四川米易海塔地区混合岩型铀矿流体包裹体特征     

郭锐  陈友良  刘凯鹏  郑玉文  胡漾 《矿物学报》2020,40(2):137-148

混合岩型铀矿是康滇地轴上最有希望取得找矿突破的铀矿类型,海塔地区的铀矿化即是该类型铀矿的典型代表。本文针对区内的长英质脉矿石、富晶质铀矿石英脉矿石和含矿热液石英脉中的石英流体包裹体进行了研究。结果表明,海塔地区混合岩型铀矿的成矿作用可分为2个阶段:早期混合岩化热液成矿阶段为高温、中低盐度流体,流体包裹体均一温度集中在380~540℃,盐度变化范围为16.15%~23.18%NaCl eqv,是区内铀成矿的主要阶段;晚期热液叠加改造成矿阶段为中低温、低盐度流体,流体包裹体均一温度集中在140~220℃,盐度变化范围为5.56%~23.18%NaCleqv,是区内富铀矿的形成阶段。流体包裹体的气相成分测试表明,长英质脉矿石石英包裹体中以CH4、CO2为主,其次为H2O和N2;而富晶质铀矿石英脉及含矿热液石英脉石英包裹体中以H2为主,部分含有CO2、CH4、H2O。氢、氧同位素研究表明,早期混合岩化成矿阶段的成矿流体可能为岩浆水与变质水的混合,而晚期热液叠加改造成矿阶段成矿流体中可能有大气降水的加入。  相似文献   

Cotton canopy reflectance under variable solar zenith angles: Implications of use in evapotranspiration models     

Christopher M. U. Neale  Maria P. Gonzalez-Dugo  Angelica Serrano-Perez  Isidro Campos  Luciano Mateos 《水文研究》2021,35(6):e14162

Evapotranspiration (ET) is an important parameter in hydrologic processes and modelling. In agricultural watersheds with competing uses of fresh water including irrigated agriculture, estimating crop evapotranspiration (ET_c) accurately is critical for improving irrigation system and basin water management. The use of remote sensing-based basal crop coefficients is becoming a common method for estimating crop evapotranspiration for multiple crops over large areas. The Normalized Difference Vegetation Index (NDVI) and the Soil Adjusted Vegetation Index (SAVI), based on reflectance in the red and near-infrared bands, are commonly used for this purpose. In this paper, we examine the effects of row crop orientation and soil background darkening due to shading and soil surface wetness on these two vegetation indices through modelling, coupled with a field experiment where canopy reflectance of a cotton crop at different solar zenith angles, was measured with a portable radiometer. The results show that the NDVI is significantly more affected than the SAVI by background shading and soil surface wetness, especially in north–south oriented rows at higher latitudes and could lead to a potential overestimation of crop evapotranspiration and irrigation water demand if used for basal crop coefficient estimation. Relationships between the analysed vegetation indices and canopy biophysical parameters such as crop height, fraction of cover and leaf area index also were developed for both indices.  相似文献   

山地叶面积指数反演理论、方法与研究进展   总被引：2，自引：0，他引：2  

江海英  贾坤  赵祥  魏香琴  王冰  姚云军  张晓通  江波 《遥感学报》2020,24(12):1433-1449

叶面积指数LAI（Leaf Area Index）是表征叶片疏密程度和冠层结构特征的重要植被参数，在气候变化、作物生长模型以及碳、水循环研究中发挥着重要作用。遥感是获取区域及全球尺度LAI的一个重要手段，当前LAI产品主要基于遥感数据反演得到，但是多数LAI产品算法并未考虑地形特征的影响，导致山地LAI遥感反演精度不确定性大。提高山地LAI遥感反演精度亟需考虑地形因子对冠层反射率的影响，其中山地冠层反射率模型和遥感数据地形校正是提升山地LAI遥感反演精度的关键。本文围绕山地LAI遥感反演理论与方法，综合分析了国内外山地冠层反射率模型和地形校正模型的研究进展，总结了目前山地LAI遥感反演存在的问题，并讨论了未来研究的发展趋势。  相似文献   

