烃源岩不同性质有机酸的分离及其检测方法     

杜佳宗  何蓓  蔡进功  雷天柱  刘庆  谢忠怀 《高校地质学报》2020,26(5):540-548

烃源岩中的有机酸来源于有机质，但有机质具有不同的赋存形式，有机酸具有不同性质，这将影响有机酸与不同赋存有机质的关系，进而影响分离和检测方法。文章在总结前人对有机质赋存形式和有机酸性质等特征的基础上，提出烃源岩中的有机酸并以非单一的形式存在，具有水溶性、脂溶性和难溶性有机酸三种类型，游离有机质中存在水溶性和脂溶性有机酸，而结合有机质中存在水溶性、脂溶性和难溶性有机酸。因此在检测方法上需采取分步分离的方法，且根据有机酸的性质选取合适的检测方法，即水溶性有机酸利用离子色谱检测，索氏抽提得到的脂溶性有机酸利用气相色谱—质谱检测，通过酸解抽提残渣得到的难溶性有机酸利用红外光谱检测，全面系统地认识烃源岩中有机酸含量和类型等特征。这对进一步探讨烃源岩各种类型有机酸特征和演化规律，深化烃源岩有机质生烃以及有机—无机相互作用等机理都具有重要意义。  相似文献   

云南墨江金厂矿床金镍赋存状态及成因关系探讨     

周凯  张洪瑞  柴鹏  张慧超  程先锋  杨澍 《矿床地质》2020,39(1):97-110

墨江金厂金镍矿床位于哀牢山造山带中段,九甲—安定大断裂上盘,是西南三江成矿带内一个独特的金镍矿床。本文在详细野外地质调查基础上,通过显微镜下观察、扫描电镜和能谱分析,结合矿石微量元素分析,对矿石中金、镍赋存状态及成因关系进行了研究。结果显示,金赋存形式主要有可见金和不可见金。可见金又可分为粒间金和包体金;不可见金是以Au~+赋存于硫锑铜银矿、黄铁矿中。镍赋存状态有两种:一是以独立矿物,如辉砷镍矿、锑硫镍矿等存在;二是以离子态赋存于黄铁矿、硫锑铜银矿中。矿石结构构造、矿物共生组合及微量元素含量等显示,金和镍为同期热液成矿,金来自岩浆热液系统远端的低温热液,镍是含金低温热液流经超基性岩体时萃取而来。成矿过程可分为早期富硅质热液和晚期富钙质热液两个阶段,成矿是在幕式构造活动下多期流体运移和沉淀的结果。  相似文献   

北京主城区伪基站时空规律分析     

汪伟  陶海燕  卓莉  李敏  李旭亮  汪珂丽  史清丽 《地球信息科学学报》2018,20(7):978-987

随着公众移动通信的快速发展,伪基站的泛滥不仅破坏正常电信秩序,危害公共安全,而且严重损害群众财产权益,侵犯公民个人隐私,已成为社会一大公害。如何从垃圾短信大数据中挖掘出伪基站活动的时空规律,寻找有效的防控方案,从源头上进行打击和治理成为管理部门和研究者共同关注的焦点。本文基于北京市垃圾短信数据,利用非负矩阵分解的方法分析伪基站的时空分布规律;并利用TF-IDF构建垃圾短信分类模型,对垃圾短信进行分类,结合土地利用数据,分析伪基站在发送不同类型垃圾短信时的时空分布规律。结果显示：北京市垃圾短信多分布于路网和中心城区;白天垃圾短信数量远远多于晚上;垃圾短信的分布随时间的推移沿着路网逐渐向内收缩;发送不同类型垃圾短信的伪基站的时空分布具有一定的差异;通过非负矩阵分解得到的结果,与垃圾短信分类后得到的结果有很好的匹配。研究表明,非负矩阵分解具有实现上的简便性、分解形式和分解结果上的可解释性等优点,可以有针对性的为有关部门建言打击伪基站的有效方案,对于伪基站违法行为的治理具有一定的意义。  相似文献   

Stratification response of soil water content during rainfall events under different rainfall patterns   总被引：2，自引：0，他引：2       下载免费PDF全文

Yinglan A  Guoqiang Wang  Wenchao Sun  Baolin Xue  Anthony Kiem 《水文研究》2018,32(20):3128-3139

