The information system of the French Peatland Observation Service: Service National d'Observation Tourbières – A valuable tool to assess the impact of global changes on the hydrology and biogeochemistry of temperate peatlands through long term monitoring     

Sébastien Gogo  Jean-Baptiste Paroissien  Fatima Laggoun-Défarge  Jean-Marc Antoine  Léonard Bernard-Jannin  Guillaume Bertrand  Philippe Binet  Stéphane Binet  Guillaume Bouger  Yohann Brossard  Thierry Camboulive  Jean-Pierre Caudal  Stéphane Chevrier  Geneviève Chiapiuso  Benoît D'Angelo  Pilar Durantez  Chris Flechard  André-Jean Francez  Didier Galop  Laure Gandois  Daniel Gilbert  Christophe Guimbaud  Louis Hinault  Adrien Jacotot  Franck Le Moing  Emilie Lerigoleur  Gaël Le Roux  Fabien Leroy  Alexandre Lhosmot  Qian Li  Elodie Machado Da Silva  Jean-Sébastien Moquet  Juanita Mora-Gomez  Laurent Perdereau  Thomas Rosset  Marie-Laure Toussaint 《水文研究》2021,35(6):e14244

Mitigating and adapting to global changes requires a better understanding of the response of the Biosphere to these environmental variations. Human disturbances and their effects act in the long term (decades to centuries) and consequently, a similar time frame is needed to fully understand the hydrological and biogeochemical functioning of a natural system. To this end, the ‘Centre National de la Recherche Scientifique’ (CNRS) promotes and certifies long-term monitoring tools called national observation services or ‘Service National d'Observation’ (SNO) in a large range of hydrological and biogeochemical systems (e.g., cryosphere, catchments, aquifers). The SNO investigating peatlands, the SNO ‘Tourbières’, was certified in 2011 ( https://www.sno-tourbieres.cnrs.fr/ ). Peatlands are mostly found in the high latitudes of the northern hemisphere and French peatlands are located in the southern part of this area. Thus, they are located in environmental conditions that will occur in northern peatlands in coming decades or centuries and can be considered as sentinels. The SNO Tourbières is composed of four peatlands: La Guette (lowland central France), Landemarais (lowland oceanic western France), Frasne (upland continental eastern France) and Bernadouze (upland southern France). Thirty target variables are monitored to study the hydrological and biogeochemical functioning of the sites. They are grouped into four datasets: hydrology, fluvial export of organic matter, greenhouse gas fluxes and meteorology/soil physics. The data from all sites follow a common processing chain from the sensors to the public repository. The raw data are stored on an FTP server. After operator or automatic processing, data are stored in a database, from which a web application extracts the data to make them available ( https://data-snot.cnrs.fr/data-access/ ). Each year at least, an archive of each dataset is stored in Zenodo, with a digital object identifier (DOI) attribution ( https://zenodo.org/communities/sno_tourbieres_data/ ).  相似文献   

First Multi‐Isotopic (Pb‐Nd‐Sr‐Zn‐Cu‐Fe) Characterisation of Dust Reference Materials (ATD and BCR‐723): A Multi‐Column Chromatographic Method Optimised to Trace Mineral and Anthropogenic Dust Sources     

Aubry Vanderstraeten  Steeve Bonneville  Stefania Gili  Jeroen de Jong  Wendy Debouge  Philippe Claeys  Nadine Mattielli 《Geostandards and Geoanalytical Research》2020,44(2):307-329

Atmospheric dust is an integral component of the Earth system with major implications for the climate, biosphere and public health. In this context, identifying and quantifying the provenance and the processes generating the various types of dust found in the atmosphere is paramount. Isotopic signatures of Pb, Nd, Sr, Zn, Cu and Fe are commonly used as sensitive geochemical tracers. However, their combined use is limited by the lack of (a) a dedicated chromatographic protocol to separate the six elements of interest for low‐mass samples and (b) specific reference materials for dust. Indeed, our work shows that USGS rock reference materials BHVO‐2, AGV‐2 and G‐2 are not applicable as substitute reference materials for dust. We characterised the isotopic signatures of these six elements in dust reference materials ATD and BCR‐723, representatives of natural and urban environments, respectively. To achieve this, we developed a specific procedure for dust, applicable in the 4–25 mg mass range, to separate the six elements using a multi‐column ion‐exchange chromatographic method and MC‐ICP‐MS measurements.  相似文献   

