Drying increases organic colloidal mobilization in the karst vadose zone: Evidence from a 15-year cave-monitoring study     

Jin Liao  Chaoyong Hu  Xiuli Li  Jiaoyang Ruan 《水文研究》2021,35(4):e14163

Understanding the hydrological processes of colloids within the karst vadose zone is vital to the security of karst groundwater and providing appropriate paleohydrological explanations of colloid-facilitated metals in speleothem. This study addresses the mobilization mechanisms driving colloidal organic matter (COM) transport in the karst vadose zone using a 15-year long monthly monitoring dataset from a cave drip point (HS4) in Heshang Cave, Qingjiang Valley, China. Variations in COM concentrations were reported as the fluorescence difference values of raw and filtered (<0.22 μm) samples at an excitation wavelength of 320 nm and emission wavelength of ~400 nm. A fluorescence humification index (HIX) lower than 0.8 and an autochthonous index (BIX) higher than 1.2 indicated that the origin of COM was mainly from the karst vadose zone, rather than the soil zone. The COM concentration varied from 0.001 to 0.038 Raman Unit (RU), with evident seasonal fluctuations. Rising limbs for COM values occurred prior to rising limbs within a dripwater hydrograph; moreover, the COM peak values corresponding to the beginning of the increasing hydrograph generally suggested that the mobilization of COM reflected the movement of the air–water interface (AWI) in the karst vadose zone rather than rainfall intensity or flow velocity. COM peak values were positively correlated with the antecedent drying duration and negatively correlated with HIX values. These phenomena may be explained by the increased amount of organic matter that was aggregated and absorbed on the surface of carbonate in the karst vadose zone during a longer drying duration. Moreover, the longer drying duration was also beneficial to autochthonous biological activity, which subsequently decreased the HIX value of the organic matter in the karst vadose zone. The movement of AWI and the drying duration are both controlled by the outside weather conditions. This study is therefore conducive to evaluating the security of karst groundwater in response to climate change, and challenges prevailing paleoclimate interpretations of colloid-facilitated metal abundance timeseries reported from speleothems.  相似文献   

长江经济带岩盐矿特征与盐穴储库适宜性评价     

刘红樱  姜月华  杨国强  金阳  杨辉  周权平 《中国地质调查》2019,6(5):89-98

长江经济带包括上海、江苏、浙江、安徽、江西、湖北、湖南、四川、重庆、云南和贵州11个省(直辖市),是我国重要的经济发展区域,油气资源长期安全可靠的储存对于该区经济可持续发展至关重要。基于长江经济带战略油气储库基地建设规划布局的需求,在充分收集利用前人地质调查和研究成果的基础上,对区内岩盐矿床进行了综合研究和分析,建立了层次结构模型,评价了盐穴油气储库建设的可行性。长江经济带除上海和贵州外,其余9省(直辖市)均发现了大量的岩盐矿床,主要成盐时代为震旦纪、三叠纪、白垩纪和古近纪; 成盐盆地范围0.29~10 000 km²,盐层累计厚度3~1 050 m,矿体埋藏深度40~3 400 m; 矿石中NaCl含量20%~99.86%; 矿体顶底板及夹层岩石主要为泥岩、粉砂质泥岩及泥质粉砂岩。地质调查揭示出区内大部分地下盐穴远离地震活动带,构造稳定,因此可以改造为石油储库。考虑储气库的密闭性及安全性,江苏金坛盆地等6个盐矿埋深适中,建穴地质条件较好,适合建造储气盐穴库; 江苏淮安等14个盆地的局部地区适合建造天然气储库; 重庆垫江等11个盐矿埋深较大,可以建造储气盐穴库,但建造成本较高; 湖南澧县等21个盐矿埋藏偏浅,应选择更深部的盐层空间建造油气储库。建议在江苏金坛、淮安、赵集和丰县,江西清江和会昌,湖北云应、天门小板和潜江等盐矿地区优先开发利用盐穴。  相似文献   

岩溶水硝酸盐污染原位修复试验     

叶进霞  夏春英  卜鸿志 《中国岩溶》2020,39(2):173-179

岩溶含水层的极不均一性特征使岩溶水溶质运移受构造、裂隙空间及其发育方向控制；因环境条件复杂，开展岩溶水污染原位修复技术难度较大，截止目前，国内尚未系统地开展岩溶含水层水污染原位修复研究工作。文章选择鲁中南山区典型岩溶发育及硝酸盐污染地段，施工组合钻孔建设修复试验工程，采用“乙醇+葡萄糖”液态碳源和“聚乙烯醇+淀粉颗粒”固态反应器分别进行岩溶水硝酸盐污染原位修复试验。结果表明:浓度500 mg?L－1、1 000 mg?L－1的“乙醇+葡萄糖”反硝化溶液对硝酸盐浓度的降解率分别为6.45 %和21.52 %；单位长度组成材料“聚乙烯醇3 kg+淀粉颗粒3 kg”、“聚乙烯醇2 kg+淀粉颗粒4 kg”的两种反硝化固态反应器对硝酸盐浓度的降解率分为33.91%和34.96%。试验证明在裂隙型岩溶地区采用孔组方案进行地下水污染原位修复技术可行、且能取得较显著效果。修复工程布设方式和试验成果对类似地区开展岩溶地下水污染原位修复具一定借鉴意义。   相似文献   

