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1.
Redox hot spots occurring as metal-rich anoxic groundwater discharges through oxic wetland and river sediments commonly result in the formation of iron (Fe) oxide precipitates. These redox-sensitive precipitates influence the release of nutrients and metals to surface water and can act as ‘contaminant sponges’ by absorbing toxic compounds. We explore the feasibility of a non-invasive, high-resolution magnetic susceptibility (MS) technique to efficiently map the spatial variations of magnetic Fe oxide precipitates in the shallow bed of three rivers impacted by anoxic groundwater discharge. Laboratory analyses on Mashpee River (MA, USA) sediments demonstrate the sensitivity of MS to sediment Fe concentrations. Field surveys in the Mashpee and Quashnet rivers (MA, USA) reveal several discrete high MS zones, which are associated with likely anoxic groundwater discharge as evaluated by riverbed temperature, vertical head gradient, and groundwater chemistry measurements. In the East River (CO, USA), widespread cobbles/rocks exhibit high background MS from geological ferrimagnetic minerals, thereby obscuring the relatively small enhancement of MS from groundwater induced Fe oxide precipitates. Our study suggests that, in settings with low geological sources of magnetic minerals such as lowland rivers and wetlands, MS may serve as a complementary tool to temperature methods for efficiently mapping Fe oxide accumulation zones due to anoxic groundwater discharges that may function as biogeochemical hot spots and water quality control points in gaining systems.  相似文献   
2.
The groundwater divide is a key feature of river basins and significantly influenced by subsurface hydrological processes. For an unconfined aquifer between two parallel rivers or ditches, it has long been defined as the top of the water table based on the Dupuit–Forchheimer approximation. However, the exact groundwater divide is subject to the interface between two local flow systems transporting groundwater to rivers from the infiltration recharge. This study contributes a new analytical model for two-dimensional groundwater flow between rivers of different water levels. The flownet is delineated in the model to identify groundwater flow systems and the exact groundwater divide. Formulas with two dimensionless parameters are derived to determine the distributed hydraulic head, the top of the water table and the groundwater divide. The locations of the groundwater divide and the top of the water table are not the same. The distance between them in horizontal can reach up to 8.9% of the distance between rivers. Numerical verifications indicate that simplifications in the analytical model do not significantly cause misestimates in the location of the groundwater divide. In contrast, the Dupuit–Forchheimer approximation yields an incorrect water table shape. The new analytical model is applied to investigate groundwater divides in the Loess Plateau, China, with a Monte Carlo simulation process taking into account the uncertainties in the parameters.  相似文献   
3.
The use of the sulphate mass balance (SMB) between precipitation and soil water as a supplementary method to estimate the diffuse recharge rate assumes that the sulphate in soil water originated entirely from atmospheric deposition; however, the origin of sulphate in soil and groundwater is often unclear, especially in loess aquifers. This study analysed the sulphur (δ34S-SO4) and oxygen (δ18O-SO4) isotopes of sulphate in precipitation, water-extractable soil water, and shallow groundwater samples and used these data along with hydrochemical data to determine the sources of sulphate in the thick unsaturated zone and groundwater of a loess aquifer. The results suggest that sulphate in groundwater mainly originated from old precipitation. When precipitation percolates through the unsaturated zone to recharge groundwater, sulphates were rarely dissolved due to the formation of CaCO3 film on the surface of sulphate minerals. The water-extractable sulphate in the deep unsaturated zone (>10 m) was mainly derived from the dissolution of evaporite minerals and there was no oxidation of sulphide minerals during the extraction of soil water by elutriating soil samples with deionized water. The water-extractable concentration of SO4 was not representative of the actual SO4 concentration in mobile soil water. Therefore, the recharge rate cannot be estimated by the SMB method using the water-extractable concentration of SO4 in the loess areas. This study is important for identifying sulphate sources and clarifying the proper method for estimating the recharge rate in loess aquifers.  相似文献   
4.
为构建温度示踪方法测算地下水流速技术体系,并应用于区域地下水资源评价,基于最小二乘法和垂向一维非稳定流水-热运移方程数值解法,提出地表暖化情形下地下水流速计算方法,并对雷州半岛东北部地下水流速进行测算。结果表明:研究区域地下水补给速度为0.796 m/a,入渗以西北部降水和运河渗漏为主;地下水排泄速度为0.269 m/a,排泄入海主要发生在东海岛、南三岛和硵州岛附近。温度示踪解析区域地下水流动情况与地下水位分布情况基本一致,观测和计算地温数据具有较强相关性(R2>0.50)和较低均方根误差(均值0.748),表明提出方法率定得到的地下水流速具有较强的可靠性。参数敏感性分析结果表明,地质体热扩散率和地表温度均对地温计算结果产生较明显的影响,参数的准确率定对利用地温计算地下水流速十分重要。  相似文献   
5.
