伊犁蒙其古尔铀矿床含矿层砂岩中黄铁矿形成机制及对铀成矿的指示意义     

丁波  刘红旭  张宾  李平  蒋宏  张虎军  谢希良  郭春杰 《矿床地质》2019,38(6):1379-1391

蒙其古尔铀矿床为伊犁盆地南缘大型层间氧化带砂岩型铀矿床,为查明该矿床含矿层中黄铁矿成因及其形成机制,探讨微生物参与铀成矿过程。文章对含矿层砂岩中黄铁矿与铀矿物矿物学特征、黄铁矿S同位素与碳酸盐胶结物的C-O同位素开展细致研究。研究表明:①蒙其古尔铀矿床中铀主要以铀矿物与吸附铀形式存在,吸附铀主要为有机质吸附铀,铀矿物以沥青铀矿为主,多与黄铁矿、炭屑共生;②蒙其古尔铀矿床含矿层砂岩中黄铁矿主要以自形晶、草莓状和不规则状集合体产出,多与沥青铀矿、碳酸盐胶结物共生,其中黄铁矿S同位素(δ~(34)S_(V-CDT)=-68.4‰～22.1‰)与碳酸盐胶结物的C-O同位素(δ~(13)C_(V-PDB)=-10.2‰～-7.4‰,δ~(18)O_(V-PDB)=-9.6‰～-5.8‰)分析表明黄铁矿具有细菌硫酸盐还原(BSR)与有机物热解2种成因,并探讨了这2种不同成因黄铁矿的形成机制。③结合前人研究成果,认为硫酸盐还原菌(SRB)参与蒙其古尔铀矿床铀成矿过程,以间接还原方式为主,在有机质、黏土矿物与颗粒表面吸附U(Ⅵ)的基础上,通过硫酸盐还原菌(SRB)还原SO_4~(2-)产生的H_2S将U(Ⅵ)被还原成U(Ⅳ),形成铀矿物。  相似文献   

吉林延边红太平铜多金属矿床脉型矿化的成矿时代与构造背景     

侯鹤楠  任云生  陆思宇  郝宇杰  杨群 《岩石学报》2020,36(3):820-836

吉林延边红太平铜多金属矿床位于兴蒙造山带东段,区内发育产于晚古生代火山沉积岩系中的层状铜多金属矿体和受岩体及构造控制的脉状铅锌矿体。为了确定脉型铅锌矿化的成矿时代与构造背景,本文对与脉状铅锌矿体相关的英安岩开展了LA-ICP-MS锆石U-Pb定年及岩石地球化学研究,并对脉状铅锌矿体中金属硫化物开展了Rb-Sr同位素定年。结果表明,英安岩中28个锆石测点的~(206)Pb/~(238)U加权平均年龄为204.1±2.0Ma(MSWD=0.24),脉状铅锌矿石中4件金属硫化物的Rb-Sr等时线年龄为206.8±9.0Ma(MSWD=2.0),二者在误差范围内基本一致,表明红太平矿床脉型铅锌矿化的成矿时代为晚三叠世末期。英安岩的稀土元素配分模式呈明显的轻稀土元素(LREEs)富集,轻重稀土分馏明显[(La/Yb)N=7.59～8.28],存在弱的Eu异常(δEu=0.65～0.68);微量元素以富集大离子亲石元素(LILEs:Rb、Ba和K)和不相容元素(U、Th),亏损高场强元素(HFSEs:Nb、Ta、P和Ti)为特征,表明原始岩浆应为壳-幔混源;脉状铅锌矿体中4件金属硫化物初始Sr同位素比值(87Sr/86Sr)i为0.705954～0.707101(均值0.706390),表明脉型铅锌矿化与壳-幔混源的岩浆作用密切相关。根据Rb-(Yb+Ta)及La/Yb-Th/Yb图解判别结果,结合区域构造演化分析,认为红太平矿区英安岩及相关的脉型铅锌矿化形成于活动大陆边缘的构造环境,与晚三叠世-早侏罗世(T_3-J_1)古太平洋板块向欧亚板块的俯冲作用密切相关。  相似文献   

