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Recent improvements in both Infra-red spectroscopy and equilibrator techniqueshave allowed to determine, for the first time, pCO2using simultaneously and continuously both the direct and indirect methods in an estuary where pCO2 values range from 500 to 8500 atm and salinity from 0 to 30. Our results show that both methods are in excellent agreement in the wholeestuary (r2 = 0.999, n = 1075, p < 0.0001). Thus, the NBS (US National Bureau of Standards) scale, although inadequate for seawater samples, is appropriate for estuarine waters and can be applied with confidence to calculate pCO2. 相似文献
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Pritchard Tobin Clark & Guinan 《Monthly notices of the Royal Astronomical Society》1998,299(4):1087-1096
Using improved techniques, high-quality CCD uvbyVI photometry has been obtained for the eclipsing binary HV 982 in the Large Magellanic Cloud (LMC). International Ultraviolet Explorer ultraviolet spectrophotometry was also obtained. These data have been analysed using the Wilson–Devinney synthetic light-curve code and Kurucz low-metallicity model atmospheres as well as the EBOP code. The system is detached and the orbit is eccentric. Apsidal motion is detected with apsidal period 205 ± 7 yr. The effective temperatures of the components are found via flux fitting to be T eff,1 = 28 000 ± 5000 K and T eff,2 = 27 200 ± 5000 K. The large errors result from uncertainties over the appropriate interstellar extinction correction. The system plausibly comprises two ∼ 8 M stars of radius 6–7 R separated by ∼ 30 R. For pedagogical and historical interest, the near simultaneity of the eclipse minima at different wavelengths is used to constrain the constancy of the speed of light with wavelength and the mass of the photon, yielding m γ < 10−41 kg. Because of the great distance to HV 982, this limit is some 102 times smaller than previously achieved with eclipse timings, but it is nevertheless 10 orders of magnitude less stringent than that which is provided by satellite measurements of planetary magnetic fields. 相似文献
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Stephen F. Crowley 《Geostandards and Geoanalytical Research》2010,34(2):193-206
International carbon and oxygen isotope calibration material NBS 19 and reference materials NBS 18, International Atomic Energy Agency (IAEA)-CO-1 and IAEA-CO-8 are prepared from naturally occurring rock specimens of marble and carbonatite. Mineralogical and chemical analysis showed that only NBS 19 and IAEA-CO-1 represent essentially pure samples of calcite containing < and minimal (< 1%) quantities of quartz. In contrast, both NBS 18 and IAEA-CO-8, although primarily composed of calcite, are contaminated by a range of additional phases. NBS 18 was estimated to contain 1% Fe-dolomite and trace (< 1%) quantities of apatite and quartz. IAEA-CO-8 was estimated to contain at least 4% non-carbonate material (including apatite, barite, biotite and magnetite). NBS 18 and IAEA-CO-8 are both derived from samples of carbonatite and the calcite component of each material is characterised by appreciable substitution of Mg + Mn + Sr ± Fe ± Ba (Σ ≈ 14000–15000 μg g-1) for Ca. The observations reported in this study complement data in the literature detailing significant grain-scale isotopic heterogeneity in NBS 18 and IAEA-CO-8. Both data sets highlight the need for careful characterisation of calibration materials prior to distribution. 相似文献
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We studied small perturbations acting on Galilean satellites. Most of them are still not computed in the analytical theories and could probably improve the ephemeris of these satellites which are outside the precision of the observations. We used a numerical method to test the effect of such perturbations. Here are reporting the main results we obtained. 相似文献
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