Fluorine and chlorine in apatites,micas, and amphiboles of layered trap intrusions of the Siberian Platform     

V.V. Ryabov  O.N. Simonov  S.G. Snisar 《Russian Geology and Geophysics》2018,59(4):363-373

Geochemistry of chlorine and fluorine in apatites, micas, and amphiboles in rocks from eight intrusive complexes of the Siberian Platform has been first studied on the basis of new factual and analytical data (more than 1000 analyses). The main attention is focused on minerals from layered intrusions. Most apatites show F > Cl; the maximum contents of halogens are specific to chlorapatite (6.97 wt.% Cl) and fluorapatite (6.04 wt.% F). The total f value (f = Fe/(Fe + Mg), at.%) of femic minerals varies from 2 to 98 at.% in micas and from 22 to 95 at.% in amphiboles. The Cl-f and F-f trends show an increase in the Cl content and a decrease in the F content in the minerals with increasing f. Chlorine clearly exhibits ferrophilic properties, and fluorine has magnesiophilic properties. The halogen-richest minerals are fluorophlogopite (F = 7.06 wt.%, f = 7 at.%), chlorannite (Cl = 6.30 wt.%, f = 89 at.%), and chloroferrihastingsite (Cl = 5.22 wt.%, f = 90 at.%). Coexisting micas and amphiboles in the rocks are close in f value, but the micas are richer in Cl than the amphiboles. We assume that the halogen-containing minerals crystallized at the high pressure of halogen-hydrocarbon fluids at the levels of the MW, IW, and QIF buffers. The reducing conditions of the magmatism process are also evidenced by the presence of graphite and native metals in the rocks. The similarity of the Cl-f and F-f trends of micas and amphiboles from different intrusive complexes indicates the same mechanisms of the melt differentiation and mineral crystallization.  相似文献   

湘南香花岭锡铅锌多金属矿田的云母类型及对成矿的指示     

高粉粉  李凯旋  冷成彪 《地质论评》2022,68(4):1320-1344

湘南癞子岭花岗质复式岩体是香花岭锡铅锌多金属矿田的主要成矿岩体,其中云母广泛出现在各期次岩（矿）体之中。笔者等在对癞子岭岩体岩相学研究的基础上,开展全岩主微量元素地球化学分析,同时对岩浆成因云母（花岗岩中的云母）、热液成因云母（矿化云英岩、晶洞矿物集合体以及条纹岩中的云母）进行了电子探针分析。结果表明,癞子岭岩体为一套高钾钙碱性—钾玄质、准铝质—过铝质花岗岩,癞子岭岩体中的云母主要为铁锂云母,从早期到晚期,呈现出FeO和Al2O3含量降低,K2O、F、MnO和Rb2O含量升高,且Pb、Zn、Fe等成矿元素含量逐渐增加的特征。热液成因云母分为以下两种： ① 产于矿化云英岩和晶洞矿物集合体中的云母主要形成于流体出溶的早期,无围岩组分参与,云母类型由铁锂云母演化为锂云母,主要沉淀Fe、Zn、Pb、Mo等成矿元素;② 产于条纹岩中的云母晚于矿化云英岩和晶洞矿物集合体中的云母,有围岩组分参与,云母类型由黑鳞云母变为富镁黑云母和富铁黑云母再变为金云母,主要沉淀Fe、Sn和W等成矿元素。随着流体演化,云母呈现SiO2、F、K2O含量逐渐降低,MgO含量逐渐升高,相应的成矿元素从富Fe 、Zn、Pb、Mo逐渐过渡到富Fe 、Sn和W。  相似文献   

余庆县小腮钒矿地质特征及工业利用性能评价     

杨光龙  孙青  黎海涛  李克庆  朱正坤  杨志书 《贵州地质》2014,31(3):195-200

余庆县小腮地区的钒矿赋存于下寒武统牛蹄塘组近底部,具有品位低、厚度大的特点,矿石类型属炭质泥岩型钒矿.钒在原矿中的价态主要以V^3＋形式存在,其次为V^4＋和V^5＋,其中V^3＋主要以类质同象形式取代Al^3＋、Fe^3＋等氧化矿物及硅酸盐矿物,而V^4＋、V^5＋则全部以吸附状态赋存于云母类矿物中.矿石通过“原矿—破碎—磨矿—浸出—固液分离—萃取—反萃—沉钒—脱铵—五氧化二钒成品”提钒工艺,其五氧化二钒浸出率达85％,五氧化二钒总回收率为79.20％,在环境保护上能得到较好的控制,所得产品质量达GB3283-87冶金用V20599牌号标准.  相似文献   

