西藏雄村斑岩型铜(金)矿床Ⅰ、Ⅱ号矿体热液黑云母特征及地质意义     

肖鸿天  谢富伟  郎兴海  冉凤琴 《岩石矿物学杂志》2020,39(4):469-480

雄村铜(金)矿区位于西藏冈底斯成矿带中段南缘,由Ⅰ、Ⅱ、Ⅲ号矿体和多个矿化体组成。本文以Ⅰ、Ⅱ号矿体钾硅酸盐化蚀变带内的热液黑云母为研究对象,采用光薄片镜下鉴定、电子探针等分析方法,系统研究了热液黑云母的产状和成分特征。结果显示,雄村矿区Ⅰ号矿体黑云母类型主要为金云母和镁质黑云母;Ⅱ号矿体黑云母类型为镁质黑云母。两个矿体黑云母都具有低Ti(TiO_2 3%)、高Al(Al_2O_315%)的特点,且具有较高的MgO含量,Mg/Fe0.5,K/Na10,显示了与矿化良好的相关性。Ⅰ号矿体热液黑云母平均结晶温度470℃,氧逸度位于镍-氧化镍缓冲剂与磁铁矿-钛铁矿缓冲剂之间(NNO—HM);Ⅱ号矿体热液黑云母平均结晶温度234℃,氧逸度位于镍-氧化镍缓冲剂与铁橄榄石-石英-磁铁矿缓冲剂之间(NNO—FQM),说明Ⅰ号矿体形成于较高温、高氧逸度的热液系统,Ⅱ号矿体形成于相对较低温、低氧逸度的热液系统。此外,Ⅰ号矿体热液黑云母Ⅳ(F)值介于0.61～2.72之间,平均值1.26,Ⅳ(Cl)值介于-5.49～-4.53之间,平均值-5.03,Ⅳ(F/Cl)值介于5.63～7.89之间,平均值6.29;Ⅱ号矿体热液黑云母Ⅳ(F)值介于1.83～3.32之间,平均值2.66,Ⅳ(Cl)值介于-5.64～-4.89之间,平均值-5.31,Ⅳ(F/Cl)值介于7.14～8.68之间,平均值7.97,说明Ⅰ、Ⅱ号矿体都形成于富Cl的热液系统,且Ⅱ号矿体热液较Ⅰ号矿体更富Cl,贫F。富Cl流体易萃取流体中的Cu和Au等金属元素并以Cl的络合物形式运移,在沿构造裂隙向上运移的过程中,物理化学条件发生改变,使得流体中金属元素络合物溶解度降低,促使硫化物沉淀成矿。  相似文献   

罗非鱼源无乳链球菌(Streptococcus agalactiae)新型AI-2信号分子受体RbsB蛋白结晶生长研究   总被引：1，自引：0，他引：1  

樊博琳  潘丽霞  王忠良  黎源  简纪常  王蓓 《海洋与湖沼》2020,51(1):132-140

为了开展无乳链球菌(Streptococcus agalactiae)核糖结合蛋白(Ribose binding protein B,RbsB)结构功能的研究,本实验根据已知无乳链球菌ZQ0910全基因组序列设计相关引物。采用PCR方法扩增其RbsB基因,随后将该基因定向克隆到原核表达载体pGEX-6p-1中,在大肠杆菌BL21(DE3)感受态细胞中进行IPTG诱导表达;采用HRV 3C蛋白酶切除GST标签,分子筛分离获得RbsB蛋白;运用生物信息学软件对RbsB基因序列进行分析,并对RbsB蛋白二级和三级结构进行预测;采用NeXtal Tubes JCSG Core Suite结晶试剂盒筛选蛋白结晶条件。研究结果表明,该基因全长为969碱基,编码322个氨基酸,RbsB蛋白理论分子量33.9ku,等电点为9.41,二级结构中α螺旋结构所占比重最高,建立RbsB蛋白三维结构模式图;经IPTG诱导后表达的融合蛋白分子量为59ku,筛选RbsB蛋白的初始结晶条件为(0.2mol/L di-Potassium hydrogen phosphate,20%(W/V)PEG3350;1.5mol/L ammonium sulfate,25%(V/V)Glycerol),获得RbsB蛋白结晶体。本研究结果可为无乳链球菌核糖结合蛋白(RbsB)的功能解析提供实验及理论基础。  相似文献   

Geochemical Characteristics and Tectonic Significance of Aoyougou Group Basalts in Western North Qilian     