地下水是张掖盆地的重要水资源,其硝酸盐污染尚未得到足够重视。对张掖盆地2004、2015年地下水硝酸盐浓度进行了系统分析,并采用美国环境保护署(USEPA)推荐的健康风险评价模型评估了地下水硝酸盐的健康风险。结果表明:自2004年以来张掖盆地地下水硝酸盐污染日趋严重。2015年硝酸盐浓度最高已达到283.32 mg·L-1,17.61%的采样点硝酸盐氮浓度超过GB5749-2006《生活饮用水卫生标准》中饮用地下水限量值(20 mg·L-1)。研究区人群经皮肤接触途径摄入硝酸盐的健康风险在可接受水平,而饮水摄入硝酸盐的健康风险较高,总风险中饮水途径引起健康风险的贡献率占99.40%,远大于皮肤接触途径。儿童经饮水摄入和皮肤接触两种途径的健康风险均显著高于成人,分别为成人的1.544倍和1.039倍。32.39%的采样点地下水硝酸盐对儿童的健康风险超出了可接受水平,14.79%的采样点地下水硝酸盐对成人的健康风险不可接受。甘州区城区、临泽县北部边缘及高台县城区周围硝酸盐浓度最高,这些区域内所有人群都面临硝酸盐引发的高健康风险,其余区域硝酸盐引发的健康风险相对较低。  相似文献   
6.
Monitoring of the fluctuations of groundwater storage is particularly important in arid and semi-arid regions where water scarcity brings about various challenges. Remote sensing data and techniques play a preponderant role in developing solutions to environmental problems. The launch of Gravity Recovery and Climate Experiment (GRACE) satellites has eased the remote monitoring and evaluation of groundwater resources with an unprecedented precision over large scales. Within the scope of the current study, the latest release (RL06) of GRACE mass concentrations (Mascons) from Jet Propulsion Laboratory (JPL) dataset as well as Global Land Data Assimilation System (GLDAS) models of Noah and Catchment Land Surface Model (CLSM) were used to provide Groundwater Storage Anomalies (GWSA) over Turkey. The temporal interactions of the estimated GWSA with the climatic variables of precipitation and temperature (derived from the reanalysis datasets of CHELSA [Climatologies at High resolution for the Earth's Land Surface Areas] and FLDAS [the Famine Early Warning Systems Network Land Data Assimilation System], respectively) were investigated statistically. The results suggest that there is a descending trend (from 2003 to 2016) for Terrestrial Water Storage Anomalies (TWSA) and GWSA over Turkey with a total loss of 11 and 6 cm of water, respectively. The statistical analysis results also indicate that the monthly variations of GWSA over Turkey are highly correlated with precipitation and temperature at 2-month lag. The analysis of the climatology (long-term) values of monthly GWSA, precipitation and temperature also revealed high agreement between the variables.  相似文献   
7.
The transition area between rivers and their adjacent riparian aquifers, which may comprise the hyporheic zone, hosts important biochemical reactions, which control water quality. The rates of these reactions and metabolic processes are temperature dependent. Yet the thermal dynamics of riparian aquifers, especially during flooding and dynamic groundwater flow conditions, has seldom been studied. Thus, we investigated heat transport in riparian aquifers during 3 flood events of different magnitudes at 2 sites along the same river. River and riparian aquifer temperature and water‐level data along the Lower Colorado River in Central Texas, USA, were monitored across 2‐dimensional vertical sections perpendicular to the bank. At the downstream site, preflood temperature penetration distance into the bank suggested that advective heat transport from lateral hyporheic exchange of river water into the riparian aquifer was occurring during relatively steady low‐flow river conditions. Although a small (20‐cm stage increase) dam‐controlled flood pulse had no observable influence on groundwater temperature, larger floods (40‐cm and >3‐m stage increases) caused lateral movement of distinct heat plumes away from the river during flood stage, which then retreated back towards the river after flood recession. These plumes result from advective heat transport caused by flood waters being forced into the riparian aquifer. These flood‐induced temperature responses were controlled by the size of the flood, river water temperature during the flood, and local factors at the study sites, such as topography and local ambient water table configuration. For the intermediate and large floods, the thermal disturbance in the riparian aquifer lasted days after flood waters receded. Large floods therefore have impacts on the temperature regime of riparian aquifers lasting long beyond the flood's timescale. These persistent thermal disturbances may have a significant impact on biochemical reaction rates, nutrient cycling, and ecological niches in the river corridor.  相似文献   
8.
