The thermal maturity of sedimentary basins as revealed by magnetic mineralogy     

Mansour M. Abdelmalak  Stéphane Polteau 《Basin Research》2020,32(6):1510-1531

The thermal evolution of sedimentary basins is usually constrained by maturity data, which is interpreted from Rock-Eval pyrolysis and vitrinite reflectance analytical results on field or boreholes samples. However, some thermal evolution models may be inaccurate due to the use of elevated maturities measured in samples collected within an undetected metamorphic contact aureole surrounding a magmatic intrusion. In this context, we investigate the maturity and magnetic mineralogy of 16 claystone samples from Disko-Svartenhuk Basin, part of the SE Baffin Bay volcanic margin. Samples were collected within thermal contact metamorphic aureoles near magma intrusions, as well as equivalent reference samples not affected by intrusions. Rock-Eval pyrolysis (T_max), and vitrinite reflectance (Ro) analysis were performed to assess the thermal maturity, which lies in the oil window when 435°C ≤ T_max ≤ 470°C and 0.6%–0.7% ≤ Ro ≤ 1.3%. In addition, we performed low- (<300K) and high-temperature (>300K) investigations of isothermal remanent magnetization to assess the magnetic mineralogy of the selected samples. The maturity results (0.37% ≤ Ro ≤ 2%, 22°C ≤ T_max ≤ 604°C) show a predominance of immature to early mature Type III organic matter, but do not reliably identify the contact aureole when compared to the reference samples. The magnetic assemblage of the immature samples consists of iron sulphide (greigite), goethite and oxidized or non-stoichiometric magnetite. The magnetic assemblage of the early mature to mature samples consists of stoichiometric magnetite and fine-grained pyrrhotite (<1 μm). These results document the disappearance of the iron sulphide (greigite) and increase in content of magnetite during normal burial. On the other hand, magnetite is interpreted to be the dominant magnetic mineral inside the contact aureole surrounding dyke/sill intrusions where palaeotemperatures indicate mature to over-mature state. Interestingly, the iron sulphide (greigite) is still detected in the contact aureole where palaeotemperatures exceeded 130°C. Therefore, the magnetic mineralogy is a sensitive method that can characterize normal burial history, as well as identify hidden metamorphic contact aureoles where the iron sulphide greigite is present at temperatures beyond its stability field.  相似文献   

云南哀牢山-红河剪切带新生代富碱侵入岩中榍石年代学和地球化学特征     

马倩  杨岳衡  赵志丹  佟鑫  武精凯  苗壮  李晨  雷杭山 《岩石学报》2020,36(9):2751-2764

榍石作为副矿物在哀牢山-红河剪切带新生代富碱侵入岩中广泛存在。原位获取榍石矿物内部微量元素、U-Pb年龄和Sm-Nd同位素的空间变化对获取矿物和岩石的成因演化信息具有重要意义。本文使用四级杆/多接收电感耦合等离子体质谱(Quadrupole/Multi-Collector Inductively Coupled Plasma Mass Spectrometry,Q/MC-ICP-MS)与激光剥蚀系统(Laser Ablation,LA)联用,对哀牢山-红河剪切带5个富碱侵入岩体(桃花岩体、宁蒗-永胜岩体、哈播岩体、铜厂岩体和十里村岩体)中榍石开展了微区原位微量元素、U-Pb年代学和Sm-Nd同位素研究。微量元素分析结果表明,三江富碱侵入岩中榍石为岩浆成因,亏损Rb、Ba、Pb、Sr等大离子亲石元素,富集Th、U、Nb、Ta、Zr、Hf等高场强元素。榍石的稀土配分图均表现为明显右倾,不具有或具有弱的Eu负异常。与云南北衙、马厂箐矽卡岩矿床中的热液榍石相比,本文榍石在稀土元素组成上,具有较高的稀土元素总量、较高的Th/U、LREE/HREE和Ce/Ce*比值,具有较低的Eu/Eu*、Nb/Ta、Zr/Hf比值。微区原位LA-Q-ICP-MS U-Pb定年结果表明,研究区富碱岩体中榍石结晶年龄在32.5～37.9Ma之间,代表了岩体形成时代,与三江地区哀牢山-红河剪切带及其附近新生代富碱岩浆活动高峰期(～35Ma)一致,属于青藏高原晚碰撞期岩浆作用的产物。榍石微区原位LA-MCICP-MS Sm-Nd同位素分析结果显示,榍石颗粒的Nd同位素组成均一,表明榍石结晶过程中寄主岩浆的Nd同位素组成没有发生明显变化。各个富碱岩体之间的榍石Nd同位素组成变化范围在-6.8～-2.1之间,与全岩的同位素特征一致,表明榍石的原位微区Sm-Nd同位素可以作为富碱侵入岩研究中有效的示踪手段之一。  相似文献   