Many researchers have studied the influence of rainfall patterns on soil water movement processes using rainfall simulation experiments. However, less attention has been paid to the influence under natural condition. In this paper, rainfall, soil water content (SWC), and soil temperature at 10‐, 20‐, 30‐, 40‐, and 50‐cm depths were simultaneously monitored at 1‐min intervals to measure the variation in SWC (SWCv) in response to rainfall under different rainfall patterns. First, we classified rainfall events into four patterns. During the study period, the main pattern was the advanced rainfall pattern (38% of all rainfall events), whereas the delayed, central, and uniform rainfall patterns had similar frequencies of about 20%. During natural rainfall, rainwater rapidly passed through the top soil layers (10–40 cm) and was accumulated in the bottom layer (50 cm). When a high rainfall pulse occurred, the water storage balance was disturbed, resulting in the drainage of initial soil water from the top layers into the deeper layers. Therefore, the critical function of the top layers and the bottom layers was infiltration and storage, respectively. The source of water stored in the bottom layer was not only rainfall but also the initial soil water in the upper soil layers. Changes in soil temperature at each soil depth were comonitored with SWCv to determine the movement characteristics of soil water under different rainfall patterns. Under the delayed rainfall pattern, preferential flows preferred to occur. Under the other rainfall patterns, matrix flow was the main form of soil water movement. Rainfall amount was a better indicator than rainfall intensity for SWCv in the bottom layer under the delayed rainfall pattern. These results provide insights into the responses of SWCv under different rainfall patterns in northern China.  相似文献   

东太平洋海隆13°N表层含金属沉积物物质组成与元素赋存状态     

荣坤波  曾志刚  武力  李康 《海洋科学》2018,42(7):70-79

为了解不同类型含金属沉积物在物质组成和元素赋存状态的差异,对东太平洋海隆13°N洋中脊两侧表层含金属沉积物(站号:E271和E53)进行了矿物学、地球化学分析,顺序提取实验,并与前人对轴部表层沉积物(站号:17A-EPR-TVG1)的研究结果作了对比分析。研究结果表明, E271和E53是远端含金属沉积物,由非浮力热液羽状流中颗粒物沉降所形成的;17A-EPR-TVG1沉积物是近喷口含金属沉积物,由黑烟囱或者热液硫化物丘状体崩塌、堆积,或者由热液羽状流中Fe-Mn氧化物和硫化物快速沉淀而形成的,近喷口沉积物比远端沉积物更富集Fe、Cu和Zn等元素。元素在两种含金属沉积物中的赋存状态基本相同,除了Fe,Cu,Zn,Mo和稀土元素(REE)等元素在远端沉积物中主要存在于Fe-Mn氧化物相,在近喷口沉积物中主要在残留相中。远端沉积物中REE页岩标准化配分模式与海水相似,表明REE主要来自海水,而近喷口沉积物中REE配分模式与热液流体相似,说明REE以高温热液流体来源为主。相关研究结果加深了对热液沉积作用研究的认识。  相似文献   

Leveraging parallel spatio-temporal computing for crime analysis in large datasets: analyzing trends in near-repeat phenomenon of crime in cities     

Jayakrishnan Ajayakumar  Eric Shook 《International journal of geographical information science》2020,34(9):1683-1707

ABSTRACT

Crime often clusters in space and time. Near-repeat patterns improve understanding of crime communicability and their space–time interactions. Near-repeat analysis requires extensive computing resources for the assessment of statistical significance of space–time interactions. A computationally intensive Monte Carlo simulation-based approach is used to evaluate the statistical significance of the space-time patterns underlying near-repeat events. Currently available software for identifying near-repeat patterns is not scalable for large crime datasets. In this paper, we show how parallel spatial programming can help to leverage spatio-temporal simulation-based analysis in large datasets. A parallel near-repeat calculator was developed and a set of experiments were conducted to compare the newly developed software with an existing implementation, assess the performance gain due to parallel computation, test the scalability of the software to handle large crime datasets and assess the utility of the new software for real-world crime data analysis. Our experimental results suggest that, efficiently designed parallel algorithms that leverage high-performance computing along with performance optimization techniques could be used to develop software that are scalable with large datasets and could provide solutions for computationally intensive statistical simulation-based approaches in crime analysis.  相似文献   

