南秦岭早古生代玄武岩的岩浆源区及演化过程   总被引：1，自引：1，他引：0  

张方毅  赖绍聪  秦江锋  朱韧之  赵少伟  杨航  朱毓  张泽中 《岩石学报》2020,36(7):2149-2162

南秦岭地区早古生代玄武岩中发育的大量单斜辉石斑晶为研究火山岩的深部演化过程及源区属性提供了重要的载体。本文通过对早古生代玄武岩及其中的单斜辉石斑晶进行矿物学、岩石学及地球化学分析,讨论火山岩的演化历程及源区属性。电子探针分析结果表明玄武岩中单斜辉石斑晶属于透辉石,其成分与全岩成分并不平衡,暗示岩石经历了单斜辉石的堆晶作用。通过质量平衡计算得到了与单斜辉石斑晶平衡的熔体并计算了单斜辉石结晶的温压条件,结果显示单斜辉石斑晶结晶压力为7.6～14.0kbar,温度为1201～1268℃。高压下的分离结晶作用导致了单斜辉石成为主要的结晶相。重建后的玄武岩具有高镁、高钙、富钛,富集高场强元素Nb、Ta,亏损Rb、K、Sr和P,Dy/Yb比值高的地球化学特征,指示其源区为含单斜辉石、磷灰石及石榴石的交代岩石圈地幔。同地区发现的玄武质角砾也具高镁及高钙的特征,其富集Ba、Nb、Ta、Ti及低Dy/Yb比值表明源区为含单斜辉石、角闪石及尖晶石的交代岩石圈地幔。  相似文献   

西秦岭温泉花岗岩体岩石学特征及岩浆混合标志   总被引：14，自引：5，他引：9  

李永军  李注苍  丁仨平  刘志武  李民贤  李金宝 《地球科学与环境学报》2004,26(3):7-12

温泉花岗岩体由酸性端元的寄主岩石和暗色微细粒镁铁质包体群及基性岩墙群组成。无岩浆混合作用或岩浆混合作用较弱区段，寄主岩石以似斑状二长花岗岩为主．显示正常的花岗岩结构构造岩浆混合作用强烈区段。岩石的异常结构构造十分发育．矿物之间自形程度差异显著．常见包晶反应、包含结构、交代边、熔蚀边、交代蚕食的港湾状结构构造及交代缝合线、矿物镶边、斜长石异常环带和矿物残留等，多见指示岩浆混合的标志性矿物针状磷灰石。暗色微粒包体中多见寄主二长花岗岩中的捕掳晶。包体的形态、结构构造以及与寄主岩石强烈地成分交换等均是岩浆混合作用的标志。  相似文献   

东秦岭火山岩的地球化学特征和成因模式     

何瑞芳  段联合 《地球科学与环境学报》1993,(2)

熊耳群为玄武粗安岩-英安流纹岩组合,大红口组为粗面岩组合,属B类的过渡型拉斑玄武岩浆系列,具以太华群为岩浆房的壳幔混染型成因;秦岭群和宽坪群为变拉斑玄武岩建造,属A类拉斑玄武岩浆系列,具幔源型成因;二郎坪群和丹凤群属细碧岩-石英角斑岩建造,C类石英角斑岩浆系列与A类拉斑玄武岩浆系列共存,具壳幔双层混合型成因。  相似文献   