川西甲基卡矿床外围中酸性侵入岩LA-ICP-MS锆石U-Pb年龄及地球化学特征     

李名则  秦宇龙  赵春  詹涵钰  周雄  孙光银 《中国地质调查》2020,7(5):1-9

在川西甲基卡矿床外围新发现了建巴村中酸性侵入岩体,为了探讨其形成时代、成岩构造背景及其成矿条件,开展了LA-ICP-MC锆石U-Pb年代学和地球化学特征研究。结果表明: 该岩体的结晶年龄为(211.8±1.0) Ma; 岩石属于钙碱性-高钾钙碱性准铝质中酸性侵入岩系列,具有I型花岗岩类的特征,其物质来源可能为壳源物质与幔源物质部分熔融。地球化学特征表明其形成于后碰撞环境,与此时期内川西地区的区域性岩浆活动相对应。建巴村岩体的构造位置及岩浆活动特征指示其可能不具备形成伟晶岩矿床的条件。  相似文献   

In situ measurements of wind‐driven salt fluxes through constructed channels in a coastal wetland ecosystem          下载免费PDF全文

Alex K. Manda  Enrique Reyes  James M. Pitt 《水文研究》2018,32(5):636-643

A suite of instruments was deployed in a coastal wetland ecosystem in the Albemarle estuarine system, North Carolina (USA), to characterize wind‐driven transport of saltwater through a constructed (man‐made) channel. Flow velocity, electrical conductivity, and stage were measured in a representative channel over a 2‐month period from May to July 2014, during which 4 wind tides were observed. Collected data show that thousands of metric tons of salt were advected through the channel into coastal wetlands during each event, which lasted up to 4 days. The results reveal that as much as 36% of advected salts accumulated in the wetlands, suggesting that the cumulative effects of these events on the health of coastal wetlands in the Albemarle system may be substantial due to the abundance of constructed channels and the frequency of wind‐driven tidal events. This study is the first to quantify wind‐driven salt fluxes through constructed channels in coastal wetland settings.  相似文献   

Data-based modelling approach for variable density flow and solute transport simulation in a coastal aquifer   总被引：1，自引：1，他引：0  

Basant Yadav  Shashi Mathur  Sudheer Ch  Brijesh Kumar Yadav 《水文科学杂志》2018,63(2):210-226

Data-based models, namely artificial neural network (ANN), support vector machine (SVM), genetic programming (GP) and extreme learning machine (ELM), were developed to approximate three-dimensional, density-dependent flow and transport processes in a coastal aquifer. A simulation model, SEAWAT, was used to generate data required for the training and testing of the data-based models. Statistical analysis of the simulation results obtained by the four models show that the data-based models could simulate the complex salt water intrusion process successfully. The selected models were also compared based on their computational ability, and the results show that the ELM is the fastest technique, taking just 0.5 s to simulate the dataset; however, the SVM is the most accurate, with a Nash-Sutcliffe efficiency (NSE) ≥ 0.95 and correlation coefficient R ≥ 0.92 for all the wells. The root mean square error (RMSE) for the SVM is also significantly less, ranging from 12.28 to 77.61 mg/L.  相似文献   

