A critical zone observatory dedicated to suspended sediment transport: The meso-scale Galabre catchment (southern French Alps)     

Cédric Legout  Guilhem Freche  Romain Biron  Michel Esteves  Oldrich Navratil  Guillaume Nord  Magdalena Uber  Thomas Grangeon  Nico Hachgenei  Brice Boudevillain  Céline Voiron  Lorenzo Spadini 《水文研究》2021,35(3):e14084

The 20 km² Galabre catchment belongs to the French network of critical zone observatories (OZCAR; Gaillardet et al., Vadose Zone Journal, 2018, 17(1), 1–24). It is representative of the sedimentary lithology and meteorological forcing found in Mediterranean and mountainous areas. Due to the presence of highly erodible and sloping badlands on various lithologies, the site was instrumented in 2007 to understand the dynamics of suspended sediments (SS) in such areas. Two meteorological stations including measurements of air temperature, wind speed and direction, air moisture, rainfall intensity, raindrop size and velocity distribution were installed both in the upper and lower part of the catchment. At the catchment outlet, a gauging station records the water level, temperature and turbidity (10 min time-step). Stream water samples are collected automatically to estimate SS concentration-turbidity relationships, allowing quantification of SS fluxes with known uncertainty. The sediment samples are further characterized by measuring their particle size distributions and by applying a low-cost sediment fingerprinting approach using spectrocolorimetric tracers. Thus, the contributions of badlands located on different lithologies to total SS flux are quantified at a high temporal resolution, providing the opportunity to better analyse the links between meteorological forcing variability and watershed hydrosedimentary response. The set of measurements was extended to the dissolved phase in 2017. Both stream water electrical conductivity and major ion concentrations are measured each week and every 3 h during storm events. This extension of measurements to the dissolved phase will allow progress in understanding both the origin of the water during the events and the partitioning between particulate and dissolved fluxes of solutes in the critical zone. All data sets are available at https://doi.osug.fr/public/DRAIXBLEONE_GAL/index.html .  相似文献   

Origin of sulphate in the unsaturated zone and groundwater of a loess aquifer     

Yin Long  Tianming Huang  Fen Zhang  Zhenbin Li  Baoqiang Ma  Yiman Li  Zhonghe Pang 《水文研究》2021,35(4):e14166

The use of the sulphate mass balance (SMB) between precipitation and soil water as a supplementary method to estimate the diffuse recharge rate assumes that the sulphate in soil water originated entirely from atmospheric deposition; however, the origin of sulphate in soil and groundwater is often unclear, especially in loess aquifers. This study analysed the sulphur (δ³⁴S-SO₄) and oxygen (δ¹⁸O-SO₄) isotopes of sulphate in precipitation, water-extractable soil water, and shallow groundwater samples and used these data along with hydrochemical data to determine the sources of sulphate in the thick unsaturated zone and groundwater of a loess aquifer. The results suggest that sulphate in groundwater mainly originated from old precipitation. When precipitation percolates through the unsaturated zone to recharge groundwater, sulphates were rarely dissolved due to the formation of CaCO₃ film on the surface of sulphate minerals. The water-extractable sulphate in the deep unsaturated zone (>10 m) was mainly derived from the dissolution of evaporite minerals and there was no oxidation of sulphide minerals during the extraction of soil water by elutriating soil samples with deionized water. The water-extractable concentration of SO₄ was not representative of the actual SO₄ concentration in mobile soil water. Therefore, the recharge rate cannot be estimated by the SMB method using the water-extractable concentration of SO₄ in the loess areas. This study is important for identifying sulphate sources and clarifying the proper method for estimating the recharge rate in loess aquifers.  相似文献   

Drying increases organic colloidal mobilization in the karst vadose zone: Evidence from a 15-year cave-monitoring study     

Jin Liao  Chaoyong Hu  Xiuli Li  Jiaoyang Ruan 《水文研究》2021,35(4):e14163

Understanding the hydrological processes of colloids within the karst vadose zone is vital to the security of karst groundwater and providing appropriate paleohydrological explanations of colloid-facilitated metals in speleothem. This study addresses the mobilization mechanisms driving colloidal organic matter (COM) transport in the karst vadose zone using a 15-year long monthly monitoring dataset from a cave drip point (HS4) in Heshang Cave, Qingjiang Valley, China. Variations in COM concentrations were reported as the fluorescence difference values of raw and filtered (<0.22 μm) samples at an excitation wavelength of 320 nm and emission wavelength of ~400 nm. A fluorescence humification index (HIX) lower than 0.8 and an autochthonous index (BIX) higher than 1.2 indicated that the origin of COM was mainly from the karst vadose zone, rather than the soil zone. The COM concentration varied from 0.001 to 0.038 Raman Unit (RU), with evident seasonal fluctuations. Rising limbs for COM values occurred prior to rising limbs within a dripwater hydrograph; moreover, the COM peak values corresponding to the beginning of the increasing hydrograph generally suggested that the mobilization of COM reflected the movement of the air–water interface (AWI) in the karst vadose zone rather than rainfall intensity or flow velocity. COM peak values were positively correlated with the antecedent drying duration and negatively correlated with HIX values. These phenomena may be explained by the increased amount of organic matter that was aggregated and absorbed on the surface of carbonate in the karst vadose zone during a longer drying duration. Moreover, the longer drying duration was also beneficial to autochthonous biological activity, which subsequently decreased the HIX value of the organic matter in the karst vadose zone. The movement of AWI and the drying duration are both controlled by the outside weather conditions. This study is therefore conducive to evaluating the security of karst groundwater in response to climate change, and challenges prevailing paleoclimate interpretations of colloid-facilitated metal abundance timeseries reported from speleothems.  相似文献   