基于邻域约束聚类的地球化学异常提取     

杨昭颖  冯磊  姜德才  朱月琴  余先川 《地质通报》2019,38(12):2077-2084

通过分析地球化学数据的元素值属性和空间位置，提出一种基于邻域约束聚类的方法，使用该方法对地球化学元素聚类后，能提取矩形、环状、半环状等特殊形状，进而提取地球化学异常。选取河南崤山地区2个实验区的地球化学数据进行实验，实验一的结果表明，出现矩形的位置与已知钨矿矿点位置一致；实验二的结果表明，出现环形的位置与已知铜矿矿点位置一致。实验证明了基于邻域约束聚类的方法在提取地球化学异常方面的有效性。  相似文献   

金矿立体地球化学探测模型与深部钻探验证   总被引：1，自引：0，他引：1  

王学求  张必敏  于学峰  杨德平  夏勇  谭亲平  刘耀文  张苏坤  田密  刘汉粮  李瑞红  韩志轩  熊玉新  吴慧  张宝云 《地球学报》2020,41(6):869-885

深部资源地球化学探测科学问题的的焦点是元素大深度垂向迁移机理和立体地球化学探测模型的建立。本文以胶东蚀变岩型金矿和贵州水银洞卡林型金矿钻孔岩芯和地表联合取样获得的数据, 建立千米深度立体地球化学探测模型。蚀变岩型金矿立体地球化学模型显示, Au、S和Hg与金矿密切相关, 分布模式既有相似性又有差异性, Au的立体几何分布模式兼具矿化剂元素S和远程指示元素Hg的双重特征, 金异常和矿化剂元素硫与矿体倾斜方向一致, 反映了成矿过程中流体沿控矿构造的轴向运移; 金异常与类气体元素汞在垂向上一致, 而且出现从矿体到地表的连续贯通式异常, 反映了流体沿微裂隙和纳米孔的垂向迁移。卡林型金矿立体地球化学模型显示, Au、As、Sb、Hg、Tl和S在不整合面都显示高含量特征, 与深部层状主矿体分布一致; 在矿体上覆地层中都存在弱异常, 显示了明显的成矿流体沿隐伏微小断裂垂向迁移特点; 所不同的是Sb和Tl元素在不整合面附近显示了最高的元素含量, 而Sb和Hg在近地表均显示了明显高的异常特征。立体几何模型清晰地显示了矿体的展布特征和范围, 而且金及其伴生元素垂向迁移在地表形成清晰异常, 为利用金及伴生元素和矿化剂元素进行深部矿体三维预测提供了重要依据, 对指导深部金矿勘查发挥了重要作用。针对胶东蚀变岩型金矿地表完全被土壤覆盖区的穿透性地球化学微细粒级土壤采样, 金属活动态提取分析圈定的异常, 经深部钻探验证, 胶东焦家成矿带五一村3200 m钻探, 在2428.00~3234.16 m深度发现6层矿化体, 其中高品位矿体位于2854 m深度; 上宫金矿地表基岩出露, 采集断层泥或裂隙岩石样品, 可以清晰探测深部异常, 经2000 m钻探, 在1312 m处发现高品位金铅锌银矿体; 贵州水银洞采集地表细粒级土壤, 能够直接有效地揭示深部金矿体, 经500~1500 m钻探验证, 在300~1500 m深度新增金资源量203 t。  相似文献   

