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1.
This paper presents a set of bulk geochemical and mineralogical data from a paleoweathering profile located in Zunyi District, Northern Guizhou, China. It was formed at the top of the Hanjiadian Formation of the Lower Silurian. A truncated, argillic, gleyed, kryptic paleospodosol is recognized in the paleoweathering profile. Ratios of immobile elements (Ti/Zr, Ti/Al) and their binary (e.g., Nb vs. Zr/TiO2 and Th/Sc vs. Zr/Sc), triangular diagrams (La-Th-Sc, Th-Sc-Zr/10, Zr-Cr-Ga) reflect that the Gaojiayan paleosol is the product of in-situ weathering of gray-green silty mudstone of the underlying Hanjiadian Formation. Mass balance calculations indicate K enrichment and Na enrichment in the upper and lower portions of paleosol, respectively. These findings both are the results of transgression, which brings substantial concentrations of such elements as K, Na, and Sr. In particular, K enrichment is achieved by the illitization of kaolinite. The biological processes of terrestrial vascular plants also enhance K concentration, especially at the top of the paleosol. Na enrichment is a consequence of albitization and/or adsorption by clay minerals through cation exchange. The mass distributions and relative mass changes of rare earth elements (REEs) in the studied profile display characteristics of vertical zonation. Three peaks in total REEs content are observed, indicating two paleoclimatic or paleoenvironmental changes. Mineralogical characteristics indicate that the paleoclimate changed first from warm and humid to cold and dry and later, to dry and lightly warmer. The corresponding soil environment varies from weakly acidic to strongly alkaline and later, to weakly acidic. Mass translocation characteristics of REEs and several transition metals suggest that the Gaojiayan paleosol may have undergone top erosion.  相似文献   
2.
江苏东南部启东地区开展的1∶5万区域地质调查工作已经完成野外工作验收,通过整理分析新获取的地质资料,发现工作区内"下切河谷"地区地表下46~59 m处普遍存在棕黄色、灰绿色、灰黑色"硬黏土层",厚度2~10 m不等;局部地区钻孔岩心剖面在本层顶部表现为明显的古土壤层,见根痕构造、钙质结核等暴露成土特征,其下部可见灰黑色富有机质、植物碎屑的粉砂质黏土层。古土壤层的发现证明了本区在末次盛冰期并不完全为下切河谷地区,更新了前人对测区晚更新世末期沉积地层的认识;而厚度0.5~2 m不等的富有机质、植物碎屑的粉砂质黏土层为本区浅层天然气提供了气源。  相似文献   
3.
The loess-paleosol sequences of the last 1.2 Ma in China have recorded two kinds of climate extremes: the strongly developed S4, S5-1 and S5-3 soils (corresponding to the marine δ18O stages 11, 13, and 15, respectively) as evidence of three episodes of great warmth and two coarse-grained loess units (L9 and L15, corresponding to the marine δ18O stages 22, 23, 24 and 38, respectively) which indicate severest glacial conditions. The climatic and geographical significance of these events are still unclear, and their cause remains a puzzle.Paleopedological, geochemical and magnetic susceptibility data from three loess sections (Xifeng, Changwu and Weinan) suggest that the S4, S5-1 and S5-3 soils were formed under sub-tropical semi-humid climates with a tentatively estimated mean annual temperature (MAT) of at least 4–6°C higher and a mean annual precipitation (MAP) of 200–300 mm higher than for the present-day, indicating a much strengthened summer monsoon. The annual rainfall was particularly accentuated for the southern-most part of the Loess Plateau, suggesting that the monsoon rain belt (the contact of the monsoonal northward warm-humid air mass with the dry-cold southward one) might have stood at the southern part of the Plateau for a relatively long period each year. The loess units L9 and L15 were deposited under semi-desertic environments with a tentatively estimated MAT and MAP of only about 1.5–3°C and 150–250 mm, indicating a much strengthened winter monsoon, and that the summer monsoon front could rarely penetrate into the Loess Plateau region.Correlation with marine carbon isotope records suggests that these climate extremes have large regional, even global, significance rather than being local phenomena in China. They match the periods with greatest/smallest Atlantic–Pacific δ13C gradients, respectively, indicating their relationships with the strength of Deep Water (NADW) production in the North Atlantic. These results suggest that the monsoon climate in the Loess Plateau region was significantly linked with the North Atlantic thermohaline circulation on timescales of 104 years.  相似文献   
4.
A number of fine-grained sericite bearing pelitic, schistose lithologies occur along the Archean (Banded Gneiss Complex)-Proterozoic (Aravalli Supergroup) contact (APC) in the Udaipur valley in NW Indian craton. These Al-rich lithologies (subsequently metamorphosed) have been described as ‘paleosols’, developed over a 3.3 Ga old Archean gneissic basement and are overlain by Paleoproterozoic Aravalli quartzite. The paleosol was developed between 2.5 and 2.1, coincident with the globally recognized Great Oxidation Event (GOE). In previous studies these paleosol sections were interpreted to have developed under reducing environment, however, the finding of a ‘ferricrete’ zone in the upper part of Tulsi Namla section (east of Udaipur) during the present study (in addition to earlier reported lithologies) has led to an alternative suggestion of oxygen-rich conditions during paleosol development. The Tulsi Namla paleosol section shows all the features characteristic of a complete paleosol section described from other Archean cratons. The paleosol includes sericite schist with kyanite as the prevalent Al-silicate in the lower part of profile while chloritoid and Fe-oxides typify the Fe-rich upper part. Alumina has remained immobile during the weathering process while Fe and Mn show a decrease in the lower part of the section and an abrupt rise in the upper part, in the ferricrete zone. The field and geochemical data indicate that the Tulsi Namla section is an in situ weathering profile and at least the upper part shows evidence of oxidizing conditions.  相似文献   
5.