The timing of salt structure growth in the Southern Permian Basin (Central Europe) and implications for basin dynamics     

Michael Warsitzka  Fabian Jhne‐Klingberg  Jonas Kley  Nina Kukowski 《Basin Research》2019,31(2):337-360

In this paper, a literature‐based compilation of the timing and history of salt tectonics in the Southern Permian Basin (Central Europe) is presented. The tectono‐stratigraphic evolution of the Southern Permian Basin is influenced by salt movement and the structural development of various types of salt structures. The compilation presented here was used to characterize the following syndepositional growth stages of the salt structures: (a) “phase of initiation”; (b) phase of fastest growth (“main activity”); and (c) phase of burial’. We have also mapped the spatial pattern of potential mechanisms that triggered the initiation of salt structures over the area studied and summarized them for distinct regions (sub‐basins, platforms, etc.). The data base compiled and the set of maps produced from it provide a detailed overview of the spatial and temporal distribution of salt tectonic activity enabling the correlation of tectonic phases between specific regions of the entire Southern Permian Basin. Accordingly, salt movements were initiated in deeply subsided graben structures and fault zones during the Early and Middle Triassic. In these areas, salt structures reached their phase of main activity already during the Late Triassic or the Jurassic and were mostly buried during the Early Cretaceous. Salt structures in less subsided sub‐basins and platform regions of the Southern Permian Basin mostly started to grow during the Late Triassic. The subsequent phase of main activity of these salt structures took place from the Late Cretaceous to the Cenozoic. The analysis of the trigger mechanisms revealed that most salt structures were initiated by large‐offset normal faults in the sub‐salt basement in the large graben structures and minor normal faulting associated with thin‐skinned extension in the less subsided basin parts.  相似文献   

13世纪以来中国海洋盐业动态演变及驱动因素     

鲍俊林  高抒 《地理科学》2019,39(4):596-605

海洋盐业是中国海洋经济的重要部分,也是沿海传统产业之一,13世纪以来不断发展演变。将沿海分为北、东、南3个地带,搜集整理与海盐经济相关的多种历史文献及方志资料,运用地理学方法分析评估了海洋盐业百年尺度的动态演化过程,并比较了资源环境与管理政策的驱动作用及其差异。研究表明：① 沿海盐业表现为传统煎法长期主导、逐步废煎改晒的过程,不同盐区的演化进程存在显著差异,北部盐区最快,东部次之,南部整体发展缓慢;② 海盐生产重心长期位于东部的两淮盐区,19世纪后期向北部盐区快速迁移;③ 资源环境与生态差异促进了各岸段海盐生产演化分异,垄断性管理政策迟滞了海洋盐业的空间集聚进程,未来沿海开发与海洋盐业的可持续发展将主要依靠基于资源生态约束的管理政策与技术。  相似文献   

South Australian geology and the State Heritage Register: an example of geoconservation of the Naracoorte Caves complex and karst environment     

I. D. Lewis 《Australian Journal of Earth Sciences》2019,66(6):785-792

South Australia’s State Heritage Register contains 2294 listed places, the majority of which are from the ‘Built’ environment, ranging from settlers’ huts, community buildings, historical industrial sites to magnificent stone mansions. Only 96 places are linked to the ‘Natural’ environment. The Register listings protect heritage places from alteration, damage or removal without formal prior consultation, compulsory under the South Australian Development Act. ‘Natural’ environments are landscape-based and oriented towards Geological, Archaeological, Palaeontological and Speleological heritage (‘GAPS heritage’). A process to provide a greater balance between ‘Natural’ and ‘Built’ listings has initiated a series of State Heritage ‘Natural’ environment assessments, mostly of single sites. Two individual caves in the Naracoorte Caves National Park are already entered in the State Heritage Register as single sites. However, an innovative broader multiple-site nomination has focused on the many different but significant GAPS features contained within the 25 caves of the Naracoorte Caves National Park, providing a further level of protection for the land and the caves’ exteriors and interiors. The example of the Naracoorte Caves draws attention to the number of important land and coastal karst (limestone) features across South Australia that were generated by steady geological uplift of three large sections of Oligocene–Miocene limestone—the Nullarbor Plain, the Murray Basin and the Gambier Karstfield (which includes Naracoorte and Mount Gambier), resulting in specific karst forms worthy of a broader coordinating management approach across South Australian karst parks.  相似文献   