基于金矿规格单元数据的机器学习方法在成矿建模分析中的应用     

张野  李明超  韩帅  任秋兵  朱月琴 《大地构造与成矿学》2020,(2):183-191

现代金矿勘察主要是通过综合地球化学和地质测量等数字化方法对深部矿床进行研究,所需要的人力物力成本较高。而通过分析积累的金矿规格单元数据,可以建立金矿成矿情况与相关成矿元素含量之间的非线性关系,从已有的勘查数据中寻找金矿成矿的一般规律。本文基于与金矿相关的成矿元素含量数据,分别采用逻辑斯蒂回归、随机森林和决策树方法对原始数据和重采样数据进行训练,综合运用召回率、精确率和准确率对模型进行评价。通过对比发现,在训练和测试原始数据过程中,由于每组之间数据量的巨大差距,导致成矿数据被淹没;而在训练重采样数据过程中,随机森林在召回率和准确率方面均有较好的表现,分别达到了90.63%和70.78%;并最终分析了随机森林模型中不同分类边界对于金矿成矿情况预测结果的影响。利用不同的测量指标对模型进行评价分析,使模型更适用于金矿成矿预测,可有效地提高金矿勘察的效率。  相似文献   

老挝班康姆铜金矿床成矿作用研究及其指示意义   总被引：1，自引：0，他引：1  

卢见昆  赵延朋  陈晓锋  康铁锁  莫江平 《矿床地质》2020,39(6):1122-1140

班康姆铜金矿床位于墨江-黎俯火山弧带的中段，成矿条件优越，区内中性侵入杂岩具有岛弧钙碱性火山岩的地球化学特征，属火山岛弧环境。氢、氧同位素特征及黄铁矿流体包裹体的He、Ar同位素特征均指示流体为岩浆流体与大气雨水型地下水的混合流体，晚期经历了开放系统的持续瑞利去气过程。硫同位素组成表明成矿系统的硫源主要为深源地幔硫，推断Au、Cu应来自地幔源区，在俯冲消减的构造背景下，携带大量Cu、Au等成矿金属构成富矿初始岩浆流体。热液成矿作用经历了高温矽卡岩蚀变阶段、中温青磐岩热液蚀变矿化阶段、低中温金矿化阶段和超低温热液碳酸盐化阶段4个阶段，中低温阶段为主要的矿化阶段，而北东-北北东向次级断裂带成为浅部重要的容矿空间。流体包裹体及稀土元素特征指示了矿床深部存在隐伏的岩体，很可能为含矿的斑岩体，这对班康姆矿床乃至成矿带的研究及勘查具有重大的意义。  相似文献   

粤北青嶂山岩体江头矿区铀矿微区矿物学、年代学特征及其成矿动力背景制约     

赖静  祁家明  陈军军  李钟枢  曹豪杰 《地质学报》2020,94(4):1128-1142

粤北诸广和贵东是华南最重要的两个花岗型铀矿密集区,青嶂山(龙源坝)岩体位于两者之间,是华南花岗岩型铀矿研究薄弱地区。江头铀矿区地处青嶂山岩体北部与南雄断陷盆地的结合部位,该矿区的铀成矿年代学研究几为空白。本文通过电子探针方法研究了青嶂山岩体、及与该岩体密切相关的江头矿区中的铀矿物微区矿物学特征,获得岩浆成因的晶质铀矿与热液成因的沥青铀矿的U-Th-Pb化学年龄,探讨了华南铀成矿作用动力学背景及成矿地质体。研究表明:青嶂山岩体粗粒斑状黑云母花岗岩和中粒斑状黑云母花岗岩中的铀矿物主要有晶质铀矿、铀石,部分晶质铀矿存在明显铀释放的特征,其晶质铀矿化学年龄分别为246.8±8.8Ma、161.5±8.0Ma,与前人获得的锆石U-Pb年龄结果在误差范围内一致,分别代表了区内印支期与燕山期花岗岩体的成岩年龄,表明在南雄断陷盆地形成之前,青嶂山岩体与诸广岩体可能为一有机整体,有着相同的成岩、成矿环境。江头矿区矿石中铀矿物主要为沥青铀矿,伴有少量钛铀矿、铀石等,沥青铀矿化学年龄分别为121.3±9.8Ma、98.8±8.0Ma、73.2±8.8Ma,分别代表区内3期铀成矿作用的时代,结合华南中生代以来构造运动特征,认为区内铀成矿作用是受中-新生代盆地边缘深大断陷活动、产铀花岗岩体分布的双要素成矿动力学背景制约,青嶂山岩体应与诸广、贵东岩体具有相似的找矿前景。  相似文献   