安徽铜陵狮子山矿田岩浆岩锆石SHRIMP定年及其成因意义   总被引：36，自引：4，他引：32  

徐晓春  陆三明  谢巧勤  柏林  储国正 《地质学报》2008,82(4):500-509

铜陵狮子山矿田发育大量岩浆岩,且与矿田中的铜金多金属成矿关系密切。锆石SHRIMP同位素精确定年表明,矿田中的岩浆侵位年龄在132.4～142.9Ma之间,即晚侏罗世—早白垩世,属燕山早期晚阶段。矿田岩浆岩体是在同期岩浆活动中多次侵位形成的,岩浆侵入活动可以划分为分别起始于140Ma前后和约136Ma的早晚两次。从岩浆上升侵位到冷却结晶的时间间隔均较短,但其中白芒山辉石二长闪长岩冷却史相对较长,且经历了早期深部岩浆房中的分离结晶作用和后期构造脉动、岩浆上升侵位、减压受热、早期晶体再熔蚀及冷却结晶的过程。结合主量元素和微量元素地球化学研究认为,狮子山矿田岩浆演化的后期,即起源于上地幔或下地壳的原生岩浆在同化了壳源物质并聚集到岩浆房中以后,在滞留的过程中发生了一定程度的分离结晶作用,但尚未固结,成分上显示了一定的带状分布,在区域构造应力松弛及构造事件诱发下,随机地沿发育的构造裂隙先后上升侵位,冷凝结晶。  相似文献   

He–Ar and Nd–Sr isotopic compositions of late Pleistocene felsic plutonic back arc basin rocks from Ulleungdo volcanic island, South Korea: Implications for the genesis of young plutonic rocks in a back arc basin     

Kyu Han Kim  Keisuke Nagao  Hirochika Sumino  Tsuyoshi Tanaka  Takamasa Hayashi  Toshio Nakamura  Jong Ik Lee 《Chemical Geology》2008,253(3-4):180-195

We report analyses of noble gases and Nd–Sr isotopes in mineral separates and whole rocks of late Pleistocene (< 0.2 Ma) monzonites from Ulleungdo, South Korea, a volcanic island within the back arc basin of the Japan island arc. A Rb–Sr mineral isochron age for the monzonites is 0.12 ± 0.01 Ma. K–Ar biotite ages from the same samples gave relatively concordant ages of 0.19 ± 0.01and 0.22 ± 0.01 Ma. ⁴⁰Ar/³⁹Ar yields a similar age of 0.29 ± 0.09 Ma. Geochemical characteristics of the felsic plutonic rocks, which are silica oversaturated alkali felsic rocks (av., 12.5 wt% in K₂O + Na₂O), are similar to those of 30 alkali volcanics from Ulleungdo in terms of concentrations of major, trace and REE elements. The initial Nd–Sr isotopic ratios of the monzonites (⁸⁷Sr/⁸⁶Sr = 0.70454–0.71264, ¹⁴³Nd/¹⁴⁴Nd = 0.512528–0.512577) are comparable with those of the alkali volcanics (⁸⁷Sr/⁸⁶Sr = 0.70466–0.70892, ¹⁴³Nd/¹⁴⁴Nd = 0.512521–0.512615) erupted in Stage 3 of Ulleungdo volcanism (0.24–0.47 Ma). The high initial ⁸⁷Sr/⁸⁶Sr values of the monzonites imply that seawater and crustally contaminated pre-existing trachytes may have been melted or assimilated during differentiation of the alkali basaltic magma.A mantle helium component (³He/⁴He ratio of up to 6.5 RA) associated with excess argon was found in the monzonites. Feldspar and biotite have preferentially lost helium during slow cooling at depth and/or during their transportation to the surface in a hot host magma. The source magma noble gas isotopic features are well preserved in fluid inclusions in hornblende, and indicate that the magma may be directly derived from subcontinental lithospheric mantle metasomatized by an ancient subduction process, or may have formed as a mixture of MORB-like mantle and crustal components. The radiometric ages, geochemical and Nd–Sr isotopic signatures of the Ulleungdo monzonites as well as the presence of mantle-derived helium and argon, suggests that these felsic plutonic rocks evolved from alkali basaltic magma that formed by partial melting of subcontinental lithospheric mantle beneath the back arc basin located along the active continental margin of the southeastern part of the Eurasian plate.  相似文献   

Environmental contamination of Zn,Cd, Ni,Cu, and Pb from industrial areas in Hamadan Province,western Iran     

