The thermal maturity of sedimentary basins as revealed by magnetic mineralogy     

Mansour M. Abdelmalak  Stéphane Polteau 《Basin Research》2020,32(6):1510-1531

The thermal evolution of sedimentary basins is usually constrained by maturity data, which is interpreted from Rock-Eval pyrolysis and vitrinite reflectance analytical results on field or boreholes samples. However, some thermal evolution models may be inaccurate due to the use of elevated maturities measured in samples collected within an undetected metamorphic contact aureole surrounding a magmatic intrusion. In this context, we investigate the maturity and magnetic mineralogy of 16 claystone samples from Disko-Svartenhuk Basin, part of the SE Baffin Bay volcanic margin. Samples were collected within thermal contact metamorphic aureoles near magma intrusions, as well as equivalent reference samples not affected by intrusions. Rock-Eval pyrolysis (T_max), and vitrinite reflectance (Ro) analysis were performed to assess the thermal maturity, which lies in the oil window when 435°C ≤ T_max ≤ 470°C and 0.6%–0.7% ≤ Ro ≤ 1.3%. In addition, we performed low- (<300K) and high-temperature (>300K) investigations of isothermal remanent magnetization to assess the magnetic mineralogy of the selected samples. The maturity results (0.37% ≤ Ro ≤ 2%, 22°C ≤ T_max ≤ 604°C) show a predominance of immature to early mature Type III organic matter, but do not reliably identify the contact aureole when compared to the reference samples. The magnetic assemblage of the immature samples consists of iron sulphide (greigite), goethite and oxidized or non-stoichiometric magnetite. The magnetic assemblage of the early mature to mature samples consists of stoichiometric magnetite and fine-grained pyrrhotite (<1 μm). These results document the disappearance of the iron sulphide (greigite) and increase in content of magnetite during normal burial. On the other hand, magnetite is interpreted to be the dominant magnetic mineral inside the contact aureole surrounding dyke/sill intrusions where palaeotemperatures indicate mature to over-mature state. Interestingly, the iron sulphide (greigite) is still detected in the contact aureole where palaeotemperatures exceeded 130°C. Therefore, the magnetic mineralogy is a sensitive method that can characterize normal burial history, as well as identify hidden metamorphic contact aureoles where the iron sulphide greigite is present at temperatures beyond its stability field.  相似文献   

新疆图拉尔根镁铁-超镁铁质杂岩体镍铜钴成矿岩浆作用过程:流体化学与碳同位素组成制约     

张铭杰  班舒悦  李思奥  宋哲  仇哲  李立武  惠卫东  李中平 《岩石学报》2020,36(12):3673-3682

东天山造山带的图拉尔根镁铁-超镁铁杂岩体为一个早古生代长期活动的幔源岩浆通道，大型铜镍钴硫化物矿体赋存于Ⅰ号超镁铁质岩体的顶部，不同类型岩石中辉石矿物的流体挥发份化学组成以H₂O为主（平均91%，5400.4mm³/g），其次为H₂（2.0%）、H₂S（2.3%）和CO₂（2.1%）；赋矿角闪橄榄岩中CO₂和H₂S含量最高，辉长岩中流体挥发份含量低于辉石橄榄岩和橄榄辉石岩等岩浆早期结晶的岩石。CO₂和CH₄的δ¹³C值位于地壳与甲烷氧化的范围内，甲烷同系物的碳同位素组成具有正序分布模式，部分样品（TLG512）释出的CH₄和C₂H₆具有较重的δ¹³C值和反序分布特征。表明I号岩体不同类型岩石可能是不同期次岩浆活动的产物，成矿岩浆具有富H₂O和H₂S的特征，可能起源于被流体交代的亏损地幔源区，混染壳源组分可能为俯冲板片来源蚀变沉积有机质组分。  相似文献   