First Multi‐Isotopic (Pb‐Nd‐Sr‐Zn‐Cu‐Fe) Characterisation of Dust Reference Materials (ATD and BCR‐723): A Multi‐Column Chromatographic Method Optimised to Trace Mineral and Anthropogenic Dust Sources     

Aubry Vanderstraeten  Steeve Bonneville  Stefania Gili  Jeroen de Jong  Wendy Debouge  Philippe Claeys  Nadine Mattielli 《Geostandards and Geoanalytical Research》2020,44(2):307-329

Atmospheric dust is an integral component of the Earth system with major implications for the climate, biosphere and public health. In this context, identifying and quantifying the provenance and the processes generating the various types of dust found in the atmosphere is paramount. Isotopic signatures of Pb, Nd, Sr, Zn, Cu and Fe are commonly used as sensitive geochemical tracers. However, their combined use is limited by the lack of (a) a dedicated chromatographic protocol to separate the six elements of interest for low‐mass samples and (b) specific reference materials for dust. Indeed, our work shows that USGS rock reference materials BHVO‐2, AGV‐2 and G‐2 are not applicable as substitute reference materials for dust. We characterised the isotopic signatures of these six elements in dust reference materials ATD and BCR‐723, representatives of natural and urban environments, respectively. To achieve this, we developed a specific procedure for dust, applicable in the 4–25 mg mass range, to separate the six elements using a multi‐column ion‐exchange chromatographic method and MC‐ICP‐MS measurements.  相似文献   

地缘政治视角下中亚“颜色革命”易发程度分析     

李希雅  王礼茂 《世界地理研究》2019,28(6):42-49

基于地缘政治视角，分析本世纪初发生在原苏联地区“颜色革命”的诱发因素，认为美国根据其地缘战略格局对“颜色革命”发生地存在一定程度的主观选择性，国家内部经济、政治、社会等层面的矛盾也同样作为发生背景。在中亚地缘格局动态分析的基础上，结合中亚五国形势，从时间和空间双重维度对中亚地区未来发生“颜色革命”的可能性进行识别与评判，得出1) 整体来看，中亚近期内爆发“颜色革命”可能性较小，但从长远来看不能掉以轻心。2)土、乌未来稳定可期，塔、吉、哈需谨防“颜色革命”卷土重来。  相似文献   

利用InSAR资料反演宁洱Ms6.4地震震源参数及库仑应力变化     

陈晨月  冯光财  高华  杨怀宁 《大地测量与地球动力学》2019,39(3):295-301

首先利用ALOS PALSAR数据，通过D-InSAR技术获取2007-06-03云南宁洱MS6.4地震的同震形变场，然后基于Okada弹性半空间位错模型反演该地震的断层几何以及精细滑动分布，最后计算宁洱地震后周边断层的静态库仑应力变化。结果表明，形变主要集中在西盘，最大视线向形变量为51.6 cm；反演得到的震源位置为23.05°N、101.02°E，深度3 km，断层走向145°，倾向49.5°，平均滑动角153°，发震断层为NNW向普洱断裂，断层活动以右旋走滑为主，兼具逆冲分量；断层面最大滑动量为1.2 m，反演得到的震级为MW619。基于库仑应力场发现，磨黑断裂处于库仑应力增加区域，而2014年景谷地震位于负值区域。结合实地考察资料和反演结果表明，宁洱地震为浅源地震，但断层并未出露地表。  相似文献   

基于GPS和水准数据的微粒群算法联合反演祁连山北缘断裂三维滑动速率     

刘杰 《大地测量与地球动力学》2019,39(9):906-909

将微粒群算法与位错理论模型相结合，采用中国地壳运动观测网络提供的青藏高原地区2001~2004年GPS测量数据和2000~2006年水准测量数据，通过常规定权和附有相对权比的方法对祁连山北缘断裂的三维滑动速率进行联合反演，并与蚁群算法反演结果进行对比。结果表明，微粒群算法收敛速度快、稳定性高，结合经典位错理论模型，是一种可以有效求解断层三维滑动速率反演问题的优化算法，在大地测量反演领域极具应用潜力。  相似文献   

