First Multi‐Isotopic (Pb‐Nd‐Sr‐Zn‐Cu‐Fe) Characterisation of Dust Reference Materials (ATD and BCR‐723): A Multi‐Column Chromatographic Method Optimised to Trace Mineral and Anthropogenic Dust Sources     

Aubry Vanderstraeten  Steeve Bonneville  Stefania Gili  Jeroen de Jong  Wendy Debouge  Philippe Claeys  Nadine Mattielli 《Geostandards and Geoanalytical Research》2020,44(2):307-329

Atmospheric dust is an integral component of the Earth system with major implications for the climate, biosphere and public health. In this context, identifying and quantifying the provenance and the processes generating the various types of dust found in the atmosphere is paramount. Isotopic signatures of Pb, Nd, Sr, Zn, Cu and Fe are commonly used as sensitive geochemical tracers. However, their combined use is limited by the lack of (a) a dedicated chromatographic protocol to separate the six elements of interest for low‐mass samples and (b) specific reference materials for dust. Indeed, our work shows that USGS rock reference materials BHVO‐2, AGV‐2 and G‐2 are not applicable as substitute reference materials for dust. We characterised the isotopic signatures of these six elements in dust reference materials ATD and BCR‐723, representatives of natural and urban environments, respectively. To achieve this, we developed a specific procedure for dust, applicable in the 4–25 mg mass range, to separate the six elements using a multi‐column ion‐exchange chromatographic method and MC‐ICP‐MS measurements.  相似文献   

Orbital control on cyclical organic matter accumulation in Early Silurian Longmaxi Formation shales     

Siding Jin  Hucheng Deng  Xing Zhu  Yan Liu  Sibing Liu  Meiyan Fu 《地学前缘(英文版)》2020,(2):533-545

High resolution(939 samples)total organic carbon content(TOC)analyses were conducted on the Shuanghe Section of^152.6 m in the Changning area,Sichuan Basin.The sampling section was divided into two units considering the distinct-different deposit environment and sediments accumulation rate.The lower part(Unit 1)and the peer part(Unit 2)with high resolution sample spacing(0.08–0.4 m)enables the identification of the precession cycle in two sedimentary sequences with distinct different sedimentary accumulation rate.MTM Power spectral analyses on untuned TOC series reveals significant peaks exceeding above the 95%confidence level and shows that both Unit 1 and Unit 2 have recorded Milankovitch cycles of 405 kyr long eccentricity,short eccentricity,obliquity and precession.The floating astronomical time scale(ATS)was constructed on the Shuanghe Section in the Early Silurian(~439.673–444.681 Ma),and which was calibrated by 405 kyr long eccentricity cycles.The total duration of the Wufeng and Longmaxi shales is 5.01 Myr.The floating ATS used for estimating the duration of the graptolite zones and each stage in the study interval.Finally,we postulated two models that could verify the linkage between orbital cycle and organic accumulation.To make sure whether productivity or preservation is the main factor that under long eccentricity control,the phase correlation between the obtained filtered signal and the theoretical orbital solution should be made clear in the further research.  相似文献   

东昆仑夏日哈木地区二长花岗岩年代学、地球化学特征及地质意义     

郭峰  王盘喜  卞孝东  冯乃琦 《中国地质调查》2020,7(6):51-60

东昆仑夏日哈木地区首次发现了早泥盆世二长花岗岩,对其开展年代学和地球化学特征研究,进一步探讨其岩石成因和构造地质背景。二长花岗岩锆石U-Pb年龄为(412.1±5.7) Ma(MSWD=0.95),形成于早泥盆世早期; 岩石为过弱铝质亚碱性花岗岩,富SiO₂(含量为71.41%~72.46%)、K₂O(含量为5.27%~6.16%),贫Fe₂O₃(含量为1.86%~2.05%)、P₂O₅(含量为0.08%~0.12%),富集轻稀土元素,具明显的负Eu异常; 在原始地幔标准化微量元素蛛网图上可以看出,岩石明显富集Rb、Th、Zr、Hf,强烈亏损Nb、Sr、P、Ti、Ba。夏日哈木地区二长花岗岩属于I型花岗岩,其源岩可能由幔源岩浆底侵加热下地壳岩石致其部分熔融而形成,处于由同碰撞向后碰撞转换的构造环境,说明东昆仑夏日哈木地区在早泥盆世早期已进入伸展阶段。  相似文献   

地缘政治视角下中亚“颜色革命”易发程度分析     

李希雅  王礼茂 《世界地理研究》2019,28(6):42-49

基于地缘政治视角，分析本世纪初发生在原苏联地区“颜色革命”的诱发因素，认为美国根据其地缘战略格局对“颜色革命”发生地存在一定程度的主观选择性，国家内部经济、政治、社会等层面的矛盾也同样作为发生背景。在中亚地缘格局动态分析的基础上，结合中亚五国形势，从时间和空间双重维度对中亚地区未来发生“颜色革命”的可能性进行识别与评判，得出1) 整体来看，中亚近期内爆发“颜色革命”可能性较小，但从长远来看不能掉以轻心。2)土、乌未来稳定可期，塔、吉、哈需谨防“颜色革命”卷土重来。  相似文献   

