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The linear stability analysis of interstitial liquid within the mushy layer relative to a steady basic state is performed in order to incorporate the effect of uniform rotation on the onset of convective instability whose existence was found by Anderson and Worster (1996). The full set of non–dimensional governing equations for the temperature field, the local solid fraction and the fluid velocity are reduced asymptotically. In particular, the limit of small dimensionless mushy layer thickness, the limit of small differences between the initial and eutectic compositions of the liquid and the limit of large Stefan number are considered. The square root of Taylor number is assumed to be of the order unity. These simplifying assumptions involved in our analysis lead to a much simplified model which can essentially be solved analytically. 相似文献
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优化偏最小二乘光度法同时测定铑铱钯的研究 总被引：6，自引：0，他引：6
采用局部加权、随机矩阵法等步骤,使建立的校准模型能充分反映未知样品的数字结构特征,达到优化的目的,从而改善偏最小二乘法在处理实际未知样品数据时的解析能力,以提高计算结果的精度。用该优化偏最小二乘法对模拟地质样品中痕量贵金属Ｒｈ、Ｉｒ、Ｐｄ进行多组分光度测定,其分析结果的相对误差均小于１０％;分别测定９．５μｇ／Ｌ、３５．０μｇ／Ｌ、６６．０μｇ／Ｌ含量的Ｒｈ、Ｉｒ和Ｐｄ７次,其标准偏差Ｒｈ为０．２;Ｉｒ为１．１;Ｐｄ为２．０。 相似文献
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概述了一个较特殊的纠偏工程实例。在同一个整板基础上的建造的一幢４单元５层楼房,东西各２个单元,中间设６ｃｍ伸缩缝,建成后,东部２单元向东倾斜２２ｃｍ,并向南倾斜４．５ｃｍ,而西部２单元未发生任何沉降,亦无倾斜。采用加固基础,断开整板,倾斜钻孔掏土纠偏和纠偏后加固等措施,获得了良好的纠偏加固效果。 相似文献
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Sustainable land management often requires redevelopment of existing and often contaminated Brownfield sites over use of Greenfield or agricultural land. Stabilisation / solidification (S/S) offer a viable remediation option with particular suitability in treating heavy metal contaminants. However, uncertainties over long-term durability and previously cheap landfill disposal costs resulted in limited use in many countries. There is a need to characterise treated material and assess components containment and release, to improve S/S confidence and inform remedial design, using the evaluation of the leaching controlling mechanisms. To improve understanding of key features that will enable improvements to such designs, this paper presents an evaluation of leaching for CEM II stabilised kaolin, using the leaching behaviour of 4 main components—aluminium, silicon, calcium and sulphur. Results show no detrimental implications on chemical durability due to kaolin degradation with hydration under induced alkalinity, with increased formation of stable cementitious minerals. Availabilities for components show that aluminium and silicon had minimal leachability compared to total content, whilst calcium and sulphur show almost total leaching availability. Decreasing calcium and silicon leachability under natural chemical conditions with increased hydration duration supports the increased formation of stable cementitious products with time, using the products of kaolin dissociation. 相似文献
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Mushy layers arise and are significant in a number of geophysical contexts, including freezing of sea ice, solidification of magma chambers and inner-core solidification. A mushy layer is a region of solid and liquid in phase equilibrium which commonly forms between the liquid and solid regions of a solidifying system composed of two or more constituents. We consider the convective instability of a plane mushy layer which advances steadily upwards as heat is withdrawn at a uniform rate from the bottom of a eutectic binary alloy. The solid which forms is assumed to be composed entirely of the denser constituent, making the residual liquid within the mush compositionally buoyant and thus prone to convective motion. In this article we focus on the large-scale mush mode of instability, arguing that the 'boundary-layer' mode is not amenable to the standard stability analysis, because convective motions occur on that scale for any non-zero value of the Rayleigh number. We quantify the minimum critical Rayleigh number and determine the structure of the convective modes of motion within the mush and the associated deflections of the mush-melt and mush-solid boundaries. This study of convective perturbations differs from previous analyses in two ways; the inhibition of motion and deformation of the mush-melt interface by the stable stratification of the overlying melt is properly quantified and deformation of the mush-solid interface is permitted and quantified. We find that the mush-melt interface is almost unaffected by convection while significant deformation of the mush-solid interface occurs. We show that each of these effects causes significant (unit-order) changes in the predicted critical Rayleigh number. The marginal modes depend on three dimensionless parameters: a scaled eutectic temperature, τ e (which characterizes the eutectic temperature relative to the depression of the liquidus), a scaled superheat, τ∞ (which measures the amount by which the temperature of the incoming melt exceeds the liquidus temperature) and the Stefan number, S (which measures the latent heat of crystallization). To survey parameter space, we focus on seven cases, a standard case having S = τ∞ = τ e = 1, and six others in which one of the parameters is either large or small compared with unity: a nearly pure case (τ e = 100; having little of the light constituent), the large superheat limit (τ∞→ ∞), a case of large latent heat (S = 100), the near eutectic limit (τ e → 0), a case of small superheat (τ∞ = 0.01) and the case of zero latent heat (S = 0). The critical Rayleigh number and the associated wavelength of the convection pattern are determined in each case. The eigenvector for each case is presented in terms of the streamlines and the isolines of the perturbation temperature and solid fraction. 相似文献