西南三江碰撞造山带沉积岩容矿Pb-Zn-Ag-Cu贱金属复合成矿与深部过程     

毕献武  唐永永  陶琰  王长明  胥磊落  戚华文  兰青  木兰 《岩石学报》2019,35(5):1341-1371

西南三江特提斯造山带中新生代沉积盆地中(沱沱河、玉树、昌都和兰坪-思茅地区)发育包括金顶超大型铅锌矿床在内的一系列以沉积岩容矿的Pb-Zn-Ag-Cu贱金属矿床,构成长达千余千米的青藏高原东缘贱金属成矿带。作为大陆碰撞环境成矿谱系的重要矿床类型,加强这些矿床的理论研究对提高和完善大陆碰撞造山成矿理论和指导找矿勘查等具有重要意义。已有研究表明这些Pb-Zn-Ag-Cu矿床的分布受盆地形成后新生代大型逆冲推覆-走滑构造控制,其容矿岩石和成矿作用特征与SEDEX和MVT矿床存在明显的差异,矿床成矿流体表现出多来源混合的特征,成矿与深部过程密切相关。尽管取得重要进展,但由于缺乏高精度年代学数据制约,成矿动力学背景及其与碰撞造山的时空联系存在较大争议。一些矿床的研究显示复合成矿迹象,但是复合成矿过程与深部驱动等问题仍不清楚。近年来我们以兰坪和昌都盆地的Pb-Zn-Ag多金属矿床和Cu多金属矿床为重点研究对象,系统开展了成矿年代学、成矿流体源-运-储系统和复合成矿机制以及深部过程对成矿制约等方面研究。结果表明,兰坪盆地西缘Cu(Mo)多金属矿床主要形成于48～58Ma,兰坪和昌都盆地Pb-Zn-Ag多金属矿床主要形成于27～33Ma。成矿流体表现出明显的多来源混合的特征,主要存在三种类型:1)变质流体与盆地卤水或大气降水复合成矿,以金满-连城Cu矿床为代表; 2)盆地卤水与大气降水复合成矿,以金顶Pb-Zn矿床为代表; 3)盆地卤水和岩浆流体复合成矿,以拉诺玛Pb-Zn-Sb矿床为代表。兰坪盆地西缘Cu矿床主要形成于新生代印度-欧亚大陆主碰撞挤压阶段,与成矿密切相关的变质流体可能来源于陆-陆碰撞俯冲引起的高压变质。Pb-Zn矿床主要形成于印度-欧亚大陆晚碰撞构造转换环境,构造挤压和造山隆起驱动盆地流体迁移,同期的岩浆活动主要为成矿提供热驱动力或成矿物质。  相似文献   

GEOCHEMICAL EXPLORATION     

《Abstract of Chinese Geological Literature》2014,(4)

正20142366Bi Yuanqing(Institute of Geophysical and Geochemical Survey Technology of Anhui Province,Hefei 230022,China);Fang Junhua Analysis of Ore-Prospecting Potential in the Taojiaxiang Mining Site,Zongyang County(Geology of Anhui,ISSN1005-6157,CN34-1111/P,23(4),2013,p.256-260,5illus.,10refs.)  相似文献   

Cathodoluminescence and Trace Element Composition of Scheelite from the Middle-Lower Yangtze River Metallogenic Belt (MLYB): Implications for Mineralization and Exploration     

NIE Liqing  ZHOU Taof  CHEN Xuefeng  WANG Fangyue  XIAO Xin 《《地质学报》英文版》2020,94(6):1977-1996