利用InSAR资料反演宁洱Ms6.4地震震源参数及库仑应力变化     

陈晨月  冯光财  高华  杨怀宁 《大地测量与地球动力学》2019,39(3):295-301

首先利用ALOS PALSAR数据，通过D-InSAR技术获取2007-06-03云南宁洱MS6.4地震的同震形变场，然后基于Okada弹性半空间位错模型反演该地震的断层几何以及精细滑动分布，最后计算宁洱地震后周边断层的静态库仑应力变化。结果表明，形变主要集中在西盘，最大视线向形变量为51.6 cm；反演得到的震源位置为23.05°N、101.02°E，深度3 km，断层走向145°，倾向49.5°，平均滑动角153°，发震断层为NNW向普洱断裂，断层活动以右旋走滑为主，兼具逆冲分量；断层面最大滑动量为1.2 m，反演得到的震级为MW619。基于库仑应力场发现，磨黑断裂处于库仑应力增加区域，而2014年景谷地震位于负值区域。结合实地考察资料和反演结果表明，宁洱地震为浅源地震，但断层并未出露地表。  相似文献   

基于GPS和水准数据的微粒群算法联合反演祁连山北缘断裂三维滑动速率     

刘杰 《大地测量与地球动力学》2019,39(9):906-909

将微粒群算法与位错理论模型相结合，采用中国地壳运动观测网络提供的青藏高原地区2001~2004年GPS测量数据和2000~2006年水准测量数据，通过常规定权和附有相对权比的方法对祁连山北缘断裂的三维滑动速率进行联合反演，并与蚁群算法反演结果进行对比。结果表明，微粒群算法收敛速度快、稳定性高，结合经典位错理论模型，是一种可以有效求解断层三维滑动速率反演问题的优化算法，在大地测量反演领域极具应用潜力。  相似文献   

辽东本溪林家组属于中三叠世之锆石、古生物和地层证据     

张宜  郑少林  李之彤  曹成润  杨佳林  张国仁  李显东  孟繁巍 《地质与资源》2019,28(5):434-442

林家组出露于辽宁东部本溪林家崴子一带.自小林贞一1942年记载以来，其时代一直有很大的争议.争议跨度从第三系到上二叠统.20世纪80年代初，张武等依据动植物化石和地层对比，提出了林家组属于中三叠世的观点.由于林家组产出的植物化石十分复杂，既有古生代，又有中生代分子，且没有锆石年龄证据，故林家组时代仍然存疑.近年来，在林家组底部找到了变质凝灰质粉砂岩，其中有很多锆石.根据30颗保存较好锆石测年结果，发现4颗最年轻锆石的²⁰⁶Pb/²³⁸U平均年龄是239.5±4.1 Ma.另外，最近前甸子地区林家组发现了少林肋木（Pleuromeia shaolinii）.因此尽管林家植物群存在二叠纪和三叠纪均有分布的重要植物，但结合锆石定年、地层对比、岩性特征、平行不整合接触关系、三叠纪代表植物及中三叠世到早白垩世均有分布的昆虫索德蠊属来综合分析，可以确认林家组确实属于中三叠世.  相似文献   

Genesis of S-type Granites in the Pengshan Sn-polymetallic Ore Field, Northern Jiangxi Province and its Implications     

YIN Qingqing  XIANG Xinkui  YU Zhendong  YANG Xiufeng  WANG Tianchen  ZHONG Bo  TAN Rong  LIAO Jianhai  ZHU Yuansong 《《地质学报》英文版》2020,94(6):1860-1873

The Pengshan Sn-polymetallic ore field is located in the southeastern part of the Yangtze block, spanning the southeast edge of the MLYDZ and the northern edge of the mid-segment of the Jiangnan Uplift, and on one side of the MLYDZ. The studies of LA–ICP–MS zircon U–Pb chronology and petrogeochemistry for Early Cretaceous acid granites from the Pengshan ore field were carried out in this paper. We report zircon U–Pb geochronology and whole-rock geochemistry for acid granites in the Pengshan ore field. The zircon U–Pb ages of the muscovite-granite, biotite adamellite and granite-porphyry are 127.6 ± 1.7 Ma, 126.9 ± 1.6 Ma and 126.6 ± 2.0 Ma, respectively. The granites in Pengshan are characterized by a high silicon content and are rich in alkali. They belong to high-potassium, calc-alkaline, peraluminous granite. The rocks have a relatively high Rb/Ba ratio, and the data points for muscovite-granite and biotite adamellite all fall within the clay-rich sources region, near the pelite-derived end-member, showing that the Pengshan muscovite-granite and biotite adamellite mainly originated from the partial melting of metapelites with high maturity. The transformation of the compressional and extensional tectonics in this region approximately 128 Ma obviously lags behind that in the mid-segment of the Jiangnan Uplift (135 Ma), but occurred earlier than the MLYDZ (126 Ma). The Pengshan ore field extends from the mid-segment of the Jiangnan Uplift to the MLYDZ. Although the tectonic stress field is constrained by the combination of the two secondary tectonic units, the time of tectonic system transformation is closer to the MLYDZ because the spatial orientation of the area is enclosed in the MLYDZ. Relevant geophysical and drilling data confirm the rationality of Pengshan–Ao’xia as a multi-center vertical zoning ore field, and show the scientificity of the prospecting idea of abutting joint between the north-west of Pengshan area and the south-east of Ao’xia area.  相似文献   

