西准噶尔红山地区晚古生代赞岐岩锆石U Pb年代学、地球化学特征及其地质意义   总被引：1，自引：0，他引：1  

马飞宙  陈宣华  徐盛林  马芬  韩乐乐  丁伟翠  王叶 《地质学报》2020,94(5):1462-1481

中亚造山带西部西准噶尔地区红山花岗岩体内部发育多期似岩墙状安山质暗色条带,LA-ICP-MS锆石U-Pb同位素定年和岩石化学与同位素分析表明,它们具有不同的形成年龄、相同的源区和相似的形成过程。其中,具有不规则状或环状形态的暗色条带,其锆石U-Pb年龄为319.1±2.9 Ma和313.3±2.4 Ma,远大于红山岩体花岗岩锆石结晶年龄(305～301Ma),可能是红山岩体侵位过程中所捕掳的围岩;具有线性展布特征的安山质暗色条带,其锆石U-Pb年龄为295±2Ma,形成于红山岩体侵位之后,构成伸展岩墙群。红山岩体中的安山质暗色条带和线状岩墙群具有相似的岩石化学组成,富SiO_2(56.48%～63.09%)、MgO(3.56%～6.31%),具有高的Mg#值(51.74～62.40)及Na_2O/K_2O值(1.34～3.43);球粒陨石标准化稀土元素(REE)配分模式呈明显的右倾型,富集轻稀土元素(LREE)和大离子亲石元素(LILE)Rb、K、Ba、U、Sr,亏损高场强元素(HFSE)Th、Nb、Ce、P和重稀土元素,具较弱的负铕异常;其同位素组成特征为(~(87 )Sr/~(86 )Sr)i=0.703295～0.703620,(~(143) Nd/~(144) Nd)i=0.512612～0.512618,εNd(t)=6.91～7.62,(~(206) Pb/~(204) Pb)t为17.6883～17.9876,(~(207) Pb/~(204) Pb)t为15.5313～15.5686,(~(208)Pb/~(204)Pb)t为37.4460～38.0581。它们具有与赞岐岩类似的地球化学特征,总体表现出与弧岩浆作用相关的地球化学特征,可能具有共同的物质来源,为准噶尔洋板片俯冲消减后同一地幔源区在不同阶段的产物。其中,形成于弧岩浆作用时期的赞岐岩(319～313 Ma),构成与岛弧花岗岩类伴生的环状似岩墙状安山质暗色条带;形成于后造山伸展岩浆作用晚期的赞岐岩(～295Ma),构成与达拉布特左行走滑作用相关的陆内伸展岩墙群。安山质暗色条带(岛弧火山作用)、红山岩体(后造山伸展)和线状岩墙群(陆内伸展)记录了西准噶尔红山地区洋陆转换的全过程。  相似文献   

2019年长宁M_S6.0地震邻区分钟采样地电场分析     

王玮铭  谭大诚 《地震》2020,40(3):41-51

2019年6月17日四川宜宾市长宁县发生M_S6.0地震, 分析震中周边600 km内7个地电场台站观测分钟值数据, 获知震前2个月左右红格等6个台站地电场均存在不同方位之间、 同方位长短极距之间的相关系数持续降低, 6月17日这些相关系数基本降至最低, 反映出这6个场地的地电场在此次地震前后发生了非均匀变化; 同时, 这6个台站的地电场优势方位角出现了约45°或90°跃变, 并伴有显著发散或收窄现象。分析表明长宁M_S6.0地震前后, 这6个场地的多种地电场异常现象具有局部场地效应、 时间准同步性。  相似文献   

A Revisited Purification of Li for ‘Na Breakthrough’ and its Isotopic Determination by MC‐ICP‐MS     

Lin Xu  Chongguang Luo  Hanjie Wen 《Geostandards and Geoanalytical Research》2020,44(1):201-214

The accurate and precise determination of Li isotopic composition by MC‐ICP‐MS suffers from the poor performance of traditional column chromatography. Previously established chromatographic processes cannot completely remove Na in complex geological samples, which is currently interpreted to be a result of Na breakthrough. In this study, Na breakthrough during single‐column purification was found to differ between simply artificial Na‐containing sample solutions, where a little Na residue was found, and silicate rocks, where a large amount of breakthrough occurred. A revised two‐step column purification for Li using 0.5 and 0.3 mol l^?1 HCl as eluents was designed to remove the Na. This modified method achieves high‐efficiency Li purification from Na and consequently avoiding high Na/Li ratio interference for subsequent MC‐ICP‐MS analyses. The proposed method was validated by the analysis of a series of reference materials, including Li₂CO₃ (IRMM‐016, ‐0.10‰), basalt (BCR‐2: 2.68‰; BHVO‐2: 4.39‰), andesite (AGV‐2: 6.46‰; RGM‐2: 2.59‰), granodiorite (GSP‐2: ?0.87‰) and seawater (CASS‐5, 30.88‰). This work reports early Na appearance prior to the elution curves in chromatography and emphasises its influence for subsequent Li isotope measurement. Based on the findings, the established two‐step method would be more secure than single‐column chemistry for Li purification.  相似文献   

