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1.
在哈密黄山铜镍矿区,采用PIMA(便携式短波红外矿物分析仪)进行野外光谱测试,用新引进的TSG(光谱地质专家)软件进行了矿物种类及相对含量识别、光谱处理分析,为蚀变矿物光谱分析起到了示范作用。详细论述了几类典型蚀变矿物的光谱特征;对绿泥石特征光谱吸收强度D(Fe-OH)、D(Mg-OH)与矿物成分的关系进行了探讨。结果表明,绿泥石Fe-OH和Mg-OH吸收强度比值可以大体上代替Fe2+/Mg2+比值,D[Mg-OH)/(Fe-OH)+(Mg-OH)]值绝大部分在0.4~0.8之间。用HyMap数据做地质信息半定量反演,准确反映了各岩相主要金属元素含量的变化。研究结果对高光谱技术识别矿物种类、反演岩矿成分具有重要意义。  相似文献   
2.
曲希玉  刘珍  高媛  陈修  于强 《沉积学报》2015,33(4):786-794
以大牛地气田含绿泥石胶结物样品为研究对象,结合国内外研究现状,研究绿泥石包壳的成因及其对储层物性的影响,并探讨其环境指示意义.大牛地气田的绿泥石包壳形成于成岩作用早期,厚10~20 μm,由原生粒间孔的边缘向中心晶形渐好,颗粒渐大.据铁质来源绿泥石包壳可分为原地和异地成因,原地成因由先体黏土矿物和岩屑溶解未排出的富铁流体生成,一般以混层黏土和晶体较小的包壳形式存在;异地成因是富铁矿物及岩屑溶蚀、溶解形成的富铁流体通过河流异地絮凝沉淀生成,结晶充分、晶形好.绿泥石包壳的储层保护机理为:①抑制石英次生加大;②增加矿物颗粒间抗压实强度,抑制压溶作用;③抑制碳酸盐胶结,促进溶蚀作用.大牛地气田的绿泥石包壳主要发育于盒一段(63%)和山二段,当其含量在15%以下时,孔隙度随绿泥石含量的增高呈线性递增.绿泥石包壳可作为三角洲(辫状河三角洲)前缘水下分流河道(水下辫状河道)等强水动力条件的微观相标志.  相似文献   
3.
迪彦钦阿木矿床位于大兴安岭中段二连浩特-东乌旗多金属成矿带,是区内新近发现的一个超大型斑岩钼矿床.为了厘清蚀变矿物的成分对找矿的指示意义,文章运用电子探针和LA-ICP-MS对迪彦钦阿木矿床青磐岩化带绿帘石亚带的绿泥石和绿帘石的主微量元素成分进行了分析.电子探针数据表明,这些绿泥石属于铁斜绿泥石(辉绿泥石).绿泥石四面体位置置换为AlⅣ对Si的替换,八面体位置置换以Fe-Mg相互置换为主;主量元素除Fe、Mg呈现此消彼长的变化外,其他元素含量变化不大.矿区绿帘石属于普通绿帘石亚族,由热液交代角闪石和斜长石等矿物形成,可分为脉状和浸染状绿帘石,其主量元素含量差别不大.LA-ICP-MS分析结果显示,靠近矿体中心的绿泥石具有较高的近端指示元素(Sc、Ti、V、Cr、Mn、Co、Cu、Ga、Sn、Ba)含量以及较高的Ti/Sr、Ti/Pb、V/Ni比值,而离矿体中心较远的绿泥石具有较高的远端指示元素(Li、Na、K、Ni、Sr)含量.绿帘石中成矿金属含量比较低,离矿体中心较远的绿帘石相对富集As、Sb、Pb等元素.此外,绿帘石中w(Cr)、w(Ti)和w(V)以及Ti/Sr和V/Ni的比值随矿体品位的升高而降低.研究表明,迪彦钦阿木矿床绿泥石中w(Ti)、w(V)和w(Ga)及Ti/Sr、Ti/Pb和V/Ni比值,以及绿帘石中w(As)、w(Sb)和w(Pb)具有指示矿化中心的作用,而绿帘石中w(Cr)、w(Ti)和w(V)以及Ti/Sr和V/Ni值可以作为寻找斑岩矿床富矿体的指标.迪彦钦阿木矿床中绿泥石和绿帘石的元素变化主要受流体成分、温度、硫逸度、矿物共生组合等因素影响.文章获得的认识或可应用于其他类似斑岩钼矿床(点)的找矿勘探中.  相似文献   
4.