Provenance discrimination of fine sediments by mid-infrared spectroscopy: Calibration and application to fluvial palaeo-environmental reconstruction     

Stoil Chapkanski  Damien Ertlen  Claire Rambeau  Laurent Schmitt 《Sedimentology》2020,67(2):1114-1134

Determining sediment provenance allows a better understanding of fluvial palaeo-dynamics, and identifying involved watersheds, at broad spatio-temporal scales. Conventional approaches for source identification are usually based on the physical, mineralogical, geochemical, magnetic or isotopic properties of sediments. Rapid, non-destructive and, in well-established contexts, highly accurate, mid-infrared spectroscopy is an alternative method for investigating sediment sources. The present research objectives are: (i) to use the mid-infrared spectroscopy method to discriminate the provenance of fine sediments, by applying discriminant analysis on a large set of reference samples from three different watersheds in the Upper Rhine area (associated with the Rhine, Ill and Vosges tributaries); (ii) to clarify whether the provenance spectra signatures are influenced by riverine depositional contexts (bars versus banks) and, to some extent, by grain size and/or high organic matter content; and (iii) to apply the mid-infrared spectroscopy – discriminant analysis method to a study of fluvial palaeo-dynamics and determine the provenance of palaeo-channel infillings. Three main sedimentary sources, divided into eight sub-categories, have been characterized by 196 modern reference samples from 78 collecting sites. Discriminant analysis displayed a strong separating power by classifying correctly the origin of samples without any inter-group overlap, independently from the geomorphological context (bar or bank) and associated slight changes in organic matter contents or grain size. Mid-infrared spectroscopy – discriminant analysis investigations of the palaeo-channel infill, complemented by radiocarbon dates and mineralogical data, allowed reconstructing general trends for the local morpho-sedimentary dynamics over the last ca 12 millennia.  相似文献   

大洋多金属结核中铁锰质矿物拉曼光谱特征初探     

赖佩欣  任江波  邓剑锋 《矿床地质》2020,39(1):126-134

拉曼光谱是一种快速无损的分析手段,它既可观察样品的显微结构构造,也可分析样品的成分和结构。为了丰富多金属结核的岩石矿物学特征,文章对西太平洋某海山区的多金属结核样品进行了X射线粉末衍射分析和拉曼光谱分析。X射线分析结果显示该区域样品主要含有水羟锰矿、钡镁锰矿、斜长石、钙十字沸石和石英,显微构造主要有纹层状构造、柱状构造、树枝状构造、充填构造等。通过分析对比潮湿样品和烘干样品铁锰质矿物的拉曼特征谱峰,得出结核中水羟锰矿的特征谱峰位于490 cm~(-1)、570 cm~(-1)和626 cm~(-1)附近,钡镁锰矿的特征谱峰则位于640 cm~(-1)附近,与陆地上对应矿物的特征拉曼谱峰不同。结核中的钡镁锰矿结构不稳定,经过风干或者抛磨后部分产生相变,不同显微结构中,相变情况不同。经与RRUFF数据库比对,识别出钙十字沸石、斜长石等自形晶,多分布于结核最内层,往结核外层总体减少。矿物微晶多见铁锰质矿物微晶和钙十字沸石微晶,铁锰质矿物绕其向外生长。  相似文献   