Mica Inclusions inside Host Mica Grains from the Sutlej Section of the Higher Himalayan Crystallines, India—Morphology and Constrains in Genesis     

Soumyajit MUKHERJEE 《《地质学报》英文版》2014,88(6):1729-1741

Abstract: Biotite and muscovite inclusions inside mica host minerals from the Sutlej section of the Higher Himalayan Crystalline were studied under an optical microscope. These inclusions formed possibly by local recrystallization of mica grains during regional prograde metamorphism, with some affected by top-to-SW shear leading to parallelogram shapes. Recrystallization may have been assisted by solution transfer along the cleavage planes of the host grains. The relative competency of deformed phyllosilicate inclusions with the same or different composition to the host depends on the size and orientation of (001) cleavage planes of the inclusions relative to the host. Shearing of mica inclusions led to their parallelogram geometries within the contained mica inclusions. Some of the sheared inclusions deflect cleavage planes in the host minerals and define flanking microstructures. Trapezoid-shaped inclusions are a new finding that deserves more attention for their genesis. These structurally anisotropic inclusions did not originate from sub-grains, secondary infillings or retrogression. These inclusions are also not related to pseudomorphism, isomorphism, folding of the bulk rock etc. Some of the inclusions formed by recrystallization of the host mineral during top-to-SW ductile shear.  相似文献   

黔东北地区钒矿物质组分研究   总被引：3，自引：1，他引：2  

陈建华  彭家强  龙启金  陈波 《贵州地质》2008,25(3)

钒矿石的主要化学成份为SiO2和Al2O3,有机质总量一般为3.24%~10%,其次为TFe1.85%~3.25%,绝大部分V2O5含量均在1%左右,少部分大于2%;伴生元素以Mo、Ag、Cu、TiO2、P2O5、Ni、Co为主。  相似文献   

Sedimentary petrology and geochemistry of siliciclastic rocks from the upper Jurassic Tordillo Formation (Neuquén Basin, western Argentina): Implications for provenance and tectonic setting     

Luis A. Spalletti  Ignasi Queralt  Sergio D. Matheos  Ferrn Colombo  Jorge Maggi 《Journal of South American Earth Sciences》2008,25(4):440-463

The Upper Jurassic Tordillo Formation is exposed along the western edge of the Neuquén Basin (west central Argentina) and consists of fluvial strata deposited under arid/semiarid conditions. The pebble composition of conglomerates, mineralogical composition of sandstones and pelitic rocks, and major- and trace-element geochemistry of sandstones, mudstones, and primary pyroclastic deposits are evaluated to determine the provenance and tectonic setting of the sedimentary basin. Conglomerates and sandstones derived almost exclusively from volcanic sources. The stratigraphic sections to the south show a clast population of conglomerates dominated by silicic volcanic fragments and a predominance of feldspathic litharenites. This framework composition records erosion of Triassic–Jurassic synrift volcaniclastic rocks and basement rocks from the Huincul arch, which was exhumed as a result of Late Jurassic inversion. In the northwestern part of the study area, conglomerates show a large proportion of mafic and acidic volcanic rock fragments, and sandstones are characterised by a high content of mafic volcanic rock fragments and plagioclase. These data suggest that the source of the sandstones and conglomerates was primarily the Andean magmatic arc, located west of the Neuquén Basin. The clay mineral assemblage is interpreted as the result of a complex set of factors, including source rock, climate, transport, and diagenesis. Postdepositional processes produced significant variations in the original compositions, especially the fine-grained deposits. The Tordillo sediments are characterised by moderate SiO₂ contents, variable abundances of K₂O and Na₂O, and a relatively high proportion of ferromagnesian elements. The degree of chemical weathering in the source area, expressed as the chemical index of alteration, is low to moderate. The major element geochemistry and Th/Sc, K/Rb, Co/Th, La/Sc, and Cr/Th values point to a significant input of detrital volcanic material of calcalkaline felsic and intermediate composition. However, major element geochemistry is not useful for interpreting the tectonic setting. Discrimination plots based on immobile trace elements, such as Ti, Zr, La, Sc, and Th, show that most data lie in the active continental margin field. Geochemical information is not sufficiently sensitive to differentiate the two different source areas recognized by petrographic and modal analyses of conglomerates and sandstones.  相似文献   