M. Jalali  Z. V. Khanlari 《Environmental Geology》2008,55(7):1537-1543

Eleven surface soil samples from calcareous soils of industrial areas in Hamadan Province, western Iran were analyzed for total concentrations of Zn, Cd, Ni, Cu and Pb and were sequentially extracted into six fractions to determine the bioavailability of various heavy metal forms. Total Zn, Cd, Ni, Cu and Pb concentrations of the contaminated soils were 658 (57–5,803), 125.8 (1.18–1,361), 45.6 (30.7–64.4), 29.7 (11.7–83.5) and 2,419 (66–24,850) mg kg⁻¹, respectively. The soils were polluted with Zn, Pb, and Cu to some extent and heavily polluted with Cd. Nickel values were not above regulatory limits. Copper existed in soil mainly in residual (RES) and organic (OM) fractions (about 42 and 33%, respectively), whereas Zn occurred essentially as RES fraction (about 69%). The considerable presence of Cd (30.8%) and Pb (39%) in the CARB fraction suggests these elements have high potential biavailability and leachability in soils from contaminated soils. The mobile and bioavailable (EXCH and CARB) fractions of Zn, Cd, Ni, Cu, and Pb in contaminated soils averaged (7.3, 40.4, 16, 12.9 and 40.8%), respectively, which suggests that the mobility and bioavailability of the five metals probably decline in the following order: Cd = Pb > Ni > Cu > Zn.  相似文献   

Regional distribution pattern of groundwater heavy metals resulting from agricultural activities   总被引：18，自引：0，他引：18  

J. Nouri  A. H. Mahvi  G. R. Jahed  A. A. Babaei 《Environmental Geology》2008,55(6):1337-1343

Contaminations of groundwater by heavy metals due to agricultural activities are growing recently. The objective of this study was to evaluate and map regional patterns of heavy metals (Cd, Zn and Cu) in groundwater on a plain with high agricultural activities. The study was conducted to investigate the concentration of heavy metals and distribution in groundwater in regions of Shush Danial and Andimeshk aquifers in the southern part of Iran. Presently, groundwater is the only appropriate and widely used source of drinking water for rural and urban communities in this region. The region covers an area of 1,100 km² between the Dez and Karkhe rivers, which lead to the Persian Gulf. For this study, the region was divided into four sub-regions A, B, C and D. Additionally, 168 groundwater samples were collected from 42 water wells during the earlier months of 2004. The flame atomic absorption spectrometry (AAS-Flame) was used to measure the concentration of heavy metals in water samples and the Surfer software was used for determination of the contour map of metal distribution. The results demonstrated that in all of the samples, Cd and Zn concentrations were below the EPA MCLG and EPA secondary standard, respectively. However, the Cu contents of 4.8 % of all samples were higher than EPA MCL. It is also indicated that the concentrations of metals were more pronounced at the southern part of the studied region than at the others. The analysis of fertilizers applied for agricultural activities at this region also indicated that a great majority of the above-mentioned heavy metals were discharged into the environment. Absence of confining layers, proximity to land surface, excess agricultural activities in the southern part and groundwater flow direction that is generally from the north to the southern parts in this area make the southern region of the Shush plain especially vulnerable to pollution by heavy metals than by other contaminants.  相似文献   

Magma Ascent and Crustal Accretion at Ultraslow-Spreading Ridges: Constraints from Plagioclase Ultraphyric Basalts from the Arctic Mid-Ocean Ridge   总被引：2，自引：0，他引：2  

