First Multi‐Isotopic (Pb‐Nd‐Sr‐Zn‐Cu‐Fe) Characterisation of Dust Reference Materials (ATD and BCR‐723): A Multi‐Column Chromatographic Method Optimised to Trace Mineral and Anthropogenic Dust Sources     

Aubry Vanderstraeten  Steeve Bonneville  Stefania Gili  Jeroen de Jong  Wendy Debouge  Philippe Claeys  Nadine Mattielli 《Geostandards and Geoanalytical Research》2020,44(2):307-329

Atmospheric dust is an integral component of the Earth system with major implications for the climate, biosphere and public health. In this context, identifying and quantifying the provenance and the processes generating the various types of dust found in the atmosphere is paramount. Isotopic signatures of Pb, Nd, Sr, Zn, Cu and Fe are commonly used as sensitive geochemical tracers. However, their combined use is limited by the lack of (a) a dedicated chromatographic protocol to separate the six elements of interest for low‐mass samples and (b) specific reference materials for dust. Indeed, our work shows that USGS rock reference materials BHVO‐2, AGV‐2 and G‐2 are not applicable as substitute reference materials for dust. We characterised the isotopic signatures of these six elements in dust reference materials ATD and BCR‐723, representatives of natural and urban environments, respectively. To achieve this, we developed a specific procedure for dust, applicable in the 4–25 mg mass range, to separate the six elements using a multi‐column ion‐exchange chromatographic method and MC‐ICP‐MS measurements.  相似文献   

凤太矿集区东塘子铅锌矿床S、Pb同位素组成对成矿物质来源的示踪     

张革利  田涛  王瑞廷  高卫宏  常宗东 《中国地质》2020,47(2):472-484

东塘子铅锌矿床是秦岭成矿带中典型的铅锌矿床之一,前人对东塘子铅锌矿床成矿作用研究较多,但受限于测试手段及认识的局限性,多年来对其物质来源的认识仍未统一。本文在充分研究东塘子铅锌矿床地质特征的基础上,开展了相关样品的S、Pb同位素分析,分析对象包括了不同类型的铅锌矿石,讨论了该铅锌矿床的成矿物质来源、区内岩浆岩与铅锌成矿的关系等。研究表明:东塘子铅锌矿床矿石硫化物δ34S值变化范围为1.8‰～12.5‰,平均7.50‰,计算获得成矿流体中总硫δ34S∑S为7.7‰,显示海水硫酸盐(蒸发膏岩)与岩浆硫的混合来源特征。矿石铅同位素组成稳定,铅源主要来自富U-Th-Pb的上地壳与深部,可能与深部岩浆活动有关。研究结果表明,东塘子铅锌矿床的成矿过程与南秦岭印支期大规模多阶段构造-岩浆-流体活动密切相关,为下一阶段区内找矿工作提供了新的思路。  相似文献   

晋北煅烧高岭土用煤矸石的应用矿物学特征   总被引：1，自引：0，他引：1  

侯龙超  王哲皓  汪灵  周东晓 《矿物学报》2020,(2):149-154

为了给晋北煅烧高岭土用煤矸石的评价和开发利用提供科学依据,采用XRD、XRF、SEM和白度计等现代分析测试技术,研究了晋北煅烧高岭土用煤矸石的应用矿物学特征。结果表明:1)根据造纸和涂料用煅烧高岭土的国家标准,晋北煤矸石主要可分为3种类型:合格原料、基本合格原料和不合格原料。2)与合格和基本合格原料相比,不合格原料煅烧产物的化学成分中SiO2、Al2O3、Fe2O3含量以及碱金属与碱土金属总含量都与前者有较大差异。3)合格和基本合格原料主要由高岭石(85%~94%)组成,不合格煤矸石矿物组合为高岭石(30%~60%)+石英(23%~38%)+伊利石(14%~26%),并含少量黄铁矿和白云石等杂质矿物,石英等杂质矿物和含铁矿物是分别导致煅烧产物化学成分和白度不合格的主要原因。4)合格原料中高岭石结晶度较好,主要为不规则片状、书册状和弯曲片状,片表面光滑,片径大小范围较大,为0.05~51.22μm,平均2.80μm,径厚比41.24。  相似文献   

