中国工业烟粉尘排放时空演化及其影响因素     

郭政  姚士谋  吴常艳 《地理科学》2020,40(12):1949-1957

采用空间分析和空间杜宾模型等方法，研究1999—2017年中国工业烟粉尘排放时空演化特征及其影响因素。结果表明：① 中国工业烟粉尘排放空间分布差异明显，其排放的基尼系数和污染物分布指数均呈现下降态势，空间集中程度有所缓和。② 中国工业烟粉尘排放空间分布呈东北?西南走向，其排放中心不断由东南向西北方向迁移。③ 中国工业烟粉尘排放存在空间相关性和空间溢出效应，其冷热点区空间分布发生显著变化。④ 能源消耗、第二产业比重、人口密度和经济发展水平的提升将会增加工业烟粉尘排放，而外资水平、治理技术水平和环境规制力度的提升则有利于减少工业烟粉尘排放。  相似文献   

地方政府土地出让干预对区域工业碳排放影响的对比分析——以中国8大经济区为例     

王博  吴天航  冯淑怡 《地理科学进展》2020,39(9):1436-1446

探讨不同区域地方政府干预对碳排放的影响差异,对于中国推进碳减排战略、协调区域经济社会发展具有重要意义。鉴于此,论文基于地方政府土地出让的视阈,以中国8大经济区为研究对象,有机耦合STIRPAT模型与CKC模型,构建形成STIRPAT拓展模型,并使用2007—2016年中国28个省(市、自治区)的工业面板数据,对比考察8大经济区政府土地出让干预对区域碳排放的影响差异。结果表明:不同经济区的地方政府土地出让干预对区域碳排放的影响存在显著差异。其中,同为CKC“倒N”型的北部沿海、南部沿海、长江中游经济区,其政府土地出让干预对区域碳排放的影响呈现出北部沿海经济区为负、南部沿海经济区为正、长江中游经济区无显著影响的差异效果;同为CKC“倒U”型的东北、西南和西北经济区,其政府土地出让干预对区域碳排放的影响,东北和西南经济区都显著为负,西北经济区未表现出显著影响;同为CKC“U”型的东部沿海和黄河中游经济区,其政府土地出让干预对碳排放也呈现出前者为负、后者为正的相反影响。研究结果可为制定碳减排差别化政策、协调区域可持续发展提供参考。  相似文献   

Coupling numerical simulation with remotely sensed information for the study of frozen soil dynamics     

HuiRan Gao  WanChang Zhang 《寒旱区科学》2020,12(6):404-417

The acquisition of spatial-temporal information of frozen soil is fundamental for the study of frozen soil dynamics and its feedback to climate change in cold regions. With advancement of remote sensing and better understanding of frozen soil dynamics, discrimination of freeze and thaw status of surface soil based on passive microwave remote sensing and numerical simulation of frozen soil processes under water and heat transfer principles provides valuable means for regional and global frozen soil dynamic monitoring and systematic spatial-temporal responses to global change. However, as an important data source of frozen soil processes, remotely sensed information has not yet been fully utilized in the numerical simulation of frozen soil processes. Although great progress has been made in remote sensing and frozen soil physics, yet few frozen soil research has been done on the application of remotely sensed information in association with the numerical model for frozen soil process studies. In the present study, a distributed numerical model for frozen soil dynamic studies based on coupled water-heat transferring theory in association with remotely sensed frozen soil datasets was developed. In order to reduce the uncertainty of the simulation, the remotely sensed frozen soil information was used to monitor and modify relevant parameters in the process of model simulation. The remotely sensed information and numerically simulated spatial-temporal frozen soil processes were validated by in-situ field observations in cold regions near the town of Naqu on the East-Central Tibetan Plateau. The results suggest that the overall accuracy of the algorithm for discriminating freeze and thaw status of surface soil based on passive microwave remote sensing was more than 95%. These results provided an accurate initial freeze and thaw status of surface soil for coupling and calibrating the numerical model of this study. The numerically simulated frozen soil processes demonstrated good performance of the distributed numerical model based on the coupled water-heat transferring theory. The relatively larger uncertainties of the numerical model were found in alternating periods between freezing and thawing of surface soil. The average accuracy increased by about 5% after integrating remotely sensed information on the surface soil. The simulation accuracy was significantly improved, especially in transition periods between freezing and thawing of the surface soil.  相似文献   

