川西甲基卡矿床外围中酸性侵入岩LA-ICP-MS锆石U-Pb年龄及地球化学特征     

李名则  秦宇龙  赵春  詹涵钰  周雄  孙光银 《中国地质调查》2020,7(5):1-9

在川西甲基卡矿床外围新发现了建巴村中酸性侵入岩体,为了探讨其形成时代、成岩构造背景及其成矿条件,开展了LA-ICP-MC锆石U-Pb年代学和地球化学特征研究。结果表明: 该岩体的结晶年龄为(211.8±1.0) Ma; 岩石属于钙碱性-高钾钙碱性准铝质中酸性侵入岩系列,具有I型花岗岩类的特征,其物质来源可能为壳源物质与幔源物质部分熔融。地球化学特征表明其形成于后碰撞环境,与此时期内川西地区的区域性岩浆活动相对应。建巴村岩体的构造位置及岩浆活动特征指示其可能不具备形成伟晶岩矿床的条件。  相似文献   

Arc magmatism in eastern Kumaun Himalaya,India: A study based on geochemistry of granitoid rocks     

D. RAMESHWAR RAO  RAJESH SHARMA 《Island Arc》2011,20(4):500-519

Petrochemical studies of granitoid rocks from the eastern part of Kumaun region suggest that the leading edge of India represents an active arc during Late Paleoproterozoic times. It has been observed that melt generation for granodiorite rocks from the eastern Almora Nappe and Chhiplakot klippe along with the Askot klippe was caused through a subduction‐related process involving hydrous partial melting of a Paleoproterozoic amphibole‐ and/or garnet‐bearing mafic source with the involvement of sediments from the subduction zone. The medium‐ to high‐K basic rocks, common in subduction‐related magmatic arcs, can also explain the generation of the high‐K granodiorites of the Chhiplakot klippe. The augen gneisses from the eastern Almora nappe and Chhiplakot klippe along with the Askot klippe further show geochemical similarity with the associated granodiorites, suggesting there is a genetic linkage with one another.  相似文献   

Trace‐element signatures of apatites in granitoids from the Mt Isa Inlier,northwestern Queensland     

E. A. Belousova  S. Walters  W. L. Griffin  S. Y. O'Reilly 《Australian Journal of Earth Sciences》2013,60(4):603-619

The concentrations of trace elements in apatite from granitoid rocks of the Mt Isa Inlier have been investigated using the laser‐ablation inductively coupled plasma‐mass spectrometry (ICP‐MS) microprobe. The results indicate that the distribution of trace elements (especially rare‐earth elements (REE), Sr, Y, Mn and Th) in apatite strongly reflects the chemical characteristics of the parental rock. The variations in the trace‐element concentrations of apatite are correlated with parameters such as the SiO₂ content, oxidation state of iron, total alkalis and the aluminium saturation index (ASI). The relative enrichment of Y, HREE and Mn and the relative depletion of Sr in the apatites studied reflect the degree of fractionation of the host granite. Apatites from strongly oxidised plutons tend to have higher concentrations of LREE relative to MREE. Manganese concentrations are higher in apatite from reduced granitoids because Mn²⁺substitutes directly for Ca²⁺. The La/Ce ratio of apatite is well‐correlated with the whole‐rock K²O and Na²O contents, as well as with the oxidation state and ASI. Because apatite trace‐element composition reflects the chemistry of the whole rock, it can be a useful indicator mineral for the recognition of mineralised granite suites, where particular mineralisation styles are associated with granitoids that have specific geochemical fingerprints.  相似文献   