GBW10010a大米标准物质复(研)制及数据特征     

杨榕  顾铁新  潘含江  刘妹  周国华 《岩矿测试》2020,39(6):866-877

随着我国对生态文明建设的重视，自然资源综合调查势在必行，对生物标准物质亦提出了新的需求。当前相关调研工作已经大面积开展，自然资源综合调查、农产品与食品安全评价都需要对生物样品元素组成进行准确测试，需要以生物标准物质作为生物成分测试量值比对和溯源的基础，因此对生物基体标准物质的需求量大幅增加。大米作为主要粮食之一，其食品安全日益受到重视，对大米中的化学成分进行准确的分析测试具有重要的现实意义，因而对大米标准物质的需求量尤为突出，但目前大米成分分析标准物质已供不应求。本文严格按照《标准物质定值的通用原则及统计学原理》（JJF 1343—2012）和《地质分析标准物质的研制》（JJF 1646—2017）等相关规范要求，开展了GBW10010a大米成分分析标准物质的复（研）制工作，包括样品采集、加工制备、均匀性检验、稳定性检验、多家实验室协作定值测试及不确定度评定等关键环节。结果表明：本次复（研）制的大米标准物质定值成分多样、量值准确可靠，符合国家一级标准物质的要求。GBW10010a共定值54项主微量元素，包括Ag、Al、As、B、Ba、Be、Bi、Ca、Cd、Ce、Co、Cr、Cs、Cu、Dy、Er、Eu、Fe、Gd、Ge、Hg、Ho、K、La、Li、Ho、Mg、Mn、Mo、N、Na、Nb、Nd、Ni、P、Pb、Pr、Rb、S、Sb、Sc、Se、Si、Sm、Sr、Tb、Th、Tl、Tm、U、V、Y、Yb、Zn，其中的39项元素给出了标准值及不确定度，包括Ag、Al、As、B、Ba、Ca、Cd、Ce、Co、Cs、Cu、Dy、Er、Fe、Hg、K、Li、Mg、Mn、Mo、N、Na、Nd、Ni、P、Pb、Pr、Rb、S、Sb、Se、Si、Sm、Sr、Tb、Tl、Y、Yb、Zn；15项元素提供参考值，包括Be、Bi、Cr、Eu、Gd、Ge、Ho、Ho、La、Nb、Sc、Th、Tm、U、V。与原有GBW10010大米标准物质相比较，GBW10010a中As、Cd、Co、Cr、Cu、Hg、Mn、Mo、Ni、Zn等重金属元素含量显著下降，其中Cd、Cu、Zn降幅较大，分别下降约39%、43%、38.7%，一定程度上反映了农田生态环境的改善。本批标准物质定值元素总数量增加了6项，新增定值元素Ag、Nb（Nb给出参考值），并且各项元素不确定度范围整体上有所缩小，如Al、Cd、Cu、Fe、K、Mg、Mo、Na、P、Pb、Se、Zn等对生物易有影响的重要元素，表明了地质分析测试方法技术的进步及定值水平的提高。本批标准物质定值元素涵盖了具有生物效应的大部分主微量元素，适用于农业生态环境地球化学调查与评价、生物样品测试、农产品质量与食品安全评价样品测试时的分析仪器校正、分析方法评价和分析质量监控等多个领域。  相似文献   

Determination of Radiogenic 87Sr/86Sr and Stable δ88/86SrSRM987 Isotope Values of Thirteen Mineral,Vegetal and Animal Reference Materials by DS‐TIMS     

Jean‐Michel Brazier  Anne‐Dsire Schmitt  Eric Pelt  Damien Lemarchand  Sophie Gangloff  Tho Tacail  Vincent Balter 《Geostandards and Geoanalytical Research》2020,44(2):331-348

