A Revisited Purification of Li for ‘Na Breakthrough’ and its Isotopic Determination by MC‐ICP‐MS     

Lin Xu  Chongguang Luo  Hanjie Wen 《Geostandards and Geoanalytical Research》2020,44(1):201-214

The accurate and precise determination of Li isotopic composition by MC‐ICP‐MS suffers from the poor performance of traditional column chromatography. Previously established chromatographic processes cannot completely remove Na in complex geological samples, which is currently interpreted to be a result of Na breakthrough. In this study, Na breakthrough during single‐column purification was found to differ between simply artificial Na‐containing sample solutions, where a little Na residue was found, and silicate rocks, where a large amount of breakthrough occurred. A revised two‐step column purification for Li using 0.5 and 0.3 mol l^?1 HCl as eluents was designed to remove the Na. This modified method achieves high‐efficiency Li purification from Na and consequently avoiding high Na/Li ratio interference for subsequent MC‐ICP‐MS analyses. The proposed method was validated by the analysis of a series of reference materials, including Li₂CO₃ (IRMM‐016, ‐0.10‰), basalt (BCR‐2: 2.68‰; BHVO‐2: 4.39‰), andesite (AGV‐2: 6.46‰; RGM‐2: 2.59‰), granodiorite (GSP‐2: ?0.87‰) and seawater (CASS‐5, 30.88‰). This work reports early Na appearance prior to the elution curves in chromatography and emphasises its influence for subsequent Li isotope measurement. Based on the findings, the established two‐step method would be more secure than single‐column chemistry for Li purification.  相似文献   

四川甲基卡锂矿伟晶岩转石分布区“3定2参”大比例尺填图法及其在青藏高原应用的意义   总被引：4，自引：0，他引：4  

刘善宝  王成辉  王登红  代鸿章  马圣钞  于扬  潘蒙  郝雪峰  杨荣 《地质学报》2020,94(1):326-332

我国西部地区无论是新疆阿尔泰还是地处青藏高原的西昆仑地区或是松潘-甘孜成矿带,都是我国伟晶岩型矿床找矿远景区,但要么剥蚀严重,要么第四系覆盖,难以找到好的地质露头。本文以地处青藏高原东南缘的川西甲基卡矿田为例,通过近10年来的实践,探索出一套在第四系覆盖严重但又有伟晶岩转石分布地区的填图找矿方法--"3定2参"1∶2000伟晶岩转石填图法,即:定伟晶岩转石类型、尺度、密度,参考矿区内伟晶岩脉产状和地形条件。实践证明,该方法能够快速有效识别伟晶岩转石类型(冰碛物、坡积物和原地或半原地型),并可进一步确定第四系覆盖区内伟晶岩脉的类型、产状及规模,为钻探工程部署提供依据。2019年在甲基卡经8个钻孔验证,在日西柯第四系覆盖区内发现16条花岗伟晶岩脉,其中锂辉石伟晶岩脉10条,实现了新的找矿突破。这一方法同样在可尔因矿集区适用,并指导2019年"松潘-甘孜成锂带锂铍多金属大型资源基地综合调查评价"项目在上述两个地区实施钻探验证,初步探获新增氧化锂资源量超过15万吨,值得进一步推广应用。  相似文献   

高分遥感技术在西昆仑大红柳滩-俘虏沟地区地质找矿中的应用          下载免费PDF全文

王辉  秦绪文  范玉海  杨金中  金谋顺  张少鹏  廖友运  杨晨  崔胜  贺小龙  匡经水  郭鹏程 《中国地质》2018,45(6):1289-1301

在西昆仑大红柳滩-俘虏沟地区,以WorldView-2高空间分辨率数据为主要信息源,在标准影像图制作基础上,针对性地进行图像增强处理,突出相关控矿要素和矿化信息,开展地质矿产遥感解译;利用ASTER数据开展矿化蚀变有关的遥感异常信息提取,配合适量的野外调查验证,发现了4种极具找矿前景的矿化带类型：①大红柳滩（含稀有金属）花岗伟晶岩带1处;②大红柳滩层控型铁多金属矿化带1处;③俘虏沟燕山期花岗岩有关热液脉型铁、铅、银、铜矿化区1处;④俘虏沟层控型含铜铅锌银的菱铁-赤铁矿矿化带4处;通过遥感综合分析,圈定遥感找矿靶区11处,其中A级遥感找矿靶区5处、B级遥感找矿靶区3处、C级遥感找矿靶区3处,为后续区域地质矿产调查项目规划部署和矿产资源勘查评价提供依据。因此,高分遥感技术在西昆仑地区矿产地质综合调查中作用显著,可实现找矿工作的快速突破,值得在相同或类似区域进一步推广应用。  相似文献   