Petrochemistry of Granitoids Along the Loei Fold Belt,Northeastern Thailand     

《Resource Geology》2018,68(4):395-424

Petrochemical characteristics of Permo‐Triassic granitoids from five regions (i) Mung Loei, (ii) Phu Thap Fah – Phu Thep, (iii) Phetchabun, (iv) Nakon Sawan – Lobburi, and (v) Rayong – Chantaburi along the Loei Fold Belt (LFB), northeastern Thailand were studied. The LFB is a north–south trending 800 km fold belt that hosts several gold and base‐metal deposits. The granitoids consist of monzogranite, granodiorite, monzodiorite, tonalite, quartz‐syenite, and quartz‐rich granitoids. These are composed of quartz, plagioclase, and K‐feldspar with mafic minerals such as hornblende and biotite. Accessory minerals, such as titanite, zircon, magnetite, ilmenite, apatite, garnet, rutile, and allanite are also present. Magnetic susceptibilities in the SI unit of granitoids vary from 6.5 × 10⁻³ to 15.2 × 10⁻³ in Muang Loei, from 0.1 × 10⁻³ to 29.4 × 10⁻³ in Phu Thap Fah – Phu Thep, from 2.7 × 10⁻³ to 34.6 × 10⁻³ in Petchabun, from 2.4 × 10⁻³ to 14.1 × 10⁻³ in Nakon Sawan – Lobburi, and from 0.03 × 10⁻³ to 2.8 × 10⁻³ in Rayong – Chantaburi. Concentration of major elements suggests that these intermediate to felsic plutonic rocks have calc‐alkaline affinities. Concentration of REE of the granitoids normalized to chondrite displays moderately elevated light REE (LREE) and relatively flat heavy (HREE) patterns, with distinct depletion of Eu. Rb versus Y/Nb and Nb/Y tectonic discrimination diagrams illustrate that the granitoids from Muang Loei, Phu Thap Fah – Phu Thep, Phetchabun, Nakon Sawan – Lobburi, and Rayong – Chantaburi formed in continental volcanic‐arc setting. New age data from radiometric K‐Ar dating on K‐feldspar from granodiorite in Loei and Nakhon Sawan areas yielded 171 ± 3 and 221 ± 5 Ma, respectively. K‐Ar dating on hornblende separated from diorite in Lobburi yielded 219 ± 8 Ma. These ages suggest that magmatism of Muang Loei occurred in the Middle Jurassic, and Nakon Sawan – Lobburi occurred in Late Triassic. Both Nb versus Y and Rb versus (Y + Nb) diagrams and age data indicate that Nakon Sawan – Lobburi granitoids intruded in Late Triassic at Nong Bua, Nakon Sawan province and Khao Wong Phra Jun, Lobburi province in volcanic arc setting. Muang Loei granitoids at the Loei province formed later in Middle Jurassic also in volcanic arc setting. The negative δ³⁴S_CDT values of ore minerals from the skarn deposit suggest that the I‐type magma has been influenced by light biogenic sulfur from local country rocks. The Au‐Cu‐Fe‐Sb deposits correlate with the magnetite‐series granitoids in Phetchabun, Nakon Sawan – Lobburi and Rayong – Chantaburi areas. Metallogeny of the Au and Cu‐Au skarn deposits and the epithermal Au deposit is related to adakitic rocks of magnetite‐series granitoids from Phetchabun and Nakon Sawan areas. All mineralizations along the LFB are generated in the volcanic arc related to the subduction of Paleo‐Tethys. The total Al (^TAl) content of biotite of granitoids increases in the following order: granitoids associated with Fe and Au deposit < with Cu deposit < barren granitoids. X_Mg of biotite in granitoids in Muang Loei indicates the crystallization of biotite in magnetite‐series granitoids under high oxygen fugacity conditions. On the other hand, low X_Mg (<0.4) of biotite in magnetite‐series granitoids in Phu Thap Fah – Phu Thep and Rayong – Chantaburi indicates a reduced environment and low oxygen fugacity, associated with Au skarn deposit (Phu Thap Fah) and Sb‐Au deposit (Bo Thong), respectively. The magnetite‐series granitoids at Phu Thap Fah having low magnetic susceptibilities and low X_Mg of biotite were formed by reduction of initially oxidizing magnetite‐series granitic magma by interaction with reducing sedimentary country rocks as suggested by negative δ³⁴S_CDT values.  相似文献   