Field, hand specimen, and microscopic investigations alongside X-ray diffraction analyses revealed four types of hydrothermal alteration (Type-A, -B, -C, and -D) based on the mode of occurrence of altered rocks and alteration mineral assemblage at Hakusui-kyo and Horai-kyo along the Arima-Takatsuki Tectonic Line (ATTL) in western Japan. Type-A alteration locally occurred as gray alteration halos with sulfide minerals. Type-B and -C alterations were confined to fault gouge veins and occurred as greenish-gray veins and brown veins, respectively. Type-C alteration crosscut Type-B alteration. These alterations were associated with a number of granitic fragments including cohesive breccia and micrographic facies. Type-D alteration occurred locally in brown sediments. Different mineralogical features in the four alterations are summarized as (Type-A) illite; (Type-B) chlorite; (Type-C) limonite (Fe3+ hydroxides and goethite) and calcite; and (Type-D) limonite. We propose that the alterations can be broadly divided into Paleocene hydrothermal alteration (Type-A) and post-Late Miocene hydrothermal alteration (Type-B, -C, and -D): Type-A alteration occurred at approximately 200 °C during hydrothermal activity after a granitic intrusion in Late Cretaceous; Type-B, -C and -D alterations occurred under hydrothermal activity accompanying deep fluids with repeated ascents invoked by the seismicity of the ATTL after the Late Miocene. The fluids may have been the “Arima-type thermal waters” (i.e., mixtures of convective groundwater and Na-Ca-Cl-HCO3-type fluids). Type-B alteration occurred in fractures at depths where the temperature was ≥150 °C. Type-C alteration overprinted Type-B alteration as a result of mixing of new deep fluids and descending oxidized meteoric water near the surface. Fe3+ hydroxides and calcite precipitated from the fluids due to the oxidation of Fe2+ and the degassing of CO2, respectively, at ambient to near-boiling temperatures. When the ascending fluids gushed out from the fractures, they generated Type-D alteration at the surface under similar temperature conditions due to the oxidation of Fe2+.  相似文献   
5.
鄂尔多斯盆地纳岭沟铀矿床绿泥石特征及地质意义   总被引:3,自引:0,他引:3  
夏菲  孟华  聂逢君  严兆彬  张成勇  李满根 《地质学报》2016,90(12):3473-3482
纳岭沟铀矿床位于鄂尔多斯盆地北部,具有明显的后期热液作用的特征,矿体空间展布主要受控于绿色-灰色砂岩的过渡界面,与绿泥石化的蚀变砂岩关系密切。通过对纳岭沟铀矿床不同颜色砂岩中的绿泥石进行详细的岩相学研究和电子探针化学成分分析,依据绿泥石的成因与共生矿物的关系,识别出绿泥石主要的3种类型:填隙物型绿泥石,片状与黄铁矿共生型绿泥石以及黑云母蚀变型绿泥石;同时通过绿泥石的Fe-Si图解确定了纳岭沟铀矿床不同颜色砂岩中的绿泥石主要为铁镁绿泥石和密绿泥石。根据Al/(Fe+Mg+Al)-Mg/(Fe+Mg)的关系图解确定出不同颜色砂岩中的绿泥石具有铁镁质流体和泥质两种来源,通过绿泥石中主要阳离子与镁的关系图解和计算得出的绿泥石形成温度共同确定出绿泥石是多期次的中低温热液流体作用的产物。综合研究表明,纳岭沟铀矿床的绿泥石形成至少经历了温度稍高的还原性流体和温度稍低的氧化性流体等两个期次的流体作用,稍高温的还原性流体与成矿关系更为重要。与绿泥石形成有关的热液流体作用不仅带入了部分铀,还促进了铀的活化和运移。  相似文献   
6.
