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1.
蔡敏  严明良  包云轩 《气象科学》2018,38(5):648-658
为了探明PM_(2.5)中水溶性无机离子的来源和气象因子对其浓度变化的影响,利用2012年2、5、8和11月苏州市PM_(2.5)中水溶性无机离子浓度和本站气象观测数据,分析了苏州市水溶性无机离子的时间变化特征,解析了当地PM_(2.5)中水溶性无机离子的主要来源,探讨了气象因素对离子组分的影响。结果表明:(1)苏州市PM_(2.5)中水溶性无机离子年均浓度大小依次为:SO_4~(2-)NO_3~-NH_4~+Na~+Cl~-K~+Ca~(2+)Mg~(2+)F~-;SO_4~(2-)、NH_4~+和NO_3~-为PM_(2.5)中最重要的3种水溶性无机离子物种,其总和占PM_(2.5)总质量浓度的50.9%。各离子的季节浓度特征均为冬季最高、夏季最低。(2)通过运用主成分分析法对苏州市PM_(2.5)中水溶性无机离子进行来源分类解析,发现第一类为二次污染源和生物质燃烧,其贡献率为32.84;第二类为道路扬尘及工业排放,其贡献率为19.99%;第三类为海盐污染,其贡献率为18.43%。(3)通过水溶性无机离子与气象条件的相关性分析发现,风向、风速和温度与水溶性无机离子浓度的相关性较显著,这三者是颗粒物浓度变化的主要影响因子。(4)利用HYSPLIT后向轨迹模式对外来污染物进入苏州市的轨迹进行聚类分析后发现:因受季风气候影响,苏州市外来污染物的输入路径存在明显的季节性变化特征,其中夏半年输送主径源自海上,冬半年主径源自内陆。  相似文献   
2.
PAH concentrations of 61 surface soil samples collected from the Yellow River Delta (YRD), China were measured to determine occurrence levels, sources, and potential toxicological significance of PAHs. The total concentrations of ∑PAHs ranged from 27 to 753 ng/g d.w., with a mean of 118 ± 132 ng/g. The highest concentrations was found in the mid-southern part of the YRD (753 ng/g), which was associated with the oil exploration. The ratios indicated that the PAHs throughout the YRD were mostly of pyrogenic origin; while various sites in mid-southern part in the region were derived mainly from the petrogenic sources. Multivariate statistical analyses supported that the PAHs in surface soils of the YRD were principally from the coal and biomass combustion, petroleum spills, and/or vehicular emissions. The toxic assessment suggested that the PAHs in soils were at low potential of ecotoxicological contamination level for the YRD.  相似文献   
3.
基于PCA和LOGIT模型的网络入侵检测方法   总被引:1,自引:0,他引:1  
针对高维度网络数据进行多类攻击行为检测的需求,提出一种基于PCA和Logit模型的网络入侵检测方法,通过PCA对网络数据降维、简化数据集和多项式Logit模型实现对不同攻击行为的识别并判别其类型。实验结果表明,方法在网络入侵识别上具有较理想的效果。  相似文献   
4.
为了分析海洋生境刀鲚(Coilia nasus)体内及生长环境菌群结构,作者采用免培养16S r DNA的PCR-DGGE指纹图谱技术,对刀鲚鳃、肠道壁、肠道内容物及水体环境中的菌群结构进行了对比分析。结果表明:变性梯度为35%~55%、浓度为8%的聚丙烯酰胺凝胶,150V 60℃下电泳10 h,DGGE带谱的分离效果较好;刀鲚鳃、肠道壁、肠道内容物及水体样品指纹图谱上分别显示出24、19、14和29条信号强度不同的条带;相同样品重复组细菌结构相似度在80%以上,差异不显著;不同样品之间,刀鲚鳃与海水聚为一支,具有较高的相似度为52%,肠壁与肠内容物相似度为41%。样品菌群主要以未培养菌为主,主要包括变形菌、放线菌和厚壁菌。本文首次成功构建海洋生境刀鲚菌群16S r DNA的PCR-DGGE指纹图谱。  相似文献   
5.
由于航空瞬变电磁二次场数据是一种宽频带信号且幅度较小,因此常常受到随机噪声、天电噪声以及人文噪声的影响。研究针对上述噪声的去噪方法,可以提高处理和解释的精度。这里给出了基于主成分分析的航空瞬变电磁去噪方法,首先应用主成分分析方法对叠加抽道后的单测点衰减曲线进行分解,然后应用曲线趋势对比法和L曲线法对分解后的成分进行分析,确定出有效信号成分,最后使用这些有效信号成分进行重构,从而达到抑制噪声的目的。模拟信号分析以及实测数据的实验结果表明,应用主成分分析法处理航空瞬变电磁数据,在保持反映地下介质分布的有效信号幅度基本不变的条件下,能有效抑制天电噪声和人文噪声,为保幅处理和解释奠定了良好的基础。  相似文献   
6.