Palaeoproterozoic granitic magmatism in the northern segment of the Jiao-Liao-Ji Belt: implications for orogenesis along the Eastern Block of the North China Craton     

Chao Li  Zhuang Li  Chuan Yang 《International Geology Review》2018,60(2):217-241

As the northern segment of the Jiao-Liao-Ji Belt (JLJB), the Palaeoproterozoic Liaoji Belt is a key region for deciphering the formation and evolution of the North China Craton (NCC). In this study, we present the geochronology, geochemical, and isotopic studies on the monzogranitic gneiss, which is one of the major lithotectonic elements of the Liaoji Belt. LA-ICP-MS zircon U–Pb dating reveals that the studied monzogranitic gneisses were formed in the period of 2213–2178 Ma. They are in tectonic contact with the Palaeoproterozoic volcano-sedimentary rocks in the field. The monzogranitic gneisses belong to the high-K calc-alkaline series, and are metaluminous to peraluminous. They have 10,000 Ga/Al ratios of 2.63–3.14 with an average of 2.90, and are thus classified as aluminous A-type granites. Their ε_Nd(t) values vary from ?3.4 to +2.5, indicating heterogeneous source region. The monzogranitic gneisses are characterized by enrichment in LREE and LILE (e.g. Rb, Ba, Th, and K) and depletion in HREE and HFSE (such as Nb, Ta, and Ti), and are typical to magmatism in active continental margins formed in a subduction-related tectonic setting. Taking into account their A-type affinity and regional geological data, we suggest that the monzogranitic gneisses were most probably generated in a local extensional back-arc environment during subduction.  相似文献   

粤东铁坑坳铁锡多金属矿床锆石及锡石U-Pb年代学、Nd-Hf同位素特征及其意义     

张志涛  柯昌辉  徐林刚  马收先  陈懋弘  叶会寿  潘玉峰 《矿床地质》2022,41(3):543-566

铁坑坳铁锡多金属矿床位于粤东莲花山断裂带西部,矿区出露的花岗岩类主要有粗粒二长花岗岩和花岗闪长斑岩,花岗质岩石与碳酸盐岩的接触带中发育铁锡多金属矿化。该矿区的成岩成矿时代尚不明确,成矿与哪一种岩体具有成因上的联系也不清楚。文章选择与铁锡多金属矿体相关的花岗岩类的锆石和块状矿石中的锡石,首次开展LA-ICP-MS U-Pb定年和Nd-Hf同位素研究。结果表明：粗粒二长花岗岩和花岗闪长斑岩的锆石U-Pb年龄分别为（132±1） Ma （n=24,MSWD=0.78）和（94±1） Ma （n=25,MSWD=1.80）;块状矿石中锡石U-Pb年龄为（130±3） Ma （n=36,MSWD=0.62）,成矿时代与粗粒二长花岗岩形成时代基本一致,均形成于早白垩世;粗粒二长花岗岩的锆石ε_Hf （t）变化于-4.9~-0.1,平均值为-2.8,地壳Hf模式年龄T_DMC=1192~1497 Ma,平均值为1366 Ma,全岩ε_Nd （t）值介于-8.8~-8.7,Nd同位素二阶段模式年龄T_DM2变化于1630~1642 Ma;花岗闪长斑岩的锆石ε_Hf （t）变化于-5.7~-2.9,平均值为-4.4,地壳Hf模式年龄T_DMC=1342~1523 Ma,平均值为1440 Ma,全岩ε_Nd （t）值介于-5.4~-4.9,Nd同位素二阶段模式年龄T_DM2变化于1291~1332 Ma。Nd-Hf同位素综合研究表明,粗粒二长花岗岩的源区物质主要来自于中元古代地壳,有少量幔源组分或新生地壳的加入,花岗闪长斑岩的源区物质中幔源组分或新生地壳的混入比例高于粗粒二长花岗岩。  相似文献   

