Drying increases organic colloidal mobilization in the karst vadose zone: Evidence from a 15-year cave-monitoring study     

Jin Liao  Chaoyong Hu  Xiuli Li  Jiaoyang Ruan 《水文研究》2021,35(4):e14163

Understanding the hydrological processes of colloids within the karst vadose zone is vital to the security of karst groundwater and providing appropriate paleohydrological explanations of colloid-facilitated metals in speleothem. This study addresses the mobilization mechanisms driving colloidal organic matter (COM) transport in the karst vadose zone using a 15-year long monthly monitoring dataset from a cave drip point (HS4) in Heshang Cave, Qingjiang Valley, China. Variations in COM concentrations were reported as the fluorescence difference values of raw and filtered (<0.22 μm) samples at an excitation wavelength of 320 nm and emission wavelength of ~400 nm. A fluorescence humification index (HIX) lower than 0.8 and an autochthonous index (BIX) higher than 1.2 indicated that the origin of COM was mainly from the karst vadose zone, rather than the soil zone. The COM concentration varied from 0.001 to 0.038 Raman Unit (RU), with evident seasonal fluctuations. Rising limbs for COM values occurred prior to rising limbs within a dripwater hydrograph; moreover, the COM peak values corresponding to the beginning of the increasing hydrograph generally suggested that the mobilization of COM reflected the movement of the air–water interface (AWI) in the karst vadose zone rather than rainfall intensity or flow velocity. COM peak values were positively correlated with the antecedent drying duration and negatively correlated with HIX values. These phenomena may be explained by the increased amount of organic matter that was aggregated and absorbed on the surface of carbonate in the karst vadose zone during a longer drying duration. Moreover, the longer drying duration was also beneficial to autochthonous biological activity, which subsequently decreased the HIX value of the organic matter in the karst vadose zone. The movement of AWI and the drying duration are both controlled by the outside weather conditions. This study is therefore conducive to evaluating the security of karst groundwater in response to climate change, and challenges prevailing paleoclimate interpretations of colloid-facilitated metal abundance timeseries reported from speleothems.  相似文献   

First Multi‐Isotopic (Pb‐Nd‐Sr‐Zn‐Cu‐Fe) Characterisation of Dust Reference Materials (ATD and BCR‐723): A Multi‐Column Chromatographic Method Optimised to Trace Mineral and Anthropogenic Dust Sources     

Aubry Vanderstraeten  Steeve Bonneville  Stefania Gili  Jeroen de Jong  Wendy Debouge  Philippe Claeys  Nadine Mattielli 《Geostandards and Geoanalytical Research》2020,44(2):307-329

Atmospheric dust is an integral component of the Earth system with major implications for the climate, biosphere and public health. In this context, identifying and quantifying the provenance and the processes generating the various types of dust found in the atmosphere is paramount. Isotopic signatures of Pb, Nd, Sr, Zn, Cu and Fe are commonly used as sensitive geochemical tracers. However, their combined use is limited by the lack of (a) a dedicated chromatographic protocol to separate the six elements of interest for low‐mass samples and (b) specific reference materials for dust. Indeed, our work shows that USGS rock reference materials BHVO‐2, AGV‐2 and G‐2 are not applicable as substitute reference materials for dust. We characterised the isotopic signatures of these six elements in dust reference materials ATD and BCR‐723, representatives of natural and urban environments, respectively. To achieve this, we developed a specific procedure for dust, applicable in the 4–25 mg mass range, to separate the six elements using a multi‐column ion‐exchange chromatographic method and MC‐ICP‐MS measurements.  相似文献   

地缘政治视角下中亚“颜色革命”易发程度分析     

李希雅  王礼茂 《世界地理研究》2019,28(6):42-49

基于地缘政治视角，分析本世纪初发生在原苏联地区“颜色革命”的诱发因素，认为美国根据其地缘战略格局对“颜色革命”发生地存在一定程度的主观选择性，国家内部经济、政治、社会等层面的矛盾也同样作为发生背景。在中亚地缘格局动态分析的基础上，结合中亚五国形势，从时间和空间双重维度对中亚地区未来发生“颜色革命”的可能性进行识别与评判，得出1) 整体来看，中亚近期内爆发“颜色革命”可能性较小，但从长远来看不能掉以轻心。2)土、乌未来稳定可期，塔、吉、哈需谨防“颜色革命”卷土重来。  相似文献   

