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1.
In snowmelt-driven mountain watersheds, the hydrologic connectivity between meteoric waters and stream flow generation varies strongly with the season, reflecting variable connection to soil and groundwater storage within the watershed. This variable connectivity regulates how streamflow generation mechanisms transform the seasonal and elevational variation in oxygen and hydrogen isotopic composition (δ18O and δD) of meteoric precipitation. Thus, water isotopes in stream flow can signal immediate connectivity or more prolonged mixing, especially in high-relief mountainous catchments. We characterized δ18O and δD values in stream water along an elevational gradient in a mountain headwater catchment in southwestern Montana. Stream water isotopic compositions related most strongly to elevation between February and March, exhibiting higher δ18O and δD values with decreasing elevation. These elevational isotopic lapse rates likely reflect increased connection between stream flow and proximal snow-derived water sources heavily subject to elevational isotopic effects. These patterns disappeared during summer sampling, when consistently lower δ18O and δD values of stream water reflected contributions from snowmelt or colder rainfall, despite much higher δ18O and δD values expected in warmer seasonal rainfall. The consistently low isotopic values and absence of a trend with elevation during summer suggest lower connectivity between summer precipitation and stream flow generation as a consequence of drier soils and greater transpiration. As further evidence of intermittent seasonal connectivity between the stream and adjacent groundwaters, we observed a late-winter flush of nitrate into the stream at higher elevations, consistent with increased connection to accumulating mineralized nitrogen in riparian wetlands. This pattern was distinct from mid-summer patterns of nitrate loading at lower elevations that suggested heightened human recreational activity along the stream corridor. These observations provide insights linking stream flow generation and seasonal water storage in high elevation mountainous watersheds. Greater understanding of the connections between surface water, soil water and groundwater in these environments will help predict how the quality and quantity of mountain runoff will respond to changing climate and allow better informed water management decisions.  相似文献   
2.
林家组出露于辽宁东部本溪林家崴子一带.自小林贞一1942年记载以来,其时代一直有很大的争议.争议跨度从第三系到上二叠统.20世纪80年代初,张武等依据动植物化石和地层对比,提出了林家组属于中三叠世的观点.由于林家组产出的植物化石十分复杂,既有古生代,又有中生代分子,且没有锆石年龄证据,故林家组时代仍然存疑.近年来,在林家组底部找到了变质凝灰质粉砂岩,其中有很多锆石.根据30颗保存较好锆石测年结果,发现4颗最年轻锆石的206Pb/238U平均年龄是239.5±4.1 Ma.另外,最近前甸子地区林家组发现了少林肋木(Pleuromeia shaolinii).因此尽管林家植物群存在二叠纪和三叠纪均有分布的重要植物,但结合锆石定年、地层对比、岩性特征、平行不整合接触关系、三叠纪代表植物及中三叠世到早白垩世均有分布的昆虫索德蠊属来综合分析,可以确认林家组确实属于中三叠世.  相似文献   
3.
狮吼山矿区是江西省内规模最大的矽卡岩型硫铁多金属矿床,伴生W、Cu、Au多种成矿元素,成矿作用与矿区出露的茶山迳复式花岗岩体有关。岩体主要包括茶山迳似斑状黑云母二长花岗岩和莲湖细粒二长花岗岩两期,为研究成矿岩体的侵位时代、岩石成因及与成矿的关系,本次工作进行了U-Pb锆石定年、岩相学和岩石地球化学等测试分析。结果表明:岩体具有高硅、高钾、富铝的特征,属高钾钙碱性系列花岗岩;轻重稀土元素分馏明显,均为右倾型,弱Eu负异常,以富集Cs、Rb、Th、U、Pb,亏损Ba、Nb、Sr、和Ti等元素为主要特征,属于低Ba-Sr壳源花岗岩类;锆石具较好晶形,具典型岩浆锆石特征,利用LA-ICP-MS进行U-Pb测年,获得谐和年龄为(162.4±0.6)Ma(MSWD=1.8),加权平均年龄为(162.4±1.4)Ma(MSWD=1.4),谐和年龄与加权平均年龄在误差范围内高度一致,表明茶山迳复式岩体侵位于燕山早期中侏罗世;综合考虑岩体矿物组合、主微量元素及高分异特征,认为其成因分类应属于S型花岗岩;对比中国花岗岩成矿元素平均含量,茶山迳两期花岗岩均具有较高的W、Mo、Bi、Pb等成矿元素含量,可同时为成矿作用提供热源、流体及物质。  相似文献   
4.