微型近红外光谱仪测量北极积雪覆盖海冰内部太阳辐照度可行性研究   总被引：1，自引：1，他引：0  

南立文  王晓萍  王杭州  周宏亮  陈鹰 《海洋学报(英文版)》2020,39(9):115-124

The extremely low temperature, high humidity and limited power supply pose considerable challenges when using spectrometers within the Arctic sea ice. The feasibility of using a miniature low-power near-infrared spectrometer module to measure solar radiation in Arctic sea ice environments was investigated in this study.Temperature and integration time dependences of the spectrometer module were examined over the entire target operating range of –50℃ to 30℃, well below the specified operating range of this spectrometer. Using these observations, a dark output prediction model was developed to represent dark output as a function of temperature and integration time. Temperature-induced biases in the saturation output and linear operating range of the spectrometer were also determined. Temperature and integration time dependences of the signal output were evaluated. Two signal output correction models were developed and compared, to convert the signal output at any temperature within the operating temperature range and integration time to that measured at the reference temperature and integration time. The overall performance of the spectrometer was evaluated by integrating it into a refined fiber optic spectrometry system and measuring solar irradiance distribution in the ice cover with thickness of 1.85 m in the Arctic during the 9th Chinese National Arctic Research Expedition. The general shape of the measured solar irradiance above the snow surface agreed well with that measured by other commercial oceanographic spectroradiometers. The measured optical properties of the sea ice were generally comparable to those of similar ice measured using other instruments. This approach provides a general framework for assessing the feasibility of using spectrometers for applications in cold environments.  相似文献   

洱海沉积物有色可溶性有机物(CDOM)三维荧光空间分布特性及指示意义   总被引：1，自引：0，他引：1  

赵海超  李艳平  王圣瑞  焦立新 《湖泊科学》2019,31(2):507-516

采用荧光光谱区域体积积分法定量研究洱海沉积物有色可溶性有机物（CDOM）三维荧光空间分布特性，结果表明，洱海沉积物CDOM中类腐殖酸组分占比最高（44.5%~74.2%），其次为溶解性微生物代谢产物（10.7%~20.4%）和类富里酸物质（8.19%~19.7%），而类蛋白组分占比最低，类腐殖酸占比与H/C和N/C均呈显著负相关；南部湖心平台区域沉积物类富里酸和类蛋白组分占比较高，其CDOM自生源占比较高；北部水生植物分布区溶解性微生物代谢产物占比较高，CDOM陆源性较强；中部深水区及南北湖湾区域类腐殖酸占比较高，随水深增加沉积物CDOM自生源特征增强.随沉积物深度增加类腐殖酸和溶解性微生物代谢产物占比呈下降趋势，类富里酸占比呈上升趋势，CDOM自生源特征增强，脂肪化程度增高.随湖泊富营养化程度增加沉积物CDOM受微生物代谢产物影响增强，陆源性增加，而自生源性降低，湖泊沉积物CDOM具有富营养化指示意义.  相似文献   

Combining two filter paper‐based analytical methods to monitor temporal variations in the geochemical properties of fluvial suspended particulate matter          下载免费PDF全文

R. J. Cooper  B. G. Rawlins  B. Lézé  T. Krueger  K. M. Hiscock 《水文研究》2014,28(13):4042-4056

Many of the commonly used analytical techniques for assessing the properties of fluvial suspended particulate matter (SPM) are neither cost effective nor time efficient, making them prohibitive to long‐term high‐resolution monitoring. We present an in‐depth methodology utilizing two types of spectroscopy which, when combined with automatic water samplers, can generate accurate, high‐temporal resolution SPM geochemistry data, inexpensively and semi‐destructively, directly from sediment covered filter papers. A combined X‐ray fluorescence spectroscopy and diffuse reflectance infrared Fourier transform spectroscopy approach is developed to estimate concentrations for a range of elements (Al, Ca, Ce, Fe, K, Mg, Mn, Na, P, Si, Ti) and compounds (organic carbon, Al_dithionate, Al_oxalate, Fe_dithionate, and Fe_oxalate) within SPM trapped on quartz fibre filters at masses as low as 3 mg. Calibration models with small prediction errors are derived, along with mass correction factor models to account for variations in retained SPM mass. Spectral pre‐processing methods are shown to enhance the reproducibility of results for some compounds, and the importance of filter paper selection and homogeneous sample preparation in minimizing spectral interference is emphasized. The geochemical signal from sediment covered filter papers is demonstrated to be time stable enabling samples to be stored for several weeks prior to analysis. Example results obtained during a heavy precipitation event in October 2012 demonstrate the methodology presented here has considerable potential to be utilized for high‐resolution monitoring of SPM geochemistry under a range of in‐stream hydrological conditions. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

