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本文介绍了碱金属硼酸盐的一些基本知识,主要回顾了其中Li2O—B2O3体系的研究历史,讨论了该体系结构与性质的关系并总结了Li2O-B2O3晶态及非晶态物质作为新型功能材料的研究进展。 相似文献
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正1 Introduction Lithium and its compounds as national strategic resources are extensively used in national defense,industrial and agricultural production.As we know,the salt lakes in the western of China are famous for its high 相似文献
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辽宁东部古元古界底部地层(南辽河群)中赋存着大型的硼酸盐矿床,含矿层位中广泛分布含电气石的变粒岩和电英岩。空间上这些含电气石的岩石与硼酸盐有着密切的联系,电气石可以作为区域硼矿找矿的标志。已有研究结果表明,该地区的硼酸盐矿床是变质蒸发岩成因。本研究对该区不同产状的电气石和硼酸盐的地质特征,全岩和矿物成分、硼同位素组成进行了分析。本区的电气石包括层状和脉状两大类,而电气石的富集与硼酸盐关系密切,电英岩往往分布在硼酸盐矿体的上盘。而矿体的下盘一般不产出富电气石的岩石。当长英质脉体穿过硼酸盐矿体时,脉体中往往会富集电气石。含电气石岩石的全岩地球化学分析表明,它们的REE及其他微量元素特征以及相关性关系与周围不含电气石的同类岩石十分相似,反映出一种成因上的联系。本区电气石主要属于镁电气石一铁电气石系列,靠近硼矿体的电气石比远离硼矿体的电气石更加富镁,有着更高的Mg/Fe比值。电气石和硼酸盐的硼同位素成分分析显示出二者在同位素组成上的相似性,前者比后者的δ^11B稍低,这可能是由于热液活动过程中同位素分馏的结果。电气石的硼同位素组成在空间上显示出变化规律:远离硼酸盐矿体的电气石的δ^11B值(-5.2‰- 3.6‰)比矿体附近的电气石低(平均 10.5‰)。以上空间和成分上的关系表明硼酸盐可能是形成电气石主要的硼来源,电气石是在热液过程中通过淋滤下伏含硼蒸发岩中的硼形成含硼热液,在与上覆沉积物交代过程中形成含电气石岩石。电气石的条带是热液顺层选择交代的结果。本区电气石与硼酸盐的关系表明,层状电气石可以通过含硼热液交代的方式形成。变质地体中的层状电气石岩石的出现可能与变质蒸发岩有关。这一认识对区域硼矿勘查工作和变质地体的沉积环境分析有借鉴意义。 相似文献
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盐湖卤水体系Li~+,Mg~(2+)/Cl~-,SO_4~(2-),borate 总被引:1,自引:0,他引:1
本文总结了作者对盐卤硼酸盐体系Li+,Mg2+/Cl-,SO42-,B4O7(2-)-H2O研究的结果,对该体系涉及的硼酸盐的合成、鉴定和性质进行了研究,并对这些盐在纯水及一些盐溶液中的存在形式进行了初步探索.完成了该体系所包含的一些次级体系的相平衡及溶液物化性质的研究.提出了一种镁硼酸盐Mg2B6O(11)·17H2O的新合成方法.首次发现三方硼镁石在水中的相转化是分两个阶段进行,从而证明了尼古拉耶夫在25℃MgO—B2O3-H2O体系研究中三方硼镁石与章氏硼镁石的共饱点,实际上是三方硼镁石向多水硼镁石发生相转化的一个动力学的平衡点,热力学的个稳点的观点. 相似文献
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The Miocene borate deposits of western Turkey are associated with extensive medium- to high-K calc-alkali ignimbritic volcanism and a differentiated comagmatic alkaline trachybasalt–trachydacite lava suite. Ignimbritic air-fall and reworked pumiceous clastic materials are intimately associated with lake sediments that host the borate deposits. Local ignimbritic volcanism is considered the primary source of the B for the Kirka borate deposit in this area. Comparison of the geochemical composition of Turkish ignimbrites associated with borates (`fertile' ignimbrites) with those that do not (`barren' ignimbrites), exhibit a number of features that might prove useful in the exploration for borates in similar volcanic domains. In particular, `fertile' ignimbrites are (a) generally a high-K calc-alkali suite, well-evolved and fractionated (K/Rb is low, <200) with a high-silica rhyolitic bulk composition, (b) exhibit a combined high content of B, As, F, Li and Pb, with high B/La (>1) and B/K (>0.001) ratios, and (c) a mildly fractionated REE pattern (LaN/YbN∼2) and large positive Eu anomaly (Eu/Eu*∼0.1). Other apparent discriminants involving both compatible and incompatible elements (relative to major silicate phases) are largely a function of different degrees of partial melting and fractionation. It is suggested that the initial source of the B (and other associated elements) was from LIL-rich fluids released by the progressive dehydration of altered oceanic crust and pelagic sediments in a subduction zone. The absence or presence of sediments in a segmented subduction zone may influence the variable lateral distribution of borates in active margins on a global scale. Once the crust has become enriched in B via previous or contemporary subduction-related calc-alkali magmatism, the effect of tectonic environment, climate and hydrothermal activity influence the local development of the deposits. 相似文献
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非晶态镍硼酸盐的制备和表征 总被引:2,自引:2,他引:0
由摩尔比分别为1:2和1:8的六水氯化镍和硼砂反应得到两种镍硼酸盐样品1.25NiO·B_2O_3·4.5H_2O和NiO·B_2O_3·3.1H_2O。用XRD、TG-DSC、FT-IR和Raman等实验方法对其进行表征,样品为非晶态,确定了样品中的阴离子等,并结合化学分析结果近似确定了上述两种非晶态镍硼酸盐样品的结构组成式,前者为三元复盐,结构式为Ni[B_3O_3(OH)_5]·0.5Ni[B_2O(OH)_6]·Ni(OH)_2·4H_2O,后者结构式为Ni[B_2O(OH)_6]。 相似文献
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Calculation of thermodynamic properties of hydrated borates by group contribution method 总被引:2,自引:0,他引:2
General equations to correlate and predict the thermodynamic properties of hydrated borates were developed based on the experimental
results according to their structural types. The thermodynamic properties (ΔH
f
0 and ΔG
f
0) of a hydrated borate phase are the sum of the contributions of the cations in aqueous solution, the borate polyanions, and
the structural water to the corresponding thermodynamic properties. This method is called the group contribution method, and
it is extensively used to calculate the thermodynamic properties of many kinds of inorganic compounds, such as silicates and
clay minerals.
Received: 23 November 1998 / Accepted: 11 October 1999 相似文献
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不同形态硼酸盐焓、熵、吉布斯自由能等热力学参数极为缺乏,其准确测定对丰富和发展盐湖硼酸盐化学理论至关重要。本文采用TAM IV微量热计测定了五水合五硼酸钠(NaB5O8.5H2O)溶解热。根据设计的热化学循环,结合Pitzer电解质模型和热力学基本公式,首次获得了NaB5O8.5H2O在298.15 K下标准生成焓(, -5189.4820 kJ×mol-1)、标准生成熵(, 4380.4771 kJ×mol-1)、标准生成吉布斯自由能(, 4380.4771 kJ×mol-1)等热力学参数。这些尚未见报道的热力学参数对丰富无机盐热力学数据和促进盐湖资源综合利用具有重要的科学价值。 相似文献
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