中亚造山带西部西准噶尔地区红山花岗岩体内部发育多期似岩墙状安山质暗色条带,LA-ICP-MS锆石U-Pb同位素定年和岩石化学与同位素分析表明,它们具有不同的形成年龄、相同的源区和相似的形成过程。其中,具有不规则状或环状形态的暗色条带,其锆石U-Pb年龄为319.1±2.9 Ma和313.3±2.4 Ma,远大于红山岩体花岗岩锆石结晶年龄(305~301Ma),可能是红山岩体侵位过程中所捕掳的围岩;具有线性展布特征的安山质暗色条带,其锆石U-Pb年龄为295±2Ma,形成于红山岩体侵位之后,构成伸展岩墙群。红山岩体中的安山质暗色条带和线状岩墙群具有相似的岩石化学组成,富SiO_2(56.48%~63.09%)、MgO(3.56%~6.31%),具有高的Mg#值(51.74~62.40)及Na_2O/K_2O值(1.34~3.43);球粒陨石标准化稀土元素(REE)配分模式呈明显的右倾型,富集轻稀土元素(LREE)和大离子亲石元素(LILE)Rb、K、Ba、U、Sr,亏损高场强元素(HFSE)Th、Nb、Ce、P和重稀土元素,具较弱的负铕异常;其同位素组成特征为(~(87 )Sr/~(86 )Sr)i=0.703295~0.703620,(~(143) Nd/~(144) Nd)i=0.512612~0.512618,εNd(t)=6.91~7.62,(~(206) Pb/~(204) Pb)t为17.6883~17.9876,(~(207) Pb/~(204) Pb)t为15.5313~15.5686,(~(208)Pb/~(204)Pb)t为37.4460~38.0581。它们具有与赞岐岩类似的地球化学特征,总体表现出与弧岩浆作用相关的地球化学特征,可能具有共同的物质来源,为准噶尔洋板片俯冲消减后同一地幔源区在不同阶段的产物。其中,形成于弧岩浆作用时期的赞岐岩(319~313 Ma),构成与岛弧花岗岩类伴生的环状似岩墙状安山质暗色条带;形成于后造山伸展岩浆作用晚期的赞岐岩(~295Ma),构成与达拉布特左行走滑作用相关的陆内伸展岩墙群。安山质暗色条带(岛弧火山作用)、红山岩体(后造山伸展)和线状岩墙群(陆内伸展)记录了西准噶尔红山地区洋陆转换的全过程。  相似文献   
5.
Hekla volcano is a major producer of large, widespread silicic tephras. About 3000 years ago, the dominant eruption mode shifted from infrequent large (>1 km3) to more frequent moderate (<1 km3) eruptions. In the following two millennia ≥20 explosive silicic-to-intermediate eruptions occurred, and six or more basaltic. Three categories can be identified with dacite/andesite to basaltic andesite in the oldest eruptions through basaltic andesite to basalt in the youngest eruptions. Ten tephra layers of the first category have distinct field characteristics: a pale lower unit and a dark upper unit (two coloured or TC-layers). Colour separation is sharp indicating a stratified magma chamber origin. The lower unit is dominantly andesitic (61–63% SiO2), while the upper unit is basaltic andesite (53–57% SiO2). Volumes of the eight largest TC-layers range from 0.2 to 0.7 km3 as freshly fallen. Radiocarbon and soil accumulation rate dates constrain the TC-layers to between 3000 and 2200 years ago. Two of these (~2890 and ~2920 b2k) are likely to occur overseas. Low SiO2 in the last erupted tephra of the TC-layers is comparable to that of historical Hekla lavas, implying a final effusive phase. The Hekla edifice may, consequently, be younger than 3000 years.  相似文献   
6.
通过青藏高原东部川西地区雀儿山花岗岩体磷灰石裂变径迹分析,新获得了4个磷灰石裂变径迹年龄值,分别为4. 9±0. 3Ma、6. 2±0. 5 Ma、7. 2±0. 4 Ma和7. 3±0. 7 Ma。运用径迹年龄-地形高差法计算出雀儿山花岗岩体新近纪的隆升速率,为0. 15~2 mm/a,平均隆升速率为0. 78mm/a。隆升速率在每个阶段有所不同,但呈现出一种快速隆升→缓慢隆升的过程,为整个青藏高原东缘的隆升过程提供了约束条件。  相似文献   
7.
