福建大田—漳平地区构造-热对煤系石墨成矿及赋存的控制探讨     

丁正云  王路  曾欢  李阳  陈泉霖  邓瑞锦  程乔  林晓炎  曹代勇 《煤田地质与勘探》2020,48(1):55-61

福建省大田—漳平地区位于东部滨太平洋构造带上，不同时期的岩浆热液作用和复杂多变的构造形变格局，为该地区形成丰富的石墨矿床提供了良好的成矿条件。为了查明大田—漳平地区煤系石墨的成矿控制因素及分布规律，通过工业分析、元素分析、X射线衍射和激光拉曼光谱等实验，对不同矿区不同变质程度的煤和煤成石墨的化学组成及微观结构特征等煤成石墨化特征进行了研究，并将不同变形特征的样品划分为煤成石墨、煤成半石墨和石墨化无烟煤三大类。研究表明:煤的变形特征与煤成石墨的演化类型基本一致，且韧性变形样品的石墨化程度最高，说明构造应力作用能促进煤的石墨化作用；煤成石墨的分布受到岩浆-构造活动的控制，石墨矿床多产出于岩浆岩侵入体外接触带或附近断裂带的有利围岩地层中，且大田—漳平地区煤系石墨矿具有明显的成区、成带分布特点，煤成石墨成矿区主要集中在闽西南坳陷南部的漳平一带；而北部大田一带分布的矿区矿体石墨化程度较漳平一带低，多为煤成半石墨或石墨化无烟煤，研究结果可为该地区煤系石墨矿产综合勘探开发利用提供有利依据。   相似文献   

四川米易海塔地区混合岩型铀矿流体包裹体特征     

郭锐  陈友良  刘凯鹏  郑玉文  胡漾 《矿物学报》2020,40(2):137-148

混合岩型铀矿是康滇地轴上最有希望取得找矿突破的铀矿类型,海塔地区的铀矿化即是该类型铀矿的典型代表。本文针对区内的长英质脉矿石、富晶质铀矿石英脉矿石和含矿热液石英脉中的石英流体包裹体进行了研究。结果表明,海塔地区混合岩型铀矿的成矿作用可分为2个阶段:早期混合岩化热液成矿阶段为高温、中低盐度流体,流体包裹体均一温度集中在380~540℃,盐度变化范围为16.15%~23.18%NaCl eqv,是区内铀成矿的主要阶段;晚期热液叠加改造成矿阶段为中低温、低盐度流体,流体包裹体均一温度集中在140~220℃,盐度变化范围为5.56%~23.18%NaCleqv,是区内富铀矿的形成阶段。流体包裹体的气相成分测试表明,长英质脉矿石石英包裹体中以CH4、CO2为主,其次为H2O和N2;而富晶质铀矿石英脉及含矿热液石英脉石英包裹体中以H2为主,部分含有CO2、CH4、H2O。氢、氧同位素研究表明,早期混合岩化成矿阶段的成矿流体可能为岩浆水与变质水的混合,而晚期热液叠加改造成矿阶段成矿流体中可能有大气降水的加入。  相似文献   

A new occurrence of retrogressed eclogite from the Sanbagawa belt of southwest Japan and its significance     

Tomoki Taguchi  Shunsuke Endo  Yohei Igami  Akira Miyake 《Island Arc》2019,28(5)

The present paper reports, for the first time, the occurrence of an omphacite‐bearing mafic schist from the Asemi‐gawa region of the Sanbagawa belt (southwest Japan). The mafic schist occurs as thin layers within pelitic schist of the albite–biotite zone. Omphacite in the mafic schist only occurs as inclusions in garnet, and albite is the major Na phase in the matrix, suggesting that the mafic schist represents highly retrogressed eclogite. Garnet grains in the sample show prograde‐type compositional zoning with no textural or compositional break, and contain mineral inclusions of omphacite, quartz, glaucophane, barroisite/hornblende, epidote and titanite. In addition to the petrographic observations, Raman spectroscopy and focused ion beam system–transmission electron microscope analyses were used for identification of omphacite in the sample. The omphacite in the sample shows a strong Raman peak at 678 cm^?1, and concomitant Raman peaks are all consistent with those of the reference omphacite Raman spectrum. The selected area electron diffraction pattern of the omphacite is compatible with the common P2/n omphacite structure. Quartz inclusions in the mafic schist preserve high residual pressure values of Δω₁ > 8.5 cm^?1, corresponding to the eclogite facies conditions. The combination of Raman geothermobarometries and garnet–clinopyroxene geothermometry gives peak pressure–temperature (P–T) conditions of 1.7–2.0 GPa and 440–540 °C for the mafic schist. The peak P–T values are comparable to those of the schistose eclogitic rocks in other Sanbagawa eclogite units of Shikoku. These findings along with previous age constraints suggest that most of the Sanbagawa schistose eclogites and associated metasedimentary rocks share similar simple P–T histories along the Late Cretaceous subduction zone.  相似文献   

