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冀东太平寨紫苏花岗岩类深熔成因的矿物标志 总被引：1，自引：0，他引：1
冀东太平寨地区紫苏花岗岩的矿物学研究结果表明,该类岩石中的主要组成矿物具有残晶相和结晶相矿物共存特点。残晶相和结晶相矿物与围岩中同类矿物对比研究表明,该区的紫苏花岗岩类是由其围岩—石英闪长质-英云闪长质紫苏斜长片麻岩深熔而成。 相似文献
2.
Arrested charnockite formation at Kottavattam, southern India 总被引：7，自引：0，他引：7
Abstract At Kottavattam, southern Kerala (India), late Proterozoic homogeneous leptynitic garnet–biotite gneisses of granitic composition have been transformed on a decimetric scale into coarse-grained massive charnockite sensu stricto along a set of conjugate fractures transecting the gneissic foliation. Charnockitization post-dates the polyphase deformation, regional high-grade metamorphism and anatexis, and evidently occurred at a late stage of the Pan-African tectonothermal history. Geothermobarometric and fluid inclusion data document textural and chemical equilibration of the gneiss and charnockite assemblages at similar Plith–T conditions (650–700°C, 5–6 kbar) in the presence of carbonic fluids internally buffered by reaction with graphite and opaque mineral phases (XCO2= 0.7–0.6; XH2O= 0.2–0.3; XN2= 0.1; log fO2= -17.5). Mineralogical zonation indicates that charnockitization of the leptynitic gneiss involved first the breakdown of biotite and oxidation of graphite in narrow, outward-migrating transition zones adjacent to the gneiss, followed by the breakdown of garnet and the neoblastesis of hypersthene in the central charnockite zone. Compared to the host gneiss, the charnockite shows higher concentrations of K, Na, Sr, Ba and Zn and lower concentrations of Mg, Fe, Ti, V, Y, Zr and the HREE, with a complementary pattern in the narrow transition zones of biotite breakdown. The Plith–T–XH2O data and chemical zonation patterns indicate charnockitization through subsolidus-dehydration reaction in an open system. Subsequent residence of the carbonic fluids in the charnockite resulted in low-grade alteration causing modification of the syn-charnockitic elemental distribution patterns and the properties of entrapped fluids. We favour an internally controlled process of arrested charnockitization in which, during near-isothermal uplift, the release of carbonic fluids from decrepitating inclusions in the host gneiss into simultaneously developing fracture zones led to a change in the fluid regime from ‘fluid-absent’in the gneiss to ‘fluid-present’in the fracture zones and to the development of an initial fluid-pressure gradient, triggering the dehydration reaction. 相似文献
3.
《International Geology Review》2012,54(13):1688-1704
The Yinshan Block, part of the Neoarchaean basement of the Western Block of the North China Craton, is composed of granite–greenstone and granulite–charnockite complexes. We report research on a suite of charnockites from the granulite–charnockite complex and characterize their geochemistry, zircon U–Pb geochronology, and Hf isotopic composition. The charnockites can be divided into intermediate (SiO2 = 59–63 wt.%) and silicic (SiO2 = 69–71 wt.%) groups. U–Pb zircon data yield protolith formation ages of 2524 ± 4 Ma, 2533 ± 15 Ma, followed by metamorphism at 2498 ± 3 Ma, 2490 ± 11 Ma, respectively, for these groups. Although the intermediate charnockites are characterized by higher Al2O3, TiO2, Fe2O3T, MnO, MgO, CaO, P2O5, K2O, Sr, and ΣREE content than the silicic charnockites, the ages and Hf isotopic composition of zircons and REE patterns of both intermediate and silicic charnockites are remarkably consistent, which indicates that they are genetically related. These charnockites are predominantly metaluminous to slightly peraluminous, calc-alkalic to calcic, and magnesian – characteristics generally related to a subduction setting. High-Sr + Ba granites with low K2O/Na2O characteristics, shown by these charnockites, imply a mixture of mafic and felsic magmas generated from an enriched mantle + lower crust. High MgO, Ni, Cr and Mg#, low K2O/Na2O, and metaluminous to slightly peraluminous natures imply that the source rocks most likely were amphibolites. Coeval calc-alkaline magmatism and high-T granulite-facies metamorphism under low-H2O activity in the area lead us to propose a model involving mid-ocean ridge subduction within a Neoarchaean convergent margin. The arc-related rocks accreted along the continent margin, and became a barrier when the lithospheric mantle ascended through the slab window. Melt derived from the decompressing mantle mixed with melt derived from the overlying, juvenile lower crust melt, which was warmed and metamorphosed by the ascending lithospheric mantle. 相似文献
4.