利用InSAR资料反演宁洱Ms6.4地震震源参数及库仑应力变化     

陈晨月  冯光财  高华  杨怀宁 《大地测量与地球动力学》2019,39(3):295-301

首先利用ALOS PALSAR数据，通过D-InSAR技术获取2007-06-03云南宁洱MS6.4地震的同震形变场，然后基于Okada弹性半空间位错模型反演该地震的断层几何以及精细滑动分布，最后计算宁洱地震后周边断层的静态库仑应力变化。结果表明，形变主要集中在西盘，最大视线向形变量为51.6 cm；反演得到的震源位置为23.05°N、101.02°E，深度3 km，断层走向145°，倾向49.5°，平均滑动角153°，发震断层为NNW向普洱断裂，断层活动以右旋走滑为主，兼具逆冲分量；断层面最大滑动量为1.2 m，反演得到的震级为MW619。基于库仑应力场发现，磨黑断裂处于库仑应力增加区域，而2014年景谷地震位于负值区域。结合实地考察资料和反演结果表明，宁洱地震为浅源地震，但断层并未出露地表。  相似文献   

基于GPS和水准数据的微粒群算法联合反演祁连山北缘断裂三维滑动速率     

刘杰 《大地测量与地球动力学》2019,39(9):906-909

将微粒群算法与位错理论模型相结合，采用中国地壳运动观测网络提供的青藏高原地区2001~2004年GPS测量数据和2000~2006年水准测量数据，通过常规定权和附有相对权比的方法对祁连山北缘断裂的三维滑动速率进行联合反演，并与蚁群算法反演结果进行对比。结果表明，微粒群算法收敛速度快、稳定性高，结合经典位错理论模型，是一种可以有效求解断层三维滑动速率反演问题的优化算法，在大地测量反演领域极具应用潜力。  相似文献   

地震异构云管理平台的技术架构设计     

郭凯  姜立新  刘晓雨  班世敏 《中国地震》2020,36(1):153-161

基于Open Stack的开源标准体系,结合中国地震台网中心和中国地震局第二监测中心的云基础设施现状,设计两级云管理架构,以异构云管理平台作为综合管理平台,纳管区域云管理平台,以统一门户的方式对地震行业云计算资源进行统一管理;通过容器化部署异构云管理平台,初步实现对地震行业云计算资源的统一监控和运行管理。  相似文献   

1960-2015年青海三江源地区降水时空特征   总被引：5，自引：0，他引：5  

刘晓琼  吴泽洲  刘彦随  赵新正  芮旸  张健 《地理学报》2019,74(9):1803-1820

青海三江源地区是中国生态系统最为敏感和脆弱的地区,其降水特别是生长季降水的波动,是影响本区及江河中下游水资源安全、生态系统可持续发展的关键因素。综合线性趋势、Mann-Kendall检验、BG分割算法、R/S、EEMD等多方法细致辨识了1960-2015年研究区降水量序列的时空特征。结果显示：① 三江源降水量总体呈现弱增趋势,21世纪以来降水量显著增加,各子源区气候倾向率不尽相同;② 年、季降水量自东南向西北递减,澜沧江源区夏季降水和黄河源区秋季降水呈弱减趋势,雨量弱减区在空间上呈斑块状分布;③ 年、季降水量年代际变化和增湿率的空间差异较明显,春夏季降水气候倾向率与经纬度、海拔的复相关性显著高于冬季;④ 20世纪90年代中后期,各子源区降水总体显现增强信号,并于2002年前后发生突变;⑤ 年际和低值年代际显著周期是造成降水量变动的主要因素;⑥ 除澜沧江源区夏季降水趋于减少外,其他年、季降水量变化呈现增幅不一的转湿趋势;⑦ 横向比较各子源区可见,长江源区降水变化更能表征高原气候变化。研究结果显示,研究区降水时空序列变化具有明显的区域和季节差异性特征,与以往类似研究存在些许差异,可见为有效提高气候序列演变过程及突变诊断的准确性,仍需进一步融合多方法实施集成分析。  相似文献   

Effect of Shale Reservoir Characteristics on Shale Oil Movability in the Lower Third Member of the Shahejie Formation,Zhanhua Sag     

NING Chuanxiang  MA Zhongliang  JIANG Zhenxue  SU Siyuan  LI Tingwei  ZHENG Lunju  WANG Guozhen  LI Fengxun 《《地质学报》英文版》2020,94(2):352-363