南海IODP 349航次基底玄武岩中碳酸盐岩脉的岩石学特征*     

许佳锐  陈毅凤  王宝云 《热带海洋学报》2018,37(6):63-73

国际大洋发现计划(International Ocean Discovery Program, IODP)349航次在南海东部次海盆和西南次海盆残留扩张脊附近的U1431和U1433站位首次钻取基底玄武岩, 通过对16块基底玄武岩内的碳酸盐岩脉薄片镜下观察以及激光拉曼光谱分析, 揭示碳酸盐矿物为方解石和文石, 为典型的洋壳低温热液蚀变次生矿物。U1431站位碳酸盐岩脉为独立的方解石脉、文石脉交替出现; 而U1433站位则存在方解石脉、文石脉和方解石-文石共生脉三种情况。此外, U1431站位在基底~42.1m处出现了平行的方解石脉和文石脉, 揭示U1431存在不同来源热液的多期活动, 即可能存在多次或多阶段不同的热液注入。U1431和U1433站位的碳酸岩脉中, 文石的矿物集合体形状基本一致, 呈块状、纤维状和放射纤维状; 而方解石存在差异, U1431的方解石以斑块状、块状、粒状和纤维状出现, 而U1433的方解石仅出现块状。U1431站位的碳酸盐岩脉的丰度明显高于U1433站位。这些均揭示U1431站位的低温热液活动强, 而U1433站位则相对弱。两个站位的热液活动不同很可能是由于区域地质环境的差异造成——U1431附近的巨大海山为其提供了热液补给, 而U1433远离热液的补给/渗漏点。  相似文献   

大洋多金属结核中铁锰质矿物拉曼光谱特征初探     

赖佩欣  任江波  邓剑锋 《矿床地质》2020,39(1):126-134

拉曼光谱是一种快速无损的分析手段,它既可观察样品的显微结构构造,也可分析样品的成分和结构。为了丰富多金属结核的岩石矿物学特征,文章对西太平洋某海山区的多金属结核样品进行了X射线粉末衍射分析和拉曼光谱分析。X射线分析结果显示该区域样品主要含有水羟锰矿、钡镁锰矿、斜长石、钙十字沸石和石英,显微构造主要有纹层状构造、柱状构造、树枝状构造、充填构造等。通过分析对比潮湿样品和烘干样品铁锰质矿物的拉曼特征谱峰,得出结核中水羟锰矿的特征谱峰位于490 cm~(-1)、570 cm~(-1)和626 cm~(-1)附近,钡镁锰矿的特征谱峰则位于640 cm~(-1)附近,与陆地上对应矿物的特征拉曼谱峰不同。结核中的钡镁锰矿结构不稳定,经过风干或者抛磨后部分产生相变,不同显微结构中,相变情况不同。经与RRUFF数据库比对,识别出钙十字沸石、斜长石等自形晶,多分布于结核最内层,往结核外层总体减少。矿物微晶多见铁锰质矿物微晶和钙十字沸石微晶,铁锰质矿物绕其向外生长。  相似文献   

