The framework data model also includes tabular objects for representing temporal information such as water levels and water quality samples that are related with spatial features.  相似文献   
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9.
Evidence for a mantle and/or basaltic component in KT boundary distal ejecta is apparently inconsistent with ejection from Chicxulub Crater since it is located on~35km thick continental crust(De Paolo et al.,1983;Montanari et al.,1983;Hildebrand and Boynton,1988,1990).This evidence,along with ejected terrestrial chromites(Olds et al.,2016)suggest the impact sampled terrestrial mafic and/or ultramafic target rocks which are not known to exist in the Chicxulub target area.Possible resolutions to the paradox are:1)the existence of an unmapped/unknown suture in Yucatan Platform basement,2)an additional small unmapped/unknown impact site on oceanic lithosphere,or 3)an additional large impact on oceanic lithosphere or continental margin transitional to oceanic lithosphere.The third hypothesis is elaborated here since:1)Ophiolites nearest to Chicxulub crater are found in Cuba and apparently were obducted in latest Cretaceous/earliest Danian times(García-Casco,2008),inconsistent with the documented Eocene collision of Cuba with the Bahamas platform;and 2)Cuba hosts the world’s thickest known KT boundary deposits(Iturralde-Vinent,1992;Kiyokawa et al.,2002;Tada et al.,2003).These and geometric considerations suggest oceanic crust and upper mantle rock,exposed as ophiolite in the Greater Antilles island chain,marks the rim of a roughly 700 km diameter impact basin deformed and dismembered from an originally circular form by at least 50 million years of left-lateral shear displacement along the North American-Caribbeantransform plate boundary.  相似文献   
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