赣南狮吼山硫铁多金属矿区花岗岩地球化学、年代学特征及其成因     

贺根文  路思明  彭琳琳  于长琦  李伟  刘翠辉 《吉林大学学报(地球科学版)》2020,50(5):1491-1504

狮吼山矿区是江西省内规模最大的矽卡岩型硫铁多金属矿床，伴生W、Cu、Au多种成矿元素，成矿作用与矿区出露的茶山迳复式花岗岩体有关。岩体主要包括茶山迳似斑状黑云母二长花岗岩和莲湖细粒二长花岗岩两期，为研究成矿岩体的侵位时代、岩石成因及与成矿的关系，本次工作进行了U-Pb锆石定年、岩相学和岩石地球化学等测试分析。结果表明：岩体具有高硅、高钾、富铝的特征，属高钾钙碱性系列花岗岩；轻重稀土元素分馏明显，均为右倾型，弱Eu负异常，以富集Cs、Rb、Th、U、Pb，亏损Ba、Nb、Sr、和Ti等元素为主要特征，属于低Ba-Sr壳源花岗岩类；锆石具较好晶形，具典型岩浆锆石特征，利用LA-ICP-MS进行U-Pb测年，获得谐和年龄为（162.4±0.6）Ma（MSWD=1.8），加权平均年龄为（162.4±1.4）Ma（MSWD=1.4），谐和年龄与加权平均年龄在误差范围内高度一致，表明茶山迳复式岩体侵位于燕山早期中侏罗世；综合考虑岩体矿物组合、主微量元素及高分异特征，认为其成因分类应属于S型花岗岩；对比中国花岗岩成矿元素平均含量，茶山迳两期花岗岩均具有较高的W、Mo、Bi、Pb等成矿元素含量，可同时为成矿作用提供热源、流体及物质。  相似文献   

Cretaceous tectonic evolution of the Neo-Tethys in Central Iran:Evidence from petrology and age of the Nain-Ashin ophiolitic basalts     

Tahmineh Pirnia  Emilio Saccani  Ghodrat Torabi  Marco Chiari  Spela Gorican  Edoardo Barbero 《地学前缘(英文版)》2020,11(1):57-81

The Nain and Ashin ophiolites consist of Mesozoic melange units that were emplaced in the Late Cretaceous onto the continental basement of the Central-East Iran microcontinent(CEIM).They largely consist of serpentinized peridotites slices;nonetheless,minor tectonic slices of sheeted dykes and pillow lavas-locally stratigraphically associated with radiolarian cherts-can be found in these ophiolitic melanges.Based on their whole rock geochemistry and mineral chemistry,these rocks can be divided into two geochemical groups.The sheeted dykes and most of the pillow lavas show island arc tholeiitic(IAT)affinity,whereas a few pillow lavas from the Nain ophiolites show calc-alkaline(CA)affinity.Petrogenetic modeling based on trace elements composition indicates that both IAT and CA rocks derived from partial melting of depleted mantle sources that underwent enrichment in subduction-derived components prior to melting.Petrogenetic modeling shows that these components were represented by pure aqueous fluids,or sediment melts,or a combination of both,suggesting that the studied rocks were formed in an arc-forearc tectonic setting.Our new biostratigraphic data indicate this arc-forearc setting was active in the Early Cretaceous.Previous tectonic interpretations suggested that the Nain ophiolites formed,in a Late Cretaceous backarc basin located in the south of the CEIM(the so-called Nain-Baft basin).However,recent studies showed that the CEIM underwent a counter-clockwise rotation in the Cenozoic,which displaced the Nain and Ashin ophiolites in their present day position from an original northeastward location.This evidence combined with our new data and a comparison of the chemical features of volcanic rocks from different ophiolites around the CEIM allow us to suggest that the Nain-Ashin volcanic rocks and dykes were formed in a volcanic arc that developed on the northern margin of the CEIM during the Early Cretaceous in association with the subduction,below the CEIM,of a Neo-Tethys oceanic branch that was existing between the CEIM and the southern margin of Eurasia.As a major conclusion of this paper,a new geodynamic model for the Cretaceous evolution of the CEIM and surrounding Neo-Tethyan oceanic basins is proposed.  相似文献