云南哀牢山-红河剪切带新生代富碱侵入岩中榍石年代学和地球化学特征     

马倩  杨岳衡  赵志丹  佟鑫  武精凯  苗壮  李晨  雷杭山 《岩石学报》2020,36(9):2751-2764

榍石作为副矿物在哀牢山-红河剪切带新生代富碱侵入岩中广泛存在。原位获取榍石矿物内部微量元素、U-Pb年龄和Sm-Nd同位素的空间变化对获取矿物和岩石的成因演化信息具有重要意义。本文使用四级杆/多接收电感耦合等离子体质谱(Quadrupole/Multi-Collector Inductively Coupled Plasma Mass Spectrometry,Q/MC-ICP-MS)与激光剥蚀系统(Laser Ablation,LA)联用,对哀牢山-红河剪切带5个富碱侵入岩体(桃花岩体、宁蒗-永胜岩体、哈播岩体、铜厂岩体和十里村岩体)中榍石开展了微区原位微量元素、U-Pb年代学和Sm-Nd同位素研究。微量元素分析结果表明,三江富碱侵入岩中榍石为岩浆成因,亏损Rb、Ba、Pb、Sr等大离子亲石元素,富集Th、U、Nb、Ta、Zr、Hf等高场强元素。榍石的稀土配分图均表现为明显右倾,不具有或具有弱的Eu负异常。与云南北衙、马厂箐矽卡岩矿床中的热液榍石相比,本文榍石在稀土元素组成上,具有较高的稀土元素总量、较高的Th/U、LREE/HREE和Ce/Ce*比值,具有较低的Eu/Eu*、Nb/Ta、Zr/Hf比值。微区原位LA-Q-ICP-MS U-Pb定年结果表明,研究区富碱岩体中榍石结晶年龄在32.5～37.9Ma之间,代表了岩体形成时代,与三江地区哀牢山-红河剪切带及其附近新生代富碱岩浆活动高峰期(～35Ma)一致,属于青藏高原晚碰撞期岩浆作用的产物。榍石微区原位LA-MCICP-MS Sm-Nd同位素分析结果显示,榍石颗粒的Nd同位素组成均一,表明榍石结晶过程中寄主岩浆的Nd同位素组成没有发生明显变化。各个富碱岩体之间的榍石Nd同位素组成变化范围在-6.8～-2.1之间,与全岩的同位素特征一致,表明榍石的原位微区Sm-Nd同位素可以作为富碱侵入岩研究中有效的示踪手段之一。  相似文献   

川西甲基卡矿床外围中酸性侵入岩LA-ICP-MS锆石U-Pb年龄及地球化学特征     

李名则  秦宇龙  赵春  詹涵钰  周雄  孙光银 《中国地质调查》2020,7(5):1-9

在川西甲基卡矿床外围新发现了建巴村中酸性侵入岩体,为了探讨其形成时代、成岩构造背景及其成矿条件,开展了LA-ICP-MC锆石U-Pb年代学和地球化学特征研究。结果表明: 该岩体的结晶年龄为(211.8±1.0) Ma; 岩石属于钙碱性-高钾钙碱性准铝质中酸性侵入岩系列,具有I型花岗岩类的特征,其物质来源可能为壳源物质与幔源物质部分熔融。地球化学特征表明其形成于后碰撞环境,与此时期内川西地区的区域性岩浆活动相对应。建巴村岩体的构造位置及岩浆活动特征指示其可能不具备形成伟晶岩矿床的条件。  相似文献   

In situ measurements of wind‐driven salt fluxes through constructed channels in a coastal wetland ecosystem          下载免费PDF全文

Alex K. Manda  Enrique Reyes  James M. Pitt 《水文研究》2018,32(5):636-643

A suite of instruments was deployed in a coastal wetland ecosystem in the Albemarle estuarine system, North Carolina (USA), to characterize wind‐driven transport of saltwater through a constructed (man‐made) channel. Flow velocity, electrical conductivity, and stage were measured in a representative channel over a 2‐month period from May to July 2014, during which 4 wind tides were observed. Collected data show that thousands of metric tons of salt were advected through the channel into coastal wetlands during each event, which lasted up to 4 days. The results reveal that as much as 36% of advected salts accumulated in the wetlands, suggesting that the cumulative effects of these events on the health of coastal wetlands in the Albemarle system may be substantial due to the abundance of constructed channels and the frequency of wind‐driven tidal events. This study is the first to quantify wind‐driven salt fluxes through constructed channels in coastal wetland settings.  相似文献   

