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浙江泰顺龟湖叶腊石矿床热液蚀变短波红外光谱分析 总被引:1,自引:0,他引:1
蚀变岩帽与斑岩体关系密切,具有形成斑岩-浅成低温热液型矿床的潜力。位于浙闽交界的龟湖地区发育规模巨大的蚀变岩帽(>30 km2),形成了龟湖超大型叶腊石矿床,矿体属于岩帽的一个分带。矿床及其围岩蚀变主要由粒度微小或隐晶质的层状硅酸盐蚀变矿物组成,矿物之间差别极为细微,仅凭肉眼难以区分。短波红外光谱技术可以有效识别这些蚀变矿物的组成。因此,文章以龟湖超大型叶腊石矿床为例,通过短波红外光谱测量,对蚀变矿物进行了精细研究,通过对矿区网格化采样及短波红外光谱分析,识别出以叶腊石、钠云母、白云母、高岭石为主的17种含羟基官能团蚀变矿物,并将矿区地表蚀变划分为硅化带、高级泥化带和泥化带3个相带。在矿区范围,绢云母光谱特征参数Pos2200低值区与IC高值区主要分布在硅化和高级泥化带中,指示了较高的蚀变温度;叶腊石光谱特征参数Pos1400与Pos2160半高宽低值区与绢云母特征参数异常值区域一致。以上指标异常值区域在矿区仰天湖东南约300 m处重合,可能存在热液中心。龟湖蚀变岩帽与福建紫金山高硫型浅成低温热液矿床具有高度相似的蚀变分带特征,文章认为该蚀变岩帽具有形成斑岩-浅成低温热液矿床的潜... 相似文献
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Tetsuichi TAKAGI Sang–Mo KOH Moon–Young KIM Kazuki NAITO Sadahisa SUDO 《Resource Geology》2000,50(4):243-256
Abstract: The Milyang pyrophyllite deposit, which is embedded in the Late Cretaceous Yuchon Group of the Kyongsang Supergroup, is one of the largest hydrothermal clay deposits in the Kyongsang basin, southeast Korea. Host rocks of the deposit are porphyritic andesite lava and minor andesitic lapilli tuff. In the Milyang district, a hydrothermally altered zone is about 2 × 3 km in extent; we can recognize the concentric arrangement of advanced argillic, propylitic, and sericitic alteration zones from the central to peripheral parts of the zone. The Milyang pyrophyllite deposit forms a part of the advanced argillic alteration zone. The Milyang pyrophyllite deposit is subdivided into the following four zones based on mineral assemblages: the pyrophyllite zones 1, 2, 3, and the silicified zone. The pyrophyllite zone 1, which occupies the central part of the deposit, comprises mainly pyrophyllite, kaolinite, and diaspore without quartz. Diaspore nodules often concentrate in beds 40–50 cm thick. Andalusite, dumortierite, and tourmaline locally occur as network veins, crack‐filler, or small spherulitic spots. The Al2O3 content of the ore ranges from 27 to 36 wt%. The pyrophyllite zone 2, which constitutes a major part of the deposit, comprises mainly pyrophyllite, kaolinite, and quartz. The Al2O3 content of the ore ranges from 15 to 24 wt%. The pyro‐phyllite zone 3 is the hematite‐rich marginal facies of the deposit. The silicified zone, which occurs as beds and septa, is mostly composed of quartz with minor pyrophyllite and kaolinite; the SiO2 contents range from 79 to 90 wt%. Comparing chemical compositions of the high‐Al ores with those of unaltered host andesite, the Fe, Ca, alkalis, HFSE, and HREE contents are significantly depleted, whereas S, B, As, Sr, and LREE are enriched. The hydrothermal alteration of the Milyang pyrophyllite deposit can be classified into the following four stages: 1) extensive sericitic and propylitic alteration, 2) medium‐temperature (200–250°C) advanced argillic alteration, 3) high‐temperature (250–350°C or more) advanced argillic alteration, and 4) retrograde low‐temperature alteration. The heat and some volatile components such as B and S would be derived from the Pulguksa Granite intruded underneath the deposit. 相似文献
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本文对Ni40Mn30Fe30合金与在不同焙烧温度下得到的含水叶蜡,在高温超高压下的反应进行了实验研究,温度测至1420℃,压是至5.5GPa,研究了该反应的物质-化学机制,以及反应速率与温度,压力,含水量等参数的关系,对高压下物质迁移运动的固有特征进行了探讨。 相似文献
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天然叶蜡石及其热处理产物的电子顺磁共振(EPR)研究 总被引:7,自引:2,他引:7
利用EPR研究了18个天然叶蜡石样及其4个热处理产物。发现天然叶蜡石有三个EPR吸收带:A(g有效≈11.4),B(g有效≈4.3)和C(g有效≈2.0),其中A是叶蜡石的特征谱。A在>400℃热处理时与B在强度上呈消长关系;<400℃热处理时A和B均随温度升高而加强;900℃时A消失,B的强度远远大于原样中的A;C附有超精细结构谱(g″=2.04,g┴=1.96,A″≈A┴=19.5×10^-4T),C在热处理时呈现复杂的变化。结果表明,A吸收带属于叶蜡石八面体AI(Fe)-O4(OH)2中的Fe^3 ,B吸收带归于八面体AI(Fe)-O2(OH)4中的Fe^3 ,C吸收带是无机自由基(如AI-O^-Si)和有机自由基的叠加谱;900℃热处理后八面体层中配位发生了变化:AI(Fe)-O4(OH2)→AI(Fe)-O5 H2O↑,AI(Fe)-O2(OH)4→AI(Fe)-O4 H2O↑;类质同象置换AI^3 的不仅有Fe^3 ,而且有Fe^2 离子。 相似文献
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叶蜡石、高岭石和迪开石的吸收光谱研究 总被引:3,自引:0,他引:3
对不同地区叶蜡石、高岭石、迪开石的吸收光谱测量及其高斯谱拟合说明,三各矿物的吸收光谱均由一个吸收边和三个吸收峰叠加而成。主吸收峰在562nm左右,峰高以迪开石为最大,高岭石次之,叶蜡石最低。同一地区不同颜色的叶蜡石,其主吸收峰位置随铁含量的增加向短波方向移动,相对峰高也随之增大。叶蜡石的颜色主要取决于主吸收峰的位置、高度和吸收边位置。可以认为,此吸收边为Fe^3 →O^2-荷移谱的低能拖尾部分,吸收峰则为铁离子的晶场谱带或晶场谱与Fe^2 →Fe^3 荷移的叠加。 相似文献
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X射线荧光光谱法测定叶腊石中的铝铁钾钠 总被引:1,自引:0,他引:1
采用同一矿区已知成分含量的叶腊石配制标样系列,克服了粉末法测定叶腊石中Al2O3,Fe2O3,K2O,Na2O的矿物和粒度效应。分析结果准确度满足出口材料的检测要求。 相似文献