The source material, precursor and formation processes of chlorite rims, and impact of pore-lining chlorite on reservoir quality of the Shiqianfeng sandstones, Dongpu Depression, Bohai Bay Basin, China, are studied using an integrated approach, including core observation, point-count analysis of thin-sections, scanning electron microscopy, electron microprobe analysis and cathode luminescence. The petrographic analysis shows that chlorite rims consist of grain-coating chlorite, poorly crystalline pore-lining chlorite and euhedral-crystallised pore-lining chlorite. The chemical composition shows that pore-lining chlorite is mainly Fe-rich with an average of 0.785 for Fe/(Fe+Mg) ratio. Petrographic analysis shows a large amount of volcanic dust (3.0~16.0 vol%, average of 7.93 vol%) in Shiqianfeng sandstones, which determines the formation of poorly crystalline pore-lining chlorite. Transformation of volcanic dust to smectite rims started with shallow burial depth at an early diagenetic stage, followed by in situ alteration of the smectite rims to poorly crystalline chlorite rims. Euhedral-crystallised chlorite mainly develops in sandstones with high porosity, high permeability and open flow systems. Pore-lining chlorite can inhibit quartz overgrowth but cannot effectively prevent pore-filling of authigenic quartz, carbonate and kaolinite cements, and therefore cannot prevent porosity destruction. However, the occurrence of pore-lining chlorite is a barometer of good reservoir quality and intense hydrodynamic conditions.  相似文献   
7.
In this study, we applied chemical geothermometers to the estimation of formation temperatures of chlorites from various types of hydrothermally altered rocks in the Toyoha geothermal field, using core samples from six drill holes (TH-2 to TH-7) together with wasted ore samples from Toyoha vein-type ore deposit. Based on the preliminary examination of mineral assemblages by X-ray powder diffraction and optical microscopy, hydrothermal alteration observed through the drill holes was classified into four types of alteration zones: propylitic, mixed-layer minerals, kaolin minerals, and ore mineralized zones. The mineral assemblage of the ore mineralized zone observed through TH-2, TH-4, and TH-6 is similar to those of Toyoha ore veins reported previously. The Fe3+/ΣFe ratios of chlorites were determined by X-ray photoelectron spectroscopy (XPS), in addition to the usual microprobe analyses. The ratios ranged from 0.20–0.26 for chlorites from the propylitic alteration zone and from 0.13 to 0.17 for those from the ore mineralized zone associated with sulfide minerals. After correcting the Fe3+ contents in the octahedral sites of chlorite structures, we obtained acceptable temperatures of the chlorite formation by application of geothermometers, for instance, a similar range of 150–300°C for chlorites from either the propylitic zone or the ore mineralized zone developed through TH-2, TH-4, and TH-6. Chlorites from the ore mineralized zone proximal to the Toyoha deposit are characterized by high Fe and Mn contents compared to the propylitic chlorites, which is similar to the Toyoha vein-filling chlorites; the formation temperatures were close to both the homogenization temperatures of fluid inclusions and the present subsurface temperatures measured through drill holes. Chlorites from the Toyoha ore veins, however, gave slightly higher formation temperatures (180–350°C) than those of chlorites from the ore mineralized zone in the drill cores. This suggests that several types of hydrothermal alteration occurred at different stages in the Toyoha geothermal field and the composition of product chlorite was controlled not only by the temperature but also the composition of fluid related to the formation. Reliable estimation of temperature for the chlorite formation provides basic information on evaluating correctly other physicochemical conditions prevalent at the formation.  相似文献   
8.