Data-based modelling approach for variable density flow and solute transport simulation in a coastal aquifer   总被引：1，自引：1，他引：0  

Basant Yadav  Shashi Mathur  Sudheer Ch  Brijesh Kumar Yadav 《水文科学杂志》2018,63(2):210-226

Data-based models, namely artificial neural network (ANN), support vector machine (SVM), genetic programming (GP) and extreme learning machine (ELM), were developed to approximate three-dimensional, density-dependent flow and transport processes in a coastal aquifer. A simulation model, SEAWAT, was used to generate data required for the training and testing of the data-based models. Statistical analysis of the simulation results obtained by the four models show that the data-based models could simulate the complex salt water intrusion process successfully. The selected models were also compared based on their computational ability, and the results show that the ELM is the fastest technique, taking just 0.5 s to simulate the dataset; however, the SVM is the most accurate, with a Nash-Sutcliffe efficiency (NSE) ≥ 0.95 and correlation coefficient R ≥ 0.92 for all the wells. The root mean square error (RMSE) for the SVM is also significantly less, ranging from 12.28 to 77.61 mg/L.  相似文献   

State of seawater intrusion and its adaptive management countermeasures in Longkou City of China          下载免费PDF全文

ZHONG Hua-ping  WU Yong-xiang 《地下水科学与工程》2020,8(1):30-42

Longkou City is a coastal area,and lacks water resources.The overexploitation of groundwater causes seawater intrusion.At present,seawater intrudes an area of 68 km2.With the decrease of groundwater extraction,the seawater intrusion area has generally declined.The paper expounds the development process of seawater intrusion as well as the corresponding prevention and control measures of using groundwater replenishment and groundwater throttling in Longkou City.In view of the seawater intrusion problem in Longkou City,some adaptive management countermeasures are put forward,which include:Adjusting industrial and agricultural structure,promoting economic and social development to match water resources;improving water usage structure,optimizing the utilization of water resources;advancing the construction of a water-saving society,using water resources efficiently;implementing inter-basin water transfer,using water resources rationally;developing and utilizing unconventional water sources,making full use of water resources;strengthening water infrastructure construction,increasing the development and utilization potential of water resources;carrying out ecological restoration,protecting water resources and ecological environment;improving the management informationalization level,strengthening the capabilities of groundwater monitoring and management;increasing publicity,improving public awareness of participation.  相似文献   

扬子地块北缘新元古代望江山层状岩体矿物成分和铂族元素特征:对岩浆演化过程和构造环境的制约   总被引：1，自引：1，他引：0  

王岩  王梦玺  焦建刚 《地质力学学报》2019,25(2):267-285

望江山层状岩体位于扬子地块北缘新元古代汉南杂岩带中，岩体从底部到顶部由超镁铁质岩过渡为中性岩:底部主要由辉石岩和橄长岩组成；中部为辉长苏长岩和辉长岩；上部为辉长岩和闪长岩。研究以中部岩相带橄榄辉长苏长岩、辉长苏长岩和辉长岩为对象，通过主要矿物的主微量元素和全岩主微量元素的分析，查明望江山岩体来源于尖晶石二辉橄榄岩组成的大陆下岩石圈地幔，并且地幔源区受到了来自俯冲板片流体的交代，岩体中部带的母岩浆为拉斑玄武质岩浆。钛铁矿—磁铁矿矿物对成分计算表明，母岩浆在形成时具有较高氧逸度。通过单斜辉石压力计得到岩体的侵位深度约为12.9~18 km。对岩体母岩浆橄榄石分离结晶过程的模拟计算表明，中部带橄榄石为母岩浆经过~28%分离结晶的产物。此外，铂族元素（PGE）组成暗示岩体并未经历过大规模的硫化物熔离，可能与缺乏地壳物质混染有关。岩体中单斜辉石与岛弧环境堆晶岩中单斜辉石成分相似，不同于裂谷环境中堆晶单斜辉石的成分；同时，全岩Th/Yb和Nb/Yb比值也与岛弧玄武岩比值相似，因此矿物和全岩成分均说明望江山层状岩体应形成于岛弧环境。研究认为扬子北缘在新元古代长期的俯冲过程中，大洋板片断离导致软流圈上涌，提供热源使交代大陆下岩石圈地幔部分熔融形成具有岛弧特征的镁铁质岩浆，在局部伸展环境中上升侵位形成汉南杂岩带中镁铁—超镁铁质层状岩体。   相似文献   

