Extraction of Lithium from Salt Lake Brine using N523-TBP Mixture System   总被引：1，自引：1，他引：0       下载免费PDF全文

SHI Dong  LI Li-juan  LI Jin-feng  JI Lian-min  SONG Fu-gen  PENG Xiao-wu  ZHANG Li-cheng  ZHANG Yu-ze  LI Hui-fang  SONG Xue-xue  NIE Feng  ZENG Zhong-min  LIU Zhi-qi  GUO Fan 《盐湖研究》2019,27(2):95-110

In this work,problems encountered by tri-butyl phosphate( TBP) in the industrialization of lithium extraction from salt lake brine were discussed in detail. The behavior of N,N-bi-( 2-ethylhexyl) acetamide( N523) during lithium extraction was investigated,and its disadvantages were analyzed in the view of practical application. An N523-TBP mixture extraction system was proposed to alleviate or avoid the defects that N523 and TBP met when they were used separately. The optimal composition of this mixture extraction system was determined to be 20% N523-30% TBP-50% kerosene.The effects of brine acidity,Fe/Li molarity ratio,phase ratio and chloride ion concentration on lithium extraction efficiency were discussed. The operation conditions in single-stage extraction were optimized as brine acidity = 0. 05 mol/L,Fe/Li molarity ratio = 1. 3,and phase ratio = 2. The high concentration of chloride ions in brine was beneficial for the extraction of lithium. The structure of the extracted complex was proposed as( LiFeCl_4·n N523·m TBP)·( 2-n) N523·( 2-m) TBP( m + n = 2) by chemical analysis and slope-fitting methods. The extraction thermodynamic functions were calculated preliminarily,and the results suggested that the extraction process was an exothermic( ΔH 0) and spontaneous( ΔG 0) reaction,and the degree of disorder increased( ΔS 0) during the extraction process. This work will give some guidance to the lithium industry of Qinghai in both the fundamental theory and practical application.  相似文献   

基于GeoStudio的边坡稳定性分析及支护方案选择的理论探讨     

何保  宋帅 《地质与勘探》2019,55(5):1329-1335

本文选择大连市中山区长利巷地区的边坡,通过现场采取岩土样,进行室内试验得出各地层力学物理参数,对边坡进行稳定性分析。针对目前所拥有的模拟软件与方法,分析并筛选出适合该边坡的模拟软件。利用GeoStudio软件建模、模拟,使用Morgenstern-Price方法进行计算,通过分析得到计算结果,该边坡的安全安全系数为1. 127,认为其属于不稳定边坡。对于不稳定边坡,本文对主流的边坡支护方法进行分析筛选,拟采用扶壁式挡土墙支护方案对其进行预防。根据规范设计挡土墙尺寸,并对该挡土墙进行抗倾覆抗滑移验算,得出的验算安全系数满足规范要求,由此可得知该支护方案方法合理,技术可行。  相似文献   

考虑冲刷影响的筒型基础竖向极限承载力研究     

陆罗观  刘润  练继建  陈广思 《海洋工程》2019,37(3):69-77

大直径宽浅式筒型基础,阻水宽度大,在位工作期间受波浪海流作用,其周围土体易被冲刷。为研究单侧地基土体受冲刷后筒型基础的竖向极限承载力变化,通过引进冲刷率的概念,采用有限元方法研究了不同冲刷率下筒型基础的竖向极限承载力;并基于Meyerhof理论建立了计算不同冲刷率下筒型基础竖向极限承载力的极限平衡方法。研究结果表明,随着冲刷率增大,筒型基础的极限承载力出现不同程度的下降,当冲刷率为0.8时,即筒型基础单侧土体冲刷深度达6.4 m时,筒型基础的竖向极限承载力折减率为3.28%。建立的极限平衡算法可准确计算冲刷条件下筒型基础的竖向极限承载力。  相似文献   

SIMULATION STUDY OF ROAD-CUT EFFECTS ON SLOPE STABILITY     

CHEN Xiao-li  WANG Ming-ming  ZHANG Ling 《地震地质》2018,40(6):1390-1401

Landslides and rock falls along the highway are common geological hazards in Southwest China. As an influencing factor on potential landslides behavior, roads or distance to roads have been successfully used in landslide susceptibility assessments in mountainous area. However, the relationship between the road-cut and the slope stability is not clear. Therefore, we performed two-dimensional slope stability calculation using the general limit equilibrium (GLE)method incorporated in the software SLOPE/W of GeoStudio for stability analysis of slopes. Our studies show that the man-made roads influence on the slope stability mainly exists in two ways:One is to create a new steep slope, which will result in rock falls and shallow landslides along the roads; the other is to influence the stability of the original slope, which will result in comparatively huge landslides. For the latter, our simulation study reveals that the road location, namely at which part of a natural slope to construct a road is important for the slope stability. For a natural slope with a potential slip surface, if a road is constructed at or near the slope toe where the potential slip surface surpasses, it will greatly degrade the slope's factor of safety (Fs) and make the slope unstable; however, if a rode-cut is near the top of the slope, it will increase the slope's Fs and make the slope more stable. The safety location is different for different slope angle, steeper slope needs a higher location for a safety road-cut in comparison with gentle slopes. Moreover, the slope stability decreases when loading a seismic force and it varies with the slope angle. Firstly, the Fs decreases when the slope angle increasing, and when the slope angle reaches 45°, the Fs then becomes greater with the slope angle increasing.  相似文献   

