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1.
The Impact of Human Activities on CO2 Intake by Carbonate Weathering: A Case Study of Conglin Karst Ridge-trough at Fuling Town,Chongqing, China 下载免费PDF全文
Chang-li LIU Chao SONG Hong-bing HOU Xiu-yan WANG Yun ZHANG Jun-kun WANG Jian-mei JIANG Li-xin PEI Bo SONG 《地下水科学与工程》2014,2(1):29-38
The chemical weathering can consume atmosphere/soil CO2. Human activities such as pollution, fertilization and acid precipitation have exerted a large impact on CO2 intake by carbonate weathering. Thus, based on the analysis on chemical component change of the karst groundwater in the karst ridge watershed of Conglin Village, Fuling District of Chongqing City, the influence of human activities such as fertilization, sewage discharges from mustard tuber processing, breeding industry and acid rain precipitation on carbonate weathering and CO2 intake in 1980, 2003 and 2006 was studied. The results showed that CO2 intake by carbonate rock declined with year. Because H+ derived from acid sewage discharge, fertilization and acid precipitation reacted with carbonate rock when mustard tuber production and swine breeding were developed fleetly after 2000 as well as the burning amount of high-sulfur coal augmented persistently, which led to the increase of (Ca2++Mg2+)/HCO3-. The difference on charge between Ca2++Mg2+ and HCO3- was balanced by NO3-+SO42-. The control on pollution and acid rain, especially the pre-neutralization of acid waste water, would rejuvenate the atmospheric CO2 intake strength of carbonate weathering besides the protection of water and soil environment 相似文献
2.
Five commercially available in Estonia brands of bottled water have been analysed for 59 chemical elements by ICP-QMS and ICP-AES techniques to assess the quality of domestic mineral waters in scope of the European Groundwater Geochemistry Project initiated by the Geochemistry Expert Group of EuroGeoSurveys. Contents of 9 cations and anions, pH and electrical conductivity (EC) were measured in the bottled mineral waters by IC, titration and photometric methods. The data showed a significant difference between natural undiluted mineral water (Värska Originaal) characterised by the highest values of pH, EC and majority of trace elements studied, and other domestic waters sold in Estonia. 相似文献
3.
Chemical data are used to clarify the hydrogeological regime in the Mafraq area in northern Jordan, as well as to determine
the status of water quality in the area. Groundwater from the shallow aquifer in the Mafraq area can be divided into two major
groups according to geographical locations and chemical compositions. Water in the basaltic eastern part of the study area
is characterized by the dominance of chloride, sulfate, sodium, and potassium, whereas waters in the limestone aquifers in
the west are dominated by the same cations but have higher concentrations of bicarbonate. Stable isotopes show that the shallow
aquifers contain a single water type which originated in a distinct climatic regime. This water type deviates from the Global
Meteoric Water Line (MWL), as well as from the eastern Mediterranean meteoric water line. The waters are poor in tritium,
and thus can be considered generally older than 50 years. Chemical mass balance models suggest that water is moving from the
west towards the north of the study area. This suggests that waters from the different basins are separated from each other.
Degradation of water quality can be attributed to agricultural fertilizers in most cases, although the waste-water treatment
plant at Khirbet es Samra is a contributor to pollution in the southwestern part of the study area.
Received: 20 August 1997 · Accepted: 3 February 1998 相似文献
4.
5.
