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1.
The majority of coalbed methane(CBM) in coal reservoirs is in adsorption states in coal matrix pores. To reveal the adsorption behavior of bituminous coal under high-temperature and high-pressure conditions and to discuss the microscopic control mechanism affecting the adsorption characteristics, isothermal adsorption experiments under hightemperature and high-pressure conditions, low-temperature liquid nitrogen adsorption-desorption experiments and CO2 adsorption experiments were performed on coal samples. Results show that the adsorption capacity of coal is comprehensively controlled by the maximum vitrinite reflectance(Ro, max), as well as temperature and pressure conditions. As the vitrinite reflectance increases, the adsorption capacity of coal increases. At low pressures, the pressure has a significant effect on the positive effect of adsorption, but the effect of temperature is relatively weak. As the pressure increases, the effect of temperature on the negative effect of adsorption gradually becomes apparent, and the influence of pressure gradually decreases. Considering pore volumes of pores with diameters of 1.7-100 nm, the peak volume of pores with diameters 10-100 nm is higher than that from pores with diameters 1.7-10 nm, especially for pores with diameters of 40-60 nm, indicating that pores with diameters of 10-100 nm are the main contributors to the pore volume. The pore specific surface area shows multiple peaks, and the peak value appears for pore diameters of 2-3 nm, indicating that this pore diameter is the main contributor to the specific surface area. For pore diameters of 0.489-1.083 nm, the pore size distribution is bimodal, with peak values at 0.56-0.62 nm and 0.82-0.88 nm. The adsorption capability of the coal reservoir depends on the development degree of the supermicroporous specific surface area, because the supermicroporous pores are the main contributors to the specific pore area. Additionally, the adsorption space increases as the adsorption equilibrium pressure increases. Under the same pressure, as the maximum vitrinite reflectance increases, the adsorption space increases. In addition, the cumulative reduction in the surface free energy increases as the maximum vitrinite reflectance increases. Furthermore, as the pressure increases, the surface free energy of each pressure point gradually decreases, indicating that as the pressure increases, it is increasingly difficult to adsorb methane molecules. 相似文献
2.
南海神狐海域沉积物自生黄铁矿和石膏S同位素特征及对甲烷渗漏强度的示踪 总被引：1，自引：1，他引：0
The northern slope of the South China Sea is a gas-hydrate-bearing region related to a high deposition rate of organic-rich sediments co-occurring with intense methanogenesis in subseafloor environments.Anaerobic oxidation of methane(AOM) coupled with bacterial sulfate reduction results in the precipitation of solid phase minerals in seepage sediment,including pyrite and gypsum.Abundant aggregates of pyrites and gypsums are observed between the depth of 667 and 850 cm below the seafloor(cmbsf) in the entire core sediment of HS328 from the northern South China Sea.Most pyrites are tubes consisting of framboidal cores and outer crusts.Gypsum aggregates occur as rosettes and spheroids consisting of plates.Some of them grow over pyrite,indicating that gypsum precipitation postdates pyrite formation.The sulfur isotopic values(δ~(34) S) of pyrite vary greatly(from –46.6‰ to –12.3‰ V-CDT) and increase with depth.Thus,the pyrite in the shallow sediments resulted from organoclastic sulfate reduction(OSR) and is influenced by AOM with depth.The relative high abundance and δ~(34) S values of pyrite in sediments at depths from 580 to 810 cmbsf indicate that this interval is the location of a paleo-sulfate methane transition zone(SMTZ).The sulfur isotopic composition of gypsum(from–25‰ to –20.7‰) is much lower than that of the seawater sulfate,indicating the existence of a 34 S-depletion source of sulfur species that most likely are products of the oxidation of pyrites formed in OSR.Pyrite oxidation is controlled by ambient electron acceptors such as MnO_2,iron(Ⅲ) and oxygen driven by the SMTZ location shift to great depths.The δ~(34) S values of gypsum at greater depth are lower than those of the associated pyrite,revealing downward diffusion of 34 S-depleted sulfate from the mixture of oxidation of pyrite derived by OSR and the seawater sulfate.These sulfates also lead to an increase of calcium ions from the dissolution of calcium carbonate mineral,which will be favor to the formation of gypsum.Overall,the mineralogy and sulfur isotopic composition of the pyrite and gypsum suggest variable redox conditions caused by reduced seepage intensities,and the pyrite and gypsum can be a recorder of the intensity evolution of methane seepage. 相似文献
3.
综述了天然气水合物赋存区甲烷渗漏活动的地球化学响应指标的研究进展,分析了应用单一指标识别甲烷渗漏活动各自所存在的问题,包括浅表层沉积物孔隙水中CH_4、SO_4~(2–)、Cl~–等离子浓度随深度的变化;浅层沉积物全岩W_(TOC)(W表示质量分数,TOC表示总有机碳)和W_(TS)(TS表示总硫)之间的相关性及比值;自生碳酸盐岩δ~(13)C和δ~(18)O;自生矿物重晶石、黄铁矿、自生石膏的δ~(34)S;有孔虫壳体和生物标志化合物的δ~(13)C等。结果表明孔隙水中的CH_4、SO4_~(2–)浓度及溶解无机碳的碳同位素组成可以用来识别目前正在发生的甲烷渗漏活动;而沉积物中的WTS、自生矿物的δ~(34)S、钡含量及其异常峰值和生物标志化合物的δ~(13)C等指标的联合使用可以更真实准确地反映地质历史时期天然气水合物赋存区的甲烷渗漏活动。因此,在实际研究过程中,可将孔隙水和沉积物两种介质的多种指标相结合。随着非传统稳定同位素(Fe、Ca、Mg等)和沉积物氧化还原敏感元素(Mo、V、U等)等研究的发展,甲烷渗漏活动地球化学响应指标的研究也将得到拓展,而多种地球化学指标的联合使用将为天然气水合物勘探及其形成分解过程识别研究提供重要的科学依据。 相似文献
4.
