不同颜色青海软玉微观形貌和矿物组成特征   总被引：1，自引：1，他引：0  

于海燕  阮青锋  孙媛  李东升 《岩矿测试》2018,37(6):626-636

青海软玉颜色丰富,近年来对青海软玉矿物学的研究不少,但针对不同颜色青海软玉矿物学特征的研究还存在欠缺。本文利用偏光显微镜、扫描电子显微镜、电子探针及粉晶X射线衍射仪器,从透闪石微形貌特征、微观结构、矿物组成及结晶度四个方面,研究了青海软玉颜色与矿物学特征的对应关系。结果表明:白玉、烟青玉、糖玉中透闪石主要为纤维状,显微纤维变晶结构,结晶度为96. 12%～96. 88%;青白玉和翠青玉中透闪石主要为叶片状,显微叶片变晶结构,结晶度为97. 35%,97. 32%;青玉和碧玉中透闪石主要为叶片状,显微叶片-隐晶质变晶结构,结晶度为95. 48%,95. 29%;黄玉中透闪石主要为柱状,显微柱状变晶结构,结晶度为97. 84%。青海软玉主要组成矿物均为透闪石,含量在95%以上,部分次要矿物如翠青玉中的榍石、黄玉中的钙长石、青玉中的菱镁矿、碧玉中的铬铁矿、糖玉中的斜黝帘石只出现在特定颜色的青海软玉样品中。研究认为不同颜色青海软玉矿物学特征确实存在差异,这些特征为研究不同颜色青海软玉成矿环境及成矿条件提供了科学依据。  相似文献   

内蒙古迪彦钦阿木斑岩钼矿床绿泥石和绿帘石矿物化学特征及其成矿指示意义     

王帏  冷成彪  张兴春  田振东 《矿床地质》2021,40(2):241-261

迪彦钦阿木矿床位于大兴安岭中段二连浩特-东乌旗多金属成矿带,是区内新近发现的一个超大型斑岩钼矿床.为了厘清蚀变矿物的成分对找矿的指示意义,文章运用电子探针和LA-ICP-MS对迪彦钦阿木矿床青磐岩化带绿帘石亚带的绿泥石和绿帘石的主微量元素成分进行了分析.电子探针数据表明,这些绿泥石属于铁斜绿泥石(辉绿泥石).绿泥石四面体位置置换为AlⅣ对Si的替换,八面体位置置换以Fe-Mg相互置换为主;主量元素除Fe、Mg呈现此消彼长的变化外,其他元素含量变化不大.矿区绿帘石属于普通绿帘石亚族,由热液交代角闪石和斜长石等矿物形成,可分为脉状和浸染状绿帘石,其主量元素含量差别不大.LA-ICP-MS分析结果显示,靠近矿体中心的绿泥石具有较高的近端指示元素(Sc、Ti、V、Cr、Mn、Co、Cu、Ga、Sn、Ba)含量以及较高的Ti/Sr、Ti/Pb、V/Ni比值,而离矿体中心较远的绿泥石具有较高的远端指示元素(Li、Na、K、Ni、Sr)含量.绿帘石中成矿金属含量比较低,离矿体中心较远的绿帘石相对富集As、Sb、Pb等元素.此外,绿帘石中w(Cr)、w(Ti)和w(V)以及Ti/Sr和V/Ni的比值随矿体品位的升高而降低.研究表明,迪彦钦阿木矿床绿泥石中w(Ti)、w(V)和w(Ga)及Ti/Sr、Ti/Pb和V/Ni比值,以及绿帘石中w(As)、w(Sb)和w(Pb)具有指示矿化中心的作用,而绿帘石中w(Cr)、w(Ti)和w(V)以及Ti/Sr和V/Ni值可以作为寻找斑岩矿床富矿体的指标.迪彦钦阿木矿床中绿泥石和绿帘石的元素变化主要受流体成分、温度、硫逸度、矿物共生组合等因素影响.文章获得的认识或可应用于其他类似斑岩钼矿床(点)的找矿勘探中.  相似文献   