天津滨海爆炸事件检测与相对定位研究     

邓莉  谭毅培  刘双庆  马婷  卞真付  曹井泉 《地震》2018,38(3):158-169

2015年8月12日发生在天津滨海新区的化学品爆炸事故造成了严重的人员伤亡和财产损失。 基于区域地震台网记录的数字化连续地震波形资料, 对爆炸发生过程的精细分析是深入调查爆炸事故发生原因、 快速估计事故所造成灾害与损失的重要手段之一。 本文首先利用震相到时和质点运动轨迹信息对记录波形中能量较强的震相性质进行分析, 再通过模板匹配算法检测爆炸过程中是否存在两次大爆炸以外的小爆炸事件, 并对检测方法的效能进行检验, 最后依据波形互相关得到的震相到时差估计两次较大爆炸的相对位置。 计算结果显示区域台网记录波形中能量最大的体波震相可能为沿沉积层顶部传播的Pg震相, 垂直向能量最强的面波震相为Rg震相, 而能量较弱的初至震相可能为结晶基底首波; 爆炸过程中除了两次能量较大的爆炸以外还能检测到两次较小的爆炸事件, 其当量相当于约M_L0.5的地震; 基于两次大爆炸Pg震相相对到时信息得到第二次大爆炸发生在第一次大爆炸的北西侧, 两次爆炸位置距离约50~55 m。 本文研究结果为爆炸事故的调查分析提供了地震学依据。  相似文献   

New constraints on granulite facies metamorphism and melt production in the Lewisian Complex,northwest Scotland          下载免费PDF全文

Yves Feisel  Richard W. White  Richard M. Palin  Tim E. Johnson 《Journal of Metamorphic Geology》2018,36(6):799-819

In this study, we investigate the metamorphic history of the Assynt and Gruinard blocks of the Archean Lewisian Complex, northwest Scotland, which are considered by some to represent discrete crustal terranes. For samples of mafic and intermediate rocks, phase diagrams were constructed in the Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–O₂ (NCKFMASHTO) system using whole‐rock compositions. Our results indicate that all samples equilibrated at similar peak metamorphic conditions of ~8–10 kbar and ~900–1,000°C, consistent with field evidence for in situ partial melting and the classic interpretation of the central region of the Lewisian Complex as representing a single crustal block. Melt‐reintegration modelling was employed in order to estimate probable protolith compositions. Phase equilibria calculated for these modelled undepleted precursors match well with those determined for a subsolidus amphibolite from Gairloch in the southern region of the Lewisian Complex. Both subsolidus lithologies exhibit similar phase relations and potential melt fertility, with both expected to produce orthopyroxene‐bearing hornblende granulites, with or without garnet, at the conditions inferred for the Badcallian metamorphic peak. For fully hydrated protoliths, prograde melting is predicted to first occur at ~620°C and ~9.5 kbar, with up to 45% partial melt predicted to form at peak conditions in a closed‐system environment. Partial melts calculated for both compositions between 610 and 1,050°C are mostly trondhjemitic. Although the melt‐reintegrated granulite is predicted to produce more potassic (granitic) melts at ~700–900°C, the modelled melts are consistent with the measured compositions of felsic sheets from the central region Lewisian Complex.  相似文献   

载波/多普勒平滑伪距在Android手机中的定位实现     

张书维  高井祥  赵龙  李增科 《测绘通报》2020,(4):63-67

针对Android手机GNSS伪距定位精度较低的问题，利用手机端观测信息，通过载波相位/多普勒平滑伪距改善手机端伪距观测值的质量，从而达到提高定位精度的效果。首先给出了Android手机GNSS原始观测量的获取方法，然后推导了载波相位平滑伪距和多普勒平滑伪距算法模型，并设计合理有效的试验对算法的精度进行评定。试验结果表明：在手机端静态定位中载波相位和多普勒平滑算法均可提高原始伪距的定位精度，且多普勒平滑算法表现更优；在手机端动态定位中多普勒平滑算法可获得比原始伪距更优的定位精度，但是载波相位平滑算法较原始伪距更差；由于硬件的制约手机端周跳和信号失锁严重，占比超过50%，载波相位在手机端的可用性较低；多普勒平滑算法的最优平滑时间常数小于等于10 s，具有实时动态定位的巨大潜力。  相似文献   

区域地震台网历史震相数据整合与共享服务     

刘伟  王庆良  王丽艳  柴旭超  王文青  朱飞鸿 《地震地磁观测与研究》2020,41(5):200-208

区域地震台网震相数据是区域地震台网产出的重要成果，是开展地球科学研究的重要资料。整理全国31个省份1973-2008年区域地震台网纸质震相报告和地震卡片，按统一格式录入震相数据，建立数据共享服务系统。文中系统阐述区域地震台网的发展过程、历史震相数据的整合、地震观测报告的主要内容及震级的测定方法，并介绍了历史震相数据共享服务系统和快速索引下载方法，为科研人员提供共享服务。  相似文献   

2017年6月3日阿拉善左旗5.0级地震震源深度测定   总被引：1，自引：1，他引：0  

郝美仙  宋晓燕  徐岩  翟浩 《地震地磁观测与研究》2018,39(2):18-24

2017年6月3日18时11分内蒙古阿拉善左旗（37.99° N，103.56° E）发生5.0级地震，利用近震深度震相sPL测定法、CAP波形反演法、sPn与Pn震相走时差法，进行震源深度精确测定。研究结果表明，3种方法测得的该地震震源深度基本一致，分布范围为8.5—11 km，表明该地震发生在上地壳。  相似文献   

西安地震台极远震震相记录特征     

冯红武  王建昌  颜文华 《地震地磁观测与研究》2018,39(6):120-129

以西安地震台记录的2001-2018年13次6级以上极远震为研究对象，依据AK135走时表进行震相分析，总结归纳典型极远震震相记录特征，以期提高震相分析水平和测震分析工作质量，为其他地震台站极远震分析工作提供借鉴。  相似文献