河北省怀安县朱家洼矿区地球化学特征与找矿方向     

王占彬 《地质与勘探》2020,56(1):102-112

河北怀安朱家洼矿区位于华北板块北缘中段太古宙、元古宙、中生代金银铅锌铁硫铁矿成矿带,为火山热液型金多金属矿。为查明该区成矿规律,明确找矿方向,在区内开展了水系沉积物测量、土壤地球化学测量等工作。通过对元素分布、元素相关性、元素异常等特征研究表明,Au、Mo为本区主成矿元素;各元素异常平面分布具有分带性,高温元素W、Sn、Bi异常位于骆驼山火山机构中心,中低温元素Pb、Zn、As、Ag等异常分布于火山机构边部及周边围岩中,成矿元素Au、Mo异常主要位于火山机构西侧围岩中。异常查证发现金钼矿化体2条,金钼矿化受火山机构和北西向构造带控制。依据成矿地质条件、地球化学异常及查证成果认为,朱家洼矿区Au、Mo成矿潜力大,火山机构西侧围岩区是该区重点找矿地段。  相似文献   

基于波形特征的露天钼矿微震事件的识别分析——以卓资山钼矿为例     

赵艳红  包金哲  王树波  翟浩  魏建民  杨智升  张晖  赵铁锁  苏日亚  王磊  王鑫  贾昕晔  刘芳 《震灾防御技术》2019,14(3):662-676

基于前人研究成果以及现场的实测结果，采用卓资山露天钼矿微震监测项目产出资料，提取了5类微震事件的波形特征和时频特征。波形特征显示:微地震的振幅、辐射均匀性和频率变化特征表明微地震是由于岩层受到单力偶和剪切力作用破裂而产生；爆破具有P波初动方向向上、S波不易识别的特点，包含“初震段、主震段、尾波段”三段变化形态；小型边坡滑坡波事件属楔体滑坡，是由多个“加速—缓冲—终止”构成，波形是由包络线呈“V”字形的多组脉冲波列组成；机械开采震动事件具有自振能量不变、脉冲幅度相差很大、持续时间间隔不确定的特点；运输车辆波形振幅具有形态“弱—强—弱”、等频率、包络线呈多段纺锤形的特征。时频空间分布可以分为相对独立、界限分明的两类:一类包含微地震、爆破、机械开采、小型边坡滑坡事件，另一类只包含车辆运输事件。  相似文献   

Groundwater contaminant source identification based on iterative local update ensemble smoother          下载免费PDF全文

YANG Ai-lin  JIANG Si-min  LIU Jin-bing  JIANG Qian-yun  ZHOU Ting  ZHANG Wen 《地下水科学与工程》2020,8(1):1-9

Identification of the location and intensity of groundwater pollution source contributes to the effect of pollution remediation, and is called groundwater contaminant source identifcation. This is a kind of typical groundwater inverse problem, and the solution is usually ill-posed. Especially considering the spatial variability of hydraulic conductivity field, the identification process is more challenging. In this paper, the solution framework of groundwater contaminant source identification is composed with groundwater pollutant transport model (MT3DMS) and a data assimilation method (Iterative local update ensemble smoother, ILUES). In addition, Karhunen-Loève expansion technique is adopted as a PCA method to realize dimension reduction. In practical problems, the geostatistical method is usually used to characterize the hydraulic conductivity feld, and only the contaminant source information is inversely calculated in the identifcation process. In this study, the identification of contaminant source information under Kriging K-field is compared with simultaneous identification of source information and K-field. The results indicate that it is necessary to carry out simultaneous identification under heterogeneous site, and ILUES has good performance in solving high-dimensional parameter inversion problems.  相似文献   

岩溶水硝酸盐污染原位修复试验     

叶进霞  夏春英  卜鸿志 《中国岩溶》2020,39(2):173-179

岩溶含水层的极不均一性特征使岩溶水溶质运移受构造、裂隙空间及其发育方向控制；因环境条件复杂，开展岩溶水污染原位修复技术难度较大，截止目前，国内尚未系统地开展岩溶含水层水污染原位修复研究工作。文章选择鲁中南山区典型岩溶发育及硝酸盐污染地段，施工组合钻孔建设修复试验工程，采用“乙醇+葡萄糖”液态碳源和“聚乙烯醇+淀粉颗粒”固态反应器分别进行岩溶水硝酸盐污染原位修复试验。结果表明:浓度500 mg?L－1、1 000 mg?L－1的“乙醇+葡萄糖”反硝化溶液对硝酸盐浓度的降解率分别为6.45 %和21.52 %；单位长度组成材料“聚乙烯醇3 kg+淀粉颗粒3 kg”、“聚乙烯醇2 kg+淀粉颗粒4 kg”的两种反硝化固态反应器对硝酸盐浓度的降解率分为33.91%和34.96%。试验证明在裂隙型岩溶地区采用孔组方案进行地下水污染原位修复技术可行、且能取得较显著效果。修复工程布设方式和试验成果对类似地区开展岩溶地下水污染原位修复具一定借鉴意义。   相似文献   