Zhou Haiyan Zhou Xun Chai Rui Yu Lan Liu Chunhui Li Liangping 《Environmental Geology》2008,53(7):1483-1489
Thermal groundwater occurs in bedrock aquifers consisting of the dolomite of the Wumishan Group of the Jixianin System and
the Cambrian carbonate in the Xiaotangshan geothermal field near the northern margin of the North China Plain, China. The
hot water in the geothermal field of basin-type discharges partly in the form of the Xiaotangshan hot spring under natural
conditions. The hot water has TDS of less than 600 mg/L and is of Na·Ca-HCO3 type. The geothermal water receives recharge from precipitation in the mountain area with elevation of about 500 m above
sea level to the north of the spring. Thermal groundwater flows slowly south and southeast through a deep circulation with
a residence time of 224 years estimated with the Ra–Rn method. The Xiaotangshan hot spring dried up in the middle of the 1980s
owing to the increasing withdrawal of the hot water in the geothermal field in the past decades. The water level of the geothermal
system still falls continually at an annual average rate of about 2 m, although water temperature changes very little, indicating
that the recharge of such a geothermal system of basin-type is limited. Over-exploitation has a dramatic impact on the geothermal
system, and reduction in exploitation and reinjection are required for the sustainable usage of the hot water. 相似文献
6.
Contributions of boron isotopes to understanding the hydrogeochemistry of the coastal detritic aquifer of Castellón Plain,Spain 总被引:1,自引:0,他引:1
The Castellón Plain alluvial aquifer, Spain, is intensively exploited to meet the demand for agricultural irrigation and industrial water supply. The geochemistry of its groundwater shows complex salinization in the northern and southern parts of the aquifer, with significant pollution from human origin in the central portion. Boron content and B isotope geochemistry are useful for distinguishing between various sources of pollution and their relative importance in different parts of this aquifer. Boron concentrations in the groundwater vary between 0.01 and 0.85 mg/L. In the more saline groundwaters, found at the northern and southern ends of the study area, the presence of B is linked to inputs from seawater and water with a calcium-magnesium sulphate facies, which feed the aquifer and clearly influence the chemistry of its waters. Evidence of B adsorption processes in some samples is shown by the low B/Cl ratios and the high values of δ11B. In the central portion of the aquifer, the high B/Cl ratios and the strongly negative δ11B are related to pollution of human origin. 相似文献
7.
Environmental isotopic and hydrochemical study of groundwater in the Ejina Basin,northwest China 总被引:5,自引:0,他引:5
The study investigates the groundwater evolution and its residence time in the Ejina Basin, northwest China according to isotope
and hydrochemical analyses results. The groundwater chemistry is mainly controlled by the dissolution of halite, Glauber’s
salt, gypsum, dolomite and calcite, also influenced by other processes such as evaporation, ion exchange, and deposition.
Based on tritium content in atmospheric precipitation and by adopting a model with exponential time distribution function,
the mean residence time of the unconfined aquifer groundwater with fairly high tritium activities (21–49 TU) is evaluated.
The results show that these groundwaters have low residence time (5–120 years) and are renewable. In contrast, the deep confined
groundwaters are tritium-free and radiocarbon values range from 18.3 to 26.7 pmc. According to the most commonly used 14C correction models, the radiocarbon groundwater ages were calculated which yield ages of approximately 4,087–9,364 years
BP. Isotopic signatures indicate formation of deep confined groundwaters in a colder and wetter climate during the late Pleistocene
and Holocene. It is suggested that long-term, rational water usage guide should be set up for the Heihe River Basin as a whole
to permit a considerable discharge to the Ejina Basin. 相似文献
8.