2020年5月6日新疆乌恰5.0级和5月9日柯坪5.2级地震总结     

马亚伟  宋治平  杨文  解孟雨  苑争一  钟骏  李美  姚丽  邓世广  臧阳 《地震地磁观测与研究》2020,41(4):179-192

2020年5月6日、5月9日，新疆地区南天山西段先后发生乌恰5.0级和柯坪5.2级地震，系统总结2次地震发生前出现的地震活动和地球物理观测异常，其中：①地震活动：震前存在调制地震集中、地震窗、5级以上地震成组等中短期异常；②地球物理观测：2次地震震中附近震前出现形变、电磁和流体观测异常，其中形变异常3项、电磁异常4项、流体异常1项，主要分布在柯坪5.2级地震震中附近。通过对2次地震序列进行跟踪，发现：乌恰5.0级地震余震较少，震后60天内共记录M_L 3.0以上余震4次，最大震级为M_L 4.5；柯坪5.2级地震后余震较丰富，震后60天内共记录M_L 3.0以上余震10次，最大震级为M_L 4.7，计算得到序列h值为1.6，b值为0.73。综合分析认为，2020年5月新疆地区2次5级以上地震前存在的地震活动异常较少，但区域地震活动水平较强，主要存在具有中短期指示意义的地球物理观测异常。  相似文献   

2020年云南省巧家县M_S 5.0地震强震动记录初步分析     

赵昆  林国良  杨黎薇  崔建文 《地震地磁观测与研究》2020,41(3):200-208

2020年5月18日云南省巧家县发生M_S5.0地震,中国数字强震动台网的13个强震台站和昭通简易烈度计示范项目建设的43个烈度计台站,共接收168条强震动记录,经常规处理,绘制震区加速度峰值等值线图,并与云南地区常用地震动衰减关系进行对比,分析加速度峰值较大的几个台站频谱特性,计算地震动能量持时,讨论中小地震中高加速度峰值/低震害现象的成因,得到以下结论:(1) PGA等值线图形状较为平滑,其长轴呈NW—SE向展布;(2)云南地区常用地震动衰减关系预测值总体衰减趋势与观测值一致,但在近场(0—30 km)时,预测值基本偏小;(3)加速度峰值较大的几个台站记录主频集中在1—5 Hz;(4)小河镇台记录的能量持时较短,说明能量衰减较快,属脉冲型记录,不会对建筑物造成较大破坏。  相似文献   

2020年1月25日西藏丁青5.1级地震总结     

臧阳  薛艳  姚琪  解孟雨  苑争一  王阅兵  马亚伟  张小涛 《地震地磁观测与研究》2020,41(3):162-173

2020年1月25日，藏东昌都丁青地区发生5.1级地震，尽管此次地震发生在监测能力较低地区，但震前仍监测到小震调制比高值、低b值等地震活动中短期异常。文中系统总结了地震构造背景、震源物理参数、序列特征以及震前出现的地震活动和地球物理观测等异常，结果发现：震源机制解显示为拉张型破裂，最近断裂为巴青—类乌齐断裂；序列活动特征、序列h值和b值计算结果显示，此次地震为主余型地震序列。目前，藏东地区仍存在一些地震活动和地球物理观测异常，表明该地区存在发生6级以上地震的强震背景，丁青5.1级地震的发生未能缓解该地区强震危险性。  相似文献   

The δ60/58Ni Values of Twenty‐Six Selected Geological Reference Materials     

Weihan Li  Jian‐Ming Zhu  Decan Tan  Guilin Han  Zhouqiao Zhao  Guangliang Wu 《Geostandards and Geoanalytical Research》2020,44(3):523-535

The high‐precision δ^60/58Ni values of twenty‐six geological reference materials, including igneous rocks, sedimentary rocks, stream sediments, soils and plants are reported. The δ^60/58Ni values of all samples were determined by double‐spike MC‐ICP‐MS (Nu Plasma III). Isotope standard solution (NIST SRM 986) and geological reference materials (BHVO‐2, BCR‐2, JP‐1, PCC‐1, etc.) were used to evaluate the measurement bias and intermediate precision over a period of six months. Our results show that the intermediate precision of Ni isotope determination was 0.05‰ (2s, n = 69) for spiked NIST SRM 986 and typically 0.06‰ for actual samples, and the δ^60/58Ni _{NIST SRM 986} values were in excellent agreement with previous studies. Eighteen high‐precision Ni isotope ratios of geological reference materials are first reported here, and their δ^60/58Ni values varied from ?0.27‰ to 0.52‰, with a mean of 0.13 ± 0.34‰ (2s, n = 18). Additionally, SGR‐1b (0.56 ± 0.04‰, 2s), GSS‐1 (?0.27 ± 0.06‰, 2s), GSS‐7 (?0.11 ± 0.01‰, 2s), GSD‐10 (0.46 ± 0.06‰, 2s) and GSB‐12 (0.52 ± 0.06‰, 2s) could potentially serve as candidate reference materials for Ni isotope fractionation and comparison of Ni isotopic compositions among different laboratories.  相似文献   