现有常规油气井产出剖面测试方法在煤层气井中适应性较差，测试范围和测量工艺等存在局限性，施工成功率低。因此，本文对煤层气井产出剖面测试技术进行了整体的系统化设计和研发。通过紧凑的结构设计、高度集成，研发了一套可同时进行温度、压力、磁性定位、热式流量、探针持气率、微波持气、涡轮流量和超声流量等多参数测量的煤层气井测井仪，并研制了一套一次下井可进行多种测试技术测量的煤层气井产出剖面测试技术。同时提高了测试仪器的精度和抗干扰能力，开发了多任务多窗口的便携地面系统操作，并研制新型偏心测试井口应用于煤层气井，实现修井作业时不间断连续测试。该技术在鄂尔多斯盆地石楼北区块3口煤层气井进行了现场试验，取得精确、连续的测试数据。测试结果显示，石楼北区块8#+9#煤层为主力产气、产水层。 相似文献
5.
平端深海偏顶蛤(Gigantidasplatifrons)是南海台西南冷泉区的典型优势物种,鳃丝上皮细胞内共生大量甲烷氧化菌,通过甲烷有氧氧化合成有机物为共生体系提供物质能量,是平端深海偏顶蛤赖以生存的重要能量来源器官,溶酶体在共生体系的营养互作和稳态维持中可能发挥重要作用,本研究使用电镜技术观测了常压培养过程中(0d,30d,90d)平端深海偏顶蛤共生体系中共生菌和溶酶体的动态变化,通过鳃上皮含菌细胞超显微结构的变化研究常压培养对深海共生体系的影响,并探讨溶酶体在宿主—共生菌营养传递和共生菌群稳态维持中的关键作用。研究发现,在原位状态样品中(0d)共生菌和溶酶体呈极化分布,细胞结构完整清晰;蓄养30d后,含菌细胞出现明显破碎,共生菌数量大幅降低,溶酶体数量、范围和消化程度大幅增加,对细胞顶端的甲烷氧化菌进行分解;而90d后,共生菌在溶酶体的作用下消失殆尽,鳃部有明显细胞脱落后留下的坑洞,细胞呈现空泡状,无法明确区分各种细胞组分。上述结果展示了长期常压蓄养过程中鳃上皮含菌细胞中溶酶体与甲烷氧化菌的动态变化,推测当共生菌丢失后溶酶体也同步降低活跃度,平端深海偏顶蛤在共生互作中通过溶酶体主导消化和调控共生菌。 相似文献
6.
The amount of methane leaked from deep sea cold seeps is enormous and potentially affects the global warming,ocean acidification and global carbon cycle. It is of great significance to study the methane bubble movement and dissolution process in the water column and its output to the atmosphere. Methane bubbles produce strong acoustic impedance in water bodies, and bubble strings released from deep sea cold seeps are called "gas flares"which expressed as flame-like strong backscatter in the water column. We characterized the morphology and movement of methane bubbles released into the water using multibeam water column data at two cold seeps. The result shows that methane at site I reached 920 m water depth without passing through the top of the gas hydrate stability zone(GHSZ, 850 m), while methane bubbles at site II passed through the top of the GHSZ(597 m) and entered the non-GHSZ(above 550 m). By applying two methods on the multibeam data, the bubble rising velocity in the water column at sites I and II were estimated to be 9.6 cm/s and 24 cm/s, respectively. Bubble velocity is positively associated with water depth which is inferred to be resulted from decrease of bubble size during methane ascending in the water. Combined with numerical simulation, we concluded that formation of gas hydrate shells plays an important role in helping methane bubbles entering the upper water bodies, while other factors, including water depth, bubble velocity, initial kinetic energy and bubble size, also influence the bubble residence time in the water and the possibility of methane entering the atmosphere. We estimate that methane gas flux at these two sites is 0.4×10~6–87.6×10~6 mol/a which is extremely small compared to the total amount of methane in the ocean body, however, methane leakage might exert significant impact on the ocean acidification considering the widespread distributed cold seeps. In addition, although methane entering the atmosphere is not observed, further research is still needed to understand its potential impact on increasing methane concentration in the surface seawater and gas-water interface methane exchange rate, which consequently increase the greenhouse effect. 相似文献
7.
超临界甲烷密度不仅是非常规天然气资源量计算与吸附能力测定的重要参数,同时也是衡量超临界甲烷扩散效率与溶解有机物能力的主要指标。通过对比分析各种气体状态方程的适用性,认为基于亥姆霍兹能量基本状态方程可以准确计算0~30 MPa、270~360 K条件下甲烷的密度。利用Microsoft Office Excel编写了甲烷密度的计算程序,与NIST （美国国家标准与技术研究院）商业软件计算结果相比,误差小于0.05%。分析了0~100 MPa、270~360 K范围内甲烷密度的变化规律。结果表明,甲烷密度随压力增大而增大,在低于30 MPa时增速较大且对温度的敏感性较强,高于30 MPa时增速逐渐变缓,且敏感性减弱。在煤层原位条件下随着埋深的增大,甲烷密度随温度升高而减小,随压力增大而增大;在温度与压力共同作用下,甲烷密度呈先增速不变、近似线性增加,后增速逐渐减小、凸曲线形增加的变化规律。游离态甲烷密度受温度的影响比吸附态甲烷小,是深部煤层气资源增量的主要贡献者。研究结果为深部煤层气赋存及其潜力预测提供了基础参数。 相似文献
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