Spatial and Temporal Distribution of Dust‐Bound Trace Metal Elements around Kuhdasht Watershed Area in Iran     

Hamid Alipour  Ahmad Jalalian  Naser Honarjoo  Norair Tommanian  Fereidoon Sarmadian 《洁净——土壤、空气、水》2019,47(10)

Dust, as a source of trace metal elements, affects the health of society. The spatial and temporal concentrations of dust‐bound trace metals (Cd, Pb, Ni, Zn, Cu, and Mn) in Kuhdasht watershed (456 km²), Lorestan Province, Iran, is investigated. Dust is collected using glass traps placed in ten research stations in the region. The spatial and temporal distribution of dust trace metals are plotted using ARC‐GIS. The highest and the lowest concentrations of Zn (9751150 mg kg^?1), Pb (46.352.9 mg kg^?1), and Cd (2.443.30 mg kg^?1) are obtained in winter, of Ni (98110 mg kg^?1) and Cu in autumn (16.053.5 mg kg^?1), and of Mn in summer (385505 mg kg^?1). The spatial concentrations of dust‐bound trace metals indicate all, except Cu, show a decreasing trend from the mountains toward the plains, similar to that of soil and of dust, except for Zn, which shows higher concentrations in dust than in soil. The potential sources of dust‐bound trace metals and their rate of contamination are also investigated using the enrichment and contamination factors. The major sources of Cd and Zn in the dust of watershed are due to anthropogenic activities or from activities outside the borders.  相似文献   

内蒙古碾子沟钼矿床成矿流体来源、演化及成矿机理     

孙丰月  王睿  王一存  李顺达  王可勇  石开拓  孙清飞  王文元 《吉林大学学报(地球科学版)》2020,50(3):768-780

内蒙古自治区碾子沟钼矿床地处华北地台北缘西拉木伦钼成矿带西段，为一典型的中型石英脉型钼矿床。该钼矿床矿脉（体）主要产于燕山早期二长花岗岩-钾长花岗岩内NNW、NW向断裂构造体系之中，成矿作用过程经历了黄铁矿±辉钼矿＋石英（Ⅰ）、辉钼矿＋黄铁矿±黄铜矿＋石英（Ⅱ）、黄铜矿＋黄铁矿±闪锌矿＋石英（Ⅲ）及石英±方解石（Ⅳ）4个阶段。系统的流体包裹体岩相学、包裹体组分析、包裹体显微测温研究表明，矿床初始成矿流体为高温、中低盐度（490~550℃，盐度（w（NaC1））2%~10%，50~62 MPa）均匀的NaCl-H₂O体系热液，δ¹⁸O_H2O-SMOW（2.21‰）及δD_H2O-SMOW（-68.9‰）表明其主要来源于岩浆热液；成矿流体上升并不断汇聚于容矿断裂空间，伴随温度、压力降低（380~460℃，26~40 MPa→360~420℃，25~30 MPa）而进入两相不混溶区，流体开始发生沸腾→强烈沸腾作用，导致成矿元素Mo大量沉淀富集成矿，成矿晚期残余流体与大气降水混合（δ¹⁸O_H2O-SMOW为-2.41‰~2.51‰，δD_H2O-SMOW为-110.1‰~-105.5‰），矿床属燕山早期中高温岩浆热液型钼矿床。  相似文献   

Investigation of gas content of organic-rich shale:A case study from Lower Permian shale in southern North China Basin,central China     

Wei Dang  Jin-Chuan Zhang  Xuan Tang  Xiao-Liang Wei  Zhong-Ming Li  Cheng-Hu Wang  Qian Chen  Chong Liu 《地学前缘(英文版)》2018,9(2):559-575

Measuring gas content is an essential step in estimating the commerciality of gas reserves. In this study,eight shale core samples from the Mouye-1 well were measured using a homemade patented gas desorption apparatus to determine their gas contents. Due to the air contamination that is introduced into the desorption canister, a mathematical method was devised to correct the gas quantity and quality.Compared to the chemical compositions of desorbed gas, the chemical compositions of residual gas are somewhat different. In residual gas, carbon dioxide and nitrogen record a slight increase, and propane is first observed. This phenomenon may be related to the exposure time during the transportation of shale samples from the drilling site to the laboratory, as well as the differences in the mass, size and adsorptivity of different gas molecules. In addition to a series of conventional methods, including the USBM direct method and the Amoco Curve Fit(ACF) method, which were used here for lost gas content estimation, a Modified Curve Fit(MCF) method, based on the 'bidisperse' diffusion model, was established to estimate lost gas content. By fitting the ACF and MCF models to gas desorption data, we determined that the MCF method could reasonably describe the gas desorption data over the entire time period, whereas the ACF method failed. The failure of the ACF method to describe the gas desorption process may be related to its restrictive assumption of a single pore size within shale samples. In comparison to the indirect method, this study demonstrates that none of the three methods studied in this investigation(USBM, ACF and MCF) could individually estimate the lost gas contents of all shale samples and that the proportion of free gas relative to total gas has a significant effect on the estimation accuracy of the selected method. When the ratio of free gas to total gas is lower than 45%, the USBM method is the best for estimating the lost gas content, whereas when the ratio ranges from 45% to 75% or is more than 75%, the ACF and MCF methods, are the best options respectively.  相似文献   