Hellevang  Bjarte; Pedersen  Rolf B. 《Journal of Petrology》2008,49(2):267-294

Plagioclase ultraphyric basalts (PUBs) with up to 54% plagioclasephenocrysts were dredged in the rift valley and adjacent flanksof the ultraslow-spreading Mohns and Knipovich ridges. The PUBsshow large variations in crystal morphologies and zoning. Thelarge variations suggest that single basalt samples containa mixture of plagioclase crystals that aggregated at differentlevels in the magma conduits. Resorbed crystals and repeatedreverse zones suggest that the magma reservoirs were replenishedand heated several times. Thin concentric zones with melt inclusions,and sharp reductions in the anorthite content of 3–7%,are common between the reverse zones. These zones, and skeletalcrystals with distinctly lower anorthite contents than massivecrystals, are interpreted to be the result of rapid crystalliztionduring strong undercooling. The changes between short periodsof cooling and longer periods with reheating are explained bymultiple advances of crystal-rich magma into cool regions followedby longer periods of gradual magma inflow and temperature increase.The porphyritic basalts are characterizd by more depleted andmore fractionated compositions than the aphyric basalts, withlower (La/Sm)_N, K₂O and Mg-numbers. This relationship, and theobservation that PUBs are sampled only close to segment centresalong these ridges, suggests that the PUBs formed by higherdegrees of melting and evolved in more long-lived magma reservoirs.We propose that the zoning patterns of plagioclase crystalsand crystal morphologies of these PUBs reflect the developmentand flow of magma through a stacked sill complex-like conduitsystem, whereas the aphyric equivalents represent later flowof magma through the conduit. The formation of voluminous higher-degreemelts may trigger the development of the magma conduits andexplain the generally depleted compositions of PUB magmas. KEY WORDS: basalt; mineral chemistry; MORB; magma mixing; magma chamber; major element  相似文献   

Pressures of Crystallization of Icelandic Magmas   总被引：1，自引：0，他引：1  

Kelley  Daniel F.; Barton  Michael 《Journal of Petrology》2008,49(3):465-492

Iceland lies astride the Mid-Atlantic Ridge and was createdby seafloor spreading that began about 55 Ma. The crust is anomalouslythick (20–40 km), indicating higher melt productivityin the underlying mantle compared with normal ridge segmentsas a result of the presence of a mantle plume or upwelling centeredbeneath the northwestern edge of the Vatnajökull ice sheet.Seismic and volcanic activity is concentrated in 50 km wideneovolcanic or rift zones, which mark the subaerial Mid-AtlanticRidge, and in three flank zones. Geodetic and geophysical studiesprovide evidence for magma chambers located over a range ofdepths (1·5–21 km) in the crust, with shallow magmachambers beneath some volcanic centers (Katla, Grimsvötn,Eyjafjallajökull), and both shallow and deep chambers beneathothers (e.g. Krafla and Askja). We have compiled analyses ofbasalt glass with geochemical characteristics indicating crystallizationof ol–plag–cpx from 28 volcanic centers in the Western,Northern and Eastern rift zones as well as from the SouthernFlank Zone. Pressures of crystallization were calculated forthese glasses, and confirm that Icelandic magmas crystallizeover a wide range of pressures (0·001 to 1 GPa), equivalentto depths of 0–35 km. This range partly reflects crystallizationof melts en route to the surface, probably in dikes and conduits,after they leave intracrustal chambers. We find no evidencefor a shallow chamber beneath Katla, which probably indicatesthat the shallow chamber identified in other studies containssilica-rich magma rather than basalt. There is reasonably goodcorrelation between the depths of deep chambers (> 17 km)and geophysical estimates of Moho depth, indicating that magmaponds at the crust–mantle boundary. Shallow chambers (<7·1 km) are located in the upper crust, and probablyform at a level of neutral buoyancy. There are also discretechambers at intermediate depths (11 km beneath the rift zones),and there is strong evidence for cooling and crystallizing magmabodies or pockets throughout the middle and lower crust thatmight resemble a crystal mush. The results suggest that themiddle and lower crust is relatively hot and porous. It is suggestedthat crustal accretion occurs over a range of depths similarto those in recent models for accretionary processes at mid-oceanridges. The presence of multiple stacked chambers and hot, porouscrust suggests that magma evolution is complex and involvespolybaric crystallization, magma mixing, and assimilation. KEY WORDS: Iceland rift zones; cotectic crystallization; pressure; depth; magma chamber; volcanic glass  相似文献   

Global Correlations of Ocean Ridge Basalt Chemistry with Axial Depth: a New Perspective   总被引：4，自引：0，他引：4  