Yixin Liu  Kexuan Hou  Xin Sha  Zhen Ma  Jinrong Wang 《地球科学进展》2018,33(2):189-205

The North Qilian orogenic belt is a typical plate suture zone, which is studded with numerous different sizes of fragments of micro-continental crust consisting of pre-Sinian metamorphic rocks and the North Qilian orogenic belt provides important study carrier for studying the pre-orogenic tectonic process of the North Qilian. The relatively complete volcanic-clastic-carbonate rocks formation of Zhulongguan Group, Changchengian System, Mesoproterozoic are distributed in the Kawa-Qiqing area, Western North Qilian orogenic belt. Geochemical characteristics of the Aoyougou Group basalts in the North Qilian indicated that the contents of major element were relatively stable, high K₂O contents(4.27%~6.07%), TFe₂O₃(10.49%~13.01%),TiO₂(1.96%~2.90%)and middle MgO(5.37%~6.71%,Mg^# 48~51), CaO(2.57%~5.51%)content. Thus, the Aoyougou Group basalts belong to potassium alkaline basalt. The contents of Cr and Ni of the basalts decreased with the decreasing of Mg^#, and there was a positive correlation between CaO and CaO/Al₂O₃, Furthermore, the Eu anomaly of samples was slightly negative, high contents of high field strength elements (HFSE, Nb, Ta, Ti), and the ratios of Gd/Yb(2.5~3.0), Zr/Y(8.6~10.2), Ta/Yb(0.96~1.23), Ti/Yb(5 074~6 021), Zr/Yb(81~97), Ce/Nb(1.87), Zr/Nb(6.41)indicated that the Aoyougou Group basalts had obvious OIB-type magmatic affinity. In combination with the regional geological background, the study results showed that Aoyougou Group alkaline basalt generated from deep enrichment mantle similar to the source of OIB, with fractional crystallization of olivine and monoclinic pyroxene and a certain degree of contamination of continental crust in the process of magmatism, formed in the background of continental rift, might response to the Proterozoic Columbia supercontinent rifting, which further provides important petrological evidences for the relationship between North China Craton rifting events and Columbia supercontinent rifting during Proterozoic.  相似文献   

伟晶质岩浆的同化混染与分离结晶(AFC)作用及铀成矿效应:以纳米比亚湖山铀矿为例     

黄冉笑  王果胜  袁国礼  邱坤峰  Hounkpe Jechonias BIDOSSESSI 《地学前缘》2022,29(1):377-402

纳米比亚湖山铀矿位于达马拉造山带的中央南部地区,工业铀矿物为晶质铀矿,属于伟晶岩型铀矿床。关于不同矿石中铀元素的富集与沉淀机制还存在一定争议。为了揭示伟晶质岩浆演化与铀矿化作用的关系,本文对矿区内不同矿物组成的伟晶岩型矿石开展了岩石和矿物地球化学研究。野外及镜下鉴定结果显示,矿化伟晶岩可以分为“简单类型”矿体和“复杂类型”矿体。前者具有正常的花岗伟晶结构,晶质铀矿均匀分布于造岩矿物之间,矿化程度低到中等;后者表现出非均匀的结构特征,且矿化程度极高,晶质铀矿在成因上与大量黑云母团块有明显的空间联系。地球化学研究表明:在“简单类型”伟晶岩中,铀元素主要通过伟晶质岩浆的分离结晶作用富集;“复杂类型”伟晶质岩浆的演化则明显受控于同化混染作用,其铀矿化为岩浆同化混染与分离结晶(assimilation-fractional crystallization,AFC)作用产物。具体而言,外来基性组分(FeO,MgO,TiO₂,MnO)的混入导致“复杂类型”熔体中矿物的结晶顺序发生改变,长石类矿物的“延后”结晶为黑云母提供了更加有利的结晶空间和条件,促使黑云母以团块状聚集的形式产出。黑云母的大量析出会引发残余岩浆中UF_m^4-m络合物的水解,导致晶质铀矿在团块黑云母内部或周围沉淀。因此,本文有关“简单类型”和“复杂类型”产铀伟晶岩的研究,有效地揭示了岩浆演化过程与铀矿化机制,丰富了伟晶岩型铀矿床理论,为后期勘查开发提供了科学依据。  相似文献   

Constraints of Mantle and Crustal Sources Interaction during Orogenesis of Pre- and Post-collision Granitoids from the Northern Arabian-Nubian Shield: A Case Study from Wadi El-Akhder Granitoids,Southern Sinai,Egypt     

