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1.
以广东省揭阳市土壤为研究对象,采集了表层土壤(0~20 cm)样1 330个和深层土壤(>150 cm)样331个,测定了土壤Pb含量。利用GIS空间分析技术、半变异函数拟合和方差分析等方法研究土壤Pb含量的空间结构、特征和影响因素。结果显示: 揭阳市不存在明显的土壤Pb污染,表层土壤Pb含量平均值39.26 mg/kg,低于揭阳市土壤Pb背景值(43.71 mg/kg),略高于广东省土壤Pb背景值(36.00 mg/kg);富集因子表明研究区表层土壤Pb富集程度主要为无富集和轻微富集,分别占52.11%和42.63%,Pb富集不明显;研究区表层土壤Pb空间分布呈中等自相关性;表层土壤Pb高值区主要分布在人类活动影响强烈的东部和南部地区。按土地利用、成土母质、土壤类型及其理化性质的分类统计表明,林地及未利用地表层土壤Pb含量最高;页岩风化形成的土壤Pb含量显著高于其他成土母质区土壤;黄壤Pb含量相对较高;有机碳和pH值均与土壤Pb含量呈显著正相关。  相似文献   
2.
The composition of the continental crust of the North China Craton (NCC) is more felsic than that of the average bulk crust, which is regarded to be the result of the delamination of the thickened lower crust during Mesozoic. However, whether the thickened continental crust existed and when the delamination event happened along the southern margin of the NCC are still debated. Here, we report geochronological, geochemical and Sr-Nd-Hf-Pb isotopic evidence that granitoids from the Late Jurassic Wuzhangshan pluton and the Early Cretaceous Huashani complex were derived by partial melting of the lower crust with different thickness. Our new data shows that the two lithofacies of the Wuzhangshan pluton were mainly formed between ca. 157 and 156 Ma, whereas the five lithofacies of the Huashani complex were mainly emplaced between ca. 132 and 125 Ma. The Wuzhangshan pluton and the earlier four lithofacies granitoids of the Huashani complex (ca. 160–125 Ma) both display adakitic geochemical features, which are characterized by as high SiO2 (63.26–72.71 wt%), Al2O3 (13.97–16.89 wt%) and Sr (413–1218 ppm) contents, and low Y (6.30–14.98 ppm) and YbN (1.55–4.43), and high Sr/Y (33−112) and (La/Yb)N (11.53–29.72) ratios. They also have high (87Sr/86Sr)i (0.7066–0.7086), and low εNd(t) (−9.9 to −18.8) and εHf(t) (−11 to −26) values, and two-stage Nd and Hf model ages ranging from 2.4 to 1.7 Ga and 2.7 to 1.7 Ga, respectively. In contrast, the late Early Cretaceous (ca. 125–110 Ma) granitoids have higher SiO2 (71.30–76.78 wt%) and lower Sr (64–333 ppm) contents, and lower Sr/Y (17–29) and (La/Yb)N (13.25–18.36) ratios, and similar εNd(t) (−10 to −16) and relatively higher εHf(t) (−10 to −14) values. These geochemical variations suggest that the ca.160–125 Ma granitoids were most probably produced by partial melting of thickened crust (>45 km) with eclogite, garnet amphibolite or amphibolite residues, whereas that the ca. 125–110 Ma granitoids were formed by partial melting of the thinner crust (<33 km). We thus suggest that the NCC likely underwent a synchronous tectonic transformation at ca. 125 Ma from a compressional setting with thickened crust to an intensive extensional setting with thinner crust at ca. 125 Ma, which demonstrates that the lower crust was most likely delaminated.  相似文献   
3.
Hafnium isotopes of zircon represent a well-dated proxy for the evolution of magmatic systems through Earth history. Time series analysis on the hafnium isotopes of zircon reveals a hierarchy of statistically significant periodic signals spanning multiple orders of magnitude (106–109 year cycles). We attribute the hierarchy of cyclicity to organizing mechanisms of mantle and lithospheric convection at various time scales, ranging from short-term cycles in magmatism and subduction to long-term cycles related to oceans, supercontinents, and superoceans. A ∼600-Myr supercontinent cycle is the strongest signal in the global hafnium database and the phase relationship implies elevated mantle-derived magmatism during supercontinent tenure and elevated crustal reworking during plate reorganization, as expected. A half-supercontinent cycle (Wilson cycle) and a double-supercontinent cycle (superocean cycle) are also present, harmonic with the supercontinent cycle, and related to each other by amplitude modulation. Analysis of local magmatic systems of the circum-Pacific subduction girdle surrounding Pangaea reveal similar significant and harmonic cycles of ∼6 and ∼20 Myr attributed to magmatic cycles and ∼60, ∼120, and ∼240 Myr attributed to subduction cycles. All subduction systems reveal a prevalent ∼60 Myr cycle attributed to an upper mantle convective cycle that has two phase relationships, suggesting that advancing and retreating arc systems can be identified with time series analysis. The harmonic hierarchy of geodynamic cycles identified herein controlled by mantle convection on long time scales and lithospheric convection on short time scales arguably completes the picture of cyclicity in the Earth system, complimenting well-known orbital, oceanic, and astronomical cycles.  相似文献   
4.