Abstract

The characteristics and distribution of clay minerals and their effects on reservoir quality in the Huagang sandstones in the Xihu Sag, East China Sea Basin were studied by using X-ray diffraction, casting thin-sections, scanning electron microscopy, electron microprobe analysis, fluid inclusion analysis, constant-rate mercury injection and nuclear magnetic resonance. Clay minerals consist of kaolinite, chlorite, illite and illite–smectite mixed layer (I/S); kaolinite forms from dissolved feldspars, chlorite occurs as clay coatings that are transformed from clay precursors owing to the flocculation of suspended detrital clays or the crystallisation of pore fluids, and illite forms from the illitisation of detrital smectite, authigenic kaolinite and K-feldspars. Clay distribution is controlled by sedimentary environments, burial history and lithologies. Typical reservoirs in the western sub-sag are thin and developed in braided river facies at relatively shallow burial depths with clays dominated by kaolinite. However, typical reservoirs in the central inversion tectonic zone are thicker and developed in a braided delta front facies at deeper burial depths with clays mainly consisting of chlorite, illite and I/S. High-quality reservoirs are characterised by coarse granularity, high quartz content and low clay content with widespread development of chlorite coatings that inhibit quartz cements at low temperatures. At higher temperatures, the high-quality reservoirs develop more pores providing growth space for quartz cements and result in the coexistence of chlorite coatings and quartz cements. The high-quality reservoirs are controlled by their lithological characteristics rather than chlorite coatings. Illite and I/S clays create severe damage to reservoirs by reducing the size and connectivity of pore-throats.  相似文献   
9.
Detrital glaucony in the Palaeogene glauconitic sandstones in Siri Canyon, Danish North Sea, has been analysed from 15 exploration wells by X‐ray diffraction, electron microprobe and scanning electron microscopy. These sandstones consist of mixed‐layer illite/smectite and have a large variability in chemical composition and structure. In the most shallow wells (ca 1700 m), the glaucony is rich in Fe and consists of mixed‐layer illite/smectite with random‐interstratification (R = 0). In the depth interval from 1700 to 2000 m, the composition changes as Si is incorporated. The structure changes to ordered R = 1. Further increase in burial leads to the loss of Fe. Ordered R = 3 mixed‐layer illite/smectite is recognized from burial depths of 2200 m. The proportion of illite in illite/smectite mixed layers increases only slightly with depth and temperature. Although the structural changes generally are associated with chemical changes, they can also take place isochemically when the detrital glaucony is tightly embedded in earlier cement, which prevented chemical exchange. The glaucony transformation in the Siri Canyon sandstones partly reflects a supply of Si and partly significant loss of Fe. Thus, the glaucony transformation relates to the general diagenesis of the host sandstone. These sandstones are cemented by microquartz at an early stage, followed by precipitation of Fe‐rich grain‐coating berthierine or chlorite.  相似文献   
10.
绿泥石片岩各向异性特性研究   总被引:9,自引:0,他引:9  
刘胜利  陈善雄  余飞  赵文光 《岩土力学》2012,33(12):3616-3623
为研究十堰地区片岩的各向异性特性,开展了武当群绿泥石片岩长方体试样的单轴压缩和圆盘试样的间接拉伸试验,探讨了试样各向异性的力学特性和在不同受力状态下的变形破裂特性,揭示了不同变形破裂的力学机制。研究表明,武当群绿泥石片岩具有明显的各向异性性质,平行片理方向强度高,垂直片理方向强度低。该片岩特殊的定向排列片束状构造和片理间的弱胶结作用,致使不同方向上的破坏特征具有明显差异,其力学机制也不相同。在压应力作用下,泊松效应容易引起平行片理面的张拉劈裂和压杆失稳,垂直片理方向容易发生片理面间的剪切破坏。在同一方向上强度具有一致性,即平行片理面抗压和抗拉强度均较垂直片理面强度大。由于片理面间的抗拉承载力极低,在小角度劈裂荷载下,容易发生张拉劈裂和拉剪破坏,因此,实际工程中应尽可能避免片理面间的受拉破坏和沿片理的拉剪破坏。研究结果可以为隧道、边坡支护加固和防水处理提供参考。  相似文献   
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