湘南铜山岭矽卡岩铜铅锌矿床矿物组合分带特征及温压条件研究     

黄旭栋  陆建军  高剑峰  章荣清  SIZARET Stanislas  马东升  王汝成 《矿床地质》2023,42(3):506-530

湘南铜山岭矽卡岩铜铅锌矿床产于铜山岭岩体北东缘隐伏接触带及其外围地层中,在成因上与铜山岭花岗闪长斑岩密切相关。铜山岭铜铅锌矿床具有独特的成矿分带,从岩体向外依次发育近端内矽卡岩、近端外矽卡岩、硫化物-石英脉和远端矽卡岩矿体。根据穿切关系、交代结构和矿物组合等地质特征可以把铜山岭铜铅锌矿床划分为4个矿化蚀变阶段,从早到晚依次为进变质矽卡岩、退变质矽卡岩、石英-硫化物和碳酸盐阶段,其中石英-硫化物阶段为主成矿阶段。闪锌矿成分压力计研究表明,近端内矽卡岩型团块状硫化物矿石中闪锌矿的形成压力为(3.1±1.0)×108Pa,对应的成矿深度为6～12 km,相当于中—上地壳水平,说明铜山岭铜铅锌矿床形成于较大深度。近端内矽卡岩、近端外矽卡岩和远端矽卡岩中都存在两阶段绿泥石。绿泥石成分温度计研究表明,3类矽卡岩中退变质矽卡岩阶段绿泥石的形成温度分别为345～388℃、296～376℃和296～338℃,代表各类矽卡岩形成温度的下限;石英-硫化物阶段绿泥石的形成温度分别为270～318℃、209～238℃和200～223℃,代表各类矽卡岩矿体的成矿温度。3类矽卡岩的绿泥石温度表现出逐步降低的趋势,指...  相似文献   

Formation of chlorite rims and the impact of pore-lining chlorite on reservoir quality: a case study from Shiqianfeng sandstones in upper Permian of Dongpu Depression,Bohai Bay Basin,eastern China     

P. J. Ma  C. Y. Lin  C. M. Dong  Y. F. Xu 《Australian Journal of Earth Sciences》2017,64(6):825-839

The source material, precursor and formation processes of chlorite rims, and impact of pore-lining chlorite on reservoir quality of the Shiqianfeng sandstones, Dongpu Depression, Bohai Bay Basin, China, are studied using an integrated approach, including core observation, point-count analysis of thin-sections, scanning electron microscopy, electron microprobe analysis and cathode luminescence. The petrographic analysis shows that chlorite rims consist of grain-coating chlorite, poorly crystalline pore-lining chlorite and euhedral-crystallised pore-lining chlorite. The chemical composition shows that pore-lining chlorite is mainly Fe-rich with an average of 0.785 for Fe/(Fe+Mg) ratio. Petrographic analysis shows a large amount of volcanic dust (3.0～16.0 vol%, average of 7.93 vol%) in Shiqianfeng sandstones, which determines the formation of poorly crystalline pore-lining chlorite. Transformation of volcanic dust to smectite rims started with shallow burial depth at an early diagenetic stage, followed by in situ alteration of the smectite rims to poorly crystalline chlorite rims. Euhedral-crystallised chlorite mainly develops in sandstones with high porosity, high permeability and open flow systems. Pore-lining chlorite can inhibit quartz overgrowth but cannot effectively prevent pore-filling of authigenic quartz, carbonate and kaolinite cements, and therefore cannot prevent porosity destruction. However, the occurrence of pore-lining chlorite is a barometer of good reservoir quality and intense hydrodynamic conditions.  相似文献   

鄂尔多斯盆地镇泾区块上三叠统延长组砂岩中绿泥石矿物特征   总被引：11，自引：0，他引：11  

张霞 《地质学报》2011,85(10):1659-1671

本文对鄂尔多斯盆地镇泾区块上三叠统延长组长8油层组砂岩中绿泥石矿物的类型、赋存状态、形成时间、晶体化学特征及成因机制进行了较为系统的研究.结果表明研究区的绿泥石以铁镁绿泥石和铁斜绿泥石为主,包括陆源碎屑绿泥石、自生绿泥石和蚀变绿泥石3种,自生绿泥石又包括颗粒包膜、孔隙衬里和孔隙充填绿泥石3种,以孔隙衬里绿泥石为主,形成...  相似文献   

