微量元素分析在判别沉积环境中的应用——以柴达木盆地西部锶矿区富锶地层为例          下载免费PDF全文

年秀清  韩凤清  韩继龙  毛庆飞  马喆 《盐湖研究》2019,27(1):66-72

沉积岩中的微量元素对沉积环境水介质的变化较为敏感,是研究沉积物沉积时古气候、古环境的有效手段。选取了对沉积环境介质较为敏感的锶(Sr)、钡(Ba)、铜(Cu)、铀(U)、钒(V)、镍(Ni)、钍(Th)等元素作为判别指标,对柴达木盆地西部上新统油砂山组、狮子沟组和更新统七个泉组三套富锶岩层的古气候和古沉积环境特征进行了研究。结果表明,柴达木盆地西部从油砂山组到七个泉组沉积时总体上为干旱的气候环境;湖盆水体的盐度较高,表现为咸水环境,且从油砂山组到七个泉组随着地层变新,盐度有逐渐增大的趋势;油砂山组、狮子沟组和七个泉组沉积时湖盆水体均表现为中等分层、湖水循环较为顺畅的氧化环境。  相似文献   

Geochemical characteristics and sedimentary environment of the Middle Devonian organic-rich shales in the Northwest of Guizhong Depression,Southwest China     

《China Geology》2020,3(4):567-574

In order to figure out the redox conditions and paleo-sedimentary environment of the Middle Devonian shales in the northwest of Guizhong Depression, the trace element analysis was conducted on the Middle Devonian cores (320.35–938.50 m) of the typical shale gas investigation well (GY-1) at a 1.50 m sampling interval through X-ray fluorescence spectroscopy (XRF) and inductively coupled plasma mass spectrometry (ICP-MS). According to the test result, the average values of V/(V+Ni), V/Cr and Ni/Co in Nabiao formation (Fm.) are larger than 0.67, 4.65 and 7.71 respectively, and Nabiao Fm. is rich in biological assemblages such as tabasheer, ammonite, etc. These evidences indicate the rising sea level rose relatively in the sedimentation period of Nabiao Fm. and a deepwater shelf environment, which was favorable for the preservation of organic matters. The V/(V+Ni), V/Cr and Ni/Co in Luofu Fm. and Tangting Fm. are 0.38–0.65, 0.73–4.10 and 3.70–6.72 respectively, indicating that the sea level dropped relatively in their sedimentation period, during which the water bodies became shallow, and the sedimentary environment was a weak oxidizing shallow water shelf environment. In addition, the variation of TOC has a high correlation with the enrichment degree of Ba element, indicating the favorable conditions for the enrichment and preservation of organic matters under an oxygen-deficient environment. Moreover, according to the identification of trace element indexes, the northwest of Guizhong Depression experienced the sedimentary cycle of relative rise to relative fall of sea level from bottom to top in the Middle Devonian sedimentation period. The relative sea level rose to the highest in the sedimentation period of Nabiao Fm., in which the organic-rich shales with stable thickness and high organic content were deposited. Hence, the Nabiao Fm. could be regarded as the favorable exploration target interval in this area.  相似文献   

西昌盆地上三叠统白果湾组富有机质泥页岩沉积岩相古地理与孔隙特征     

客昆  秦建华  牟必鑫  魏洪刚  何伟  雷玉雪  陈杨  刘治成 《沉积与特提斯地质》2020,40(3):140-150

海陆过渡相富有机质泥页岩是页岩气勘查开发的重要领域。本文以西昌盆地上三叠统白果湾组富有机质泥页岩为研究对象，对研究区内富有机质泥页岩的沉积岩相古地理特征、微观孔隙类型、孔隙结构特征进行研究。白果湾组富有机质泥页岩段沉积相主要为湖泊相、三角洲相、河流相。发育不同类型的微孔隙，孔隙主要以小孔为主，微孔次之，平均孔径分布在5.56~56.89nm之间，比表面积平均为9.44m²/g，总孔体积平均为0.0187cm³/g。页岩气主要形成于滨浅湖亚相及半深湖亚相中，并主要吸附于富有机质泥页岩的小孔、微孔内；西昌盆地白果湾组富有机质泥页岩储集空间较好，具有良好的勘探潜力。  相似文献   