This work presents new ⁸⁷Sr/⁸⁶Sr and δ^88/86Sr_SRM987 isotopic values of thirteen mineral, vegetal and animal reference materials. Except for UB‐N, all our results are consistent with previously published data. Our results highlight intermediate precisions among the best presently published and a non‐significant systematic shift with the calculated δ^88/86Sr_SRM987 mean values for the three most analysed reference materials in the literature (i.e., IAPSO, BCR‐2 and JCp‐1). By comparison with the literature and between two distinct digestions, a significant bias of δ^88/86Sr_SRM987 values was highlighted for two reference materials (UB‐N and GS‐N). It has also been shown that digestion protocols (nitric and multi‐acid) have a moderate impact on the δ^88/86Sr_SRM987 isotopic values for the Jls‐1 reference materials suggesting that a nitric acid digestion of carbonate can be used without significant bias from partial digestion of non‐carbonate impurities. Different δ^88/86Sr_SRM987 values were measured after two independent Sr/matrix separations, according to the same protocol, for a fat‐rich organic reference material (BCR‐380R) and have been related to a potential post‐digestion heterogeneity. Finally, the δ^88/86Sr_SRM987 value differences measured between animal‐vegetal and between coral‐seawater reference materials agree with the previously published results, highlighting an Sr isotopic fractionation along the trophic chain and during carbonate precipitation.  相似文献   

High‐Precision Measurement of 187Os/188Os Isotope Ratios of Nanogram to Picogram Amounts of Os in Geological Samples by N‐TIMS using Faraday Cups Equipped with 1013 Ω Amplifiers     

Guiqin Wang  Hauke Vollstaedt  Jifeng Xu  Wengui Liu 《Geostandards and Geoanalytical Research》2019,43(3):419-433

N(¹⁸⁷Os)/N(¹⁸⁸Os) ratios of six geological reference materials were measured using static Faraday cups (FCs) with 10¹³ Ω amplifiers by N‐TIMS. Our results show that the repeatability precision was 2–3‰ (2 RSD, n = 3), when taking ~ 1 g of BHVO‐2 with 76 pg g^?1 of Os mass fraction and ~ 2 g of BCR‐2 with 21 pg g^?1 of Os mass fraction for each sample, whether measured by FCs or by secondary electron multiplier. The repeatability precision measured by FCs was 1–0.2‰ (2 RSD, n = 3) when taking ~ 1 g of BIR‐2 with 350 pg g^?1 of Os mass fraction, ~ 1 g of WGB‐1 with 493 pg g^?1 of Os mass fraction or ~ 0.5 g of WPR‐1 with 13.3 ng g^?1 of Os mass fraction for each sample, which is much better than those measured by secondary electron multiplier. Instead, when taking ~ 2 g of AGV‐2 with 4 pg g^?1 Os mass fraction, the repeatability precision measured by secondary electron multiplier is 3–4‰ (RSD, n = 3), which is better than those measured by FCs. Of the six reference materials analysed, WPR‐1 and BIR‐1a are the most homogeneous with regard to Os isotopic composition (2 RSD of 0.08% and 0.23%, respectively) when test portion masses are 0.5–1 g.  相似文献   

科尔沁湿草甸参考作物蒸散发模拟分析     

李霞  刘廷玺  段利民  王冠丽  童新  周亚军  杨晓君 《中国沙漠》2020,40(2):134-143

为探明气候变化下干旱半干旱地区湿草甸参考作物蒸散发(ET₀)影响因子,使用FAO 56 P-M模型对科尔沁湿草甸ET₀进行模拟,利用涡度相关系统对模型的适用性进行评价,并通过通径分析及指标敏感性分析对ET₀的影响因子进行辨识。结果表明:(1)小时尺度模拟精度最高,日尺度次之,月尺度较差,小时尺度上晴、阴、雨3种天气条件下模拟效果不同,晴天最优,阴雨天较差。(2)ET₀年内变化呈单峰曲线状,生长季明显高于非生长季,集中在3—10月,占全年89.79%。生长季典型晴天ET₀逐小时分布特征遵循倒“U”单峰型变化规律。(3)通径分析结果显示,对ET₀的通径系数以及对回归方程估测可靠程度E的总贡献均表现为VPD(饱和水汽压差) > T_min(最低气温) > R_n(冠层表面净辐射)>u₂(2 m高度风速),即VPD为影响ET₀最重要的因子;指标敏感性分析中,在去除VPD后引起的E变化最大,说明ET₀对VPD的变化最为敏感,其次为u₂、T_min和R_n。  相似文献   