Chemical Procedures for Rhenium Extraction from Geological Samples: Optimising the Anion Resin Bead Clean‐up Step     

Gang Yang  Aaron Zimmerman  Nicole C. Hurtig  Svetoslav V. Georgiev  Vineet Goswami  Judith L. Hannah  Holly J. Stein 《Geostandards and Geoanalytical Research》2020,44(2):231-242

Rhenium–osmium geochronometry for samples with low Re and complex matrices requires improved Re extraction methods. Here, we investigate plausible controls on efficiency and efficacy of Re extraction during our anion resin bead purification. Four different protocols are compared, each isolating a single variable to test. Rhenium concentrations for solutions at each step of each protocol document differences in chemical recovery/yield. The negative‐thermal ionisation mass spectrometry (N‐TIMS) signal intensity serves as a proxy for Re yield and purity. These data document correlations between the N‐TIMS signal intensity and (a) the duration of anion resin bead conditioning prior to loading with Re‐bearing solution, and (b) both duration and strength of nitric acid used during rinsing of the Re‐loaded anion resin bead. The optimal protocol improved Re signal intensity around fourteen times compared with our current Re extraction protocol, an aggregate of 2.4 times improvement in chemical recovery (yield) and 5.8 times improvement in emission efficiency (purity). Repeated N‐TIMS isotopic measurements on our in‐house Re standard solution (1407) verify that our optimal protocol‐3 does not fractionate Re isotopes. The improved anion resin bead method considerably lowers the Re detection limit and allows Re‐Os isotopic analysis of picogram‐level Re hosted in geological samples with complex matrices.  相似文献   

Barium Isotopic Compositions in Thirty‐Four Geological Reference Materials Analysed by MC‐ICP‐MS     

Ya‐Jun An  Xin Li  Zhao‐Feng Zhang 《Geostandards and Geoanalytical Research》2020,44(1):183-199

Measurement of Ba isotope ratios of widely available reference materials is required for interlaboratory comparison of data. Here, we present new Ba isotope data for thirty‐four geological reference materials, including silicates, carbonates, river/marine sediments and soils. These reference materials (RMs) cover a wide range of compositions, with Ba mass fractions ranging from 6.4 to 1900 µg g^?1, SiO₂ from 0.62% to 90.36% m/m and MgO from 0.08% to 41.03% m/m. Accuracy and precision of our data were assessed by the analyses of duplicate samples and USGS rock RMs. Barium isotopic compositions for all RMs were in agreement with each other within uncertainty. The variation of δ^138/134Ba in these RMs was up to 0.7‰. The shale reference sample, affected by a high degree of chemical weathering, had the highest δ^138/134Ba (0.37 ± 0.03‰), while the stream sediment obtained from a tributary draining carbonate rocks was characterised by the lowest δ^138/134Ba (?0.30 ± 0.05‰). Geochemical RMs play a fundamental role in the high‐precision and accurate determination of Ba isotopic compositions for natural samples with similar matrices. Analyses of these RMs could provide universal comparability for Ba isotope data and enable assessment of accuracy for interlaboratory data.  相似文献   

Development and Re‐Evaluation of Tourmaline Reference Materials for In Situ Measurement of Boron δ Values by Secondary Ion Mass Spectrometry     

Katharina Marger  Matthieu Harlaux  Andrea Rielli  Lukas P. Baumgartner  Andrea Dini  Barbara L. Dutrow  Anne‐Sophie Bouvier 《Geostandards and Geoanalytical Research》2020,44(3):593-615

Six tourmaline samples were investigated as potential reference materials (RMs) for boron isotope measurement by secondary ion mass spectrometry (SIMS). The tourmaline samples are chemically homogeneous and cover a compositional range of tourmaline supergroup minerals (primarily Fe, Mg and Li end‐members). Additionally, they have homogeneous boron delta values with intermediate precision values during SIMS analyses of less than 0.6‰ (2s). These samples were compared with four established tourmaline RMs, that is, schorl IAEA‐B‐4 and three Harvard tourmalines (schorl HS#112566, dravite HS#108796 and elbaite HS#98144). They were re‐evaluated for their major element and boron delta values using the same measurement procedure as the new tourmaline samples investigated. A discrepancy of about 1.5‰ in δ¹¹B was found between the previously published reference values for established RMs and the values determined in this study. Significant instrumental mass fractionation (IMF) of up to 8‰ in δ¹¹B was observed for schorl–dravite–elbaite solid solutions during SIMS analysis. Using the new reference values determined in this study, the IMF of the ten tourmaline samples can be modelled by a linear combination of the chemical parameters FeO + MnO, SiO₂ and F. The new tourmaline RMs, together with the four established RMs, extend the boron isotope analysis of tourmaline towards the Mg‐ and Al‐rich compositional range. Consequently, the in situ boron isotope ratio of many natural tourmalines can now be determined with an uncertainty of less than 0.8‰ (2s).  相似文献