河南产宝石级高温高压合成钻石的谱学特征及电磁性研究     

杨池玉  陆太进  张健  宋中华  陈华  柯捷  何明跃 《岩矿测试》2021,(2):217-226

为快速鉴定高温高压(HPHT)合成钻石,前人已开展了系统的发光特征和谱学特征研究,但对比性分析较少,且对电学性质和磁学性质关注不多。本文结合常规宝石学观察、高精度谱学测试以及导电性和磁性测试,对49粒无色、黄色样品进行了深入研究和对比分析。结果表明:①铁、钴、镍等金属元素的触媒残余是HPHT合成钻石的磁性来源,测试样品均能被磁强达到12000Gs的磁棒吸引。②无色HPHT合成钻石为Ⅱa+Ⅱb型钻石,硼元素的存在导致其具有良好的导电能力,且随着硼含量的增多,导电能力逐渐增强;黄色样品为Ⅰb+ⅠaA型钻石,约三分之一的孤氮转化为A集合体,揭示合成钻石在生长完成后经过了高温退火处理。③硼元素的普遍存在,以及氮元素主要以孤氮原子和A集合体的方式存在,导致了HPHT合成钻石的特征红外光谱;HPHT合成钻石中常含有氮、镍、硅等杂质元素引起的晶格缺陷,导致了特征的光致发光光谱。④无色HPHT合成钻石具有强蓝绿色荧光和磷光,黄色HPHT合成钻石具有绿色荧光,可见明显的立方体-八面体分区现象。本研究表明:谱学特征和发光特征仍然是筛查鉴定HPHT合成钻石的重要依据。现生长技术下合成的HPHT合成钻石在导电性和磁性两方面也与天然钻石存在明显差异,可以作为快速鉴定合成钻石的辅助性依据。  相似文献   

微波等离子体原子发射光谱法测定偏远矿区海泡石中的主微量元素     

周学忠  谢华林 《岩矿测试》2021,(5):680-687

海泡石是具有层状结构的含水富镁硅酸盐黏土矿物,其中无机元素含量是揭示其成矿物质来源、成矿流体性质和矿床成因的重要依据,通常采用电感耦合等离子体发射光谱/质谱法(ICP-OES/MS)进行测定,等离子体(ICP)的高温激发会产生成大量谱线干扰,维持ICP稳定工作需使用高纯氩气,持续供气对于偏远矿区海泡石的检测还将面对气体采购和运输不便的问题。本文基于微波等离子体原子发射光谱(MP-AES)的低温激发技术减少光谱干扰,建立了准确测定偏远矿区海泡石中主量元素Mg、Al、Ca、Fe、K、Na和微量元素Cu、Zn、Mn、Pb含量的分析方法。利用硝酸-盐酸-氢氟酸混合酸对海泡石进行微波消解,避免了样品处理过程中分析元素的损失,加快了样品处理速度,同时提高了样品溶液的稳定性。通过选择各元素光谱线的分析波长,并利用快速线性干扰校正(FLIC)技术校正光谱干扰,以Lu为内标元素校正基体效应,提高了灵敏度和准确度。各元素的检出限为0.19～14.6μg/L。海泡石国家标准物质(GBW07138)各元素测定值与认定值的相对误差在-5.0%～6.7%之间。本方法具有检出限低、线性范围宽、结果准确等优点;MP-AES采用自带的氮气发生器为等离子体提供氮气作为工作气,无需引入复杂气体,提高了分析效率,尤其适用于气体采购和运输不便的偏远矿区。  相似文献