藏北昂吾地区超基性岩的蛇纹石化和磁铁矿化过程及影响因素     

李静超  赵涛  刘治博  林赟  邵华胜  袁国礼  宋扬 《岩石学报》2019,35(7):2158-2172

班公湖-怒江缝合带广泛分布超基性岩及蛇纹石化超基性岩,已有研究表明它们与区域成矿关系密切,其蛇纹石化过程使一些元素活化并具有一定的成矿潜力。位于班-怒带中段的昂吾地区蛇纹石化超基性岩主要矿物成分有橄榄石、单斜辉石、铬铁矿、利蛇纹石、磁铁矿和绿泥石等,原岩恢复表明该超基性岩为单辉橄榄岩。镜下鉴定、背散射电子图像、能谱成分分析和电子探针分析结果显示单辉橄榄岩的蛇纹石化及蚀变过程可分为三个阶段:(Ⅰ)以形成相对富铁蛇纹石(Mg#=75～88)为主,基本无磁铁矿析出;(Ⅱ)形成相对富镁的蛇纹石(Mg# 90),析出磁铁矿;(Ⅲ)蛇纹石进一步蚀变成绿泥石。热力学模拟及多组分矿物相平衡图表明,在蛇纹石化过程中,昂吾地区超基性岩中的辉石脱硅致使反应体系SiO_2活度升高,限制了磁铁矿的生成。同时也发现,在利蛇纹石稳定存在的温度区间内(100～300℃),本研究的蛇纹石化体系温度倾向高值区,不利于磁铁矿的析出。进而探讨了原岩成分、反应体系SiO_2活度及温度等因素对蛇纹石化过程中磁铁矿析出的影响。本研究有助于理解班-怒带内超基性岩的蛇纹石化过程及磁铁矿化机制。  相似文献   

高精度磁测在维西拉嘎洛铁矿勘查中的应用     

王进朝  李石磊  燕永锋  苏昌学  于斌 《云南地质》2011,30(3):332-335,361

测区引起磁异常的有磁铁矿(化)体和玄武岩,二者之间的磁性差异很大,为磁法勘探寻找磁铁矿奠定物性基础。通过磁法勘探的野外作业和室内数据整理分析,并经异常推断解释圈出矿体5个,并经坑探验证有效。  相似文献   

云南西双版纳曼远铁矿矿床地质     

孙云堂 《云南地质》2011,30(3):321-322,311

曼远铁矿以磁铁矿、赤铁矿、磁赤铁矿为主,赋存于澜沧群勐井山组上段中部。该组地层中夹多层中性—基性火山岩、火山凝灰岩,属典型的火山沉积变质型铁矿。  相似文献   

东昆仑迪木那里克铁矿地质特征与找矿标志   总被引：1，自引：0，他引：1  

胡秀军  夏昭德  丁海波  张朋 《亚热带资源与环境学报》2011,6(2):49-53

迪木那里克铁矿位于阿尔金大断裂南侧,矿体主要赋存于中-上奥陶统祁曼塔格群浅变质的碎屑岩-火山碎屑岩中.矿体多呈似层状、条带状产出,部分矿体塑性变形较强,矿体与地层产状基本一致,层控作用比较明显;矿石主要为条带状石英-磁铁矿和块状磁铁矿矿石;矿石品位较低（TFe=20%～40%）;围岩蚀变特征明显.该铁矿属沉积变质型铁矿...  相似文献   

LA-ICP-MS Analysis of Magnetite and Application in Genesis of Mineral Deposit     

Huang Ke  Zhu Mingtian  Zhang Lianchang  Li Wenjun  Gao Bingyu 《地球科学进展》2017,32(3):262-275

Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS) is well characterized by the in-situ, real time, lower limit of detection and high space resolution, etc. Therefore, it is more excellent in the analysis of trace element for varied minerals in comparison to other micro-zone analysis technologies. Magnetite as a common mineral from different deposits and rocks has been focused on chemical compositions by researchers worldwide. In fact, as the insignificant matrix effect for most elements in magnetite, analysis results could be calculated effectively against Fe-rich silicate glass as the reference material. Therefore, researches on trace element distribution of magnetite have been developed rapidly in recent years, and it has a wide application prospect in reflecting the condition of ore-forming, discriminating different deposit types and indicating prospecting exploration. Comparing varied previous discrimination diagrams about magnetite via collecting trace element data from available literatures based on 25 deposits, we found that there was an urgent need for further detailing and reexamining the boundary of fields representing different genetic types, and it was vital for interpreting the data through carefully petrographical observation before analysis. In addition, we discussed several complex physicochemical factors, which would influence the element concentration of magmatite in igneous and hydrothermal processes, such as melt/fluid composition, temperature, cooling rate, pressure, oxygen fugacity, sulfur fugacity and silica activity. In magma stage, Magnetite’s components are closely related to melts composition and differentiation, while fluid features would also significantly change magnetie's components. Furthermore, there is serious interference for discriminating the genesis of magnetite because of late stage fluids and equilibrium again in subsolidus condition. This paper reviewed the developments of trace elements analysis by LA-ICP-MS and important applications about magnetite in mineral deposit so that unique thoughts for the research on mineralization and ore-forming processes could be obtained.  相似文献   

Presumed magnetic biosignatures observed in magnetite derived from abiotic reductive alteration of nanogoethite     

Jessica L. Till  Yohan Guyodo  France Lagroix  Guillaume Morin  Nicolas Menguy  Georges Ona-Nguema 《Comptes Rendus Geoscience》2017,349(2):63-70

The oriented chains of nanoscale Fe-oxide particles produced by magnetotactic bacteria are a striking example of biomineralization. Several distinguishing features of magnetite particles that comprise bacterial magnetosomes have been proposed to collectively constitute a biosignature of magnetotactic bacteria (Thomas-Keprta et al., 2001). These features include high crystallinity, chemical purity, a single-domain magnetic structure, well-defined crystal morphology, and arrangement of particles in chain structures. Here, we show that magnetite derived from the inorganic breakdown of nanocrystalline goethite exhibits magnetic properties and morphologies remarkably similar to those of biogenic magnetite from magnetosomes. During heating in reducing conditions, oriented nanogoethite aggregates undergo dehydroxylation and transform into stoichiometric magnetite. We demonstrate that highly crystalline single-domain magnetite with euhedral grain morphologies produced abiogenically from goethite meets several of the biogenicity criteria commonly used for the identi?cation of magnetofossils. Furthermore, the suboxic conditions necessary for magnetofossil preservation in sediments are conducive to the reductive alteration of nanogoethite, as well as the preservation of detrital magnetite originally formed from goethite. The findings of this study have potential implications for the identification of biogenic magnetite, particularly in older sediments where diagenesis commonly disrupts the chain structure of magnetosomes. Our results indicate that isolated magnetofossils cannot be positively distinguished from inorganic magnetite on the basis of their magnetic properties and morphology, and that intact chain structures remain the only reliable distinguishing feature of fossil magnetosomes.  相似文献   

Magnetite geochemistry of the Longqiao and Tieshan Fe–(Cu) deposits in the Middle-Lower Yangtze River Belt: Implications for deposit type and ore genesis     