鄂尔多斯盆地东南部延长组储层成岩体系研究   总被引：8，自引：2，他引：6  

丁晓琪  张哨楠  葛鹏莉  易超 《沉积学报》2011,29(1):97-104

鄂尔多斯盆地东南部延长组具有丰富的油气资源,储集层为一套致密低渗透砂岩,油气的富集与致密低渗透背景下的高效储层有关。通过铸体薄片、背散射、扫描电镜及能谱分析,结合孔、渗测定,认为:①延长组高效储层的形成与绿泥石环边有密切关系,绿泥石环边的出现是三角洲前缘沉积环境、富黑云母的长石砂岩和咸—微咸水的湖泊水体在空间上耦合的产物;②绿泥石环边抵消了一部分埋藏过程中上覆地层的机械压实作用,减缓了由于压实作用而引起的原生孔隙的减低,而且有抑制石英次生加大的作用;③同生期形成的方解石可以使颗粒呈嵌晶接触,形成致密层,但是这部分方解石量小且分布不均匀;④自生石英在纵向上变化明显,封闭体系中形成的SiO2由于绿泥石环边的抑制作用,以雏晶的形式产出;而半封闭体系中形成的SiO2可向上发生运移,在绿泥石环边不连续或欠发育的层段以加大边的形式产出。通过成岩体系研究,可以明确高效储层的形成机理,指导岩性油气藏的勘探。  相似文献   

绿泥石包壳对碎屑岩储层物性的影响及其形成环境--以鄂尔多斯盆地大牛地气田上古生界为例   总被引：1，自引：0，他引：1  

曲希玉  刘珍  高媛  陈修  于强 《沉积学报》2015,33(4):786-794

以大牛地气田含绿泥石胶结物样品为研究对象,结合国内外研究现状,研究绿泥石包壳的成因及其对储层物性的影响,并探讨其环境指示意义.大牛地气田的绿泥石包壳形成于成岩作用早期,厚10~20 μm,由原生粒间孔的边缘向中心晶形渐好,颗粒渐大.据铁质来源绿泥石包壳可分为原地和异地成因,原地成因由先体黏土矿物和岩屑溶解未排出的富铁流体生成,一般以混层黏土和晶体较小的包壳形式存在;异地成因是富铁矿物及岩屑溶蚀、溶解形成的富铁流体通过河流异地絮凝沉淀生成,结晶充分、晶形好.绿泥石包壳的储层保护机理为:①抑制石英次生加大;②增加矿物颗粒间抗压实强度,抑制压溶作用;③抑制碳酸盐胶结,促进溶蚀作用.大牛地气田的绿泥石包壳主要发育于盒一段(63%)和山二段,当其含量在15%以下时,孔隙度随绿泥石含量的增高呈线性递增.绿泥石包壳可作为三角洲(辫状河三角洲)前缘水下分流河道(水下辫状河道)等强水动力条件的微观相标志.  相似文献   

Characteristics and distribution of clay minerals and their effects on reservoir quality: Huagang Formation in the Xihu Sag,East China Sea Basin     

