黔北镇远牛蹄塘组黑色页岩沉积环境与有机质富集关系   总被引：1，自引：0，他引：1  

夏鹏  付勇  杨镇  郭川  黄金强  黄明勇 《地质学报》2020,94(3):947-956

通过矿物组分、主量元素、微量元素、碳氧同位素等特征，分析了黔北地区镇远县ZX井牛蹄塘组黑色页岩的岩相类型和不同岩相页岩的沉积环境及其与有机质富集间的关系。结果表明，牛蹄塘组下段以硅质页岩为主，TOC含量4. 96%~10. 10%；上段以富泥硅质页岩为主，TOC含量1. 43%~9. 04%。下段硅质页岩沉积于水流停滞的深水陆棚环境，沉积古水体为贫氧的还原状态；上段富泥硅质页岩沉积时期，仍为贫氧的还原环境，但水体滞留程度、还原性较下段硅质页岩沉积期弱。贫氧的还原环境是影响牛蹄塘组黑色页岩有机质富集的主要因素，热液作用和陆源碎屑对牛蹄塘组黑色页岩有机质富集的影响较小。  相似文献   

Redox evolution of western Tianshan subduction zone and its effect on deep carbon cycle     

《地学前缘(英文版)》2020,11(3):915-924

Knowing the phase relations of carbon-bearing phases at high-pressure(HP) and high-temperature(HT) condition is essential for understanding the deep carbon cycle in the subduction zones.In particular,the phase relation of carbon-bearing phases is also strongly influenced by redox condition of subduction zones,which is poorly explored.Here we summarized the phase relations of carbon-bearing phases(calcite,aragonite,dolomite,magnesite,graphite,hydrocarbon) in HP metamorphic rocks(marble,metapelite,eclogite) from the Western Tianshan subduction zone and high-pressure experiments.During prograde progress of subduction,carbonates in altered oceanic crust change from Ca-carbonate(calcite) to Ca,Mg-carbonate(dolomite),then finally to Mgcarbonate(magnesite) via Mg-Ca cation exchange reaction between silicate and carbonate,while calcite in sedimentary calcareous ooze on oceanic crust directly transfers to high-pressure aragonite in marble or amorphous CaCO3 in subduction zones.Redox evolution also plays a significant effect on the carbon speciation in the Western Tianshan subduction zone.The prograde oxygen fugacity of the Western Tianshan subduction zone was constrained by mineral assemblage of garnet-omphacite from FMQ-1.9 to FMQ-2.5 at its metamorphic peak(maximum P-T) conditions.In comparison with redox conditions of other subduction zones,Western Tianshan has the lowest oxygen fugacity.Graphite and light hydrocarbon inclusions were ubiqutously identified in Western Tianshan HP metamorphic rocks and speculated to be formed from reduction of Fe-carbonate at low redox condition,which is also confirmed by high-pressure experimental simulation.Based on petrological observation and high-pressure simulation,a polarized redox model of reducing slab but oxidizing mantle wedge in subduction zone is proposed,and its effect on deep carbon cycle in subduction zones is further discussed.  相似文献   

利用偏光显微镜反射光系统观察黑色生油岩电子探针薄片中的生烃母质特征     

郑庆华  刘行军  刘乔  梁秀玲  张小龙  左琴  杨开艳  马婷  许锋 《岩矿测试》2020,39(3):442-450

鄂尔多斯盆地上三叠统延长组长7油层组的黑色泥岩、油页岩等黑色生油岩薄片中的生烃母质,因黑色石油、沥青等黑色有机质的覆盖或不透明,导致其在偏光显微镜透射光系统下观察常局部或整体呈现为黑色。因此,建立一种黑色生油岩薄片中生烃母质有效观察的方法,对致密油、页岩油的生烃研究具有重要的理论和实际意义。本文提出了一种利用电子探针薄片和偏光显微镜的反射光系统观察黑色生油岩中生烃母质特征的方法。该方法能够克服黑色生油岩薄片中生烃母质因被黑色有机质覆盖或不透明,而在偏光显微镜的透射光系统下局部或整体呈黑色的弊端,能够对生烃母质的大小、形态、结构、分布和物质成分等特征进行整体且清晰的观察。实践表明,本文提出的利用偏光显微镜反射光系统观察黑色生油岩电子探针薄片中生烃母质特征的方法,简单有效,易在致密油、页岩油的生烃研究领域推广使用。  相似文献   