《Ore Geology Reviews》2017

Magnetite is a common mineral in many ore deposits and their host rocks, and contains a wide range of trace elements (e.g., Ti, V, Mg, Cr, Mn, Ca, Al, Ni, Ga, Sn) that can be used for deposit type fingerprinting. In this study, we present new magnetite geochemical data for the Longqiao Fe deposit (Luzong ore district) and Tieshan Fe–(Cu) deposit (Edong ore district), which are important magmatic-hydrothermal deposits in eastern China.Textural features, mineral assemblages and paragenesis of the Longqiao and Tieshan ore samples have suggested the presence of two main mineralization periods (sedimentary and hydrothermal) at Longqiao, among which the hydrothermal period comprises four stages (skarn, magnetite, sulfide and carbonate); whilst the Tieshan Fe–(Cu) deposit comprises four mineralization stages (skarn, magnetite, quartz-sulfide and carbonate).Magnetite from the Longqiao and Tieshan deposits has different geochemistry, and can be clearly discriminated by the Sn vs. Ga, Ni vs. Cr, Ga vs. Al, Ni vs. Al, V vs. Ti, and Al vs. Mg diagrams. Such difference may be applied to distinguish other typical skarn (Tieshan) and multi-origin hydrothermal (Longqiao) deposits in the MLYRB. The fluid–rock interactions, influence of the co-crystallizing minerals and other physicochemical parameters, such as temperature and fO₂, may have altogether controlled the magnetite trace element contents of both deposits. The Tieshan deposit may have had higher degree of fO₂, but lower fluid–rock interactions and ore-forming temperature than the Longqiao deposit. The TiO₂–Al₂O₃–(MgO + MnO) and (Ca + Al + Mn) vs. (Ti + V) magnetite discrimination diagrams show that the Longqiao Fe deposit has both sedimentary and hydrothermal features, whereas the Tieshan Fe–(Cu) deposit is skarn-type and was likely formed via hydrothermal metasomatism, consistent with the ore characteristics observed.  相似文献   

云南金平太平桥铁矿矿床地质及远景预测     

孙云堂  陈斌 《云南地质》2012,(2):208-210

受红河右旋走滑深大断裂构造控制,铁矿床主要赋存于华力西期侵入基性-超基性岩杂岩体内,成矿专属性明显,矿床属晚期岩浆结晶分异型磁铁矿矿床。  相似文献   

Removal of Ni(II) from Aqueous Solutions by Nanoscale Magnetite     

Xue Song Wang  Jun Jun Ren  Hai Jie Lu  Lei Zhu  Fei Liu  Qian Qian Zhang  Juan Xie 《洁净——土壤、空气、水》2010,38(12):1131-1136

Magnetite nanoparticles were applied to remove Ni(II) from aqueous solutions as a function of pH, contact time, supporting electrolyte concentration, and analytical initial Ni(II) concentration. The highly crystalline nature of the magnetite structure with diameter of around 10 nm was characterized with transmission electron microscopy (TEM) and X‐ray diffractometry (XRD). The surface area was determined to be 115.3 m²/g. Surface chemical properties of magnetite at 25°C in aqueous suspensions were investigated. The point of zero charge (pHzpc) was found to be 7.33 and the intrinsic acidity constants (${\rm p}K_{{\rm a}1}^{{\rm s}} $ and ${\rm p}K_{{\rm a}2}^{{\rm s}} $ ) were found to be 9.3 and 5.9, respectively. The surface functional groups were investigated with Fourier transform‐infrared spectroscopy (FTIR) as well. Batch experiments were carried out to determine the adsorption kinetics and mechanism of Ni(II) by these magnetite nanoparticles. The adsorption process was found to be pH dependent. In NaCl solutions, Ni(II) adsorption increased with increasing ionic strength while in NaClO₄ solutions, Ni(II) adsorption exhibited little dependence on the ionic strength of the solution. The adsorption process better followed the pseudo‐second order equation and Freundlich isotherm.  相似文献   

攀枝花钒钛磁铁矿区土壤重金属地球化学特征及污染评价   总被引：9，自引：0，他引：9  

庹先国  徐争启  滕彦国  穆克亮 《矿物岩石地球化学通报》2007,26(2):127-131

为了解攀枝花钒钛磁铁矿区土壤重金属的特征及污染程度,采集了矿区表层土壤样品和两个土壤剖面,用多种分析方法有针对性地分析了Cu、Pb、Zn、Ti、V、Co、Ni、As、Cd、Cr、Hg、Mn十二种元素。在分析分布特征基础上,对重金属进行了污染物负荷指数评价,结果发现:1)攀枝花钒钛磁铁矿矿区表层土壤大部分属于中等污染,少数属于强污染,个别达到了极强污染;2)Co、V、Cu、Cd、Ti几种元素的最高污染系数大,Zn、Mn、Ni、Cr四种元素的最高污染系数次之,Hg、Pb两种元素的最高污染系数较小,As的最高污染系数最小;3)从各区域的污染物负荷指数来看,排土场周围和朱矿采矿场下游附近污染程度较大,远离矿区以及矿区上游污染较小。  相似文献