Julie C. Gattacceca Christine Vallet-Coulomb Adriano Mayer Christelle Claude Olivier Radakovitch Enrico Conchetto Bruno Hamelin 《Journal of Hydrology》2009,378(1-2):46-61
The coastal plain bordering the southern Venice Lagoon is a reclaimed lowland characterized by high subsidence rate, and ground level and water-table depth below sea level. In this agricultural region, where the surface hydrologic network is entirely artificially controlled by irrigation/drainage canals, salinization problems have long been encountered in soils and groundwaters. Here we use isotopic and geochemical tracers to improve our understanding of the origin of salinization and mineralization of the semi-confined aquifer (0–40 m), and the freshwater inputs to this hydrological system. Water samples have been collected at different seasons in the coastal Adriatic Sea, lagoon, rivers and irrigation canals, as well as in the semi-confined aquifer at depths between 12 and 35 m (14 boreholes), and in the first confined aquifer (three boreholes drilled between 40 and 80 m depth). Stable isotopes (δ18O and δD) and conductivity profiles show that direct saline intrusion from the sea or the lagoon is observed only in a restricted coastal strip, while brackish groundwaters are found over the entire topographic and piezometric depression in the centre of the study area. Fresh groundwaters are found only in the most western zone. The sharp isotopic contrast between the western and central regions suggests disconnected hydrological circulations between these two parts of the shallow aquifer. The border between these two regions also corresponds to the limits of the most strongly subsiding zone.Our results can be interpreted in terms of a four end-member mixing scheme, involving (1) marine water from the lagoon or the open sea, (2) alpine and pre-alpine regional recharge waters carried either by the main rivers Adige, Bacchiglione and Brenta (irrigation waters) or by the regional groundwater circulation, (3) local precipitation, and (4) evaporated waters infiltrated from the surface. Infiltration from the surface is also revealed by the stratification of the electrical conductivity profiles, showing that the brackish groundwaters are overlain by a shallow layer of less saline water all over the central depression. In the first confined aquifer, the groundwaters have isotopic compositions similar to the deep groundwaters of the Venetian confined aquifers (40–400 m depth). The isotopic data and the Br/Cl ratio show that the origin of the salinization of the phreatic aquifer can be ascribed to seawater intrusion alone, with no indication of the involvement of deep brines (identified at 450 m depth) in the process.The chemical composition of the saline and brackish groundwaters is characterized by an excess of sodium and a deficit of calcium compared to conservative mixing between fresh groundwaters and seawater. This suggests that the phreatic aquifer is progressively freshening, as a consequence of the beneficial influence of the extensive irrigation/drainage network, including raised canals acting as a hydraulic barrier along the coast. This freshening tendency may have been lasting since the reclamation in the mid-twentieth century, and has probably been accelerated by the ban on groundwater abstraction since the 1970s. 相似文献
9.
Hydrogeochemical investigations and groundwater provinces of the Friuli Venezia Giulia Plain aquifers,northeastern Italy 总被引:2,自引:0,他引:2
Water resources are a key factor, particularly for the planning of the sustainable regional development of agriculture, as
well as for socio-economic development in general. A hydrochemical investigation was conducted in the Friuli Venezia Giulia
aquifer systems to identify groundwater evolution, recharge and extent of pollution. Temperature, pH, electric conductivity,
total dissolved solids, alkalinity, total hardness, SAR, Ca2+, Na+, K+, Mg2+, Cl−, SO4
2−, NO3
−, HCO3
−
, water quality and type, saturation indexes and the environmental stable isotope δ18O were determined in 149 sampling stations. The pattern of geochemical and oxygen stable isotope variations suggests that
the sub-surface groundwater (from phreatic and shallow confined aquifers) is being recharged by modern precipitations and
local river infiltrations. Four hydrogeological provinces have been recognised and mapped in the Friuli Venezia Giulia Plain
having similar geochemical signatures. These provinces have different degrees of vulnerability to contamination. The deep
confined groundwater samples are significantly less impacted by surface activities; and it appears that these important water
resources have very low recharge rates and would, therefore, be severely impacted by overabstraction. 相似文献
10.
A long-term study on the chemistry of percolating waters in a very large touristic karst cave (Grotta Gigante, northern Italy)
was carried out in order to define recharge zones, flowpaths, and possible anthropogenic contamination from the neighboring
area. On the basis of a multivaried analysis of the chemical parameters, a discrimination of the dripping points was attempted.
Percolation waters whose recharge zone is in the northernmost sector of the cave appeared permanently affected by the anthropic
settlements and agricultural activity on the ground surface.
Received: 28 April 1997 · Accepted: 3 February 1998 相似文献