First Multi‐Isotopic (Pb‐Nd‐Sr‐Zn‐Cu‐Fe) Characterisation of Dust Reference Materials (ATD and BCR‐723): A Multi‐Column Chromatographic Method Optimised to Trace Mineral and Anthropogenic Dust Sources     

Aubry Vanderstraeten  Steeve Bonneville  Stefania Gili  Jeroen de Jong  Wendy Debouge  Philippe Claeys  Nadine Mattielli 《Geostandards and Geoanalytical Research》2020,44(2):307-329

Atmospheric dust is an integral component of the Earth system with major implications for the climate, biosphere and public health. In this context, identifying and quantifying the provenance and the processes generating the various types of dust found in the atmosphere is paramount. Isotopic signatures of Pb, Nd, Sr, Zn, Cu and Fe are commonly used as sensitive geochemical tracers. However, their combined use is limited by the lack of (a) a dedicated chromatographic protocol to separate the six elements of interest for low‐mass samples and (b) specific reference materials for dust. Indeed, our work shows that USGS rock reference materials BHVO‐2, AGV‐2 and G‐2 are not applicable as substitute reference materials for dust. We characterised the isotopic signatures of these six elements in dust reference materials ATD and BCR‐723, representatives of natural and urban environments, respectively. To achieve this, we developed a specific procedure for dust, applicable in the 4–25 mg mass range, to separate the six elements using a multi‐column ion‐exchange chromatographic method and MC‐ICP‐MS measurements.  相似文献   

基于邻域约束聚类的地球化学异常提取     

杨昭颖  冯磊  姜德才  朱月琴  余先川 《地质通报》2019,38(12):2077-2084

通过分析地球化学数据的元素值属性和空间位置，提出一种基于邻域约束聚类的方法，使用该方法对地球化学元素聚类后，能提取矩形、环状、半环状等特殊形状，进而提取地球化学异常。选取河南崤山地区2个实验区的地球化学数据进行实验，实验一的结果表明，出现矩形的位置与已知钨矿矿点位置一致；实验二的结果表明，出现环形的位置与已知铜矿矿点位置一致。实验证明了基于邻域约束聚类的方法在提取地球化学异常方面的有效性。  相似文献   

金矿立体地球化学探测模型与深部钻探验证   总被引：1，自引：0，他引：1  

王学求  张必敏  于学峰  杨德平  夏勇  谭亲平  刘耀文  张苏坤  田密  刘汉粮  李瑞红  韩志轩  熊玉新  吴慧  张宝云 《地球学报》2020,41(6):869-885

深部资源地球化学探测科学问题的的焦点是元素大深度垂向迁移机理和立体地球化学探测模型的建立。本文以胶东蚀变岩型金矿和贵州水银洞卡林型金矿钻孔岩芯和地表联合取样获得的数据, 建立千米深度立体地球化学探测模型。蚀变岩型金矿立体地球化学模型显示, Au、S和Hg与金矿密切相关, 分布模式既有相似性又有差异性, Au的立体几何分布模式兼具矿化剂元素S和远程指示元素Hg的双重特征, 金异常和矿化剂元素硫与矿体倾斜方向一致, 反映了成矿过程中流体沿控矿构造的轴向运移; 金异常与类气体元素汞在垂向上一致, 而且出现从矿体到地表的连续贯通式异常, 反映了流体沿微裂隙和纳米孔的垂向迁移。卡林型金矿立体地球化学模型显示, Au、As、Sb、Hg、Tl和S在不整合面都显示高含量特征, 与深部层状主矿体分布一致; 在矿体上覆地层中都存在弱异常, 显示了明显的成矿流体沿隐伏微小断裂垂向迁移特点; 所不同的是Sb和Tl元素在不整合面附近显示了最高的元素含量, 而Sb和Hg在近地表均显示了明显高的异常特征。立体几何模型清晰地显示了矿体的展布特征和范围, 而且金及其伴生元素垂向迁移在地表形成清晰异常, 为利用金及伴生元素和矿化剂元素进行深部矿体三维预测提供了重要依据, 对指导深部金矿勘查发挥了重要作用。针对胶东蚀变岩型金矿地表完全被土壤覆盖区的穿透性地球化学微细粒级土壤采样, 金属活动态提取分析圈定的异常, 经深部钻探验证, 胶东焦家成矿带五一村3200 m钻探, 在2428.00~3234.16 m深度发现6层矿化体, 其中高品位矿体位于2854 m深度; 上宫金矿地表基岩出露, 采集断层泥或裂隙岩石样品, 可以清晰探测深部异常, 经2000 m钻探, 在1312 m处发现高品位金铅锌银矿体; 贵州水银洞采集地表细粒级土壤, 能够直接有效地揭示深部金矿体, 经500~1500 m钻探验证, 在300~1500 m深度新增金资源量203 t。  相似文献   