历史遗址类旅游地的生命周期研究——以美国14家历史遗址公园为例     

杨小露  张红  张春晖 《地理科学进展》2019,38(6):918-929

实证研究中旅游地生命周期理论的运用潜力备受质疑。论文选取美国14家国家历史遗址公园为例,采用旅游研究中较少使用的四参数Logistic模型结合一次函数、二次函数、三次函数、高斯多峰分析法拟合旅游地的生命周期。研究发现：四参数Logistic模型结合一次函数、二次函数、三次函数能较好地拟合旅游地的生命周期;利用四参数Logistic曲线的上弯点、拐点、下弯点能定量的划分出旅游地的起步探索、发展、巩固、停滞阶段,一次函数、二次函数、三次函数能拟合旅游地的衰退或复兴阶段,这回答了学者们对生命周期阶段难以定量划分的质疑。根据旅游地停滞期之后的发展趋势还能归纳出该类旅游地的生命周期类型;高斯多峰分析法将旅游地的生命周期拟合成一个个波动的高斯峰,更大程度上保留了旅游地演进的波动特征;将高斯多峰分析法与四参数Logistic模型结合起来,不仅能定量划分旅游地的生命周期阶段,还能准确地描述在生命周期阶段内的波动情况,甚至分析各生命周期阶段对整个生命周期的影响和作用。  相似文献   

基于镁铁-超镁铁岩中单斜辉石主量元素含量的决策树集成算法对比     

孙建鹍  杜雪亮  章宝月  王龙  金维浚  张旗  罗熊  朱月琴 《地质通报》2019,38(12):1981-1991

依靠岩浆构造环境的地球化学成分认识岩浆形成过程是岩石地球化学中的重要应用。当前利用岩石地球化学成分判别构造环境的工作还不够深入。用4种基于决策树的机器学习方法对来自全球新生代洋岛玄武岩(OIB)、岛弧玄武岩(IAB)及大洋中脊玄武岩(MORB)等镁铁-超镁铁岩中单斜辉石的13种主量元素构成数据集进行了岩浆构造环境判别和主要特征排序。通过对比4种基于决策树的机器学习方法,验证了树类算法对于地球化学成分识别问题的有效性,并总结出4种方法在处理岩浆构造环境判别问题时的优劣:决策树算法判别过程更易于理解,但是其准确率欠佳;boosting算法中的AdaBoost和GBDT对于岩浆构造环境的鉴别准确度较高,但构造过程复杂;bagging集成算法随机森林在权衡性能和模型可理解性时不失为一个良好的选择。此外,还通过4种算法的特征重要性排序得出Cr_2O_3,TFeO,TiO_2,FeO和Al_2O_3是进行岩浆构造环境判别的重要成分。  相似文献   

城镇增长下的收缩：以武汉为例     

高喆  尹宁玮  童馨仪  李东欣  顾江 《热带地理》2019,39(1):29-36

首先从人口、经济、用地3个维度综合考察武汉市增长与收缩的全貌，并采用县区及街道2个尺度的数据定量描述了武汉市增长与收缩的特征与空间格局，发现武汉市下辖青山区、硚口区、汉阳区和蔡甸区存在局部较严重的收缩现象，空间上形成集聚，形态上呈“穿孔式”。进一步以青山区为案例，着重从资本视角探讨发生局部收缩的内在机制，发现其存在老龄化、少子化趋势，但局部收缩的主因是资本从产业部门的“逃逸”。  相似文献   

内蒙古格勒敖包奥陶纪岩体锆石U-Pb年龄及地球化学特征     

曹磊  苏茂荣  周飞  李磊  杨宝宏 《地质通报》2019,38(4):632-642

内蒙古格勒敖包位于兴蒙造山带内,对该区奥陶纪岩浆岩的研究,有助于进一步认识该造山带早古生代的构造格局及其演化。正长花岗岩和斑状二长花岗岩样品LA-ICP-MS锆石年龄为441.6±3.7～454.9±4.6Ma,形成时代为奥陶纪。经地球化学分析,岩体为高钾钙碱性系列;铝饱和指数显示其为过铝质花岗岩。岩石富集大离子亲石元素(LILEs)Rb、Th、U、K,亏损Ba、Sr;富集高场强元素(HFSEs)La、Ce、Nd、Zr,亏损Nb、P、Ti;稀土元素总量为38.7×10~(-6)～120.23×10~(-6),轻稀土元素较重稀土元素分异明显,分馏程度较高,表现出较弱的负Eu异常。综合区域地质资料,认为格勒敖包奥陶纪岩浆源区为上地壳物质的部分熔融,其形成环境为弧后盆地,在古亚洲洋向北俯冲之后经历了岛弧岩浆作用旋回,为弧后伸张阶段的产物。  相似文献   