The Middle–Lower Yangtze River Metallogenic Belt (MLYB) is known to contain abundant copper and iron porphyry-skarn deposits, with an increasing number of tungsten deposits and scheelite in Fe–Cu deposits being discovered in the MLYB during recent decades. The ore genesis of the newly-discovered tungsten mineralization in the MLYB is poorly understood. We investigate four sets of scheelite samples from tungsten, iron and copper deposits, using CL imaging and LA–ICP–MS techniques to reveal internal zonation patterns and trace element compositions. The REE distribution patterns of four studied deposits show varying degrees of LREE enrichment with negative Eu anomalies. The oxygen fugacity of ore-forming fluid increased in Donggushan, while the oxygen fugacity of ore-forming fluid decreased in Ruanjiawan, Guilinzheng and Gaojiabang. The scheelites from the Donggushan, Ruanjiawan, Guilinzheng and Gaojiabang deposits show enrichment in LREEs and HFSE, with Nb/La ratios ranging from 1.217 to 52.455, indicating that the four tungsten deposits are enriched in the volatile fluorine. A plot of (La/Lu)N versus Mo/δEu can be used to distinguish quartz vein type, porphyry and skarn tungsten deposits. This study demonstrates that scheelite grains can be used to infer tungsten mineralization and are effective in identifying magmatic types of tungsten deposits in prospective mining sites.  相似文献   

西准噶尔白杨河铍铀矿床中铍与铀成生关系初探——来自围岩蚀变和矿石矿物接触关系的证据     

刘畅 《地质与勘探》2020,56(3):465-477

与高硅富氟火成岩(流纹岩或花岗斑岩)有关的铍矿床中常伴有铀矿化,其成矿特色明显,是认识岩浆-岩浆热液-热液演化过程中铍与铀地球化学行为异同的理想对象,但其中铍与铀成矿的时空关系及成因关系尚不清楚。为了理解该类矿床中铍与铀的成生关系,并为区域内铍与铀的找矿勘查提供理论支撑,本文选取该类矿床的典型代表—西准噶尔白杨河铍铀矿床为研究对象,通过镜下观察、扫描电镜能谱和激光拉曼光谱分析,对矿区内单铍矿石、单铀矿石和铍铀矿石开展了系统的岩相和矿相学研究。结果显示,与铍矿化相关的围岩蚀变为钠长石化、电气石化、白云母化、萤石化、碳酸盐化和绿泥石化,与铀矿化相关的围岩蚀变为硅化、赤铁矿化、萤石化、伊利石化和锰矿化(含少量铅),且铍铀矿石中可见沥青铀矿切穿羟硅铍石的现象。结合铍与铀的地球化学行为和前人研究成果,认为白杨河铍铀矿床中铍矿化与铀矿化应是不同期热液作用的结果:铍矿化可能是花岗斑岩深部岩浆房分异的岩浆热液在不断演化过程中形成的,而铀矿化可能与后期流体(如幔源流体、加热循环的大气降水等)的淋滤作用有关。  相似文献   

Geochemical and geochronological characteristics of the Um Rus granite intrusion and associated gold deposit,Eastern Desert,Egypt     

Basem Zoheir  Richard Goldfarb  Astrid Holzheid  Hassan Helmy  Ahmed El Sheikh 《地学前缘(英文版)》2020,11(1):325-345