白岗岩是大陆碰撞过程中陆壳低比例熔融的产物,与铀及多金属矿床在成因上密切关联。甘肃红石泉铀矿床含矿主岩为伟晶状白岗岩,前人对伟晶状白岗岩的成岩年龄研究较少且精度有限,影响了对铀矿床成因和构造背景的深入认识。对甘肃红石泉铀矿床含矿主岩——伟晶状白岗岩开展了高精度LA-ICP-MS锆石U-Pb同位素测年,获得伟晶状白岗岩成岩平均年龄值为2493.5Ma,形成时代为新太古代晚期—古元古代早期。认为伟晶状白岗岩应属于新太古代晚期-古元古代早期华北克拉通微陆块拼合作用后期的产物,同时也是华北克拉通约2.5Ga岩浆构造热事件在西部地块的响应。伟晶状白岗岩与红石泉铀矿床铀成矿没有直接成因关系,只是作为铀矿的含矿主岩。  相似文献   
8.
N(187Os)/N(188Os) ratios of six geological reference materials were measured using static Faraday cups (FCs) with 1013 Ω amplifiers by N‐TIMS. Our results show that the repeatability precision was 2–3‰ (2 RSD,= 3), when taking ~ 1 g of BHVO‐2 with 76 pg g?1 of Os mass fraction and ~ 2 g of BCR‐2 with 21 pg g?1 of Os mass fraction for each sample, whether measured by FCs or by secondary electron multiplier. The repeatability precision measured by FCs was 1–0.2‰ (2 RSD,= 3) when taking ~ 1 g of BIR‐2 with 350 pg g?1 of Os mass fraction, ~ 1 g of WGB‐1 with 493 pg g?1 of Os mass fraction or ~ 0.5 g of WPR‐1 with 13.3 ng g?1 of Os mass fraction for each sample, which is much better than those measured by secondary electron multiplier. Instead, when taking ~ 2 g of AGV‐2 with 4 pg g?1 Os mass fraction, the repeatability precision measured by secondary electron multiplier is 3–4‰ (RSD,= 3), which is better than those measured by FCs. Of the six reference materials analysed, WPR‐1 and BIR‐1a are the most homogeneous with regard to Os isotopic composition (2 RSD of 0.08% and 0.23%, respectively) when test portion masses are 0.5–1 g.  相似文献   
9.
To investigate stable isotopic variability of precipitation in Singapore, we continuously analysed the δ‐value of individual rain events from November 2014 to August 2017 using an online system composed of a diffusion sampler coupled to Cavity Ring‐Down Spectrometer. Over this period, the average value (δ18OAvg), the lowest value (δ18OLow), and the initial value (δ18OInit) varied significantly, ranging from ?0.45 to ?15.54‰, ?0.9 to ?17.65‰, and 0 to ?13.13‰, respectively. All 3 values share similar variability, and events with low δ18OLow and δ18OAvg values have low δ18OInit value. Individual events have limited intraevent variability in δ‐value (Δδ) with the majority having a Δδ below 4‰. Correlation of δ18OLow and δ18OAvg with δ18OInit is much higher than that with Δδ, suggesting that convective activities prior to events have more control over δ‐value than on‐site convective activities. The d‐excess of events also varies considerably in response to the seasonal variation in moisture sources. A 2‐month running mean analysis of δ18O reveals clear seasonal and interannual variability. Seasonal variability is associated with the meridional movement of the Intertropical Convergence Zone and evolution of the Asian monsoon. El Niño–Southern Oscillation is a likely driver of interannual variability. During 2015–2016, the strongest El Niño year in recorded history, the majority of events have a δ18O value higher than the weighted average δ18O of daily precipitation. δ18O shows a positive correlation with outgoing longwave radiation in the western Pacific and the Asian monsoon region, and also with Oceanic Niño Index. During El Niño, the convection centre shifts eastward to the central/eastern Pacific, weakening convective activities in Southeast Asia. Our study shows that precipitation δ‐value contains information about El Niño–Southern Oscillation and the Intertropical Convergence Zone, which has a significant implication for the interpretation of water isotope data and understanding of hydrological processes in tropical regions.  相似文献   
10.
滇中昆阳群一直是华南前寒武纪地质研究的热点之一,其地层序列、时代与区域对比长期存在争议。通过对滇中易门县小街乡普家村-岔河水库剖面禄表组2个凝灰岩样品进行SHRIMP锆石U-Pb定年,获得禄表组凝灰岩的锆石206Pb/238U年龄为878.5±4.7Ma和878.0±4.0Ma,首次证实禄表组的形成时代为新元古代中期。禄表组凝灰岩SHRIMP锆石U-Pb年龄的获得,有利于正确认识昆阳群的划属关系,并为西南地区青白口纪地层格架的建立和对比提供可靠的年代学依据。  相似文献   
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