To reveal the effect of shale reservoir characteristics on the movability of shale oil and its action mechanism in the lower third member of the Shahejie Formation(Es3l), samples with different features were selected and analyzed using N2 adsorption, high-pressure mercury injection capillary pressure(MICP), nuclear magnetic resonance(NMR), high-speed centrifugation, and displacement image techniques. The results show that shale pore structure characteristics control shale oil movability directly. Movable oil saturation has a positive relationship with pore volume for radius > 2 μm, as larger pores often have higher movable oil saturation, indicating that movable oil is present in relatively larger pores. The main reasons for this are as follows. The relatively smaller pores often have oil-wetting properties because of organic matter, which has an unfavorable effect on the flow of oil, while the relatively larger pores are often wetted by water, which is helpful to shale oil movability. The rich surface provided by the relatively smaller pores is beneficial to the adsorption of immovable oil. Meanwhile, the relatively larger pores create significant pore volume for movable oil. Moreover, the larger pores often have good pore connectivity. Pores and fractures are interconnected to form a complex fracture network, which provides a good permeability channel for shale oil flow. The smaller pores are mostly distributed separately;thus, they are not conducive to the flow of shale oil. The mineral composition and fabric macroscopically affect the movability of shale oil. Calcite plays an active role in shale oil movability by increasing the brittleness of shale and is more likely to form micro-cracks under the same stress background. Clay does not utilize shale oil flow because of its large specific surface area and its block effect. The bedding structure increases the large-scale storage space and improves the connectivity of pores at different scales, which is conducive to the movability of shale oil.  相似文献   

岩溶水硝酸盐污染原位修复试验     

叶进霞  夏春英  卜鸿志 《中国岩溶》2020,39(2):173-179

岩溶含水层的极不均一性特征使岩溶水溶质运移受构造、裂隙空间及其发育方向控制；因环境条件复杂，开展岩溶水污染原位修复技术难度较大，截止目前，国内尚未系统地开展岩溶含水层水污染原位修复研究工作。文章选择鲁中南山区典型岩溶发育及硝酸盐污染地段，施工组合钻孔建设修复试验工程，采用“乙醇+葡萄糖”液态碳源和“聚乙烯醇+淀粉颗粒”固态反应器分别进行岩溶水硝酸盐污染原位修复试验。结果表明:浓度500 mg?L－1、1 000 mg?L－1的“乙醇+葡萄糖”反硝化溶液对硝酸盐浓度的降解率分别为6.45 %和21.52 %；单位长度组成材料“聚乙烯醇3 kg+淀粉颗粒3 kg”、“聚乙烯醇2 kg+淀粉颗粒4 kg”的两种反硝化固态反应器对硝酸盐浓度的降解率分为33.91%和34.96%。试验证明在裂隙型岩溶地区采用孔组方案进行地下水污染原位修复技术可行、且能取得较显著效果。修复工程布设方式和试验成果对类似地区开展岩溶地下水污染原位修复具一定借鉴意义。   相似文献   

东海盆地中、新生代盆架结构与构造演化   总被引：6，自引：0，他引：6  

刘金水  许怀智  蒋一鸣  王军  何新建 《地质学报》2020,94(3):675-691

基于地貌、钻井、岩石测年和地震等资料,分析盆地地层分布、盆架结构、构造单元划分和裂陷迁移规律,结果表明东海盆地由台北坳陷、舟山隆起、浙东坳陷、钓鱼岛隆褶带和冲绳坳陷构成,是以新生代沉积为主、中生代沉积为辅的大型中、新生代叠合含油气盆地;古元古代变质岩系构成了盆地的基底。该盆地不仅是印度-太平洋前后相继的动力体系作用下形成的西太平洋沟-弧-盆构造体系域一部分,而且也是古亚洲洋动力体系作用下形成的古亚洲洋构造域和特提斯洋动力体系作用下形成的特提斯洋构造域一部分,晚侏罗世至早白垩世经历了构造体制转换,盆地格局发生重大变革,早白垩世以前主要受古亚洲-特提斯洋构造体制影响的强烈挤压造山和地壳增厚作用演变为早白垩世以来主要受太平洋构造体制控制的陆缘伸展裂陷和岩石圈减薄作用,经历侏罗纪古亚洲-特提斯构造体制大陆边缘拗陷和白垩纪以来太平洋构造体制弧后裂陷两大演化阶段。白垩纪以来太平洋构造体制的弧后裂陷演化阶段可细分为早白垩世至始新世裂陷期、渐新世至晚中新世拗陷期和中新世末至全新世裂陷期。  相似文献