Relationship Between Electrical Properties and Sedimentary Environment of the Longmaxi Formation Shale, Southern Sichuan     

YANG Kai  ZHANG Bing  WANG Xuben  HE Lanfang  YANG Hongyu  WANG Pengwan  TANG Jialin  DENG Jixin  ZHANG Cong 《《地质学报》英文版》2020,94(5):1531-1546

The Lower Silurian Longmaxi Formation in the south of Sichuan is a key player in the exploration and development of shale gas in China. Due to a highly complex topographic area, electromagnetic methods (EM) become important exploration means in this area. Many studies have been conducted on the shale mineral composition and electrical properties of shale, however, the correlation between sedimentary environments and the electrical properties of shale remain poorly understood. The electrical properties and sedimentary environment of the organic-rich shale of the Longmaxi Formation have been studied by means of X-ray diffraction, organic geochemistry, scanning electron microscopy and complex resistivity measurements. The discovered high quartz content of the Longmaxi Formation shale results in low resistivity. Deep-water shelf biogenic quartz contributes lower resistivity more than that of shallow-water terrigenous quartz. The deep-water anoxic and organic sedimentary environment led to major enrichment of pyrite, leading to a high polarization effect in shale. We present the correlation between the lithofacies types and electrical properties of Longmaxi Formation. The mixed siliceous shale lithofacies is the most favorable among the three lithofacies, which is characterized by high total organic carbon (TOC) content, high brittleness mineral content, high polarization and low resistivity (“three high and one low”). This feature is an effective identification of shale gas reservoirs by electromagnetic prospecting. Our study can provide constraints on electrical parameters of rocks for electromagnetic “sweet spot” exploration of shale gas, and so this has important geological significance to shale gas exploration and development.  相似文献   

岩溶水硝酸盐污染原位修复试验     

叶进霞  夏春英  卜鸿志 《中国岩溶》2020,39(2):173-179

岩溶含水层的极不均一性特征使岩溶水溶质运移受构造、裂隙空间及其发育方向控制；因环境条件复杂，开展岩溶水污染原位修复技术难度较大，截止目前，国内尚未系统地开展岩溶含水层水污染原位修复研究工作。文章选择鲁中南山区典型岩溶发育及硝酸盐污染地段，施工组合钻孔建设修复试验工程，采用“乙醇+葡萄糖”液态碳源和“聚乙烯醇+淀粉颗粒”固态反应器分别进行岩溶水硝酸盐污染原位修复试验。结果表明:浓度500 mg?L－1、1 000 mg?L－1的“乙醇+葡萄糖”反硝化溶液对硝酸盐浓度的降解率分别为6.45 %和21.52 %；单位长度组成材料“聚乙烯醇3 kg+淀粉颗粒3 kg”、“聚乙烯醇2 kg+淀粉颗粒4 kg”的两种反硝化固态反应器对硝酸盐浓度的降解率分为33.91%和34.96%。试验证明在裂隙型岩溶地区采用孔组方案进行地下水污染原位修复技术可行、且能取得较显著效果。修复工程布设方式和试验成果对类似地区开展岩溶地下水污染原位修复具一定借鉴意义。   相似文献   

Post-earthquake economic resilience and recovery efficiency in the border areas of the Tibetan Plateau: A case study of areas affected by the Wenchuan Ms 8.0 Earthquake in Sichuan,China in 2008     

Zhou  Kan  Liu  Baoyin  Fan  Jie 《地理学报(英文版)》2020,30(8):1363-1381

Journal of Geographical Sciences - The border areas of the Tibetan Plateau and the neighboring mountainous areas have a high incidence of earthquakes with a magnitude greater than Ms 5.0, as well...  相似文献   

