Geochemical characteristics and sedimentary environment of the Middle Devonian organic-rich shales in the Northwest of Guizhong Depression,Southwest China     

《China Geology》2020,3(4):567-574

In order to figure out the redox conditions and paleo-sedimentary environment of the Middle Devonian shales in the northwest of Guizhong Depression, the trace element analysis was conducted on the Middle Devonian cores (320.35–938.50 m) of the typical shale gas investigation well (GY-1) at a 1.50 m sampling interval through X-ray fluorescence spectroscopy (XRF) and inductively coupled plasma mass spectrometry (ICP-MS). According to the test result, the average values of V/(V+Ni), V/Cr and Ni/Co in Nabiao formation (Fm.) are larger than 0.67, 4.65 and 7.71 respectively, and Nabiao Fm. is rich in biological assemblages such as tabasheer, ammonite, etc. These evidences indicate the rising sea level rose relatively in the sedimentation period of Nabiao Fm. and a deepwater shelf environment, which was favorable for the preservation of organic matters. The V/(V+Ni), V/Cr and Ni/Co in Luofu Fm. and Tangting Fm. are 0.38–0.65, 0.73–4.10 and 3.70–6.72 respectively, indicating that the sea level dropped relatively in their sedimentation period, during which the water bodies became shallow, and the sedimentary environment was a weak oxidizing shallow water shelf environment. In addition, the variation of TOC has a high correlation with the enrichment degree of Ba element, indicating the favorable conditions for the enrichment and preservation of organic matters under an oxygen-deficient environment. Moreover, according to the identification of trace element indexes, the northwest of Guizhong Depression experienced the sedimentary cycle of relative rise to relative fall of sea level from bottom to top in the Middle Devonian sedimentation period. The relative sea level rose to the highest in the sedimentation period of Nabiao Fm., in which the organic-rich shales with stable thickness and high organic content were deposited. Hence, the Nabiao Fm. could be regarded as the favorable exploration target interval in this area.  相似文献   

超慢速扩张环境下超镁铁质岩系统的热液硫化物成矿机理以及启示     

曹红  孙治雷  刘昌岭  姜学钧  何拥军  黄威  尚鲁宁  王利波  张喜林  耿威  施美娟  李东义 《海洋学报》2018,40(4):61-75

西南印度洋63.5°E热液区是在超慢速扩张洋脊发现的首个超镁铁质岩热液系统。对取自该区的热液硫化物样品进行了系统的矿物学和地球化学分析，矿物学分析结果表明:该热液区硫化物为富Fe型高温硫化物，且经历了较深程度的氧化蚀变，大量中间态的Fe氧化物充填在硫化物矿物间的孔隙及内部解理中；这些硫化物相以白铁矿为主，其次是等轴古巴矿和少量铜蓝，缺乏黄铁矿、闪锌矿。据推断，该区的热液成矿作用分为4个阶段:低温白铁矿阶段→高温等轴古巴矿阶段→自形白铁矿阶段→后期海底风化阶段（少量铜蓝以及大量的Fe的羟氧化物）。与之相对应，地球化学分析结果表明这些硫化物的Fe含量较高（31.57%~44.59%），Cu含量次之（0.16%~7.24%），而Zn含量普遍较低（0.01%~0.11%）；微量元素较为富集Co（328×10-6~2 400×10-6）和Mn（48.5×10-6~1 730×10-6）。该区硫化物中较高含量的Fe、Co与超镁铁质岩热液系统相似，明显高于镁铁质岩热液系统。独特的热液硫化物矿物学特征和元素组成可能与该区普遍出露的地幔岩、橄榄岩蛇纹石化作用以及拆离断层的广泛发育的环境有关。  相似文献   