满洲里-额尔古纳地区中生代花岗岩的锆石U-Pb年代学与岩石组合：对区域构造演化的制约   总被引：9，自引：0，他引：9  

王伟  许文良  王枫  孟恩 《高校地质学报》2012,18(1):88-105

本文对满洲里地区灵泉盆地、包格德乌拉盆地及额尔古纳地区上护林盆地和恩和盆地及周边的原确定为古生代和中
生代的花岗质岩石进行了岩石学和锆石LA-ICP-MS U-Pb 年代学研究,以便揭示研究区中生代的构造演化历史。研究区内
12 个代表性花岗岩中的锆石均呈自形-半自形晶,显示出典型的岩浆生长环带,结合其较高的Th/U比值（0.31~3.63）,暗
示其为岩浆成因。测年结果表明,该区中生代花岗质岩浆活动可划分成以下三期：（1）中三叠世岩浆活动,可进一步划分
成241 Ma 和229 Ma 两期岩浆事件,241 Ma 黑云母正长花岗岩和229 Ma 正长花岗岩的存在可能与古亚洲洋闭合后的伸展环
境有关;（2）早- 中侏罗世岩浆事件,可进一步划分成（180±5）Ma 和（171±2）Ma 两期岩浆事件,黑云母二长花岗岩-
正长花岗岩组合,结合其斑岩型Mo 矿的存在,反映研究区处于活动陆缘的构造背景,可能与蒙古- 鄂霍茨克洋的俯冲作用
有关;（3）早白垩世早期岩浆活动,可进一步划分成（140~150）Ma 和（134±2）Ma 两期岩浆事件,前者与区域内发育的
吉祥峰组火山岩形成时代相近,后者的火口充填型产状表明它们应是该期岩浆事件演化晚期的产物,该期岩浆事件在松辽
盆地以东地区的缺乏暗示它们形成于伸展环境,并与蒙古-鄂霍茨克缝合带的演化有关。  相似文献   

内蒙古二连浩特北部阿仁绍布地区晚石炭世花岗岩Sr-Yb分类及其成因   总被引：2，自引：1，他引：1  

许立权  鞠文信  刘翠  贺宏云  李满英 《地质通报》2012,31(9):1410-1419

对分布在内蒙古二连浩特北部阿仁绍布地区的晚石炭世花岗岩类,依据Sr、Yb含量,划分为低Sr高Yb型、极低Sr高Yb型和低Sr低Yb型花岗岩3种类型。低Sr高Yb型花岗岩类相对低Si、富Al,Na2O>K2O,稀土元素分馏中等,有或无负Eu异常,Sr含量低,平均为183×10-6,Ba含量较高,平均585×10-6,Y含量高,平均30.06×10-6,Rb/Sr比值较低,平均0.97;极低Sr高Yb型花岗岩富Si、REE,低Al、Sr、Ba,高的Rb/Sr比值(平均为7.47),具明显的负Eu异常等;低Sr低Yb型花岗岩富Si,贫Al、Ca、Mg,重稀土元素(Y、Yb)含量低,Y含量在(7.26～10.6)×10-6之间,平均9.76×10-6,Yb含量在(1.04～1.89)×10-6之间,平均1.44×10-6,δEu=0.64～0.94,具弱负Eu异常,微量元素Ba含量高,Rb/Sr比值低。3种类型的花岗岩类过铝指数(A/CNK)多小于1.0,说明它们均源自变质火成岩的部分熔融。由于源区的深度不同(pT条件不同)和残留的主要矿物相不同,它们的岩石地球化学特征存在差异。极低Sr高Yb型花岗岩形成深度最浅(中上地壳),熔融残留相以斜长石为主;低Sr高Yb型花岗岩类形成于中下地壳,熔融残留相为斜长石和辉石;低Sr低Yb型花岗岩形成深度最深,推测可能形成于加厚下地壳(>40km)底部,熔融残留相为石榴子石、斜长石和角闪石。  相似文献   