The Um Rus tonalite-granodiorite intrusion(~6 km2)occurs at the eastern end of the Neoproterozoic,ENE-trending Wadi Muba rak shear belt in the Central Eastern Desert of Egypt.Gold-bearing quartz veins hosted by the Um Rus intrusion were mined intermittently,and initially by the ancient Egyptians and until the early 1900 s.The relationship between the gold mineralization,host intrusion,and regional structures has always been unclear.We present new geochemical and geochronological data that help to define the tectonic environment and age of the Um Rus intrusion.In addition,field studies are integrated with EPMA and LA-ICP-MS data for gold-associated sulfides to better understand the formation and distribution of gold mineralization.The bulk-rock geochemical data of fresh host rocks indicate a calc-alkaline,metaluminous to mildly peraluminous,I-type granite signature.Their trace element composition reflects a tectonic setting intermediate between subduction-related and within-plate environments,presumably transitional between syn-and post-collisional stages.The crystallization age of the Um Rus intrusion was determined by in situ SHRIMP 206 Pb/238 U and 207Pb/235U measurements on accessory monazite grains.The resultant monazite U-Pb weighted mean age(643±9 Ma;MSWD 1.8)roughly overlaps existing geochronological data for similar granitic intrusions that are confined to major shear systems and are locally associated with gold mineralization in the Central Eastrn Desert(e.g.,Fawakhir and Hangaliya).This age is also consistent with magmatism recognized as concomitant to transpressional tectonics(D2:~650 Ma)during the evolution of the Wadi Mubark belt.Formation of the gold-bearing quartz veins in NNE-SSW and N-S striking fault segments was likely linked to the change from transpressional to transtensional tectonics and terrane exhumation(D3:620-580 Ma).The development of N-S throughgoing fault arrays and dike swarms(~595 Ma)led to heterogeneous deformation and recrystallization of the mineralized quartz veins.Ore minerals in the auriferous quartz veins include ubiquitous pyrite and arsenopyrite,with less abundant pyrrhotite,chalcopyrite,sphalerite,and galena.Uncommon pentlandite,gersdorffite,and cobaltite inclusions hosted in quartz veins with meladiorite slivers are interpreted as pre-ore sulfide phases.The gold-sulfide paragenesis encompasses an early pyrite-arsenopyrite±loellingite assemblage,a transitional pyrite-arsenopyrite assemblage,and a late pyrrhotite-chalcopyrite-sphalerite±galena assemblage.Free-milling gold/electrum grains(10 sμm-long)are scattered in extensively deformed vein quartz and in and adjacent to sulfide grains.Marcasite,malachite,and nodular goethite are authigenic alteration phases after pyrrhotite,chalcopyrite,and pyrite and arsenopyrite,respectively.A combined ore petrography,EPMA,and LA-ICP-MS study distinguishes morphological and compositional differences in the early and transitional pyrites(PyⅠ,PyⅡ)and arsenopyrite(ApyⅠ,ApyⅡ).Py I forms uncommon small euhedral inclusions in later PyⅡand Apy II.PyⅡforms large subhedral crystals with porous inner zones and massive outer zones,separated by narrow As-rich irregular mantles.The Fe and As contents in PyⅡare variable,and the LA-ICP-MS analysis shows erratic concentrations of Au(<1 to 177 ppm)and other trace elements(e.g.,Ag,Te,and Sb)in the porous inner zones,most likely related to discrete sub-microscopic sulfide inclusions.The outer massive zones have a rather homogenous composition,with consistently lower abundances of base metals and Au(mean 1.28 ppm).The early arsenopyrite(Apy I)forms fine-grained euhedral crystals enriched in Au(mean 17.7 ppm)and many other trace elements(i.e.,Ni,Co,Se,Ag,Sb,Te,Hg,and Bi).On the other hand,ApyⅡoccurs as coarsegrained subhedral crystals with lower and less variable concentrations of Au(mean 4 ppm).Elevated concentrations of Au(max.327 ppm)and other trace elements are measured in fragmented and aggregated pyrite and arsenopyrite grains,whereas the undeformed intact zones of the same grains are poor in all trace elements.The occurrence of gold/electrum as secondary inclusions in deformed pyrite and arsenopyrite crystals indicates that gold introduction was relatively late in the paragenesis.The LAICP-MS results are consistent with gold redistribution by the N-S though-going faults/dikes overprinted the earlier NNW-SSE quartz veins in the southeastern part of the intrusion,where the underground mining is concentrated.Formation of the Um Rus intrusion and gold-bearing quartz veins can be related to the evolution of the Wadi Mubarak shear belt,where the granitic intrusion formed during or just subsequent to D2 and provided dilatation spaces for gold-quartz vein deposition when deformed by D3 structures.  相似文献