R. K. LAL 《Journal of Metamorphic Geology》1993,11(6):855-866
Abstract Three reactions are calibrated as geothermobarometers for garnet–orthopyroxene–plagioclase–quartz assemblages, namely: 1/2 ferrosilite + 1/3 pyrope ± 1/2 enstatite + 1/3 almandine (A): ferrosilite + anorthite ± 2/3 almandine + 1/3 grossularite + quartz (B); and enstatite + anorthite ± 2/3 pyrope + 1/3 grossularite + quartz (C). The internally consistent geothermobarometers based on reactions (A), (B) and (C) are calibrated from experimental data only. The thermodynamic parameters of reaction (A) are derived from published experimental data in the FMAS system (n= 104) in the range 700–1400°C and 5–50 kbar, while those for reaction (B) are derived by summation of the existing reversed experimental data of the mineral equilibria: ferrosilite ± fayalite + quartz (D) and anorthite + fayalite ± 2/3 almandine + 1/3 grossularite (E). The retrieved thermodynamic parameters for reactions (A), (B) and (C) are, respectively: (ΔH0, cal) -3367 ± 209, -2749 ± 350 and +3985 ± 545; (ΔS0, cal K?1) -1.634 ± 0.163, -8.644 ± 0.298 and -5.376 ± 0.391; and (ΔV01,298, cal bar?1) -0.024, -0.60946 and -0.5614. On a one-cation basis, the derived Margules parameters of the ternary Ca–Fe–Mg in garnet are: WFe–Mg= -1256 + 1.0 (～0.23) T(K), WMg–Fe= 2880 -1.7 (～0.13) T(K), WCa–Mg= 4047 (～77) -1.5 T(K), WMg–Ca= 1000 (～77) -1.5 T(K), WCa–Fe= -723 + 0.332 (～0.02) T(K), WFe–Ca= 1090, (cal) and the ternary constant C123= -4498 + 1.516 (～0.265) T(K) cal (subregular solution model of non-ideal mixing); and Fe–Mg–Al in orthopyroxene: WFe–Mg= 948 (～200) -0.34 (～0.10) T(K), WFe–Al= -1950 (～500) and WMg–Al= 0 (cal) (regular solution model of non-ideal mixing). The anorthite activity in plagioclase is calculated by the ‘Al-avoidance’model of subregular Ca–Na mixing commonly used for geobarometry based on reactions (B) and (C). When the geothermobarometers are applied to garnet–orthopyroxene–plagioclase–quartz assemblages (n= 45) of wide compositional range from the Precambrian South Indian granulites, temperature ranges of 690–860°C (X= 760 ± 45°C) and pressure ranges of 5–10 kbar were obtained. The P–T values were estimated simultaneously and there is no difference in the pressure calculated from PMg (reaction C) and PFe (reaction B). In the existing calibrations this difference is 1 kbar or more. Furthermore, there is no compositional dependence of the ln K of the experimental data in the FMAS (n= 104) and the CFMAS (n= 78) systems at different temperatures and the estimated temperatures of the South Indian granulites. 相似文献
5.