Niu  Yaoling; O'Hara  Michael J. 《Journal of Petrology》2008,49(4):633-664

The petrological parameters Na₈ and Fe₈, which are Na₂O andFeO contents in mid-ocean ridge basalt (MORB) melts correctedfor fractionation effects to MgO = 8 wt%, have been widely usedas indicators of the extent and pressure of mantle melting beneathocean ridges. We find that these parameters are unreliable.Fe₈ is used to compute the mantle solidus depth (P_o) and temperature(T_o), and it is the values and range of Fe₈ that have led tothe notion that mantle potential temperature variation of T_P= 250 K is required to explain the global ocean ridge systematics.This interpreted T_P = 250 K range applies to ocean ridges awayfrom ‘hotspots’. We find no convincing evidencethat calculated values for P_o, T_o, and T_P using Fe₈ have anysignificance. We correct for fractionation effect to Mg^# = 0·72,which reveals mostly signals of mantle processes because meltswith Mg^# = 0·72 are in equilibrium with mantle olivineof Fo_89·6 (vs evolved olivine of Fo_{88·1–79·6}in equilibrium with melts of Fe₈). To reveal first-order MORBchemical systematics as a function of ridge axial depth, weaverage out possible effects of spreading rate variation, local-scalemantle source heterogeneity, melting region geometry variation,and dynamic topography on regional and segment scales by usingactual sample depths, regardless of geographical location, withineach of 22 ridge depth intervals of 250 m on a global scale.These depth-interval averages give Fe₇₂ = 7·5–8·5,which would give T_P = 41 K (vs 250 K based on Fe₈) beneathglobal ocean ridges. The lack of Fe₇₂–Si₇₂ and Si₇₂–ridgedepth correlations provides no evidence that MORB melts preservepressure signatures as a function of ridge axial depth. We thusfind no convincing evidence for T_P > 50 K beneath globalocean ridges. The averages have also revealed significantcorrelations of MORB chemistry (e.g. Ti₇₂, Al₇₂, Fe₇₂,Mg₇₂, Ca₇₂, Na₇₂ and Ca₇₂/Al₇₂) with ridge axial depth. Thechemistry–depth correlation points to an intrinsic linkbetween the two. That is, the 5 km global ridge axial reliefand MORB chemistry both result from a common cause: subsolidusmantle compositional variation (vs T_P), which determines themineralogy, lithology and density variations that (1) isostaticallycompensate the 5 km ocean ridge relief and (2) determine thefirst-order MORB compositional variation on a global scale.A progressively more enriched (or less depleted) fertileperidotite source (i.e. high Al₂O₃ and Na₂O, and low CaO/Al₂O₃)beneath deep ridges ensures a greater amount of modal garnet(high Al₂O₃) and higher jadeite/diopside ratios in clinopyroxene(high Na₂O and Al₂O₃, and lower CaO), making a denser mantle,and thus deeper ridges. The dense fertile mantle beneath deepridges retards the rate and restricts the amplitude of the upwelling,reduces the rate and extent of decompression melting, givesway to conductive cooling to a deep level, forces melting tostop at such a deep level, leads to a short melting column,and thus produces less melt and probably a thin magmatic crustrelative to the less dense (more refractory) fertile mantlebeneath shallow ridges. Compositions of primitive MORB meltsresult from the combination of two different, but geneticallyrelated processes: (1) mantle source inheritance and (2) meltingprocess enhancement. The subsolidus mantle compositional variationneeded to explain MORB chemistry and ridge axial depth variationrequires a deep isostatic compensation depth, probably in thetransition zone. Therefore, although ocean ridges are of shalloworigin, their working is largely controlled by deep processesas well as the effect of plate spreading rate variation at shallowlevels. KEY WORDS: mid-ocean ridges; mantle melting; magma differentiation; petrogenesis; MORB chemistry variation; ridge depth variation; global correlations; mantle compositional variation; mantle source density variation; mantle potential temperature variation; isostatic compensation  相似文献