河南禹州铝土矿"三位一体"找矿模型及资源潜力     

董运如  王宏运  董化祥  谢祥  陈宇  董寒杰 《地质与资源》2019,28(4):332-338

禹州铝土矿位于华北地台西南部的嵩箕台隆南缘，嵩箕铝土矿成矿区.该区具有明显的地台型基底和盖层二元结构，基底由古元古界嵩山岩群构成，盖层系较标准的地台型沉积，由一套古生界海相碎屑岩-碳酸盐岩建造，古生界海陆交互相含铝、煤建造和陆相碎屑岩建造组成.通过对该区铝土矿控矿因素及找矿标志分析，建立了该区铝土矿找矿模型，并对该区铝土矿的资源潜力进行了评价.  相似文献   

黔东北寒武系牛蹄塘组沉积学特征及沉积环境演化          下载免费PDF全文

唐佐其  刘凌云  谯文浪  陈武  华兴  吕留彦  马义波 《贵州地质》2019,36(1):61-68

通过对黔东北松桃-江口地区寒武系牛蹄塘组调查研究及系统的样品控制,以岩石学、层序地层学、微量元素地球化学为技术手段,研究发现该组地层岩石主要为富含炭质细碎屑岩组合,沉积构造丰富,识别出该地层组为完整的三级层序,自下而上可进一步划分为盆地-大陆斜坡-深水陆棚相沉积。微量元素总体上富亲铜、亲铁元素,贫亲石元素;以V、Ni、Mo、Re、As、Cd、U元素丰度及U/Th、δU、V/(V+Ni)、V/Cr、Ni/Co比值指标证实研究区牛蹄塘组中下部沉积条件均位于氧化界以下,属于贫氧-厌氧还原环境,为区域上V、Mo等元素的超常富集提供必要条件,至本组上部为贫氧-弱氧化环境,划分出Ⅶ个氧化还原幕次,细化了研究区牛蹄塘组沉积环境条件及其演化特征。  相似文献   

中东地区阿普特阶Shuaiba组碳酸盐岩沉积体系特征及模式探究     

罗贝维  张庆春  段海岗  吕明胜  贾民强  杨沛广  林腾飞  杨超 《岩石学报》2019,35(4):1291-1301

中东地区主力产油层系Shuaiba组的勘探及研究逐渐以地层岩性圈闭为主,笔者通过总结Bab盆地阿普特阶Shuaiba组沉积相类型,多油田地层格架及空间展布特征的对比,为系统恢复Shuaiba组沉积演化过程及模式提供地质依据。研究表明,阿普特阶Shuaiba组共发育开阔台地、台地边缘、台缘斜坡及盆地相4种沉积相单元和6种亚相类型,各相带单元受控于四个三级层序且沿Bab盆地周缘呈带状展布。开阔台地一侧,主要沉积了第二个三级层序对应的Lower Shuaiba地层;台地边缘往Bab台内盆地区域,则以第三和第四个三级层序对应的Upper Shuaiba地层为主。Shuaiba组生物礁、滩建造集中发育在第二个三级层序的高位域阶段,滩间海、缓坡及盆地相受控于海进和低位体系域。阿普特阶Shuaiba台地边缘生物建隆、台内浅滩在空间上相互叠置并成带展布,符合弱镶边型缓坡台地沉积模式,该类型台地具备深水陆棚性质的非常宽缓的斜坡,且缓坡往盆地一侧发育一个镶边台地边缘。  相似文献   

贵州省松桃县木耳溪锰矿地质特征及找矿方向     

陈旭  许乔 《云南地质》2020,(1):31-36

贵州松桃县木耳溪锰矿为典型的层控型锰矿床,矿体呈层状赋存于南华系下统大塘坡组第一段(Pt2b3d 1)底部的炭质页岩中,产出层位稳定,矿体产状与围岩产状一致。通过统计对比,锰矿层的矿化程度与含锰岩系的厚度呈正比,即当南华系大塘坡组地层厚度大于15m时,有可能成为锰矿的主要找矿方向。  相似文献   

Evaluating new fault-controlled hydrothermal dolomitization models: Insights from the Cambrian Dolomite,Western Canadian Sedimentary Basin     

Ardiansyah Koeshidayatullah  Hilary Corlett  Jack Stacey  Peter K. Swart  Adrian Boyce  Hamish Robertson  Fiona Whitaker  Cathy Hollis 《Sedimentology》2020,67(6):2945-2973