敞开酸溶和偏硼酸锂碱熔ICP-MS法测定多金属矿中的稀土元素及铌钽锆铪   总被引：2，自引：2，他引：0  

门倩妮  沈平  甘黎明  冯博鑫 《岩矿测试》2020,39(1):59-67

用电感耦合等离子体质谱法(ICP-MS)测定地质样品中的稀土及难熔元素,混合酸敞开酸溶法和碱熔融法是两种主要的溶样方法。但地质样品组分复杂,元素之间存在相互共生的现象,对于特殊元素、特殊样品用传统酸溶法会造成部分元素消解不完全,使测定结果不准确;而碱熔法的操作过程繁琐,且溶液盐度高,易产生基体干扰和堵塞仪器进样系统。本文改进了传统四酸和五酸体系,采用氢氟酸-硝酸-硫酸敞开酸溶体系,用国家一级标准物质制作标准曲线测定15种稀土元素,方法准确度(ΔlgC)为0.001～0.027。同时改进了偏硼酸锂碱熔法,样品用偏硼酸锂碱熔提取,加入氢氧化钠调节溶液至碱性条件,所测元素与偏硼酸锂共沉淀后过滤分离熔剂,再用硝酸复溶测定15种稀土元素及铌钽锆铪。两种溶样方法的测定值与认定值的相对误差为1.09%～9.30%。将混合酸敞开酸溶法测定稀土元素、偏硼酸锂碱熔法测定铌钽锆铪的结果与其他实验室密闭酸溶法相比,两组数据的相对偏差为0.13%～15.32%。本实验表明,混合酸敞开酸溶法适用于测定地质样品中的稀土元素,偏硼酸锂碱熔法不仅适用于测定地质样品中的稀土元素及铌钽锆铪,也适用于测定如古老高压变质岩石及铝含量高的样品中的铌钽锆铪。  相似文献   

A review of fully coupled atmosphere-hydrology simulations     

Ning  Like  Zhan  Chesheng  Luo  Yong  Wang  Yueling  Liu  Liangmeizi 《地理学报(英文版)》2019,29(3):465-479

Journal of Geographical Sciences - The terrestrial hydrological process is an essential but weak link in global/regional climate models. In this paper, the development status, research hotspots and...  相似文献   

利用模板匹配技术检测米尺度岩石断层黏滑实验中的声发射事件   总被引：1，自引：0，他引：1       下载免费PDF全文

侯金欣  谢凡  任雅琼  王宝善 《地球物理学报》2020,63(4):1630-1641

声发射观测是岩石摩擦实验中研究强震孕育机制的重要观测手段之一.传统的声发射观测以触发记录为主,难以捕捉并提取微弱的声发射信号.近年来天然地震学中发展的模板匹配技术可以在连续波形记录中识别出微弱的事件,大大提升事件检测能力.本文发展了适用于多通道连续记录的声发射信号的模板匹配技术,并将该技术应用于分析米尺度岩石断层黏滑失稳过程.研究结果显示:模板匹配技术识别出的声发射数量约为传统方法识别的5倍,相对完备震级降低约0.3.临近失稳,检测目录完备震级以上声发射率表现出幂律增加的特征,且声发射事件聚集在失稳破裂起始点附近.失稳后,检测目录完备震级以上声发射率表现出幂律衰减,其中失稳后早期表现出较慢的衰减速度.另外,失稳后早期声发射事件表现出随对数时间沿断层迁移的趋势.最后,通过与天然地震学观测的结果对比表明,声发射模板匹配识别技术是研究大尺度岩石摩擦滑动失稳过程中前震和余震时空演化规律的有效手段,该技术助于在方法上为室内实验和野外观测进行融合研究提供思路.  相似文献   

Chemical Procedures for Rhenium Extraction from Geological Samples: Optimising the Anion Resin Bead Clean‐up Step     

Gang Yang  Aaron Zimmerman  Nicole C. Hurtig  Svetoslav V. Georgiev  Vineet Goswami  Judith L. Hannah  Holly J. Stein 《Geostandards and Geoanalytical Research》2020,44(2):231-242

Rhenium–osmium geochronometry for samples with low Re and complex matrices requires improved Re extraction methods. Here, we investigate plausible controls on efficiency and efficacy of Re extraction during our anion resin bead purification. Four different protocols are compared, each isolating a single variable to test. Rhenium concentrations for solutions at each step of each protocol document differences in chemical recovery/yield. The negative‐thermal ionisation mass spectrometry (N‐TIMS) signal intensity serves as a proxy for Re yield and purity. These data document correlations between the N‐TIMS signal intensity and (a) the duration of anion resin bead conditioning prior to loading with Re‐bearing solution, and (b) both duration and strength of nitric acid used during rinsing of the Re‐loaded anion resin bead. The optimal protocol improved Re signal intensity around fourteen times compared with our current Re extraction protocol, an aggregate of 2.4 times improvement in chemical recovery (yield) and 5.8 times improvement in emission efficiency (purity). Repeated N‐TIMS isotopic measurements on our in‐house Re standard solution (1407) verify that our optimal protocol‐3 does not fractionate Re isotopes. The improved anion resin bead method considerably lowers the Re detection limit and allows Re‐Os isotopic analysis of picogram‐level Re hosted in geological samples with complex matrices.  相似文献   

Development and Re‐Evaluation of Tourmaline Reference Materials for In Situ Measurement of Boron δ Values by Secondary Ion Mass Spectrometry     