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Contrasting stratified plutons exposed in tilt blocks, Eldorado Mountains, Colorado River Rift, NV, USA 总被引：2，自引：0，他引：2
Roof-to-floor exposures of mid-Miocene plutons in tilt blocks south of Las Vegas, NV, reveal distinct but strongly contrasting magma chamber statigraphy. The Searchlight and Aztec Wash plutons are well-exposed, stratified intrusions that show a similar broad range in composition from 45–75 wt.% SiO2. Homogeneous granites that comprise about one-third of each intrusion are virtually identical in texture and elemental and isotopic chemistry. Mafic rocks that are present in both plutons document basaltic input into felsic magma chambers. Isotopic compositions suggest that mafic magmas were derived from enriched lithospheric mantle with minor crustal contamination, whereas more felsic rocks are hybrids that are either juvenile basaltic magma+crustal melt mixtures or products of anatexis of ancient crust+young (Mesozoic or Miocene?) mafic intraplate.
Despite general similarities, the two plutons differ markedly in dimensions and lithologic stratigraphy. The Searchlight pluton is much thicker (10 vs. 3 km) and has thick quartz monzonite zones at its roof and floor that are absent in the Aztec Wash pluton. Isotopic and elemental data from Searchlight pluton suggest that the upper and lower zones are cogenetic with the granite; we interpret the finer grained, slightly more felsic upper zone to represent a downward migrating solidification front and the lower zone to be cumulate. In contrast, the upper part of the Aztec Wash pluton is granite, and a heterogeneous, mafic-rich injection zone with distinct isotopic chemistry forms the lower two-thirds of the intrusion. Similar mafic rocks are relatively sparse in Searchlight pluton and do not appear to have played a central role in construction of the pluton. Large felsic and composite dikes that attest to repeated recharging and intrachamber magma transfer are common in the Aztec Wash pluton but absent in the Searchlight pluton. Thus, although both intrusions were filled by similar magmas and both developed internal stratification, the two intrusions evolved very differently. The distinctions may be attributable to scale and resulting longevity and/or to subtle differences in tectonic setting. 相似文献
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We evaluated the quantitative effects of artificial barriers, water-cooling and guiding channels on lava flow using the lava
simulation program LavaSIM. Lava flow is basically subject to the topography around the path, effusive rate and viscosity.
To prevent damage due to lava flow, we conducted experiments in controlling the flow direction, velocity and temperature.
The simulation demonstrated that artificial barriers can successfully change the direction of a lava flow and is more effective
when placed nearly parallel to the flow direction at a point where the topography is not very steep, while a barrier placed
perpendicular to the flow direction can only stop the flux temporarily, ultimately allowing the solidified crust to accumulate
and causing the following mass to go over the barrier. The water-cooling trial was also effective in controlling the direction
and temperature, although the amount of water was as much order as 105 m3. The guiding channels successfully control the direction and inundated area but only in local areas. 相似文献
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The automotive industry plays a major role in the worldwide economy and represents an opportunity to increase the performance of the Turkish economy. Phosphating units in the automotive manufacturing plants generate phosphate sludge as waste, which is classified as hazardous waste in the European Waste Catalogue. Phosphate sludge must be disposed of in licensed disposal plants according to the current environmental regulations. Solidification/stabilization (S/S) is a widely used treatment technology for the disposal of hazardous wastes. Portland cement is used for the solidification and stabilization processes to immobilize Ni and Zn in the phosphate sludge as well as to create construction material to be used as cobble stone for pavement. Examination of products obtained by S/S processes is performed for two points: to determine the quality and to assess the environmental impacts. The phosphate sludge samples are subjected to chemical characterization and a size distribution analysis leaching test. Concrete for cobble stone was produced by the S/S process with the addition of phosphate sludge to replace sand. Tests for the quality of the product were carried out to determine compressive strength, permeability, and elasticity. At the end of the leaching test, elution concentrations of Zn and Ni while using water with pH values of 4.0, 5.4, and 9.0 were determined to be under the limit of inert material properties. Use of phosphate sludge should be considered as a sand replacement in the proportion of 1% of phosphate sludge to cement in concrete production, such as for cobble stone for pavement, without any adverse environmental impacts. 相似文献