云南金平县阿德博独居石矿床成矿时代及地质意义     

王炳华 《地质与勘探》2020,56(3):523-539

西南三江地区是我国重要的成矿区带之一,具有复合叠加成矿特征。阿德博独居石矿床位于云南省金平县境内,印度地块、哀牢山-金沙江断裂带南侧,属于哀牢山隆起的东南延伸部分。该矿床赋存于花岗质风化壳中,岩性主要有片麻状花岗岩、二长花岗岩、花岗片麻岩;矿体中主要含有独居石,少量磷钇矿、锆石、金红石、钛铁矿、榍石。岩体中片麻状花岗岩的锆石U-Pb谐和年龄为31.40±0.16Ma(MSWD=7.8),二长花岗岩的锆石U-Pb谐和年龄为34.52±0.22 Ma(MSWD=1.3),表明阿德博岩体形成于新生代古近纪,与三江地区构造体制转换阶段富碱斑岩体的成矿时期一致。片麻状花岗岩中45个锆石Hf同位素数据结果较均一,(~(176)Hf/~(177)Hf)i比值范围为0.282583～0.282712,平均为0.282633,εHf(t=31.40 Ma)范围为-6.00～-1.44,平均值为-4.21。二长花岗岩中13个锆石Hf同位素数据结果变化范围较大,(~(176)Hf/~(177)Hf)i=0.282484～0.282814(平均值为0.282681),εHf(t=31.40 Ma)=-9.43～2.22(平均值为-2.45);其中有8粒锆石的εHf(t)为负值,5颗锆石的εHf(t)为正值,暗示岩体的源区主要为地壳物质的部分熔融,可能有地幔物质的混合。  相似文献   

云南三江造山带西部的重要断裂特征与构造单元划分     

杨绍文  张星培  梅文周  严城民  周听全  吴昌进 《地质与资源》2019,28(4):315

经资料搜集与野外调研，对云南三江造山带西部重要断裂的位置、特征及南北连接，形成了一些新的认识.即：①怒江断裂在滇西北为高黎贡山变质基底杂岩与丙中洛地块、滇西南为潞西断块与保山地块的边界断裂，属三级构造单元的边界断裂；②班公错-东巧断裂进入云南后，北段、中段与位于高黎贡山主峰的向东倾斜的高黎贡山逆冲推覆断裂相连接，南段称为龙陵-瑞丽断裂；③高黎贡山断裂、龙陵-瑞丽断裂为腾冲造山带与三江造山带的边界断裂，属一级构造单元的边界断裂；④昌宁-孟连结合带东西两侧的双江-竹塘断裂、沧源断裂北延至滇西北后，分别与位于碧罗雪山西坡的福贡断裂、捧当断裂相连接；⑤迪麻洛-昌宁-孟连结合带为二级构造单元，东西两侧的二级构造单元分别为崇山-临沧地块、丙中洛-保山陆块.云南三江造山带西部划分为2个二级构造单元、7个三级构造单元.  相似文献   

The magmatic activity mechanism of the fossil spreading center in the Southwest sub-basin,South China Sea   总被引：1，自引：0，他引：1  

MENG Lin  ZHANG Jian 《中国科学:地球科学(英文版)》2014,57(7):1653-1663

Petrogeochemical data indicate that after the end of seafloor spreading,residual magmatic activity still exists in the deep basin of the South China Sea.By using different viscous structure models beneath the fossil spreading center of the Southwest sub-basin we simulated the amount of melt produced,the length of the melting period,and the thermal evolution process in terms of geothermics and the buoyant decompression melting mechanism.We compared the results of our model with observed heat flow,seismic,and petrogeochemistry data.The results show that depletion buoyancy induced by buoyant decompression melting plays an important role in the melting process,while retention buoyancy,thermal buoyancy,and viscous shear force have only a weak influence on the melting process.From the length of the melting period,we determined that for the three viscous structures models the magmatic activity lasted about 5,12,and 15 Ma.Under the effect of buoyant depression melting,local high-temperature areas will develop under the basin,which can explain the low-velocity layer detected by seismic exploration in the middle and upper lithosphere of the Southwest sub-basin.We also simulated the possible lithology distribution beneath the fossil spreading center with the physical conditions of different viscous structure,different temperature structure,and different melting fraction,which provided a greater understanding of the rock petrogeochemical data of the deep sea basin in the South China Sea.  相似文献   