Fault-controlled hydrothermal dolomitization in tectonically complex basins can occur at any depth and from different fluid compositions, including ‘deep-seated’, ‘crustal’ or ‘basinal’ brines. Nevertheless, many studies have failed to identify the actual source of these fluids, resulting in a gap in our knowledge on the likely source of magnesium of hydrothermal dolomitization. With development of new concepts in hydrothermal dolomitization, the study aims in particular to test the hypothesis that dolomitizing fluids were sourced from either seawater, ultramafic carbonation or a mixture between the two by utilizing the Cambrian Mount Whyte Formation as an example. Here, the large-scale dolostone bodies are fabric-destructive with a range of crystal fabrics, including euhedral replacement (RD1) and anhedral replacement (RD2). Since dolomite is cross-cut by low amplitude stylolites, dolomitization is interpreted to have occurred shortly after deposition, at a very shallow depth (<1 km). At this time, there would have been sufficient porosity in the mudstones for extensive dolomitization to occur, and the necessary high heat flows and faulting associated with Cambrian rifting to transfer hot brines into the near surface. While the δ¹⁸O_water and ⁸⁷Sr/⁸⁶Sr ratios values of RD1 are comparable with Cambrian seawater, RD2 shows higher values in both parameters. Therefore, although aspects of the fluid geochemistry are consistent with dolomitization from seawater, very high fluid temperature and salinity could be suggestive of mixing with another, hydrothermal fluid. The very hot temperature, positive Eu anomaly, enriched metal concentrations, and cogenetic relation with quartz could indicate that hot brines were at least partially sourced from ultramafic rocks, potentially as a result of interaction between the underlying Proterozoic serpentinites and CO₂-rich fluids. This study highlights that large-scale hydrothermal dolostone bodies can form at shallow burial depths via mixing during fluid pulses, providing a potential explanation for the mass balance problem often associated with their genesis.  相似文献   

西昆仑山古近纪隆升变形：时间、证据和争论     

张世杰  胡修棉  郜周全  赵永强  马安林  许艺炜 《地质论评》2021,67(3):67040013-67040013

西昆仑山新生代隆升变形过程对于中亚的地貌与水系演化、资源和能源矿产分布、气候及环境变迁等都具有重要的影响,然而至今尚没有形成统一的认识。西昆仑山新生代初始隆升与变形的时间存在三种不同观点,分别为古新世、中—晚始新世、渐新世末期—中新世早期。本文通过对塔西南地区地层学、沉积学、物源分析和热年代学的研究综述,详细讨论了西昆仑山古新世、中—晚始新世隆升变形的时间、证据、解释和争议。在此基础上,确定了西昆仑山在古新世发生了隆升变形,中—晚始新世是新生代变形中的一个加速节点。这两期隆升变形分别对应于印度—亚洲大陆初始碰撞、新特提斯洋俯冲板片断离的远程响应,反映了印度板块向北的碰撞拼贴与持续挤压的过程。  相似文献   

中国铝土岩系中伴生钪资源富集规律及富集机制初探     

刘国栋  付勇  何伟  唐波  龙珍  杨颖  龙克树 《地质论评》2021,67(3):67040003-67040003

钪(Sc)作为新世纪的重要资源,广泛分布于自然界中,但其分布极为稀散,钪的独立矿物稀少,独立矿床几乎没有。铝土岩系中的钪资源储量巨大,本文统计了中国各铝土矿成矿带Sc数据,在对比山西(断隆)成铝区、华北陆块南缘成铝区、渝南—黔北成铝带、黔中成铝区和滇东南—桂西成铝区的数据基础上,发现滇东南—桂西成铝区的Sc含量最高,含钪铝土岩系形成时代主要为石炭纪和二叠纪。通过对比分析A/S与钪的关系,在A/S小于2.5,钪的含量总体较高,且与A/S正相关,大于2.5后,与A/S负相关。从而得出在铝土岩系中,Sc分布在顶层的黏土岩、中部的铁质铝土矿以及底部的铁质黏土岩、铁质岩,尤其是在含铁铝土岩系中高度富集。通过对比分析铝土岩系各元素含量,发现钪与铁、铌、钒、铬元素成正相关,综合铝土岩系中其他元素的矿物表现形式,推测钪在铝土岩系中的赋存形式可能为：类质同象、离子吸附、和超显微非结构混入物。本文初步探讨总结钪在铝土岩系中可能的赋存形式、时空分布规律及钪的迁移转化机制,为铝土矿中伴生钪资源的综合利用开发提供理论支撑。  相似文献