甘肃祁连山西段金矿分布特征及控矿因素分析          下载免费PDF全文

佘小龙  矫润田  赵梦  贾志磊 《甘肃地质》2018,(2):43-52

祁连西段是甘肃省重要的金成矿带,分布有鹰嘴山、寒山、阳凹大泉、车路沟、金湾子等金矿床,近年又新发现豹子沟南、滴水山、牛毛泉、积阴功台金矿,显示出较大的区域找矿潜力。本文通过典型金矿床和新发现金矿成矿地质条件分析,总结了甘肃祁连山西段金矿的空间分布特征、控矿因素。初步研究认为祁连山西段主要的金矿床呈带状分布于阿尔金走滑断裂与北祁连褶皱断裂构造带交汇部位,明显受不同规模、不同序次的韧、脆性断裂构造破碎带控制;成矿与区域内不同规模中酸性—中基性岩体及岩脉有关;古生代火山碎屑岩、浅变质碎屑岩为主要容矿岩性及含矿建造;矿体普遍具有延深大于延长、深部明显富集的特征。新发现金矿多以化探异常查证为重点,不断浓缩异常源,实现找矿突破。本文对祁连山西段的金矿勘查具有指导意义,对该地区的金矿研究也提供了重要的基础资料。  相似文献   

热屏障井对地下水源热泵换热影响模拟          下载免费PDF全文

肖锐  黄坚  王小清 《水文地质工程地质》2021,48(2):190-198

对于场地受限的地下水源热泵项目,随着系统运行时间的增加易引发热贯通现象进而降低机组运行效率。地下水源热泵设计中,在抽灌水井连线间布设热屏障井可改变地下水流场,降低热量在抽灌井间的运移速度,有利于延长热贯通发生时间并缓解热贯通程度。通过构建地下水换热模型,模拟计算夏季制冷工况条件下36组热泵运行场景,分析了热屏障井的位置,过滤管长度及回灌量对热贯通和含水层温度场的影响规律。结果表明:热屏障井回灌量的增加有利于提升热屏障效果,但提升幅度随回灌量的增加逐渐减弱;最大水位降深值随着热屏障井回灌量的增加呈线性增长;增加热屏障井滤管长度可提升热屏障效果,提升效果随屏障井回灌量的增加逐渐增强。通过模型多周期、长时间模拟计算发现,热屏障井的运行可促使回灌的冷热量集中在回灌井一侧,对于采用冬夏季抽灌井交换运行模式的热泵系统,可充分利用含水层储能,提升机组运行效率。  相似文献   

A Numerical Simulation Study of Temperature and Pressure Effects on the Breakthrough Pressure of CO2 in Unsaturated Low-permeability Rock Core     

HU Zhikai  LI Yi  LI Qi  DIAO Yujie  MA Xin  LIU Hejuan  FENG Guanhong  WANG Fugang  YU Qingchun 《《地质学报》英文版》2023,97(3):911-924

Gas breakthrough pressure is a key parameter to evaluate the sealing capacity of caprock, and it also plays important roles in safety and capacity of CO2 geological storage. Based on the published experimental results, we present numerical simulations on CO2 breakthrough pressure in unsaturated low-permeability rock under 9 multiple P-T conditions (which can keep CO2 in gaseous, liquid and supercritical states) and thus, a numerical method which can be used to accurately predict CO2 breakthrough pressure on rock-core scale is proposed. The simulation results show that CO2 breakthrough pressure and breakthrough time are exponential correlated with P-T conditions. Meanwhile, pressure has stronger effects on experimental results than that of temperature. Moreover, we performed sensitivity studies on the pore distribution index λ (0.6, 0.7, 0.8, and 0.9) in van Genuchten-Muale model. Results show that with the increase of λ, CO2 breakthrough pressure and breakthrough time both show decreasing trends. In other words, the larger the value of λ is, the better the permeability of the caprock is, and the worse the CO2 sealing capacity is. The numerical method established in this study can provide an important reference for the prediction of gas breakthrough pressure on rock-core scale and for related numerical studies.  相似文献   