广西土壤有机质空间变异特征及其影响因素研究   总被引：2，自引：0，他引：2  

钟聪  李小洁  何园燕  邱微文  李杰  张新英  胡宝清 《地理科学》2020,40(3):478-485

基于广西第二次土壤普查的270个土壤剖面资料,结合1∶50万数字化土壤类型图、土地利用类型图和气象监测数据等资料,利用地统计学和逐步回归分析等方法对广西表层土壤有机质空间变异特征及其影响因素进行了探究。结果表明：广西表层土壤有机质平均含量为3.11±2.19%,变异系数为70.72%,空间分布呈北高南低的趋势。广西表层土壤有机质空间分布受到自然和人为因素的共同影响,土壤类型、成土母质、海拔、土地利用、气候和坡度6个环境因子对全区土壤有机质含量变异的综合解释能力为47.9%。其中,土壤类型是最重要的影响因素,能独立解释其变异的36.0%,海拔和成土母质分别能独立解释28.5%和15.8%。气温对广西土壤有机质空间分布的影响比降水量更加显著,从而造成了广西土壤有机质整体呈南低北高的趋势。同时,土壤有机质对气温的敏感性在一定程度上受到降雨量的制约。此外,研究区农业耕作管理等因素对土壤有机质的影响也不容忽视。  相似文献   

用比电导法研究活性炭的吸附特性     

陈以良 《广东海洋大学学报》1992,(1)

用比电导法研究两种活性炭自稀水溶液中吸附强电解质硫酸铬和硫酸铜的吸附平衡特性。结果表明,在本文的研究条件下,两种活性炭对硫酸铬和硫酸铜都有吸附作用。同时,活性炭吸附硫酸铜的吸附平衡特性可以用 Freundlich 方程式来描述。研究的结果对固体在溶液中的吸附基础理论以及处理工业废水具有一定的意义。  相似文献   

一种基于自证明公钥的可公开验证的认证加密方案     

彭银桥  甘元驹  邓锐  彭凌西  陈月峰 《广东海洋大学学报》2005,25(3):73-75

针对现有的基于证书的认证加密方案通信量和计算量大的缺点,提出了基于自证明公钥的可公开验证的认证加密方案。详细阐述了方案的系统初始化、签名生成、消息恢复验证以及公开验证4个阶段,方案的安全性是基于求解离散对数的困难性(DLP)和强单向hash函数(OWFH)的不可逆。该方案在没有签名者的协作下,任何验证者都可验证签名者的诚实性,在验证签名的同时可认证签名者的公钥,因而减少了存储空间、通信量和计算量。  相似文献   

Biological and granulometric controls on sedimentary organic matter of an intertidal mudflat     

Lawrence M. Mayer  Peter T. Rahaim  William Guerin  Stephen A. Macko  Les Watling  Franz E. Anderson 《Estuarine, Coastal and Shelf Science》1985,20(4):491-503

A variety of measures of organic matter concentration and quality were made on samples collected from the top few mm of intertidal mudflat sediment over the course of a year, in order to assess the relative importance of biological and sedimentological influences on sedimentary organic matter. Winter and summer were times of relatively fine-grained sediment accumulation, caused by biological deposition or stabilization processes and resulting in higher organic matter concentrations. Stable carbon isotope and Br:C ratios indicated a planktonic source of bulk organic matter. Ratios of organic carbon to specific surface area of the sediments were consistent with an organic monolayer coverage of sediment grains. Correction for changing grain size during the year showed no change in the organic concentration per unit surface area, in spite of organic matter inputs by in situ primary production, buildup of heterotroph biomass and mucus coatings, and biodeposition of organic-rich seston. There were also no indications of changes in bulk organic quality, measured as hydrolyzable carbohydrates and amino acids, in response to these biological processes. It is concluded that biological processes on a seasonal time scale affect the bulk organic matter of these sediments via a modulation of grain size rather than creation or decay of organic matter.  相似文献