Sedimentary and geochemical characterization of Middle–Late Miocene formations in the Neogene Tsugaru Basin,Japan by means of DTH27‐1 well sediment analysis     

Paolo Martizzi  Shun Chiyonobu  Hiroyuki Arato 《Island Arc》2020,29(1)

Middle–Late Miocene age siliceous formations outcropping along the northwestern side of Honshu Island are considered prospective source rocks for hydrocarbons. An analysis of geophysical, sedimentological, and geochemical properties is essential to evaluate the formations' source potential, and to understand the factors that determined the accumulation and preservation of organic matter. This study investigates the Middle–Late Miocene geological record of the Tsugaru back‐arc basin, located in the western part of Aomori prefecture, through an analysis of a 200 m long portion of a core from the DTH27‐1 well; this core is composed of the diatomaceous siltstones of the Akaishi Formation and the siliceous mudstones of the Odoji Formation. Sedimentological and geophysical characterization showed that the Akaishi Formation's diatomaceous siltstones are mostly massive and bioturbated, have low magnetic susceptibility, and demonstrate moderate natural radioactivity. Although the Odoji Formation's siliceous mudstones are massive, they have exceedingly low magnetic susceptibility and high natural radioactivity. Geochemical data from a Rock‐Eval Pyrolysis such as total organic carbon and generative potential (S1 + S2) revealed that, in the Tsugaru area, only the Odoji Formation is a likely prospective source rock for hydrocarbons. On the other hand, T_max values indicate that both the formations are thermally immature for generating hydrocarbons. The difference between the Akaishi and Odoji Formation in the sedimentological facies, in terms of the degree of bioturbation and the organic carbon content, indicates variations in lithological properties, such as porosity and grain size; moreover, this difference indicates a variation in the paleo‐oxygenation of bottom waters, with the transition from oxygen‐deficient conditions in the Middle Miocene to the more oxygenated conditions in the Late Miocene. Both the lithological and paleo‐environmental factors possibly influenced the organic richness in the two formations.  相似文献   

Redox evolution of western Tianshan subduction zone and its effect on deep carbon cycle     

《地学前缘(英文版)》2020,11(3):915-924

Knowing the phase relations of carbon-bearing phases at high-pressure(HP) and high-temperature(HT) condition is essential for understanding the deep carbon cycle in the subduction zones.In particular,the phase relation of carbon-bearing phases is also strongly influenced by redox condition of subduction zones,which is poorly explored.Here we summarized the phase relations of carbon-bearing phases(calcite,aragonite,dolomite,magnesite,graphite,hydrocarbon) in HP metamorphic rocks(marble,metapelite,eclogite) from the Western Tianshan subduction zone and high-pressure experiments.During prograde progress of subduction,carbonates in altered oceanic crust change from Ca-carbonate(calcite) to Ca,Mg-carbonate(dolomite),then finally to Mgcarbonate(magnesite) via Mg-Ca cation exchange reaction between silicate and carbonate,while calcite in sedimentary calcareous ooze on oceanic crust directly transfers to high-pressure aragonite in marble or amorphous CaCO3 in subduction zones.Redox evolution also plays a significant effect on the carbon speciation in the Western Tianshan subduction zone.The prograde oxygen fugacity of the Western Tianshan subduction zone was constrained by mineral assemblage of garnet-omphacite from FMQ-1.9 to FMQ-2.5 at its metamorphic peak(maximum P-T) conditions.In comparison with redox conditions of other subduction zones,Western Tianshan has the lowest oxygen fugacity.Graphite and light hydrocarbon inclusions were ubiqutously identified in Western Tianshan HP metamorphic rocks and speculated to be formed from reduction of Fe-carbonate at low redox condition,which is also confirmed by high-pressure experimental simulation.Based on petrological observation and high-pressure simulation,a polarized redox model of reducing slab but oxidizing mantle wedge in subduction zone is proposed,and its effect on deep carbon cycle in subduction zones is further discussed.  相似文献