State of seawater intrusion and its adaptive management countermeasures in Longkou City of China          下载免费PDF全文

ZHONG Hua-ping  WU Yong-xiang 《地下水科学与工程》2020,8(1):30-42

Longkou City is a coastal area,and lacks water resources.The overexploitation of groundwater causes seawater intrusion.At present,seawater intrudes an area of 68 km2.With the decrease of groundwater extraction,the seawater intrusion area has generally declined.The paper expounds the development process of seawater intrusion as well as the corresponding prevention and control measures of using groundwater replenishment and groundwater throttling in Longkou City.In view of the seawater intrusion problem in Longkou City,some adaptive management countermeasures are put forward,which include:Adjusting industrial and agricultural structure,promoting economic and social development to match water resources;improving water usage structure,optimizing the utilization of water resources;advancing the construction of a water-saving society,using water resources efficiently;implementing inter-basin water transfer,using water resources rationally;developing and utilizing unconventional water sources,making full use of water resources;strengthening water infrastructure construction,increasing the development and utilization potential of water resources;carrying out ecological restoration,protecting water resources and ecological environment;improving the management informationalization level,strengthening the capabilities of groundwater monitoring and management;increasing publicity,improving public awareness of participation.  相似文献   

Sea‐level rise impact on fresh groundwater lenses in two‐layer small islands          下载免费PDF全文

Hamed Ketabchi  Davood Mahmoodzadeh  Behzad Ataie‐Ashtiani  Adrian D. Werner  Craig T. Simmons 《水文研究》2014,28(24):5938-5953

The fresh groundwater lenses (FGLs) of small islands can be highly vulnerable to climate change impacts, including sea‐level rise (SLR). Many real cases of atoll or sandy islands involve two‐layer hydrogeological conceptualizations. In this paper, the influential factors that affect FGLs in two‐layer small islands subject to SLR are investigated. An analytical solution describing FGLs in circular islands, composed of two geological layers, is developed for the simplified case of steady‐state and sharp‐interface conditions. An application of the developed model is demonstrated to estimate the FGL thickness of some real‐world islands by comparison with existing FGL thickness data. Furthermore, numerical modelling is applied to extend the analysis to consider dispersion effects and to confirm comparable results for both cases. Sensitivity analyses are used to assess the importance of land‐surface inundation caused by SLR, relative to other parameters (i.e. thickness of aquifer layers, hydraulic conductivity, recharge rate and land‐surface slope) that influence the FGL. Dimensionless parameters are used to generalize the findings. The results demonstrate that land‐surface inundation has a considerable impact on a FGL influenced by SLR, as expected, although the FGL volume is more sensitive to recharge, aquifer thickness and hydraulic conductivity than SLR impacts, considering typical parameter ranges. The methodology presented in this study provides water resource managers with a rapid‐assessment tool for evaluating the likely impacts of SLR and accompanying LSI on FGLs.  相似文献   

西秦岭中—晚三叠世构造属性:来自将其那梁侵入杂岩体的年代学及地球化学证据     

严镜  刘景显  蒲万峰  魏学平  李智斌 《现代地质》2021,35(6):1677-1690

西秦岭造山带印支早期的构造环境仍存在较多争论,选择西秦岭将其那梁杂岩体进行详细的年代学、岩石学及地球化学分析,以期对该科学问题进行深入探讨。将其那梁杂岩体由石英闪长岩和花岗斑岩组成,石英闪长岩LA-ICP-MS锆石U-Pb年龄为(240.0±1.5) Ma,形成时代为中三叠世,属于早印支期。将其那梁杂岩体具有富钾(K₂O=3.09%~3.54%)、富碱(K₂O+Na₂O=6.44%~7.20%)和过铝质(A/CNK=1.05~1.56)特征,Mg^#值(54~67)较高,属于过铝质高钾钙碱性岩类。将其那梁杂岩体石英闪长岩和花岗斑岩具有相似的微量元素及稀土元素组成,轻重稀土元素分馏明显(LREE/HREE=8.19~14.63),呈右倾特征,显示无或弱负Eu异常(δEu=0.87~1.03),具有亏损Nb、Ta、Zr等高场强元素和富集Ba、Rb、Sr等大离子亲石元素的地球化学特征。岩石地球化学特征指示,将其那梁杂岩体主要源于下地壳高钾变基性岩的部分熔融,且有幔源物质参与其中。结合区域地质背景,认为将其那梁杂岩体形成于火山弧构造环境,可能与中—晚三叠世阿尼玛卿—勉略洋向北俯冲有关,反映了中—晚三叠世西秦岭地区具有活动大陆边缘的属性。  相似文献   