粉色水晶内针状包裹体的成分与分布特征研究   总被引：1，自引：1，他引：0  

胡哲  郭颖 《岩矿测试》2018,37(3):306-312

粉色水晶内部的针状包裹体常被认为是三组呈三方对称的金红石或蓝线石,至今未有定论。本文选取含有针状包裹体的4颗星光粉晶,利用宝石学显微镜、激光拉曼光谱仪及紫外可见分光光度计对样品进行观察与测试,以确定包裹体的分布特征及矿物种类。无损拉曼测试发现包裹体的特征振动峰949 cm-1、999 cm-1与蓝线石标准峰相匹配,可确定针状包裹体为蓝线石或与其极为相近的矿物。放大检查发现,包裹体直径约0.5μm,长度可达毫米级,近定向分布,整体上呈汇聚状,在某些位置可粗略分为三组,同组针状包裹体近似平行分布。造成六射星光的三组蓝线石立体相交,未观察到明显的三方对称关系,与水晶的结晶习性无直接关系,故认为蓝线石为先成包裹体,在水晶的生长过程中被捕获。紫外可见分光光谱仅显示粉色蓝线石的特征吸收,表明大量的粉色蓝线石包裹体对粉色水晶的粉色有一定贡献。  相似文献   

Crucial control on magmatic-hydrothermal Sn deposit in the Tengchong block,SW China: Evidence from magma differentiation and zircon geochemistry     

《地学前缘(英文版)》2022,13(4):101401

Magmatic-hydrothermal Sn deposits are commonly associated with high silica magmas, but why most global high silica granites do not bear economic Sn ore grades remains unclear. Two crucial factors controlling magmatic-hydrothermal Sn mineralization, including advanced fractionation and depressurization-induced rapid cooling, were revealed in the case study of the Guyong granitic pluton linked with the Xiaolonghe Sn deposit, in the Tengchong block, SW China. The Guyong granitic pluton comprises three petrological facies: less evolved biotite syenogranite, evolved alkali granite and leucogranite, and highly evolved facies (the protolith of greisenized granite). Similar crystallization ages (～77 Ma) and gradual contact between different petrological facies indicate the Guyong granitic pluton records a continuous fractionation process. Monte Carlo-revised Rayleigh fractionation model suggests the fractionation degree of the Guyong pluton is markedly high (>87 wt.%) that can only be achieved by a high initial water (≥4 wt.%) content in the parent granitic magma revealed by rhyolite-MELTS calculation. Advanced degree fractionation causes the first Sn enrichment but it also significantly increases the viscosity of evolved magmas, suppressing the exsolution and transport of hydrothermal fluids. Hence, it must be compensated by the second critical factor: depressurization-induced rapid cooling, reflected by the occurrence of highly metamict zircons in the greisenized granite. The highly metamict feature, indicated by the large full width at half maximum (FWHM) values of zircon ν₃(SiO₄) peak (>19.5 cm^?1), suggests these zircons do not experience thermal annealing but rapidly ascend into a shallow cooling environment. Depressurization-induced rapid cooling facilitates exsolution and transport of hydrothermal fluids, interacting with wall rocks and resulting in Sn mineralization.  相似文献   

新疆奇台县黄羊山石墨矿床特征、物质来源及成因     

孙新浩  任云生  孙珍军  李作武  王承洋 《岩石学报》2021,37(6):1867-1882

黄羊山石墨矿床位于新疆东准噶尔造山带南部的卡拉麦里地区东南段,是近年来新发现的国内外首个产于花岗岩体中的超大型石墨矿床。成矿地质条件、矿床地质特征研究表明,该矿床与黄羊山碱性花岗岩体具有密切的时空及成因联系,矿石具独特的球状构造,球体中石墨与长英质矿物及磁黄铁矿、黄铜矿等金属硫化物密切共生。为确定黄羊山石墨矿床的成因和成矿物质来源,本文开展了球状矿石中的石墨拉曼光谱分析和C同位素测试,对与石墨密切共生的金属硫化物开展S-Pb同位素分析。结果表明,黄羊山矿床球状矿石不同部位石墨的拉曼谱峰相似,显示具有很高的结晶程度,估算结晶温度为750～800℃;7件石墨样品的δ~(13)C值在-19.27‰～-19.90‰,分布非常集中,介于岩浆碳值和有机碳值之间,表明具有两者的混合来源。4件磁黄铁矿样品的δ~(34)S值集中在-2.3‰～-2.9‰之间,接近原始地幔值;在Pb同位素构造环境判别图解上,Pb同位素比值(~(206)Pb/~(204) Pb=18.114～19.040,~(207)Pb/~(204) Pb=15.448 ～ 15.543,~(208) Pb/~(204)Pb=38.253～38.915)显示较好的线性关系,延伸方向与地幔演化曲线的延伸方向基本一致;S-Pb同位素测试结果表明,与石墨共生金属硫化物具有幔源特征。综合黄羊山矿床成矿地质条件、成矿特征、石墨及共生硫化物的物质来源等研究结果,本文初步认为,黄羊山石墨矿床形成于碱性花岗岩的岩浆作用阶段,矿石中的金属硫化物来自岩浆混合作用中的幔源基性端元,碳质由于岩浆同化混染作用达到饱和,在硫化物的催化下沉积形成石墨。  相似文献   