A multiscale work-analysis approach for geotechnical structures     

Hao Xiong  Zhen-Yu Yin  François Nicot 《国际地质力学数值与分析法杂志》2019,43(6):1230-1250

This paper presents a second-order work analysis in application to geotechnical problems by using a novel effective multiscale approach. To abandon complicated equations involved in conventional phenomenological models, this multiscale approach employs a micromechanically-based formulation, in which only four parameters are involved. The multiscale approach makes it possible a coupling of the finite element method (FEM) and the micromechanically-based model. The FEM is used to solve the boundary value problem (BVP) while the micromechanically-based model is utilized at the Gauss point of the FEM. Then, the multiscale approach is used to simulate a three-dimensional triaxial test and a plain-strain footing. On the basis of the simulations, material instabilities are analyzed at both mesoscale and global scale. The second-order work criterion is then used to analyze the numerical results. It opens a road to interpret and understand the micromechanisms hiding behind the occurrence of failure in geotechnical issues.  相似文献   

Duluth Complex apatites: Age reference material for LA–ICP–MS‐based fission‐track dating     

Hideki Iwano  Tohru Danhara  Takashi Yuguchi  Takafumi Hirata  Masatsugu Ogasawara 《地学学报》2019,31(3):247-256

Anorthositic series apatites of the Duluth Complex, Minnesota, USA, have high spontaneous fission‐track densities of up to ~10⁷ cm^–2 and a homogeneous age of ~900 Ma, allowing high‐precision fission‐track dating based on LA–ICP–MS U analysis. Absolute fission‐track dating, track‐length measurement and chemical composition analysis were performed to evaluate a cooling history, which is essential for age reference materials. Preliminary inverse modelling for a sample with a shortened track‐length distribution yielded a monotonic cooling history from ~100°C at 925 Ma. The apatites incur an over‐etching problem when employing the commonly used etching protocol involving 5.5 M HNO₃.  相似文献   

Copper Isotopic Analysis in Geological and Biological Reference Materials by MC‐ICP‐MS     

Kaj Sullivan  Daniel Layton‐Matthews  Matthew Leybourne  James Kidder  Zoltn Mester  Lu Yang 《Geostandards and Geoanalytical Research》2020,44(2):349-362

The characterisation of relative copper isotope amount ratios (δ⁶⁵Cu) helps constrain a variety of geochemical processes occurring in the geosphere, biosphere and hydrosphere. The accurate and precise determination of δ⁶⁵Cu in matrix reference materials is crucial in the effort to validate measurement methods. With the goal of expanding the number and variety of available geological and biological materials, we have characterised the δ⁶⁵Cu values of ten reference materials by MC‐ICP‐MS using C‐SSBIN model for mass bias correction. SGR‐1b (Green River shale), DOLT‐5 (dogfish liver), DORM‐4 (fish protein), TORT‐3 (lobster hepatopancreas), MESS‐4 (marine sediment) and PACS‐3 (marine sediment) have for the first time been characterised for δ⁶⁵Cu. Additionally, four reference materials (with published δ⁶⁵Cu values) have been characterised: BHVO‐1 (Hawaiian basalt), BIR‐1 (Icelandic basalt), W‐2a (diabase) and Seronorm? Trace Elements Serum L‐1 (human serum). The reference materials measured in this study possess complex and varied matrices with copper mass fractions ranging from 1.2 µg g^?1 to 497 µg g^?1 and δ⁶⁵Cu values ranging from ?0.20‰ to 0.52‰ with a mean expanded uncertainty of ± 0.07‰ (U, k = 2), covering much of the natural copper isotope variability observed in the environment.  相似文献