基于镁铁-超镁铁岩中单斜辉石主量元素含量的决策树集成算法对比     

孙建鹍  杜雪亮  章宝月  王龙  金维浚  张旗  罗熊  朱月琴 《地质通报》2019,38(12):1981-1991

依靠岩浆构造环境的地球化学成分认识岩浆形成过程是岩石地球化学中的重要应用。当前利用岩石地球化学成分判别构造环境的工作还不够深入。用4种基于决策树的机器学习方法对来自全球新生代洋岛玄武岩(OIB)、岛弧玄武岩(IAB)及大洋中脊玄武岩(MORB)等镁铁-超镁铁岩中单斜辉石的13种主量元素构成数据集进行了岩浆构造环境判别和主要特征排序。通过对比4种基于决策树的机器学习方法,验证了树类算法对于地球化学成分识别问题的有效性,并总结出4种方法在处理岩浆构造环境判别问题时的优劣:决策树算法判别过程更易于理解,但是其准确率欠佳;boosting算法中的AdaBoost和GBDT对于岩浆构造环境的鉴别准确度较高,但构造过程复杂;bagging集成算法随机森林在权衡性能和模型可理解性时不失为一个良好的选择。此外,还通过4种算法的特征重要性排序得出Cr_2O_3,TFeO,TiO_2,FeO和Al_2O_3是进行岩浆构造环境判别的重要成分。  相似文献   

Bathymetry,substrate and fishing areas of Southeast Atlantic high-seas seamounts   总被引：1，自引：0，他引：1  

OA Bergstad  ÅS Høines  R Sarralde  G Campanis  M Gil  F Ramil 《African Journal of Marine Science》2019,41(1):11-28

Most of the Southeast Atlantic Ocean is abyssal, and global bathymetries suggest that only ～3.2% of the areas beyond national jurisdiction (ABNJ; also known as the high seas, as defined in the United Nations Convention on the Law of the Sea [UNCLOS]) are shallower than 2 500 m. This study mapped bathymetry and characterised substrates in selected seamount summit areas, including several that have been or may become fishing areas. The southernmost location, the Schmitt-Ott Seamount, has exposed volcanic bedrock with surrounding flats covered by thin biogenic sediments and/or coral rubble that appears ancient. At Wüst, Vema, Valdivia and Ewing seamounts the basaltic base appears to be overlain by coral caps and other coral substrates (sheets, rubble). Adjacent summit plains have biogenic sediments of varying thickness. Vema has a flat, roughly circular summit, <100 m deep, with the shallowest point being a 22-m-deep summit knoll; the upper slopes have ancient coral framework, but the summit has a mixture of coralline and volcanic rock and coarse sediments, including extensive areas with coralline algae and kelp forests. Valdivia Bank is a 230-m-deep, flat, rocky area (～11 × 5 km), protruding steeply from the extensive multi-summit Valdivia subarea of the Walvis Ridge. The distribution of past fisheries in the Convention Area of the South East Atlantic Fisheries Organisation (SEAFO) was considered in relation to the new information on bathymetry and substrate.  相似文献   