水成沉积与风成沉积及古土壤的磁组构特征   总被引:14,自引:2,他引:14  
晚第四纪水成沉积、风成沉积、古土壤等的磁组构研究表明,不同成因的沉积物具有明显不同的磁组构特征。一般地,水成沉积的体积磁化率K受物源和水动力因素控制,P和F均>1.02,q<0.5;风成沉积的K受物源控制,内陆黄土的K明显高于沿海黄土及海岸风沙K,P和F均<1.02,q的平均值>0.55;古土壤的K受母质沉积类型和成土环境的氧化还原条件控制,内陆古土壤的K偏高,沿海古土壤的K偏低,内陆古土壤的K远高于沿海古土壤的K,P和F均<1.02,q的平均值在0.5左右。运用典型沉积的磁组构特征对比分析未知沉积物,可以得到未知沉积物的物源、沉积过程和环境信息。  相似文献   
6.
离子色谱分析在黄土和粉尘研究中的应用   总被引:1,自引:0,他引:1  
黄土中存在着大量的碱金属及碱土金属,以往的测试方法多为原子吸收和ICP—MS,离子色谱法在测试黄土样品的碱金属和碱土金属元素含量中应用不多。将黄土地质标准样品进行消解后用离子色谱进行测试,测试效果良好,重复测试的相对标准偏差小于5%,与推荐值的相对误差小于5%,准确度和精密度符舍相关的质量控制要求。本实验方法测试的离子含量都在仪器响应呈线性的最佳测试范围之内,标准曲线经回归后相关系数均达到0.9999。黄土样品的分析结果与粉尘气溶胶样品的离子分析结果对比表明,此方法对于探讨粉尘起源以及沙尘暴天气的研究具有重要意义。  相似文献   
7.
西峰地区晚第三纪红土稀土元素的初步研究   总被引:9,自引:1,他引:9  
本文基于对甘肃西峰地区晚第三纪红土和第四纪风成黄土及古土壤稀土元素的分析,揭示出红土稀土元素丰度与黄土及古土壤相比变化范围较大,可能与碳酸盐的相对淋溶与沉积有关;红土∑LREE/∑HREE值明显低于黄土,批示着一定程度的风化作用;而稀土参数δEu、δCe等变化不大,红土、黄土和古土壤稀土模式具有很大的一致性,特别是将红土的稀土元素丰度用碳酸盐校正后,这个特点更加明显,反映了红土与第四纪黄土和古土致  相似文献   
8.
PALEOSOLSOFSANDYLANDSANDENVIRONMENTALCHANGESINTHEWESTERNPARTOFNORTHEASTPLAINOFCHINAWESTERNDURINGHOLOCENE¥QiuShanwen(裘善文)LiQus...  相似文献   
9.
Morphological characteristics and microstructures of magnetic minerals extracted from Chinese loess and paleosols were investigated using powder X-ray diffraction (XRD) and high-resolution transmission electron microscopy (HRTEM). Our results indicate that maghemite in loess–paleosol sequences was transformed from magnetite through oxidation of magnetite. Maghemite transformed from eolian magnetite during chemical weathering has low-angle grain boundaries among maghemite nano-crystals. Some nano-crystalline maghemites with nanoporous texture resulted from microbe-induced precipitation of magnetite or transformation of poorly crystalline ferric Fe (oxy)hydroxides in presence of Fe-reducing bacteria. Aggregates of euhedral maghemite nano-crystals were transformed from magnetite magnetosomes. Both microbe-induced nanoporous magnetite and microbe-produced magnetite magnetosomes are directly related to microbial activities and pedogenesis of the paleosols. It is proposed that the formation of nano-crystalline maghemite with superparamagnetic property in paleosol results in the enhancement of magnetic susceptibility, although the total amount (weight percent) of magnetic minerals in both paleosol and loess units is similar. Our results also show that nano-crystalline and nanoporous magnetite grains prefer to transform into maghemite in semi-arid soil environments instead of hematite, although hematite is a thermodynamically stable phase. This result also indicates that a decrease in crystal size will increase stability of maghemite. It is also inferred that surface energy of maghemite is lower than that of hematite.  相似文献   
10.
季峻峰  陈骏  王洪涛 《地质论评》1997,43(2):181-185
伊利石是我国黄土和古土壤中最主要的粘土矿物。本文选择陕西洛川黄土-古土壤国际典型剖面为研究对象,通过测定伊利石的结晶度(Kubler指数)、Srodon峰强比值(Ir)和2M_1多型含量,发现黄土物质的起源与中高温(>280℃)地质环境有关;黄土样品中伊利石结晶度值为0.25°2θ(Cu Ka),古土壤样品中伊利石结晶度值大于0.27°2θ(Cu Ka);黄土和古土壤中伊利石结晶度值的差别,是由于古土壤中伊利石含少量的膨胀层,而黄土样品中的伊利石不含有膨胀层而引起的。古土壤中伊利石的膨胀层的成因,与伊利石  相似文献   
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