冈底斯东段古新世朱拉岩体LA-ICP-MS锆石U-Pb定年和岩石地球化学特征   总被引：1，自引：0，他引：1  

李奋其  刘伟  张士贞  王保弟 《地质通报》2012,31(9):1420-1434

朱拉岩体位于冈底斯带东部,主要由黑云母二长花岗岩组成,其中发育闪长质包体,二者呈渐变过渡关系。3件寄主岩石LA-ICP-MS锆石U-Pb年龄加权平均值分别为64.6Ma±0.8Ma、64.3Ma±0.8Ma和63.9Ma±0.5Ma,含776Ma的继承岩浆锆石。1件闪长质包体样品年龄加权平均值为66.1Ma±0.3Ma。闪长质包体低Si,中Mg(Mg﹟平均41.1),属铝质高钾钙碱性系列,Nb/Ta值为22,Sr/Y值为3.69,稀土元素分馏较低,LREE/HREE平均值为1.92,Eu强烈亏损,富集大离子亲石元素(Rb、K、U、Th),亏损高场强元素(Nb、Ta、Sr、Ti),暗示岩浆成分主要为幔源。寄主岩石富Si、K,贫P,属铝质—偏铝质钙碱性—高钾钙碱性系列,Nb/Ta值15.9,富集大离子亲石元素(Rb、K、Th),亏损高场强元素(Nb、Ta、Ba、P、Ti),具有活动陆缘钙碱性岩系的微量元素分布特征。寄主岩石与闪长质包体具有密切的成生联系,闪长岩形成于富集俯冲带组分的地幔熔体,在上升过程中混染了一定量的壳源物质结晶分异产物,寄主岩石则为底侵作用产生的大量壳源熔体与少量幔源熔体混合并发生一定程度分离结晶后的产物。结合前人的研究成果,认为古新世朱拉岩体与雅鲁藏布江大洋的向北消减有关。  相似文献   

华北克拉通阜平杂岩中~2.7GaTTG片麻岩的厘定及其地质意义   总被引：7，自引：7，他引：0  

路增龙  宋会侠  杜利林  任留东  耿元生  杨崇辉 《岩石学报》2014,30(10):2872-2884

通过详细的地质工作,本文从阜平杂岩中厘定出一套~2.7Ga的条带状TTG片麻岩系,其原岩主要为英云闪长岩,经历了强烈的变形和深熔改造。该片麻岩可分为岩石主体和条带,按条带形态和成分可分为三种:细小的暗色条带、深熔浅色条带和后期注入的长英质脉体。用LA-MC-ICPMS法对英云闪长岩中锆石进行了原位U-Pb年龄测试,其形成年龄为2669.2±9.7Ma。该片麻岩SiO2=64.32%~70.02%,具有高铝(Al2O3=14.00%~15.87%)富钠(Na2O=3.85%~4.22%)贫钾(K2O=1.13%~2.42%)及低K/Na比值的特点,Mg#指数为39.5~49.6。该片麻岩具有中等-强烈程度的稀土元素分异[(La/Yb)N=3.67~51.38],Eu异常不明显。其富集Sr(303×10-6~431×10-6)、Ba(191×10-6~696×10-6)等大离子亲石元素,亏损Nb(4.70×10-6~9.78×10-6)、Ta(0.19×10-6~0.75×10-6)、Ti(1378×10-6~3259×10-6)、P(174.6×10-6~960.6×10-6)等高场强元素,Cr(5.87×10-6~119.4×10-6)、Ni(6.72×10-6~45.75×10-6)等相容元素含量也较低。Yb(0.31×10-6~1.75×10-6)和Y(3.61×10-6~18.88×10-6)含量低,Sr/Y比值高(16.0~119.1),属于高铝的TTG,与高硅埃达克岩特征相似。推断是热的太古宙新生洋壳部分熔融而成。阜平地区~2.7Ga TTG片麻岩的厘定,进一步证实了华北克拉通在新太古代早期经历了强烈的陆壳增生,并为华北克拉通早期岩浆事件与世界范围的岩浆事件的对比提供了新的依据,为华北克拉通早期陆块及绿岩带的划分提供了新的限定。  相似文献