Sampling efficiency in Monte Carlo based uncertainty propagation strategies: Application in seawater intrusion simulations     

《Advances in water resources》2014

The implementation of Monte Carlo simulations (MCSs) for the propagation of uncertainty in real-world seawater intrusion (SWI) numerical models often becomes computationally prohibitive due to the large number of deterministic solves needed to achieve an acceptable level of accuracy. Previous studies have mostly relied on parallelization and grid computing to decrease the computational time of MCSs. However, another approach which has received less attention in the literature is to decrease the number of deterministic simulations by using more efficient sampling strategies. Sampling efficiency is a measure of the optimality of a sampling strategy. A more efficient sampling strategy requires fewer simulations and less computational time to reach a certain level of accuracy. The efficiency of a sampling strategy is highly related to its space-filling characteristics.This paper illustrates that the use of optimized Latin hypercube sampling (OLHS) strategies instead of the widely employed simple random sampling (SRS) and Latin hypercube sampling (LHS) strategies, can significantly improve sampling efficiency and hence decrease the simulation time of MCSs. Nine OLHS strategies are evaluated including: improved Latin hypercube sampling (IHS); optimum Latin hypercube (OLH) sampling; genetic optimum Latin hypercube (GOLH) sampling; three sampling strategies based on the enhanced stochastic evolutionary (ESE) algorithm namely φ_p-ESE which employs the φ_p space-filling criterion, CLD-ESE which utilizes the centered L₂-discrepancy (CLD) space-filling criterion, and SLD-ESE which uses the star L₂-discrepancy (SLD) space-filling criterion; and three sampling strategies based on the simulated annealing (SA) algorithm namely φ_p-SA which employs the φ_p criterion, CLD-SA which uses the CLD criterion, and SLD-SA which utilizes the SLD criterion. The study applies SRS, LHS and the nine OLHS strategies to MCSs of two synthetic test cases of SWI. The two test cases are the Henry problem and a two-dimensional radial representation of SWI in a circular island. The comparison demonstrates that the CLD-ESE strategy is the most efficient among the evaluated strategies. This paper also demonstrates how the space-filling characteristics of different OLHS designs change with variations in the input arguments of their optimization algorithms.  相似文献   

Sea‐level rise impact on fresh groundwater lenses in two‐layer small islands          下载免费PDF全文

Hamed Ketabchi  Davood Mahmoodzadeh  Behzad Ataie‐Ashtiani  Adrian D. Werner  Craig T. Simmons 《水文研究》2014,28(24):5938-5953

The fresh groundwater lenses (FGLs) of small islands can be highly vulnerable to climate change impacts, including sea‐level rise (SLR). Many real cases of atoll or sandy islands involve two‐layer hydrogeological conceptualizations. In this paper, the influential factors that affect FGLs in two‐layer small islands subject to SLR are investigated. An analytical solution describing FGLs in circular islands, composed of two geological layers, is developed for the simplified case of steady‐state and sharp‐interface conditions. An application of the developed model is demonstrated to estimate the FGL thickness of some real‐world islands by comparison with existing FGL thickness data. Furthermore, numerical modelling is applied to extend the analysis to consider dispersion effects and to confirm comparable results for both cases. Sensitivity analyses are used to assess the importance of land‐surface inundation caused by SLR, relative to other parameters (i.e. thickness of aquifer layers, hydraulic conductivity, recharge rate and land‐surface slope) that influence the FGL. Dimensionless parameters are used to generalize the findings. The results demonstrate that land‐surface inundation has a considerable impact on a FGL influenced by SLR, as expected, although the FGL volume is more sensitive to recharge, aquifer thickness and hydraulic conductivity than SLR impacts, considering typical parameter ranges. The methodology presented in this study provides water resource managers with a rapid‐assessment tool for evaluating the likely impacts of SLR and accompanying LSI on FGLs.  相似文献