Several incidents involving damage to submarine pipelines indicate that there will be potential hazards for many submarine structures if the geotechnical properties of the soil in pockmarks remain unclear. Based on a geophysical survey, geological drilling, in-situ measurement, and shallow gas eruption experiment, two large pockmarks near the Zhongjieshan Archipelago in the East China Sea were analyzed comprehensively. The geophysical and in-situ data indicated that the soil below the two pockmarks contains free or dissolved shallow gas, which continues to migrate upward from the deep zones, but there is no high-pressure gas reservoir in the pockmark soil. In-situ piezocone data, geotechnical results, and shallow gas eruption experiments have demonstrated that the pockmark soil has strengthened mechanical properties and zoning characteristics. After analyzing the pockmark soil in the area where the study was conducted, it was concluded that the pockmark soil in this area is not suitable for the accumulation of high-pressure, shallow gas. It also was concluded that the pockmark soil had stronger mechanical properties than virgin sediment due to the compaction of the soil caused by the eruption of the shallow gas. The zoning characteristics of pockmark soil are due to the regional differences in the ability of shallow gas to carry soil particles, which is a new finding that is worthy of attention in off-shore engineering.  相似文献   
5.
The late Mesozoic terrestrial strata in numerous basins in S (South) China provide important sedimentary archives to understand the tectonic evolution of S China and East Asia. However, establishing regional stratigraphic framework within a basin and precisely correlating strata among basins remain challenging due to limited chronological constraints. In this study, we report zircon U-Pb ages of 21 samples and a compilation of 132 reliable age data from 15 type sections of the volcanic-sedimentary basins in S China. The synthesized geochronology allows us to establish a refined chronostratigraphy for the late Mesozoic terrestrial strata. New calibrated results indicate that most of the lithostratigraphic units are diachronic, laterally stacking, and/or interfingering. Six stacking styles are classified for the relationship of lithostratigraphic units. Analysis of the refined chronostratigraphy and the stratal stacking styles, together with lithological composition, reveals three episodes of tectono-stratigraphic evolution. Episode I (~145–125 Ma) is characterized by intense volcanism, as evidenced by widespread occurrence of volcanic strata and (137–120 Ma) A-type granites, and was probably related to the rollback of the subducting Paleo-Pacific plate; The strata deposited during Episode II (~125–100 Ma) are composed of variegated sediments associated with/without volcanic intercalations in sedimentary faulted-depression basins, indicating the waning of volcanism and tectonism attributed to the ending of the Izanagi/Kula plate subduction; In Episode III (<~100 Ma), red strata occurred along the NE-SW sinistral strike-slip faulting or failed rifting in small basins, which probably resulted from the drastic directional change of the Paleo-Pacific plate subduction from NW to SN.  相似文献   
6.
【目的】制备富含岩藻黄素的三角褐指藻(Phaeodactylum tricornutum)生物质。【方法】采用470 L室内管道光生物反应器系统,研究自养培养下光源、调光策略、补料培养操作条件对于细胞生长、生物量浓度和岩藻黄素积累的影响。【结果】在采用LED灯、梯度提升照度及重复补料半连续培养模式下,三角褐指藻细胞密度、生物量和岩藻黄素产率最高分别可达3.16×107mL-1、1.64 g/L和1.90 mg/(L·d),分别是日光灯为光源条件下的2.77倍、3.09倍和2.38倍(P<0.01)。【结论】在管道光生物反应器中获得的自养培养条件,可强化三角褐指藻生物量和岩藻黄素积累,为三角褐指藻积累岩藻黄素的室内可控规模化技术开发提供指导。  相似文献   
7.
以粤港澳大湾区为例,利用卫星遥感资料结合大气化学模式模拟,分析2003―2018年城市热岛强度、气溶胶光学厚度的变化规律,定性和定量研究气溶胶对白天城市热岛强度的影响。结果表明:2003―2018年粤港澳大湾区城市热岛强度呈波动上升趋势,夏季热岛强度最大,冬季热岛强度最小;气溶胶光学厚度呈波动下降趋势,春季气溶胶光学厚度最大,冬季气溶胶光学厚度最小。在年际和季节尺度,城市热岛强度与城区、郊区气溶胶光学厚度之差均呈弱的正相关。基于WRF-Chem的模拟实验表明,气溶胶的存在导致城区、郊区地表向下总辐射减少、地表温度降低,且城区地表向下总辐射减少多于郊区、降温幅度大于郊区,进而导致了热岛强度减弱。气溶胶对城市热岛强度的贡献率为?2.187%,冬季贡献率绝对值略高于夏季。  相似文献   
8.