晚中生代沂沭断裂带左旋韧性剪切与岩浆迁移规律     

李盛  倪金龙  张尚坤  申颖 《现代地质》2021,35(3):776-786

沂沭断裂带内部的岩浆侵入与断裂活动关系密切,开展沂沭断裂带内部岩浆年代学研究,对于沂沭断裂带构造背景研究具有积极的参考意义。选取沂沭断裂带内部的莒县浮来山正长岩体、边部的莒南官坊石英正长岩体及侵入该岩体的闪长玢岩脉,开展岩石学及年代学研究。首次发现晚中生代沂沭断裂带左旋韧性剪切,获得浮来山岩体的LA-ICP-MS锆石U-Pb年龄为(125.1±1.7) Ma,官坊岩体年龄为(125.6±2.0) Ma, 发生韧性变形的闪长玢岩脉年龄为(122.8±2.1) Ma。获得的125 Ma岩浆活动年龄与沂沭断裂带东侧的五莲变质核杂岩快速剥露(122~128 Ma)、诸城断陷盆地快速沉降的时间相吻合,该时期沂沭断裂带处于岩石圈减薄与破坏强烈的时期;闪长玢岩脉的122.8 Ma结晶年龄,与五莲变质核杂岩后构造岩体(石场、坊子岩体等)结晶年龄一致,该时期沂沭断裂带处于弱伸展状态,同时也说明胶东半岛岩石圈减薄具有时间上的一致性。晚中生代时期,沂沭断裂带两侧岩浆活动具有逆时针迁移的规律,这一规律可能与伊佐奈岐板块向欧亚板块俯冲的方向、角度、速度的变换有关。  相似文献   

华南地区春季平流层入侵对对流层低层臭氧影响的模拟研究     

赵恺辉  包云轩  黄建平  张潇艳  刘诚  戚慧雯  许玮 《大气科学》2019,43(1):75-86

利用中尺度大气化学模式WRF/Chem对2013年3月6日华南地区一次平流层入侵事件及其对对流层低层臭氧的影响进行模拟研究。通过加入UBC（Upper Boundary Condition）上边界处理方案,弥补WRF/Chem模式未考虑平流层臭氧化学反应的不足。结合臭氧探空廓线资料、地面O₃、CO、NO_x、相对湿度、温度和风速等观测资料以及再分析资料对模拟结果进行定量评估,结果表明模式能较为真实地模拟本次平流层入侵过程。模拟分析进一步揭示:（1）副热带高空急流是本次平流层入侵的主要原因。当华南地区处在副热带急流入口区左侧下沉区域时,平流层入侵将富含臭氧的干燥空气输送到对流层中低层。（2）本次平流层入侵对对流层低层臭氧收支有重要影响,导致香港地区近地层臭氧体积混合比浓度明显上升,如塔门站夜间臭氧浓度升高21.3 ppb（1 ppb=1×10-9）。地面气象场和化学物种的分析进一步确认了平流层入侵的贡献。（3）采用动力学对流层顶高度时零维箱式模型和Wei公式计算得到的平流层入侵通量相当,分别为-1.42×10-3 kg m-2 s-1和-1.59×10-3 kg m-2 s-1,这一结果与前人研究相吻合,且与采用热力学对流层顶高度计算所得到的结果具有可比性。  相似文献