深海弯曲水道内部一种特殊的沉积单元:凹岸坝     

冯潇飞  赵晓明  谭程鹏  齐昆  谢涛  张迎春  陆文明  徐睿 《沉积学报》2020,38(2):440-450

在深海水道研究过程中,识别出深海弯曲水道内部存在一种特殊的沉积单元--凹岸坝,基于尼日尔三角洲陆坡区浅层高频三维地震资料,利用地震相分析技术,探究了凹岸坝的沉积结构特征和形成机制,讨论了其与水道弯曲丘(nested mounds)、曲流河凹岸滩坝之间的差异。研究结果表明:凹岸坝是分布于曲率较大、以垂向加积为主的末期水道弯曲凹岸处的坝体沉积单元,该沉积单元在地震剖面上表现为强振幅、连续性较好的反射特征,其内部沉积界面倾向于水道弯曲凸岸处,倾角约1°~20°,且在凹岸弧顶处达到最大值。凹岸坝形成的关键在于惯性作用,其造成水道内部重力流流体在弯曲处发生溢岸,导致流量减少,流体动能相应降低,流体携砂能力小于沉积物负载,造成沉积物快速沉降,从而形成凹岸坝。由于凹岸坝是一种连续性较好的砂体沉积,所以其可成为潜在的、储集性能较好的油气储集体。  相似文献   

甘肃省地热资源赋存特征及潜力评价     

谢娜  喻生波  丁宏伟  张明泉 《中国地质》2020,47(6):1804-1812

甘肃省地热资源丰富，其地热资源的开发利用具有较大的潜力。本文介绍了甘肃省地热资源分布概况，结合地区构造、地热水化学特征、地热资源量及开发利用现状探讨了甘肃隆起山地对流型与沉积盆地传导型地热资源的赋存特征，并对两种类型地热资源潜力进行了分析评价。结果表明，沉积盆地地热资源分布于河西、陇西及陇东盆地等，热储类型为裂隙型和孔隙型，热储层自元古宙至新生代均有发育，岩性以砂岩为主；隆起山地型地热资源主要分布于祁连山和西秦岭造山带，热储类型为断裂破碎带，岩性以花岗岩为主；通过潜力计算得知，全省热量开采系数≥0.4的仅占29.17%，表明目前甘肃地热资源开采程度较低，开采潜力较大。  相似文献   

Spatial variability in specific discharge and streamwater chemistry during low flows: Results from snapshot sampling campaigns in eleven Swiss catchments     

Marius G. Floriancic  Benjamin M. C. Fischer  Peter Molnar  James W. Kirchner  Ilja H.J. van Meerveld 《水文研究》2019,33(22):2847-2866

Catchments consist of distinct landforms that affect the storage and release of subsurface water. Certain landforms may be the main contributors to streamflow during extended dry periods, and these may vary for different catchments in a given region. We present a unique dataset from snapshot field campaigns during low‐flow conditions in 11 catchments across Switzerland to illustrate this. The catchments differed in size (10 to 110 km²), varied from predominantly agricultural lowlands to Alpine areas, and covered a range of physical characteristics. During each snapshot campaign, we jointly measured streamflow and collected water samples for the analysis of major ions and stable water isotopes. For every sampling location (basin), we determined several landscape characteristics from national geo‐datasets, including drainage area, elevation, slope, flowpath length, dominant land use, and geological and geomorphological characteristics, such as the lithology and fraction of quaternary deposits. The results demonstrate very large spatial variability in specific low‐flow discharge and water chemistry: Neighboring sampling locations could differ significantly in their specific discharge, isotopic composition, and ion concentrations, indicating that different sources contribute to streamflow during extended dry periods. However, none of the landscape characteristics that we analysed could explain the spatial variability in specific discharge or streamwater chemistry in multiple catchments. This suggests that local features determine the spatial differences in discharge and water chemistry during low‐flow conditions and that this variability cannot be assessed a priori from available geodata and statistical relations to landscape characteristics. The results furthermore suggest that measurements at the catchment outlet during low‐flow conditions do not reflect the heterogeneity of the different source areas in the catchment that contribute to streamflow.  相似文献   

关中盆地浅层地热能赋存规律及资源量估算     

周阳  洪增林  张卉  曹晓凡  穆根胥 《中国地质调查》2020,7(2):21-29

通过野外地质调查及室内综合研究,分析了关中盆地浅层地热能的开发利用情况、赋存特征和形成模式,并对资源量进行了估算,总结了盆地不同地貌单元、不同岩性的岩土体热物性参数特征,计算了区域恒温带深度和浅层大地热流值。关中盆地地热能的形成模式主要为热传导型和热对流型: 热传导型地热资源主要分布于西安凹陷、固市凹陷等完整地质块体内; 热对流型地热资源主要分布于深大断裂直接沟通地表的区域以及断裂带周边区域。采用层次分析法对关中盆地浅层地热能进行适宜性分区,认为关中盆地整体属于地埋管地源热泵系统适宜区或较适宜区,地下水地源热泵系统适宜区和较适宜区主要分布在盆地中部漫滩区和阶地区。利用热储法,计算关中盆地浅层地热能热容量为1.38×10¹⁶ kJ/℃,浅层地热能储量巨大,开发利用前景优良。  相似文献