黑龙江铁力鹿鸣斑岩型钼矿床埃达克岩的发现及其地质意义     

郗爱华  葛玉辉  刘珏  徐博文  李碧乐  朱玉娣 《岩石学报》2018,34(3):719-732

鹿鸣钼矿是伊春-延寿成矿带内近年发现的大型斑岩钼矿,矿区主要出露含矿的二长花岗岩、花岗斑岩,不含矿的花岗闪长岩及似斑状花岗闪长岩四种岩性。二长花岗岩与花岗斑岩具有相似的低Sr高Y等地球化学特征,形成于194.8±0.7Ma~184Ma前后的早侏罗世,是斑岩型矿床的赋矿围岩。花岗闪长岩及似斑状花岗闪长岩含有暗色岩包体,主要为高钾钙碱性系列岩石,但以高Sr、低Y及富Na为特征,部分地球化学指标与中国东部埃达克岩极为相似,形成于176.2±2.1Ma并与辉钼矿Re-Os法获得的成矿年龄一致,被认定为斑岩型矿床的成矿母岩。高Sr和低Sr两类花岗岩形成于不同的构造背景,与中生代时期中国东部及其邻区几次重大地质事件密切相关。鹿鸣斑岩型钼矿床与中侏罗世太平洋板块俯冲在高氧逸度条件下熔融形成的埃达克质岩浆高侵位有关。鹿鸣矿区埃达克岩的发现表明中侏罗世太平洋板块已经发生了萎缩与消减,与之相关的岩浆作用及成矿应该具有广泛的区域性,扎实的岩石学工作可为区域更多斑岩型矿床的发现提供线索。  相似文献   

内蒙古曹四夭钼矿区花岗斑岩地球化学特征及地质意义          下载免费PDF全文

邱慧远  崔邢涛  邱铁栋  栾文楼 《地质找矿论丛》2018,33(2):221-234

曹四夭钼矿床位于华北克拉通北缘凉城断隆东侧,其矿化与多期次侵位的花岗质杂岩体具有密切的时间和空间联系。杂岩体的岩石类型包括:少斑状花岗斑岩、多斑状花岗斑岩、中细粒花岗岩、二长花岗斑岩和正长花岗斑岩等;前人的锆石U-Pb法测年数据表明,矿区岩浆活动可以分为155 Ma、149~140 Ma、134~131 Ma三个期次。本次研究获得矿区少斑状花岗斑岩的锆石LA-ICP-MS U-Pb法测年加权平均年龄为167Ma±1.2Ma,反映矿区可能还存在较早期的岩浆活动(中-晚侏罗世),其可与155 Ma岩浆岩划分为矿区早期的岩浆活动。花岗斑岩体具有高酸度、高钾和高铝质含量特征,总体属于酸性富钾钙碱性系列;花岗斑岩体含铝指数(A/CNK)介于1.20~2.49之间,Tb、Nd、Ga和LREE(Eu除外)富集,Eu、Ti、Sr、P亏损,属于高度分异的A型花岗岩系列。曹四夭花岗斑岩体形成于中-晚侏罗世构造机制转化时期,可能与蒙古-鄂霍次克洋闭合后的后造山伸展有关,为晚侏罗世钼多金属矿化的母岩。  相似文献   

青海省大干沟地区黑色岩系中V-Mo-PGE矿床找矿前景分析   总被引：1，自引：0，他引：1       下载免费PDF全文

陈巧妹  孙华山  刘晓康  陈建洲 《地质找矿论丛》2018,33(3):360-364

分布在东昆仑山南坡青海省大干沟地区的浩特洛哇组黑色岩系,属陆缘裂陷滨海—浅海相沉积的碎屑岩—碳酸盐岩建造,形成于缺氧环境。区内的大干沟钒钼矿床、大干沟口V-MoPGE矿床均赋存于浩特洛哇组(C2P1h)中,矿体均为层状、似层状,具层控特征。近年工作在大干沟口浩特洛哇组碳质板岩中发现了Mo、Au等元素的化探异常,通过少量的槽探及钻探工程控制钒钼矿体8个;钻孔ZK001、ZK701中均见Pd矿化,w(Pd)=0.03×10~(-6)~0.16×10~(-6),达到伴生矿床工业开采品位。大干沟黑色岩系中伴生铂族元素的发现,给青海省柴南缘地区非传统类型的铂族元素矿床的找矿突破带了希望,与黑色岩系有关的V-Mo-PGE矿产找矿前景光明。  相似文献