Katharina Marger  Matthieu Harlaux  Andrea Rielli  Lukas P. Baumgartner  Andrea Dini  Barbara L. Dutrow  Anne‐Sophie Bouvier 《Geostandards and Geoanalytical Research》2020,44(3):593-615

Six tourmaline samples were investigated as potential reference materials (RMs) for boron isotope measurement by secondary ion mass spectrometry (SIMS). The tourmaline samples are chemically homogeneous and cover a compositional range of tourmaline supergroup minerals (primarily Fe, Mg and Li end‐members). Additionally, they have homogeneous boron delta values with intermediate precision values during SIMS analyses of less than 0.6‰ (2s). These samples were compared with four established tourmaline RMs, that is, schorl IAEA‐B‐4 and three Harvard tourmalines (schorl HS#112566, dravite HS#108796 and elbaite HS#98144). They were re‐evaluated for their major element and boron delta values using the same measurement procedure as the new tourmaline samples investigated. A discrepancy of about 1.5‰ in δ¹¹B was found between the previously published reference values for established RMs and the values determined in this study. Significant instrumental mass fractionation (IMF) of up to 8‰ in δ¹¹B was observed for schorl–dravite–elbaite solid solutions during SIMS analysis. Using the new reference values determined in this study, the IMF of the ten tourmaline samples can be modelled by a linear combination of the chemical parameters FeO + MnO, SiO₂ and F. The new tourmaline RMs, together with the four established RMs, extend the boron isotope analysis of tourmaline towards the Mg‐ and Al‐rich compositional range. Consequently, the in situ boron isotope ratio of many natural tourmalines can now be determined with an uncertainty of less than 0.8‰ (2s).  相似文献   

车辆碾压作用下戈壁地表起尘浓度   总被引：1，自引：1，他引：0  

孟小楠  严平  王振亭  董苗  王勇 《中国沙漠》2019,39(1):80-87

通过野外观测车辆碾压作用下戈壁地表PM₁₀释放浓度，探讨其主要影响因素。针对戈壁区砾石、砂砾、砂质和砂土4种路面类型，应用TSI粉尘仪多次重复观测车辆碾压产生的PM₁₀浓度，进而阐明碾压次数、车速和地表水分等因素对起尘浓度的影响。结果表明：4种路面的平均起尘浓度依次为5.339、9.089、16.944、50.251 mg·m^-3，是自然状态下的5~50倍；起尘浓度随碾压次数增多而增大，其中砂土路情况下的增长最显著；随土层厚度的增大呈现出幂函数的增长趋势；降雨后路面起尘浓度显著减小，且降雨量会影响降雨后起尘浓度的变化趋势。最后提出了针对性的建议和措施以减弱车辆碾压导致的戈壁地表起尘。  相似文献   

集聚空间组织型式对中国地市尺度工业SO2排放的影响     

胡志强  苗长虹  袁丰 《地理学报》2019,74(10):2045-2061

集聚外部性是集聚影响工业污染排放的重要机制,不同的集聚空间组织型式具有不同的污染排放行为和减排效果。以中国285个地市工业SO₂排放为例,依据集聚经济理论,将集聚空间组织型式细分为集聚密度、企业地理临近度、专业化、多样性、相关多样性、非相关多样性等不同类型,在系统分析工业SO₂排放与集聚空间格局的基础上,通过构建计量经济模型,考察了不同集聚空间组织型式对工业SO₂排放强度的影响。结果表明：① 工业SO₂排放强度与工业集聚密度在空间上具有非对称性,污染排放强度西高东低,工业集聚密度、企业地理临近、多样性、相关和非相关多样性为东中高西部低;② 工业集聚对工业SO₂排放强度的影响存在空间溢出效应,相邻地区集聚密度、多样性和相关多样性水平的上升有利于本区域工业污染排放强度的下降,但专业化水平的上升则会提升本区域的工业污染排放强度;③ 提高集聚密度、引导企业集中布局有利于工业SO₂排放强度下降,多样且关联的产业组织结构有利于污染减排,而专业化和非关联产业的集中会提高污染排放强度;④ 集聚型式对工业SO₂排放强度的影响存在区域和城市规模上的异质性,集聚密度、企业地理临近、多样性和相关多样性对中西部污染减排的作用比东部明显,专业化和非相关多样性不利于东中部地区的污染减排;城区人口规模20万以下的小城市提高集聚密度、减少多样性特别是非相关多样性更有利于污染减排;城区人口规模20~50万的小城市和50~100万的中等城市,提高企业的地理接近度和多样性水平特别是相关多样性水平,有利于其降低污染排放强度;城区人口规模在100万以上的大城市,提高集聚密度和产业多样性水平在一定程度上有利于其污染减排,但其减排效果因拥挤效应而明显下降;⑤ 进一步降低工业SO₂排放强度,需要走集聚化道路,坚持提高集聚密度,因地制宜引导企业集中布局,着力提高产业在关联基础上的多样性水平,加强区域间联防联控,重视区域间的产业联系与环保合作。  相似文献