R. C. NEWTON 《Journal of Metamorphic Geology》1992,10(3):383-400
Charnockitic alteration (arrested orthopyroxene formation in biotite- and amphibole-bearing rocks) occurs in high-grade terranes of all ages. Three criteria are used to show that this alteration was produced in many locations by a migrating fluid phase: (i) diffuseness of the alteration—the alteration zones are often quite unlike discrete migmatitic veins; (ii) relation to deformation—most occurrences show alteration closely associated with warping of foliation or dilation cracks; (iii) open-system alteration—whilst some occurrences represent nearly isochemical alteration, slight changes in bulk composition, often loss of mafic constituents and gain of Na and Si, are evident in detailed mass-balance analysis. Y and sometimes Rb are characteristically depleted. Partial melting sometimes accompanied volatile infiltration, as evidenced by more discrete veins and euhedral orthopyroxene. It is quite unlikely, however, that open-system alteration was produced by escape of viscous quartzo-feldspathic melts. Pervasive migration of low-T lamprophyric (mafic–alkaline, CO2-charged) interstitial liquids is a possibility by virtue of their extreme fluidity, but CO2 infiltration was needed to generate these liquids. Vapour-deficient dehydration melting is another feasible mechanism of orthopyroxene formation which may have operated in conjunction with CO2 infiltration. Characteristic development of charnockitic alteration in some prograde amphibolite to granulite facies transitions, as in the Dharwar Craton of South India, suggests that the alteration is a fundamental feature of the granulite facies metamorphism, implying active and causal participation of migrating fluids. In other high-grade terranes like the Adirondack Mountains of New York, this kind of alteration is rare, and fluid action does not seem to have been important in the metamorphism. A vapour phase participating in charnockitic metamorphism was necessarily one of relatively low H2O, therefore presumably rich in CO2. Consideration of possible large CO2 sources leads to the conclusion that emanations from volatile-rich basalts emplaced in the lower crust are the most probable source of charnockitizing fluids. The ultimate source would therefore be enriched subcontinental lithosphere or asthenosphere. The Rb-depleted pyroxene gneiss (charnockitic) terranes may be characteristic of zones of large-scale transcurrent or oblique-motion faults which tap such great depths. 相似文献
6.
Thermal perturbation during charnockitization and granulite facies metamorphism in southern India 总被引：1，自引：0，他引：1
Abstract We have deduced the steady-state lithospheric geotherm at c. 1 Ga in the south Indian shield area using the available data on the concentration of radioactive elements, and the P-T conditions of Proterozoic mantle xenoliths in the south Indian kimberlites as constraints. The geotherm was adjusted back to 2.5 Ga by keeping the surface temperature constant and calculating the temperature change at the top of convecting upper mantle. The reduced or mantle heat flux, which was treated as an adjustable parameter, was 20.9–21.3 mW/m2 at 1–2.5 Ga. Comparison of the calculated steady-state geotherm with the available P-T data of the Archaean (c. 2.5 Ga) charnockites and granulites from southern India suggests that the granulite facies metamorphism in this region had resulted from a major thermal perturbation, which was c. 400° C at 25 km. Seismic tomographic and gravity data essentially preclude any significant magma underplating of the granulitic crust in southern India. Previous workers have suggested that the formation of charnockites in this region was associated with copious CO2 influx from a deep-seated source, possibly the mantle. In this work, we have evaluated both the transient and steady-state thermal effects of the heat convected by CO2 outgassing from upper mantle. It is shown that the thermobarometric array of charnockites and granulites can be produced by the convective perturbation of the steady-state geotherm, and that a flux of CO2 of ±90 mol/m2 yr (corresponding to Darcy velocity of ±0.30 cm/yr) for a period of ±30 Ma was needed to produce the required perturbation. This is c. 150 times the average CO2 flux through the tectonically active area of the Earth's crust at the present time. There is, however, an uncertainty of a factor of 3 in this value. Seismic tomographic and gravity data independently suggest thickening of the crust beneath the granulite terrane compared with the adjacent Dharwar craton. This suggests thermal perturbation due to overthrusting as a major potential cause for the granulite facies metamorphism in south India. Overthrusting of a 30–35-km-thick thrust block was needed to produce the required thermal effect. The estimated thickness of the original crust from geobarometric and seismic tomographic data south of the orthopyroxene isograd or ‘transition zone’is compatible with the emplacement of a thrust block of this magnitude. However, the latter fails to match the estimated pre-uplift crustal thickness at the transition zone, if it is assumed that the crust has not thinned by non-erosional processes since the Archaean. Thus, we propose a combination of overthrusting and CO2 fluxing from a deep-seated source as the cause for the formation of charnockites in this zone. The required focusing of CO2 in this case is c. 40% of that estimated in the model where CO2 fluxing was considered to be the sole reason for thermal perturbation. This combined thrusting—CO2 fluxing model also helps explain the development of patchy charnockites in the transition zone from amphibolite facies rocks. 相似文献
7.