Moustafa M. MOGAHED  Khaled M. ABDELFADIL 《《地质学报》英文版》2021,95(5):1527-1550

The Egyptian older and younger granitic rocks emplaced during pre- and post-collision stages of Neoproterozoic Pan-African orogeny, respectively, are widely distributed in the southern Sinai Peninsula, constituting 70% of the basement outcrops. The Wadi El-Akhder, southwestern Sinai, is a mountainous terrain exposing two granitoid suites, namely the Wadi El-Akhder Older Granites (AOG) and the Homra Younger Granites (HYG). The AOG (granodiorites with subordinate tonalite compositions) have geochemical characteristics of medium-K calc-alkaline, metaluminous to mildly peraluminous granitoids formed in an island-arc environment, which are conformable with well-known Egyptian older granitoids rocks, whereas the HYG display calc-alkaline to slightly alkaline nature, peraluminous syeno-, monzogranites and alkali feldspar granites matching well those of the Egyptian younger granites. With respect to the AOG granitoids, the HYG granites contain lower Al2O3, FeO*, MgO, MnO, CaO, TiO2, Sr, Ba, and V, but higher Na2O, K2O, Nb, Zr, Th, and Rb. The AOG are generally characterized by enrichment in LILE and LREE and depletion in HFSE relative to N-MORB values (e.g., negative Nb and Ta anomalies). The geochemical features of the AOG follow assimilation-fractional crystallization (AFC) trends indicative of extensive crustal contamination of magma derived from a mantle source. The chemical characteristics of the AOG are remarkably similar to those of subduction-related granitoids from the Arabian-Nubian Shield (ANS). The compositional variations from monzogranites through syenogranites to alkali feldspar granite within HYG could not be explained by fractional crystallization solely. Correlating the whole-rock composition of the HYG to melts generated by experimental dehydration melting of meta-sedimentary and magmatic rocks reveals that they appear to be derived by extended melting of psammitic and pelitic metasediments, which is similar to the most of younger granitic suites in the ANS.  相似文献   

喜马拉雅淡色花岗岩——关键金属Sn-Cs-Tl的富集机制     

高利娥  曾令森  严立龙  高家昊  赵令浩 《岩石学报》2021,37(10):2923-2943

关键金属是全球高科技产业不可或缺的战略性资源,其富集机制和成矿作用是目前国际矿床学研究的热点之一。我们对喜马拉雅带吉隆和亚东地区淡色花岗岩开展系统的地球化学研究,发现侵入到藏南拆离系的淡色花岗岩含有较高的Sn、Cs、Tl、Be、W、B、Li和Bi。全岩元素地球化学分析表明,这些淡色花岗岩具有如下特征：（1）富集关键金属元素;（2）为原始岩浆经历斜长石、锆石、独居石、磷灰石、云母分离结晶作用后的残余熔体;（3）关键元素的富集和矿化与花岗岩高度分离结晶作用密切相关。随着分异程度的增强,岩浆变为富挥发分的高SiO₂体系,关键金属元素在残余熔体中富集,并且最后可能形成具有工业价值的矿床。由于地球化学特征的相似性,Cs和Tl呈类质同象替代钾、铷进入云母中。富集关键金属元素的花岗岩在时间上和空间上属于与藏南拆离系相关的同构造侵位花岗岩,藏南拆离系的活动促使了原始岩浆的广泛分离结晶作用,以及后期的关键金属元素（如Rb、Cs和Tl）的富集。  相似文献   

估算钙碱性长英质侵入岩结晶压力的地质压力计评述     

徐鸿雪  汪洋 《地质论评》2023,69(4):2023040029-2023040029

本文对四种常见的矿物压力计（角闪石全铝压力计、黑云母压力计、榍石压力计和“石英”压力计）的适用性进行了经验性检验。基于国内外典型钙碱性长英质岩体的矿物化学和全岩化学成分数据,采用不同压力计估算岩体侵位压力,并与角闪石全铝压力计结果对比。结果表明：角闪石六次配位Al压力计与广泛使用的角闪石全铝压力计的估算值存在系统相关性;榍石压力计计算的压力与角闪石全铝压力计的估计结果相关性较为显著;基于Qtz—Ab—Or简并花岗岩体系的“石英”压力计可以用于估计准铝质—弱过铝质钙碱性（狭义）花岗岩的结晶压力。但是,经验性的黑云母压力计和基于实验数据的黑云母压力压计均不能很好地复现角闪石全铝压力计的结果。黑云母压力计不适用于估算钙碱性侵入岩的结晶压力。  相似文献   

Was the Panzhihua Large Fe-Ti Oxide Deposit,SW China,Formed by Silicate Immiscibility?     