云南中甸地区晚白垩世斑岩型Mo-Cu矿床磷灰石、锆石裂变径迹年代学研究     

刘学龙  杨志明  卢映祥  梅社华  张娜  朱俊  陈建航  刘思晗  李振焕 《地质学报》2021,95(11):3366-3379

云南中甸地区位于西南三江铜钼铅锌金多金属矿集区的南端,是一个独具特色的Cu-Mo多金属复合叠加成矿带.本文采用裂变径迹低温热年代学技术对区内晚白垩世铜厂沟、休瓦促、热林成矿斑岩体,进行了锆石、磷灰石裂变径迹分析测试,开展了晚白垩世以来的构造热史演化模拟,揭示了区内构造-岩浆成矿事件及热史演化过程.研究表明,锆石裂变径迹年龄值变化于52±2～96±5 Ma;磷灰石裂变径迹的年龄值变化于15±1～48±3 Ma,总体变化幅度不大,中心年龄与池年龄在误差范围也基本一致.通过锆石、磷灰石的裂变径迹分析,揭示出云南中甸地区自晚白垩世以来主要经历了三个阶段的构造热事件.第一阶段(96～60 Ma),主要为岩浆侵位后快速降温的热史演化阶段;第二阶段(52～39 Ma),为缓慢的降温作用过程;第三阶段(16～15 Ma),揭示了受中新世以来青藏高原隆升造山作用的影响,该区经历了快速降温的地质演化过程.综合锆石裂变径迹、磷灰石裂变径迹的热史反演结果,表明区内晚白垩世典型成矿斑岩体具有相似的隆升过程和剥蚀历史,并获得了剥蚀量与剥蚀速率的定量计算结果,为区内矿床的资源潜力评价及勘查工作提供了科学参考.  相似文献   

三江平原西部土壤硒分布特征及其影响因素   总被引：1，自引：0，他引：1  

牛雪  何锦  庞雅婕  明圆圆 《物探与化探》2021,(1):223-229

近年来在黑龙江三江平原局部地区发现有珍贵的富硒土地,但对三江平原土壤硒的分布以及土壤硒含量的控制因素研究较少。三江平原西部地区土地质量地球化学调查发现,该区表层土壤主要以足硒为主,未见硒中毒土壤,富硒土壤主要分布于完达山山前至沿挠力河之间的冲湖积低平原地区,少量分布于萝北县城北部的湖成剥蚀台地,硒不足或硒潜在不足地区主要沿松花江河流以及萝北地区黑龙江古河道展布。根据相关性分析、因子分析、聚类分析结果,并结合硒元素地球化学空间分布,认为三江平原表层土壤硒含量主要受表层土壤中有机质以及土壤质地中黏土的吸附作用影响,铁、锰等氧化物以及土壤pH对硒富集具有一定影响,但作用较小。土壤环境质量综合评价显示三江平原地区多为无风险区,是一块珍贵的清洁土地资源,当地可依托富硒土地发展绿色富硒农业。  相似文献   

Groundwater characteristics and climate and ecological evolution in the Badain Jaran Desert in the southwest Mongolian Plateau     

《China Geology》2021,4(3):421-432

The Badain Jaran Desert is the third largest desert in China, covering an area of 50000 km². It lies in Northwest China, where the arid and rainless natural environment has a great impact on the climate, environment, and human living conditions. Based on the results of 1∶250000 regional hydrogeological surveys and previous researches, this study systematically investigates the circulation characteristics and resource properties of the groundwater as well as the evolution of the climate and ecological environment since the Quaternary in the Badain Jaran Desert by means of geophysical exploration, hydrogeological drilling, hydrogeochemistry, and isotopic tracing. The results are as follows. (1) The groundwater in the Badain Jaran Desert is mainly recharged through the infiltration of local precipitation and has poor renewability. The groundwater recharge in the desert was calculated to be 1.8684×10⁸ m³/a using the water balance method. (2) The Badain Jaran Desert has experienced four humid stages since the Quaternary, namely MIS 13-15, MIS 5, MIS 3, and the Early–Middle Holocene, but the climate in the desert has shown a trend towards aridity overall. The average annual temperature in the Badain Jaran Desert has significantly increased in the past 50 years. In detail, it has increased by about 2.5°C, with a higher rate in the south than in the north. Meanwhile, the precipitation amount has shown high spatial variability and the climate has shown a warming-drying trend in the past 50 years. (3) The lakes in the hinterland of the Badain Jaran Desert continuously shrank during 1973–2015. However, the vegetation communities maintained a highly natural distribution during 2000–2016, with the vegetation cover has increased overall. Accordingly, the Badain Jaran Desert did not show any notable expansion in that period. This study deepens the understanding of groundwater circulation and the climate and ecological evolution in the Badain Jaran Desert. It will provide a scientific basis for the rational exploitation of the groundwater resources and the ecological protection and restoration in the Badain Jaran Desert.© 2021 China Geology Editorial Office.  相似文献   