【Title】
There are knowledge gaps in our understanding of vegetation responses to multi-scale climate-related variables in tropical/subtropical mountainous islands in the Asia-Pacific region. Therefore, this study investigated inter-annual vegetation dynamics and regular/irregular climate patterns in Taiwan. We applied principal component analysis (PCA) on 11 years (2001~2011) of high-dimensional monthly photosynthetically active vegetation cover (PV) derived from the Moderate Resolution Imaging Spectroradiometer (MODIS) and investigated the relationships between spatiotemporal patterns of the eigenvectors and loadings of each component through time and multi-scale climate-related variations. Results showed that the first five components contributed to 96.4% of the total variance. The first component (PC1, explaining 94.5% of variance) loadings, as expected, were significantly correlated with the temporal dynamics of the PV (r = 0.94), which was mainly governed by regional climate. The temporal loadings of PC2 and PC3 (0.8% and 0.6% of variance, respectively) were significantly correlated with the temporal dynamics of the PV of forests (r = 0.72) and the farmlands (r = 0.80), respectively. The low-order components (PC4 and PC5, 0.3% and 0.2% of variance, respectively) were closely related to the occurrence of drought (r = 0.49) and to irregular ENSO associated climate anomalies (r = -0.54), respectively. Pronounced correlations were also observed between PC5 and the Southern Oscillation Index (SOI) with one to three months of time lags (r = -0.35 ~ -0.43, respectively), revealing biophysical memory effects on the time-series pattern of the vegetation through ENSO-related rainfall patterns. Our findings reveal that the sensitivity of the ecosystems in this tropical/subtropical mountainous island may not only be regulated by regional climate and human activities but also be susceptible to large-scale climate anomalies which are crucial and comparable to previous large scale analyses. This study demonstrates that PCA can be an effective tool for analyzing seasonal and inter-annual variability of vegetation dynamics across this tropical/subtropical mountainous islandin the Pacific Ocean, which provides an opportunity to forecast the responses and feedbacks of terrestrial environments to future climate scenarios.  相似文献   
7.
In karst regions,the spatial heterogeneity of soil mineral oxides and environmental variables is still not clear.We investigated the spatial heterogeneity of SiO2,Al2O3,Fe2O3,CaO,MgO,P2O5,K2O,and MnO contents in the soils of slope land,plantation forest,secondary forest,and primary forest,as well as their relationships with environmental variables in a karst region of Southwest China.Geostatistics,principal component analysis(PCA),and canonical correlation analysis(CCA)were applied to analyze the field data.The results show that SiO2was the predominant mineral in the soils(45.02%–67.33%),followed by Al2O3and Fe2O3.Most soil mineral oxide components had a strong spatial dependence,except for CaO,MgO,and P2O5in the plantation forest,MgO and P2O5in the secondary forest,and CaO in the slope land.Dimensionality reduction in PCA was not appropriate due to the strong spatial heterogeneity in the ecosystems.Soil mineral oxide components,the main factors in all ecosystems,had greater influences on vegetation than those of conventional soil properties.There were close relationships between soil mineral oxide components and vegetation,topography,and conventional soil properties.Mineral oxide components affected species diversity,organic matter and nitrogen levels.  相似文献   
8.
Identification of ore deposit types is an important part of mineral exploration. Traditional methods for predicting deposit size are time-consuming, laborious and costly. In order to improve prospecting efficiency and accuracy and reveal potential relation between chemical composition and the size of gold mineralization, we propose here an integrated approach using the Principal Component Analysis (PCA) and Support Vector Machine (SVM) algorithms. In this approach, we first extract the major features of samples using PCA, and we then train a set of SVM classifiers by these features to predict deposit sizes. In this study, we collected and analyzed 3812 gold mine samples from Beishan, Gansu region to establish a PCA-SVM model with the training accuracy of 92.3% and the test accuracy of 88.7%, which were 14.3% and 17.1% higher, respectively, than using SVM. We demonstrated that the PCA-SVM method not only can eliminate subjective factors, but also can improve the accuracy of identifying ore deposits as well as prospecting efficiency, thus to provide reliable support for decision making.  相似文献   
9.
Principal component analysis (PCA) was applied to hydrochemical and isotopic data of 34 groundwater samples. This allowed the reduction of 20 variables to four significant PCs that explain 81.9% of the total variance; F1 (47.1%) explains the groundwater mineralization, whereas F2 (17%) shows isotopic enrichment and nitrate pollution. Based on an iso-factor scores map of F1, three water zones were delineated: Zone A (F1 < ?1), with fresh groundwater from the unconfined aquifer; Zone B (1 > F1 > ?1), with moderate mineralization from the confined–unconfined aquifer boundary; and Zone C (F1 > 1), with the most mineralized hot water from the confined aquifer. The iso-factor scores map of F2 delineates positive values representing samples from the unconfined aquifer, with freshwater and nitrate contamination associated with stable isotope enrichment, whereas negative values represent samples from the confined aquifer. The results clearly demonstrate the usefulness of PCA in groundwater hydrochemistry investigations.  相似文献   
10.
A first preliminary interlaboratory trial was planned to prepare ISO/DIS 12010: Water quality – determination of short chain polychlorinated alkanes (SCCP) in water – method using GC/MS and electron capture negative ionisation (ECNI). The task was to determine the sum of short chain polychlorinated n‐alkanes with carbon chain lengths of C10–C13 and a chlorine content between 49 and 67% in water by GC‐ECNI‐MS and quantification by multiple linear regression described in ISO/DIS 12010 as the compulsory method. Distributed samples were obtained from a real water extract spiked with a target concentration of 0.4 µg/mL sum of SCCP, i.e. the environmental quality target level according to the Water Framework Directive. The interlaboratory trial included the calibration, a column chromatographic clean up, a concentration step and an integration of chromatographic unresolved humps as well as the quantification with multiple linear regression. Reproducibility standard deviations between 21.5 and 22.9% were achieved by 17 participating laboratories from four countries. The method outlined no significant difference of the results between the standard solution and a real water matrix extract. On the basis of this succeeded preliminary interlaboratory trial the final interlaboratory trial for validation of ISO 12010 was prepared in autumn 2010.  相似文献   
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