X. L. Sun  X. G. Zhang  J. L. Lin  Z. X. Zhao  D. W. Huang 《Australian Journal of Earth Sciences》2013,60(8):1163-1174

Abstract

The characteristics and distribution of clay minerals and their effects on reservoir quality in the Huagang sandstones in the Xihu Sag, East China Sea Basin were studied by using X-ray diffraction, casting thin-sections, scanning electron microscopy, electron microprobe analysis, fluid inclusion analysis, constant-rate mercury injection and nuclear magnetic resonance. Clay minerals consist of kaolinite, chlorite, illite and illite–smectite mixed layer (I/S); kaolinite forms from dissolved feldspars, chlorite occurs as clay coatings that are transformed from clay precursors owing to the flocculation of suspended detrital clays or the crystallisation of pore fluids, and illite forms from the illitisation of detrital smectite, authigenic kaolinite and K-feldspars. Clay distribution is controlled by sedimentary environments, burial history and lithologies. Typical reservoirs in the western sub-sag are thin and developed in braided river facies at relatively shallow burial depths with clays dominated by kaolinite. However, typical reservoirs in the central inversion tectonic zone are thicker and developed in a braided delta front facies at deeper burial depths with clays mainly consisting of chlorite, illite and I/S. High-quality reservoirs are characterised by coarse granularity, high quartz content and low clay content with widespread development of chlorite coatings that inhibit quartz cements at low temperatures. At higher temperatures, the high-quality reservoirs develop more pores providing growth space for quartz cements and result in the coexistence of chlorite coatings and quartz cements. The high-quality reservoirs are controlled by their lithological characteristics rather than chlorite coatings. Illite and I/S clays create severe damage to reservoirs by reducing the size and connectivity of pore-throats.  相似文献   

The assemblage stilpnomelane–chlorite–phengitic mica: a geothermobarometer for blueschist and associated greenschist terranes     

Currie  & Van Staal 《Journal of Metamorphic Geology》1999,17(6):613-620

Two anhydrous equilibria can be written among the components of stilpnomelane, chlorite, white mica and quartz, namely 89 daphnite+131 Fe-celadonite+190 quartz=96 stilpnomelane+71 muscovite, and amesite+Mg-celadonite=muscovite+clinochlore. We assume that the free energy change of reaction, ΔG=ΔG^o+ΣRT lna_i^j, is approximated by ΔG=A?BT +C(P?1)+ΣRT lna_i^j, where ΔG^o is the free energy change of the end-member components at temperature T and pressure P, a_i is the activity of component i whose coefficient in the equilibrium is j, and A, B and C are constants to be determined. Values of C can be approximated by the change in volume on reaction, namely C=406.517 J/bar for the first reaction and C=0.613 J/bar for the second reaction. Constants A and B were determined by using six occurrences of the assemblage stilpnomelane–chlorite–white mica for which P–T have been otherwise estimated. Using solution models from the literature, linear regression gives for the first equation A=?6118.269 kJ, B=?4584.09 J/K, and for the second equation A=19.397 kJ, B=66.72 J/K. These values predict P–T within 0.5 kbar and 25 K for all occurrences, and appear reasonably robust relative to probable analytical errors. P–T are determined by intersection of the curves generated by given compositions in P–T space. Fine-grained and/or zoned chlorite and white mica make application of the geothermobarometer difficult in some instances, but our work in the Bathurst region of New Brunswick suggests that, with patience and care, useful analyses can be obtained, and the database for the geothermobarometer greatly expanded.  相似文献   

Metamorphic and cooling history of the Shimanto accretionary complex,Kyushu, Southwest Japan: Implications for the timing of out‐of‐sequence thrusting     

Hidetoshi Hara  Katsumi Kimura 《Island Arc》2008,17(4):546-559

Illite crystallinity, K–Ar dating of illite, and fission‐track dating of zircon are analyzed in the hanging wall (Sampodake unit) and footwall (Mikado unit) of a seismogenic out‐of‐sequence thrust (Nobeoka thrust) within the Shimanto accretionary complex of central Kyushu, southwest Japan. The obtained metamorphic temperatures, and timing of metamorphism and cooling, reveal the tectono‐metamorphic evolution of the complex, and related development of the Nobeoka thrust. Illite crystallinity data indicate that the Late Cretaceous Sampodake unit was metamorphosed at temperatures of around 300 to 310°C, while the Middle Eocene Mikado unit was metamorphosed at 260 to 300°C. Illite K–Ar ages and zircon fission‐track ages constrain the timing of metamorphism of the Sampodake unit to the early Middle Eocene (46 to 50 Ma, mean = 48 Ma). Metamorphism of the Mikado unit occurred no earlier than 40 Ma, which is the youngest depositional age of the unit. The Nobeoka thrust is inferred to have been active during about 40 to 48 Ma, as the Sampodake unit started its post metamorphic cooling after 48 Ma and was thrust over the Mikado unit at about 40 Ma along the Nobeoka thrust. These results indicate that the Nobeoka thrust was active for more than 10 million years.  相似文献