通过对山东沂水地区紫苏花岗岩野外地质特征、岩相学及地球化学特征等的研究,认为山东沂水地区紫苏花岗岩为变质表壳岩经深熔作用形成．其主要证据为：（１）紫苏花岗岩与变质表壳岩在空间上密切伴生,二者多为渐变过渡接触关系,且他们的片麻理协调一致;（２）在变质表壳岩中发育大量长英质或花岗质脉体,这些脉体的矿物成分、地球化学特征与紫苏花岗岩一致;（３）紫苏花岗岩与变质表壳岩具有相似的稀土配分型式;（４）紫苏花岗岩亏损大离子亲石元素及生热元素,其原岩应为经历了深变质作用的岩石;（５）紫苏花岗岩中锆石多为圆粒状和椭球状,并发育磨蚀坑,说明其原岩主要为变沉积岩;（６）麻粒岩相变质作用时间与紫苏花岗岩形成时间基本一致． 相似文献
8.
A. M. Larin 《Stratigraphy and Geological Correlation》2009,17(3):235-258
Rapakivi granites characteristic practically of all old platforms are greatly variable in age and irregularly distributed over the globe. Four types of magmatic associations, which include rapakivi granites, are represented by anorthosite-mangerite-charnockite-rapakivi granite, anorthosite-mangerite-rapakivi-peralkaline granite, gabbro-rapakivi granite-foidite, and rapakivi granite-shoshonite rock series. Granitoids of these associations used to be divided into the following three groups: (1) classical rapakivi granites from magmatic associations of the first three types, which correspond to subalkaline high-K and high-Fe reduced A2-type granites exemplifying the plumasitic trend of evolution; (2) peralkaline granites of the second magmatic association representing the highly differentiated A1-type reduced granites of Na-series, which are extremely enriched in incompatible elements and show the agpaitic trend of evolution; and (3) subalkaline oxidized granites of the fourth magmatic association ranging in composition from potassic A2-type granites to S-granites. Magmatic complexes including rapakivi granites originated during the geochronological interval that spanned three supercontinental cycles 2.7?1.8, 1.8?1.0 and 1.0?0.55 Ga ago. The onset and end of each cycle constrained the assembly periods of supercontinents and the formation epochs of predominantly anorthosite-charnockite complexes of the anorthosite-mangerite-charnockite-rapakivi granite magmatic association. Peak of the respective magmatism at the time of Grenvillian Orogeny signified the transition from the tectonics of small lithospheric plates to the subsequent plate tectonics of the current type. The outburst of rapakivi granite magmatism was typical of the second cycle exclusively. The anorthosite-mangerite-charnockite-rapakivi granite magmatic series associated with this magmatism originated in back-arc settings, if we consider the latter in a broad sense as corresponding to the rear parts of peripheral orogens whose evolution lasted from ～1.9 to 1.0 Ga. Magmatism of this kind was most active 1.8?1.3 Ga ago and represented the distal effect of subduction or collisional events along the convergent boundaries of lithospheric plates. An important factor that favored the emplacement of rapakivi granites and anorthosites in a huge volume was the thermal and rheologic state of the lithosphere inherited from antedating orogenic events, first of all from the event ～1.9 Ga ago, which was unique in terms of heat capacity transferred into the lithosphere. Anorthosite-mangerite-rapakivi granite-peralkaline granite magmatism is connected with activity of the mantle plums only. Degradation of the rapakivi granite magmatism toward the terminal Proterozoic was controlled by the general cooling of the Earth in the course of the steady dissipation of its endogenic energy, as these processes became accelerated since the Late Riphean 相似文献
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