甘肃省新一轮战略性矿产资源找矿突破措施与对策          下载免费PDF全文

刘子锐 《甘肃地质》2023,(2):1-5

甘肃省是矿产资源大省,矿产资源丰富、种类齐全。矿业是甘肃省的支柱产业。根据新一轮找矿突破战略行动的相关要求,甘肃省编制了瓜州—肃北、敦煌—白银、甘南—陇南战略性矿产资源调查“三个工程”可行性报告,在基础调查区、重点调查区、重点勘查区和重要矿山“四区”部署了56片167个子项目。结合甘肃省矿产资源分布、特点、优势矿种和矿床类型,提出甘肃省新一轮战略性矿产资源找矿突破布局、措施与对策。  相似文献   

云南弥渡县云景地区多元地学信息集成及找矿模型     

缪宇  宋文婷  何茂源  徐乐 《地质与勘探》2019,55(6):1367-1378

云南弥渡县云景预查区位于巍山县扎村金矿东缘,属于西南三江成矿省昌都-普洱成矿带。本文结合前人地质资料以及野外地物化遥等多元勘查手段,对该预查区多元地学信息进行分析和集成。研究发现,该区成矿作用与区内浅层侵入岩关系密切,接触交代成矿作用明显,矿化受南北向构造控制,构造交汇部位矿化集中发育。斑岩体构成了区内主要的磁性源,含矿石英砂岩体具有接触过渡带高阻、高极化率的特征,中深部找矿潜力巨大;地球化学异常特征表现为热液叠加改造型金矿的元素组合特征,亲铜元素相对富集,成矿阶段呈多期次性,金成矿贯穿早期高温热液成矿阶段。通过多元地学信息集成提出了适合本区的热液叠加改造型金矿找矿模型。  相似文献   

甘肃阿尔金南缘白石头沟石墨矿地质特征、成矿条件及找矿标志     

穆可斌  连志义  王学银 《地质与勘探》2019,55(3):701-711

甘肃白石头沟石墨矿位于阿尔金南缘敦煌地块，赋存于前寒武纪敦煌岩群大理岩和石英片岩之中，目前圈定矿体33条，主要矿体2条。作为研究白石头沟石墨矿理想地层的敦煌岩群，是一套以变质碎屑沉积岩和变质基性岩为主的变质岩浆杂岩。本文从矿床角度出发，立足于区域地质勘查资料，结合前人研究成果，在对白石头沟石墨矿成矿地质背景、矿床及矿体特征、组合样化学分析、矿石矿物赋存状态及特征研究的基础上，对矿床的成因进行初步探讨并归纳区域找矿标志。研究表明，白石头沟石墨矿可分为大理岩型和石英片岩型两种类型，是古元古代经历区域动力热液变质作用而形成的沉积变质型矿床，成矿物质主要来源于变质碎屑沉积岩类的原岩（海相陆源碎屑岩和碳酸盐岩）本身，成矿环境为古老活动大陆边缘。找矿标志具有特定层位、岩性、矿化及物探特征。  相似文献   

Soil pipe flow tracer experiments: 1. Connectivity and transport characteristics          下载免费PDF全文

G. V. Wilson  J. R. Rigby  M. Ursic  S. M. Dabney 《水文研究》2016,30(8):1265-1279

Much debate has occurred in catchment hydrology regarding the connectivity of flow paths from upslope areas to catchment outlets. This study was conducted in two catchments, one with three upper branches, in a loess soil with a fragipan that fosters lateral flow and exhibits an extensive distribution of soil pipe collapse features. The study aimed to determine the connectivity of multiple soil pipe networks as well as determine pipe flow velocities during storm events. Fluorescein dye was injected directly into soil pipes at the upper most pipe collapse feature of four different hillslopes. Breakthrough curves (BTC) were determined by sampling multiple pipe collapse features downslope. The BTCs were used to determine the ‘average’ (centre of mass) and ‘maximum’ (first arrival) flow velocities. This study confirmed that these catchments contain individual continuous soil pipe networks that extend over 190 m and connect the upper most hillslopes areas with the catchment outlet. While the flow paths are continuous, the individual pipe networks consist of alternating reaches of subsurface flow through soil pipes and reaches of surface flow through gullies formed by pipe collapses. In addition, flow can be occurring both through the subsurface soil pipes simultaneous with surface flow generated by artesian flow from the soil pipes. The pipe flow velocities were as high as 0.3 m/s, which was in the range of streamflow velocities. These pipe flow velocities were also in the range of velocities observed in pinhole erosion tests suggesting that these large, mature soil pipes are still actively eroding. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献