内蒙古格勒敖包奥陶纪岩体锆石U-Pb年龄及地球化学特征     

曹磊  苏茂荣  周飞  李磊  杨宝宏 《地质通报》2019,38(4):632-642

内蒙古格勒敖包位于兴蒙造山带内,对该区奥陶纪岩浆岩的研究,有助于进一步认识该造山带早古生代的构造格局及其演化。正长花岗岩和斑状二长花岗岩样品LA-ICP-MS锆石年龄为441.6±3.7～454.9±4.6Ma,形成时代为奥陶纪。经地球化学分析,岩体为高钾钙碱性系列;铝饱和指数显示其为过铝质花岗岩。岩石富集大离子亲石元素(LILEs)Rb、Th、U、K,亏损Ba、Sr;富集高场强元素(HFSEs)La、Ce、Nd、Zr,亏损Nb、P、Ti;稀土元素总量为38.7×10~(-6)～120.23×10~(-6),轻稀土元素较重稀土元素分异明显,分馏程度较高,表现出较弱的负Eu异常。综合区域地质资料,认为格勒敖包奥陶纪岩浆源区为上地壳物质的部分熔融,其形成环境为弧后盆地,在古亚洲洋向北俯冲之后经历了岛弧岩浆作用旋回,为弧后伸张阶段的产物。  相似文献   

Sedimentary and geochemical characterization of Middle–Late Miocene formations in the Neogene Tsugaru Basin,Japan by means of DTH27‐1 well sediment analysis     

Paolo Martizzi  Shun Chiyonobu  Hiroyuki Arato 《Island Arc》2020,29(1)

Middle–Late Miocene age siliceous formations outcropping along the northwestern side of Honshu Island are considered prospective source rocks for hydrocarbons. An analysis of geophysical, sedimentological, and geochemical properties is essential to evaluate the formations' source potential, and to understand the factors that determined the accumulation and preservation of organic matter. This study investigates the Middle–Late Miocene geological record of the Tsugaru back‐arc basin, located in the western part of Aomori prefecture, through an analysis of a 200 m long portion of a core from the DTH27‐1 well; this core is composed of the diatomaceous siltstones of the Akaishi Formation and the siliceous mudstones of the Odoji Formation. Sedimentological and geophysical characterization showed that the Akaishi Formation's diatomaceous siltstones are mostly massive and bioturbated, have low magnetic susceptibility, and demonstrate moderate natural radioactivity. Although the Odoji Formation's siliceous mudstones are massive, they have exceedingly low magnetic susceptibility and high natural radioactivity. Geochemical data from a Rock‐Eval Pyrolysis such as total organic carbon and generative potential (S1 + S2) revealed that, in the Tsugaru area, only the Odoji Formation is a likely prospective source rock for hydrocarbons. On the other hand, T_max values indicate that both the formations are thermally immature for generating hydrocarbons. The difference between the Akaishi and Odoji Formation in the sedimentological facies, in terms of the degree of bioturbation and the organic carbon content, indicates variations in lithological properties, such as porosity and grain size; moreover, this difference indicates a variation in the paleo‐oxygenation of bottom waters, with the transition from oxygen‐deficient conditions in the Middle Miocene to the more oxygenated conditions in the Late Miocene. Both the lithological and paleo‐environmental factors possibly influenced the organic richness in the two formations.  相似文献   

晋西北地区表层土壤粒度与地球化学元素组成   总被引：1，自引：1，他引：0  

李继彦  周玲  刘益  张倩  蔡莹莹  张宝贵 《中国沙漠》2019,39(5):155-162

对晋西北地区表层土壤的物质组成进行研究，可以明确其物质来源、沉积环境及化学风化特征。选择区内表层土壤（深度0、10、20 cm）及其附近的河流沉积物，进行粒度和化学元素组成测试。结果表明：（1）晋西北地区表层土壤粒度组成以黏土和粉沙为主，且有自地表向下粗颗粒组分含量增加的趋势。（2）常量化学元素组成以SiO₂、Al₂O₃、CaO、Fe₂O₃为主，其余元素含量均较低。化学元素组成模式表明研究区内表层土壤物质与黄土高原腹地黄土有相同的物质源区，黄河河流沉积物对其贡献不大。（3）晋西北表层土壤的CIA值为52.70~57.89，平均54.06，说明它们的化学风化程度较低，处于早期的脱Na、Ca阶段。这是由于研究区地理位置比洛川更靠北，气温和降水量均低于洛川，降水量与兰州相差不大，但是年平均气温和年温差比兰州低。该研究明确了晋西北地区表层土壤的物质组成特征，为区域潜在沙漠化危害防治提供了数据支撑。  相似文献   