In order to model non‐Fickian transport behaviour in groundwater aquifers, various forms of the time–space fractional advection–dispersion equation have been developed and used by several researchers in the last decade. The solute transport in groundwater aquifers in fractional time–space takes place by means of an underlying groundwater flow field. However, the governing equations for such groundwater flow in fractional time–space are yet to be developed in a comprehensive framework. In this study, a finite difference numerical scheme based on Caputo fractional derivative is proposed to investigate the properties of a newly developed time–space fractional governing equations of transient groundwater flow in confined aquifers in terms of the time–space fractional mass conservation equation and the time–space fractional water flux equation. Here, we apply these time–space fractional governing equations numerically to transient groundwater flow in a confined aquifer for different boundary conditions to explore their behaviour in modelling groundwater flow in fractional time–space. The numerical results demonstrate that the proposed time–space fractional governing equation for groundwater flow in confined aquifers may provide a new perspective on modelling groundwater flow and on interpreting the dynamics of groundwater level fluctuations. Additionally, the numerical results may imply that the newly derived fractional groundwater governing equation may help explain the observed heavy‐tailed solute transport behaviour in groundwater flow by incorporating nonlocal or long‐range dependence of the underlying groundwater flow field.  相似文献   
9.
地下水稳定同位素组成的时空变化特征可以反映不同时期、不同区域地下水补给来源的差异。通过青海湖沙柳河流域浅层地下水氢氧稳定同位素组成的时空变化特征以及地下水、河水与降雨之间的补给关系的分析,结果显示:季风时期,地下水主要受降雨入渗和河流侧向补给为主,在补给过程中蒸发作用是影响地下水稳定同位素值的主要因素;非季风期,冰雪融水对低值区的地下水影响显著,同时降水的快速入渗则是该时期高值区地下水的主要补给方式之一。地下水同位素高值区,地下水与河水间补给作用较弱,补给时间超过5个月;地下水同位素低值区,地下水与河水补给关系较为密切,补给时间在1~4个月间。本文所得结论可初步反映干旱半干旱内陆流域地下水稳定同位素特征以及补给方式的基本规律,在一定程度上可为流域地下水及其他水体间的转换研究提供科学依据,并为地下水资源管理和水环境治理提供一定理论指导。  相似文献   
10.
Proglacial aquifers are an important water store in glacierised mountain catchments that supplement meltwater-fed river flows and support freshwater ecosystems. Climate change and glacier retreat will perturb water storage in these aquifers, yet the climate-glacier-groundwater response cascade has rarely been studied and remains poorly understood. This study implements an integrated modelling approach that combines distributed glacio-hydrological and groundwater models with climate change projections to evaluate the evolution of groundwater storage dynamics and surface-groundwater exchanges in a temperate, glacierised catchment in Iceland. Focused infiltration along the meltwater-fed Virkisá River channel is found to be an important source of groundwater recharge and is projected to provide 14%–20% of total groundwater recharge by the 2080s. The simulations highlight a mechanism by which glacier retreat could inhibit river recharge in the future due to the loss of diurnal melt cycling in the runoff hydrograph. However, the evolution of proglacial groundwater level dynamics show considerable resilience to changes in river recharge and, instead, are driven by changes in the magnitude and seasonal timing of diffuse recharge from year-round rainfall. The majority of scenarios simulate an overall reduction in groundwater levels with a maximum 30-day average groundwater level reduction of 1 m. The simulations replicate observational studies of baseflow to the river, where up to 15% of the 30-day average river flow comes from groundwater outside of the melt season. This is forecast to reduce to 3%–8% by the 2080s due to increased contributions from rainfall and meltwater runoff. During the melt season, groundwater will continue to contribute 1%–3% of river flow despite significant reductions in meltwater runoff inputs. Therefore it is concluded that, in the proglacial region, groundwater will continue to provide only limited buffering of river flows as the glacier retreats.  相似文献   
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