刘家峡水库西南部水域表层沉积物重金属污染评价   总被引:1,自引:0,他引:1  
为了研究刘家峡水库西南部水域表层沉积物中重金属的污染状况,对采集的55个表层沉积物样品中的6种重金属元素Cr、Cd、Ni、Cu、Zn和Pb的含量进行测试,其平均含量分别为77.03μg/g、0.16μg/g、33.53μg/g、32.09μg/g、291.77μg/g、22.44μg/g。在研究表层沉积物重金属含量空间分布的基础上,运用单因子污染指数法、内梅罗综合污染指数法、地累积指数法、潜在生态风险指数法,综合判断水库的受污染程度并对其潜在生态风险进行评估。6种元素的地累积指数排序依次为:Zn > Cu > Cd > Ni > Pb > Cr;潜在生态风险系数排序依次为:Cd > Cu > Pb > Zn > Ni > Cr;各区域重金属污染程度或潜在生态风险水平依次为黄河主河道 > 大夏河河口 > 黄河横剖面。综合4种方法的评价结果,认为对刘家峡水库西南部表层沉积物重金属污染及潜在生态风险评价贡献率较高的重金属污染因子是Zn、Cu和Cd;综合相关性分析与主成分分析,认为研究区沉积物重金属污染主要来源于两个方面:(1) Zn、Cu主要来源于生活污染或工业污染;(2) Cd主要来源于工农业活动产生的污染。  相似文献   
9.
风尘堆积的物源研究对于揭示物源区的环境演化状况、重建古风场强度和古大气环流格局等都具有重要的意义。目前长江下游地区下蜀土的物质来源问题仍然存在争议。为了解决这一争议问题,本文以南京泰山新村下蜀土剖面为研究对象,开展了系统的地球化学研究。通过对南京下蜀土的常量元素、微量元素、Nd同位素进行测试,并与黄土高原同期黄土进行对比分析,探讨其对长江下游下蜀土的物源指示意义。南京下蜀土与北方黄土具有相似的常、微量元素UCC标准化曲线和稀土元素球粒陨石标准化曲线,但是它的Zr、Hf含量较高,Tl、Pb含量较低,且具有较高的SiO2/Al2O3、TiO2/Al2O3、Nb/Ta和GdN/YbN,较低的SiO2/TiO2、Zr/Hf、Y/Ho、Lu/Hf和εNd(0)值,说明南京下蜀土的物质来源明显有别于黄土高原黄土。南京下蜀土与长江中游下蜀土在地球化学特征方面有较多的相似性,指示其物质来源与中游下蜀土的物质来源相似,主要来源于长江中下游地区的松散沉积物。  相似文献   
10.
海南抱伦金矿区的金矿脉与大量辉绿岩脉在空间上紧密相关。在详细的野外地质调查基础上,本文对这些辉绿岩脉开展了岩相学和矿相学观察、全岩主量和微量元素分析、Sm-Nd同位素组成分析、金丰度分析以及SHRIMP锆石U-Pb定年,初步探讨了辉绿岩脉的成因、岩浆演化和构造背景以及与金成矿作用的关系。地球化学分析结果表明,辉绿岩脉形成于拉斑玄武质岩浆,主要为左倾型的稀土配分模式;相对N-MORB,富集Sr、K、Rb和Ba等LILE和Th,亏损HFSE,ε_(Nd)(t)为0. 3~5. 6,说明岩浆源区为受到俯冲带含水流体影响和少量地壳混染的亏损地幔。辉绿岩脉的SHRIMP锆石U-Pb年龄为231. 6±2. 6Ma,与尖峰岭花岗质岩体的年龄(236±3. 5Ma~249±5Ma)相近,产出位置相邻,类似于海南兴隆地区的双峰式侵入岩,表明它们产出于造山后伸展环境。辉绿岩脉对应的岩浆富含CO_2、H_2O、F、K、Rb、Ba和适量的S,为抱伦金矿等单金矿床中Au的合适载体。金丰度分析结果表明,辉绿岩脉中的Au曾被活化迁移。再结合辉绿岩脉成岩年龄与抱伦矿区的成矿年龄在误差范围内一致的特征,认为抱伦金矿的Au可能来源于辉绿岩脉。  相似文献   
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