High-precision analysis of carbon isotopic composition for individual CO2 inclusions via Raman spectroscopy to reveal the multiple-stages evolution of CO2- bearing fluids and melts     

《地学前缘(英文版)》2023,14(3):101528

The carbon isotopic composition of CO₂ inclusions trapped in minerals reflects the origin and evolution of CO₂-bearing fluids and melts, and records the multiple-stages carbon geodynamic cycle, as CO₂ took part in various geological processes widely. However, the practical method for determination isotope composition of individual CO₂ inclusion is still lacking. Developing a microanalytical technique with spatial resolution in micrometers to precisely determinate the δ¹³C value of individual CO₂ inclusion, will make it possible to analyze a tiny portion of a zoning mineral crystal, distinguish the differences in micro-scale, and possible to find many useful information that could not be obtained with the bulk extraction and analysis techniques. In this study, we systematically collected Raman spectra of CO₂ standards with different δ¹³C values (?34.9 ‰ to 3.58 ‰) at 32.0 °C and from ～7.0 MPa to 120.0 MPa, and developed a new procedure to precisely determinate the δ¹³C value of individual CO₂ inclusion. We investigated the relationship among the Raman peak intensity ratio, δ¹³C value, and CO₂ density, and established a calibration model with high accuracy (0.5 ‰?1.5 ‰), sufficient for geological application to distinguish different source of CO₂ with varying δ¹³CO₂. As a demonstration, we measured the δ¹³C values and the density of CO₂ inclusions in the growth zones of alkali basalt-hosted corundum megacrysts from Changle, Shandong Province. We found the significant differences of density and δ¹³C between the CO₂ inclusions in the core of corundum and those inclusions in the outer growth zones, the δ¹³C value decreases from core to rim with decreasing density: δ¹³C values are from ?7.5 ‰ to ?9.2 ‰ for the inclusions in the core, indicating the corundum core was crystallized from mantle-derived magmas; from ?13.5 ‰ to ?18.5 ‰ for CO₂ inclusions in zone 1 and from ?16.5 ‰ to –22.0 ‰ for inclusions in zone 2, indicating the outer zones of corundum grew in a low δ¹³C value environment, resulted from an infilling of low δ¹³C value fluid and/or degassing of the ascending basaltic magma.  相似文献   

A Raman investigation on the boron form occurring in salt lake brine during evaporation          下载免费PDF全文

彭姣玉  陈婧  王兴鹏  董亚萍  李武 《盐湖研究》2019,27(1)

Boron resources are abundant in Da Qaidam salt lake of Qaidamu Basin. It has been given great attention for the polyborate species present in brine. In this study, the Raman spectroscopy was applied to investigate the existing-form of boron in brine during evaporation. The prepared solutions of MgO·2B2O3-H2O, MgO·2B2O3-MgCl2 -H2O, and MgO·2B2O3-MgSO4-H2O was also evaporated and recorded to study the influence of boron concentration, pH, and electrolytes on the borate speciation in brine. The mononborates of B(OH)3 and B(OH)4- were found to be the only forms present in the original salt lake brine. Brine evaporation promotes the formation of polyborate anions B3O3(OH)4-, B5O6(OH)4-, and B6O7(OH)62- and also disappearance of the B(OH)4- ion in brine with boron concentration of more than 11 g/L in B2O3. The pentaborate ion of B5O6(OH)4- was sensitive to the solution pH and found to be appeared under the pH value of 8.0. While the hexaborate ion of B6O7(OH)62- was observed more dependent on the electrolyte of magnesium chloride due to its special properties, such as promoting boron accumulation, lowering solution pH, and also the strong af?nity for water molecules, which is beneficial to the polymerization of borate ions in brine. The interaction mechanisms among polyborate anions during evaporation had also been proposed.  相似文献