高原涡和西南涡影响的两次四川暴雨过程的对比分析          下载免费PDF全文

周玉淑  颜玲  吴天贻  谢泽明 《大气科学》2019,43(4):813-830

为了进一步研究高原涡、西南涡对西南地区暴雨的影响,本文用中国气象局自动站与CMORPH降水数据融合的逐时降水资料、国家卫星气象中心的逐时FY-2E卫星的云顶亮温（TBB）资料、欧洲气象资料中心（ERA-interim）的再分析资料,通过天气学诊断分析方法以及拉格朗日轨迹模式HYSPLITv4.9,对发生在四川盆地的有高原涡东移影响西南涡发展引发暴雨的两次过程进行对比分析,发现:（1）两次暴雨过程的降水强度和分布有明显区别,并且TBB活动特征显示在过程一中有MCC（Mesoscale Convective Complex）的产生和发展,过程二则没有。（2）对于过程一,500 hPa上,高原涡逐渐减弱为高原槽并伸展到四川盆地上空,850 hPa上,在鞍型场附近有MCC的产生和发展,200 hPa上,高原涡在南亚高压北部偏西风急流下方的强辐散区内,位于南亚高压东南侧急流区下方稳定少动,偏东风急流北部有辐散中心,有利于西南涡的加强。对于过程二,500 hPa高原涡东移在四川盆地上空与西南涡耦合,形成一个稳定且深厚的系统,这也是过程二的暴雨强度比过程一强的最主要原因。200 hPa上,四川盆地始终位于南亚高压东侧的西北气流中,“抽吸作用”明显。（3）在过程一中,位涡逐渐东传且位涡增加的地方对应强降水区与MCC发展区,反映了暴雨和位涡的发展基本一致。在过程二中,中层位涡高值区从高原上东移并下传至盆地上空,两涡耦合使得上下层打通,位涡值比耦合之前单独的两涡强度更强。 MCC产生的必要条件是中层大气要有强正涡度、强辐合和强上升运动,在未产生MCC前,过程一与过程二在盆地上空的动力条件甚至是相反的;从热力条件看,过程一中有明显的干冷空气入侵,增强不稳定条件,有利于MCC的产生并引发强降水;另一方面,本文也应证了二阶位涡的水平分布与暴雨落区有较好的对应关系。（4）通过拉格朗日方法的水汽轨迹追踪模式和聚类分析方法分析可得两次暴雨过程的水汽输送源地和通道也有明显区别,过程一主要有两条水汽通道,通道一来自阿拉伯海和孟加拉湾洋面的底层,通道二来自四川南部750 m以下高度;而过程二的主要水汽输送通道有三条,通道一来自西方地中海、黑海和里海上空1500～2500 m高度附近,通道二来自阿拉伯海和印度洋的底层,通道三的水汽从孟加拉湾低层绕过云贵高原直接输送到四川盆地。  相似文献   

三江造山带义敦岛弧中段格聂（南）花岗岩体地球化学特征及地质意义   总被引：2，自引：0，他引：2  

马比阿伟  木合塔尔·扎日  文登奎  张明春 《地质学报》2015,89(2):305-318

夹持于甘孜—理塘结合带与金沙江结合带之间的义敦弧岩浆岩带上发育了3条纵贯南北的造山花岗岩带,其中:中带形成了由20余个岩体组成的雀而山—格聂花岗岩带和相关的银、锌、铅-锌多金属矿床。本文对格聂(南)花岗岩体进行研究,发现其岩石类型为花岗闪长岩、二长花岗岩和钾长花岗岩三类,以二长花岗岩为主体。锆石LA-ICP-MS U-Pb定年结果表明格聂花岗岩的成岩年龄为89.9±3.6Ma。地球化学研究表明,岩石中主量元素化学成分具有富硅、富铝、低钠高钾的特征,为典型的S型花岗岩。铝饱和指数ASI1,指示岩浆源自地壳;(CaO)%/(Na2O)%值等于0.1左右,表明源岩为大陆地壳沉积岩区的泥质岩。稀土总量均值228.83×10-6,稀土配分曲线呈略右倾近直线海鸥型,与地壳熔融型花岗岩形态一致。轻重稀土分馏不明显;铕出现明显负异常(δEu=0.13),显示岩浆分异结晶作用强烈。微量元素蛛网图上明显亏损大离子亲石元素Sr;富集高场强元素U。Rb/Sr平均比值14.97,表明格聂花岗岩的源岩为上部陆壳。结合Rb-(Y+Nb)图解、(Rb/30)-Hf-(Ta×3)图解、R1-R2变异图解,格聂南岩体形成于后碰撞造山环境,应是甘孜-理塘洋盆和金沙江洋盆闭合后,造山后伸展作用活动的产物。  相似文献