辽东铀成矿带连山关地区韧性剪切带与铀成矿作用     

吴迪  刘永江  李伟民  常瑞虹 《岩石学报》2020,36(8):2571-2588

连山关地区位于华北克拉通北缘铀成矿省辽东铀成矿带，已知铀矿床（点）均发育在韧性剪切带附近。为了解韧性剪切带运动学、几何学构造变形机制及与铀矿的关系，本文以连山关岩体周缘韧性剪切带为研究对象，通过野外宏观调查和室内微观研究相结合的研究方法，探讨构造变形期次、韧性剪切带形成机理及其对铀成矿的控制作用。研究表明：连山关岩体周缘发育的韧性剪切带与近南北向挤压构造变形有关，其右行韧性剪切带应变类型为压扁应变，属于一般压缩-平面应变范围，Flinn指数K值在0.19~0.69之间，岩石类型属于S/SL型构造岩。研究区内铀矿体均为隐伏盲矿体，主要赋存于沿着连山关岩体和辽河群接触带右行剪切作用形成的背斜褶皱核部，和北东东向断裂关系密切。综合分析认为，连山关岩体南缘北西向韧性剪切带为一级控矿构造，是区内铀矿热液运移的通道，而剪切带边部的晚期北东东向断裂则是铀矿储存空间；铀源可能来自于太古宙古风化壳，并在大型韧性剪切活动（提供热液运移通道）和基性脉岩侵入（提供热源和还原剂）等综合因素作用下运移、富集成矿。  相似文献   

赣南狮吼山硫铁多金属矿区花岗岩地球化学、年代学特征及其成因     

贺根文  路思明  彭琳琳  于长琦  李伟  刘翠辉 《吉林大学学报(地球科学版)》2020,50(5):1491-1504

狮吼山矿区是江西省内规模最大的矽卡岩型硫铁多金属矿床，伴生W、Cu、Au多种成矿元素，成矿作用与矿区出露的茶山迳复式花岗岩体有关。岩体主要包括茶山迳似斑状黑云母二长花岗岩和莲湖细粒二长花岗岩两期，为研究成矿岩体的侵位时代、岩石成因及与成矿的关系，本次工作进行了U-Pb锆石定年、岩相学和岩石地球化学等测试分析。结果表明：岩体具有高硅、高钾、富铝的特征，属高钾钙碱性系列花岗岩；轻重稀土元素分馏明显，均为右倾型，弱Eu负异常，以富集Cs、Rb、Th、U、Pb，亏损Ba、Nb、Sr、和Ti等元素为主要特征，属于低Ba-Sr壳源花岗岩类；锆石具较好晶形，具典型岩浆锆石特征，利用LA-ICP-MS进行U-Pb测年，获得谐和年龄为（162.4±0.6）Ma（MSWD=1.8），加权平均年龄为（162.4±1.4）Ma（MSWD=1.4），谐和年龄与加权平均年龄在误差范围内高度一致，表明茶山迳复式岩体侵位于燕山早期中侏罗世；综合考虑岩体矿物组合、主微量元素及高分异特征，认为其成因分类应属于S型花岗岩；对比中国花岗岩成矿元素平均含量，茶山迳两期花岗岩均具有较高的W、Mo、Bi、Pb等成矿元素含量，可同时为成矿作用提供热源、流体及物质。  相似文献   

Conversion relationship of rainfall-soil moisture-groundwater in Quaternary thick cohesive soil in Jianghan Plain,Hubei Province,China     

《China Geology》2020,3(3):462-472

The scientific field test site of rainfall-soil moisture-groundwater conversion in Dabie Mountain Area–Jianghan Plain is located in the northern region of the Jianghan Plain, the transition zone between the Dabie Mountain Area and Jianghan Plain. It’s a great field test site to study the material and energy exchange among rainfall, soil moisture, and groundwater of the Earth ’s critical zone in subtropical monsoon climate plain areas. This paper analyzed the connection between rainfall and volume water content (VWC) of soil at different depths of several soil profiles, and the dynamic feature of groundwater was discussed, which reveals the rainfall infiltration recharge of Quaternary Upper Pleistocene strata. The results show that the Quaternary Upper Pleistocene aquifer groundwater accepts a little direct rainfall recharge, while the lateral recharge is the main supplement source. There were 75 effective rainfall events among 120 rainfall events during the monitoring period, with an accumulated amount of 672.9 mm, and the percentages of effective rainfall amount and duration time were 62.50% and 91.56%, respectively. The max evaporation depth at the upper part in Quaternary cohesive soil was no less than 1.4 m. The soil profile was divided into four zones: (1) The sensitive zone of rainfall infiltration within 1.4 m, where the material and energy exchange frequently near the interface between atmosphere and soil; (2) the buffer zone of rainfall infiltration between 1.4 m and 3.5 m; (3) the migration zone of rainfall infiltration between 3.5 m and 5.0 m; and (4) the rainfall infiltration and groundwater level co-influenced zone below 5.0 m. The results revealed the reaction of soil moisture and groundwater to rainfall in the area covered by cohesive soil under humid climate in Earth ’s critical zone, which is of great theoretical and practical significance for groundwater resources evaluation and development, groundwater environmental protection, ecological environmental improvement, drought disaster prevention, and flood disaster prevention in subtropical monsoon climate plain areas.  相似文献