江汉盆地东部早中生代沉积地层碎屑云母成分:对大别高压-超高压岩石暴露作用的约束   总被引：1，自引：0，他引：1  

李超  王岳军  范蔚茗  彭头平  陈新跃 《大地构造与成矿学》2006,30(3):392-400

碎屑白云母是碎屑岩中常见的、来自源区的稳定成分,可以用来指示源区性质,多硅白云母是碰撞造山高压-超高压变质岩石的特征矿物。对大别造山带同造山期沉积而成的江汉盆地东部上三叠统-中侏罗统砂岩碎屑白云母化学成分研究表明:上三叠统该区地层砂岩中碎屑白云母多以低硅白云母(Si<3.2)为特征,暗示此时大别造山带高压-超高压岩石很可能没有出露地表;自下侏罗统开始,砂岩中碎屑白云母中多硅白云母(Si>3.3)大量出现,中侏罗统砂岩多硅和低硅白云母发育,表明大别高压-超高压岩石在早侏罗世即已出露地表并经剥蚀搬运至盆地。这一结果从沉积学角度为约束高压-超高压岩石的折返时序和大别造山带演化提供了新的资料。  相似文献   

The Relationship between Tectono-metamorphic Evolution and Argon Isotope Records in White Mica: Constraints from in situ 40Ar-39Ar Laser Analysis of the Variscan Basement of Sardinia     

DI VINCENZO  GIANFRANCO; CAROSI  RODOLFO; PALMERI  ROSARIA 《Journal of Petrology》2004,45(5):1013-1043

The basement of Sardinia represents a nearly complete sectionof a segment of the Variscan belt that experienced a polyphasetectono-metamorphic evolution and Barrovian metamorphism. Thisbasement is well suited to investigate the relationship betweentectono-metamorphic evolution and argon isotope records in whitemica. Micaschists from the garnet zone (maximum T of up to 520–560°C)contain two texturally and chemically resolvable generationsof white mica: (1) deformed celadonite-rich flakes, defininga relict S₁ foliation preserved within the main S₂ foliationor enclosed in rotated albite porphyroblasts; (2) celadonite-poorwhite micas aligned along the main S₂ foliation. The S₁ foliationdeveloped earlier and at a deeper crustal level with respectto that at which the thermal peak was reached. From the staurolitezone (T of up to 590–625°C) to the sillimanite + K-feldsparzone, white mica is nearly uniform in composition (muscovite)and is predominantly aligned along the S₂ foliation or is oflater crystallization. In situ ⁴⁰Ar–³⁹Ar laser analysesof white mica yielded ages of  相似文献   

Provenance of Palaeozoic sandstones from the Carnic Alps (Austria): petrographic and geochemical indicators   总被引：1，自引：0，他引：1  

Dieter?MaderEmail author  Franz?Neubauer 《International Journal of Earth Sciences》2004,93(2):262-281

An integrated approach of petrographic analysis, whole rock geochemistry and microprobe analysis has been applied to obtain information on the geodynamic development and the provenance for Ordovician to Permian siliciclastic successions exposed within the Carnic Alps (Austria). Sandstone detrital mode and geochemical results refine previous geodynamic interpretations. Late Ordovician samples indicate a stable craton and recycled orogenic and, possible, extensional setting. The Early Carboniferous is interpreted to represent a compressional environment, followed by a Late Carboniferous molasse-type foreland basin, and a Permian extensional geodynamic setting. Contrasting geochemical patterns of post-Variscan and Permian sequences suggest a rift setting. Electron microprobe data of detrital white mica also indicate changes in the provenance. Compositional data reflect a shift from low- to medium-grade metamorphic (Ordovician) to high-grade metamorphic (Carboniferous) to low- to medium-grade metamorphic and plutonic source rocks (Permian). Additionally, our data show that various chemical discrimination diagrams do not include all possible ranges of sandstones, and that high contents of detrital mica and ultra-stable heavy minerals may cause misclassification. Consequently, we propose the use of multi-method approach for provenance studies, including the control of geochemical data by modal analysis and heavy mineral investigations.  相似文献   

右江盆地三叠纪岩层极低级变质作用及地球动力学意义   总被引：16，自引：1，他引：15       下载免费PDF全文

索书田  毕先梅  赵文霞  侯光久 《地质科学》1998,(4):395

 右江盆地三叠纪槽盆相浊流沉积岩系遭受过区域极低级变质作用。依据地质观察和伊利石结晶度、绿泥石-云母堆垛集合体、标志性粘土矿物及白云母(伊利石)b0参数测定资料,阐述了泥质岩石的成岩变质作用经浅层(近)变质作用到浅变质作用的转换特征。变质温度区间为150-350℃,低压类型,具高地温梯度(40-43℃/km).变质级及亚带总体与地层时代及岩层在地层柱中的位置有耦合关系,而与区域变形强度无关。最后指出区域极低级变质作用是印支-燕山构造旋回早期及区域变形前的地质事件,属于地壳伸展构造背景下右江边缘型盆地内部的埋藏型变质作用。  相似文献