DING Xiangli  CHEN Xuanhu  SHAO Zhaogang 《《地质学报》英文版》2023,97(5):1451-1461

The Panzhihua mafic intrusion, which hosts a world-class Fe-Ti-V ore deposit, is in the western Emeishan region, SW China. The formation age(～260 Ma), and Sr and Nd isotopes indicate that the Panzhihua intrusion is part of the Emeishan large igneous province and has little crustal contamination. To assess ore genesis of the Panzhihua Fe-Ti-V ore deposit, two different models have been provided to explain the formation, namely silicate immiscibility and normal fractional crystallization. Silicate...  相似文献   

Formation of anorthosite on the Moon through magma ocean fractional crystallization   总被引：1，自引：1，他引：0  

Tatsuyuki Arai  Shigenori Maruyama 《地学前缘(英文版)》2017,8(2):299-308

Lunar anorthosite is a major rock of the lunar highlands,which formed as a result of plagioclasefloatation in the lunar magma ocean(LMO).Constraints on the sufficient conditions that resulted in the formation of a thick pure anorthosite(mode of plagioclase 95 vol.%) is a key to reveal the early magmatic evolution of the terrestrial planets.To form the pure lunar anorthosite,plagioclase should have separated from the magma ocean with low crystal fraction.Crystal networks of plagioclase and mafic minerals develop when the crystal fraction in the magma(φ) is higher than ca.40-60 vol.%,which inhibit the formation of pure anorthosite.In contrast,when φ is small,the magma ocean is highly turbulent,and plagioclase is likely to become entrained in the turbulent magma rather than separated from the melt.To determine the necessary conditions in which anorthosite forms from the LMO,this study adopted the energy criterion formulated by Solomatov.The composition of melt,temperature,and pressure when plagioclase crystallizes are constrained by using MELTS/pMELTS to calculate the density and viscosity of the melt.When plagioclase starts to crystallize,the Mg~# of melt becomes 0.59 at 1291 C.The density of the melt is smaller than that of plagioclase for P 2.1 kbar(ca.50 km deep),and the critical diameter of plagioclase to separate from the melt becomes larger than the typical crystal diameter of plagioclase(1.8-3 cm).This suggests that plagioclase is likely entrained in the LMO just after the plagioclase starts to crystallize.When the Mg~# of melt becomes 0.54 at 1263 C,the density of melt becomes larger than that of plagioclase even for 0 kbar.When the Mg~# of melt decreases down to 0.46 at 1218 C,the critical diameter of plagioclase to separate from the melt becomes 1.5-2.5 cm,which is nearly equal to the typical plagioclase of the lunar anorthosite.This suggests that plagioclase could separate from the melt.One of the differences between the Earth and the Moon is the presence of water.If the terrestrial magma ocean was saturated with H_2O,plagioclase could not crystallize,and anorthosite could not form.  相似文献   

Petrogenesis and geochemical characteristics of plagiogranites from Naga Ophiolite Belt,northeast India: Fractional crystallization of MORB-type magma     

《Chemie der Erde / Geochemistry》2017,77(1):183-194

The Naga Ophiolite Belt is a part of the Naga-Arakan-Yoma flysch trough that occurs along the Indo-Myanmar border. It is represented by peridotites, mafic-ultramafic cumulates, mafic volcanics, mafic dykes, plagiogranites, pelagic sediments and minor felsic to intermediate intrusives. Minor plagiogranites, gabbros and thin serpentinite bands occur juxtaposed near Luthur, with the slate-phyllite-metagreywacke sequence (Phokpur Formation) adjacent to the contact. The development of tonalites, trondhjemites and diorites in the oceanic crust, which is grouped as plagiogranites, offers an opportunity to study the process of formation of silicic melts from mafic crust. Plagiogranites from Naga Ophiolite Belt contains moderate SiO₂ (51.81–56.71 wt.%), low K₂O (0.08–1.65 wt.%) and high Na₂O (4.3–5.03 wt.%). The Naga Ophiolite Belt plagiogranites like ocean-ridge granites contain low K₂O, high Na₂O and CaO. The rocks investigated from Naga Ophiolite Belt contain TiO₂ concentrations above the lower limit for fractionated Mid Oceanic Ridge Basalt which is above 1 wt% of TiO₂ and the ternary plots of A (Na₂O + K₂O) F(FeO^T) M(MgO) and TiO₂-K₂O-SiO₂/50 indicate that the plagiogranite are tholeiitic in character and gabbro samples are calc-alkaline in nature. The plagiogranites are enriched in Rb, Ba, Th, U, Nb and Sm against chondrite with negative anomalies on Sr and Zr whereas Y and Yb are depleted to Mid Oceanic Ridge Basalt. The chondrite normalized REE patterns of the plagiogranite display enrichments in LREE (La_N/Sm_N: 2.37–3.62) and flat HREE (Eu/Eu*: 0.90–1.06). The Mid Oceanic Ridge Basalt normalization of gabbro is characterized by strong enrichment of LILE like Ba and Th. The REE pattern is about 50–100 times chondrite with slight enrichment of LREE (La_N/Sm_N = 2.21–3.13) and flat HREE (Eu/Eu*: 0.94–1.19). The major-element and trace element data of the NOB plagiogranites and their intrusive nature with host gabbroic rock suggest that the plagiogranites were produced by fractional crystallization of basaltic parental magmas at Mid Oceanic Ridge.  相似文献