The evolution of brittle and ductile structures at the surface of a partly debris-covered,rapidly thinning and slowly moving glacier in 1998–2012 (Pasterze Glacier,Austria)     

Andreas Kellerer-Pirklbauer  Bernd Kulmer 《地球表面变化过程与地形》2019,44(5):1034-1049

Many glaciers in alpine regions are currently rapidly receding and thinning at historically unobserved rates causing changes in the velocity field and in normal and shear stresses affecting the surface expression of structures within the ice. We studied the distribution of brittle and ductile structures at the surface of Pasterze Glacier during a 14-year period by analysing orthophotos and digital elevation models of five stages (1998, 2003, 2006, 2009 and 2012). A structural glaciological mapping key was applied. Normal faults, strike-slip faults, en échelon structures (systematic stepping of fractures), thrust faults, and band ogives were distinguished. Results indicate substantial deceleration and glacier thinning in 1998–2012. Glacier thinning was not homogenous over time related to the uneven distribution of supraglacial debris causing differential ablation or the selective ablation effects of subglacial water channels. Peculiar supraglacial features observed are circular collapse structures with concentric crevasses which form when the ice between the surface and the roof of water channels decreases. The total length of brittle structures increased from 38.4 km to 56.9 km whereas the extent of the glacier tongue decreased by 25%. The fracture density doubled from 0.009 to 0.018 m/m². Areas of the glacier tongue which were up to 100 m away from the nearest brittle structure increased by 16%. The visual appearance of thrust faults shifted upglacier due to decreasing glacier velocity causing horizontal shortening or due to exhumation of faults that did not previously extend to the surface. A large number of brittle structures are progressively independent from glacier motion. Our study suggests that glacier tongues which are in a state of rapid decay and thinning are prone to fracturing due to normal fault formation and glacier disintegration. Water further increases ablation rates substantially if rather large amounts drain through supra-, en- or subglacial water channels. © 2018 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd.  相似文献   

基于参与式制图方法的景观服务评估与空间结构研究     

朱亚茹  高峻  邴振华  张中浩  付晶 《地球信息科学学报》2020,22(5):1106-1119

景观服务评估核心是人与环境之间复杂的动态关系,基于利益相关者的参与式制图方法是建立景观服务分类体系和量化指标的有效途径。本文采用参与式制图方法,以九寨沟自然保护区为例,根据景观服务分类研究成果,并结合九寨沟自然资源特点和景观服务使用者半结构式访谈数据,提出了适用于九寨沟的景观服务指标体系。本研究方法以管理局工作人员、居民和游客等服务使用者作为参与式调研对象,分别就其需求和景观服务感知程度进行半结构式访谈,并利用GIS技术将数据空间位置和功能属性结合,得到九寨沟有3大类景观服务和17个相关指标,以及737个景观服务点。通过研究结果可知,当地村落建筑与众多景观服务指标（包括观鸟场所、野营旅游、民俗与节庆等13个指标）具有极强的空间关联性。同时,景观服务使用者感知的景观价值在空间上属于聚集分布形式,主要围绕着开放生态旅游的3条沟谷分布,并向外围扩散。其中景观服务的“高—高”空间聚集区主要分布在沟口等与人类需求密切联系的区域,而景观服务的“低—低”空间聚集区则主要分布在原始森林等与人类居住、活动相距较远的区域。综上,基于参与式制图方法建立的景观服务分类和空间分析,发现九寨沟景观服务的空间位置与使用者紧密相关,其景观价值的空间结构特征是服务使用者与环境长期互动的结果,该结果可以用来引导并进一步优化九寨沟的功能分区规划。  相似文献