黄土高原沟谷地貌发育演化研究进展与展望     

熊礼阳  汤国安 《地球信息科学学报》2020,22(4):816-826

黄土沟谷是黄土地貌中最有活力、最具变化、最富特色的对象单元,黄土高原千沟万壑的地貌形态以及触目惊心的侵蚀状态也让区域内沟谷地貌的形成、发育及演化问题成为研究中焦点及前沿性科学问题。近年来,诸多学者采用地学测年法、特征表达法、监测模拟法力图实现对黄土沟谷发育演化进程中“过去-现代-未来”的科学认知。这些研究在相当程度上丰富了黄土沟谷发育过程的认知。本文梳理了黄土高原沟谷地貌演化相关研究的现状,并从黄土高原地貌演化、黄土沟谷发育、基于DEM的沟谷信息提取与表达等研究进行了系统的回顾、梳理与分析。此外,本文提出“黄土沟道剖面群组”概念与方法,试图从新的视角审视黄土沟谷地貌发育演化过程。沟道剖面在黄土沟谷发育演化进程中传递物质能量和累积地形动力,并通过径流节点的串联实现剖面群的连接与组合,形成独特的剖面“群组”模式;该沟道剖面群组是集黄土沟谷地貌特征与过程于一体的综合信息集成体,其三维空间结构是对黄土沟谷地貌发育演化的高度抽象与映射,并可望进一步丰富黄土高原数字地形分析理论与方法体系,为黄土高原黄土地貌成因机理与空间分异格局带来创新的认识。  相似文献   

滇西南钾盐调查MK-3大口径超深井绳索取心钻进工艺          下载免费PDF全文

吕利强 《探矿工程》2020,47(3):53-58

滇西南中生代盐盆地钾盐资源调查评价项目MK-3井，设计井深2700 m，全孔取心，岩心直径≮80 mm，一般井段岩心采取率达到80%以上，盐岩段岩心采取率＞95%。工程技术要求高，施工难度大。施工中遇到了地层坍塌、涌水、掉块、盐岩溶蚀等问题，通过采用氯化镁饱和盐水冲洗液，HXY-9B型钻机取心钻进、TSJ-2000型水源钻机扩孔钻进，分级下管隔离等措施，圆满完成了钻探任务。完钻井深2701 m，岩心采取率90%，盐岩段岩心采取率达98.65%，终孔口径127 mm，岩心直径81 mm。经地球物理测井，各项指标都达到了设计要求。刷新了国内CHD127标准绳索取心钻杆P口径钻探深度的记录。  相似文献   

Tectono-sedimentary evolution of Jurassic–Cretaceous diapiric structures: Miravete anticline,Maestrat Basin,Spain     

Jaume Vergés  Yohann Poprawski  Ylènia Almar  Peter A. Drzewiecki  Mar Moragas  Telm Bover-Arnal  Chiara Macchiavelli  Wayne Wright  Grégoire Messager  Jean-Christophe Embry  David Hunt 《Basin Research》2020,32(6):1653-1684

Integration of extensive fieldwork, remote sensing mapping and 3D models from high-quality drone photographs relates tectonics and sedimentation to define the Jurassic–early Albian diapiric evolution of the N–S Miravete anticline, the NW-SE Castel de Cabra anticline and the NW-SE Cañada Vellida ridge in the Maestrat Basin (Iberian Ranges, Spain). The pre shortening diapiric structures are defined by well-exposed and unambiguous halokinetic geometries such as hooks and flaps, salt walls and collapse normal faults. These were developed on Triassic salt-bearing deposits, previously misinterpreted because they were hidden and overprinted by the Alpine shortening. The Miravete anticline grew during the Jurassic and Early Cretaceous and was rejuvenated during Cenozoic shortening. Its evolution is separated into four halokinetic stages, including the latest Alpine compression. Regionally, the well-exposed Castel de Cabra salt anticline and Cañada Vellida salt wall confirm the widespread Jurassic and Early Cretaceous diapiric evolution of the Maestrat Basin. The NE flank of the Cañada Vellida salt wall is characterized by hook patterns and by a 500-m-long thin Upper Jurassic carbonates defining an upturned flap, inferred as the roof of the salt wall before NE-directed salt extrusion. A regional E-W cross section through the Ababuj, Miravete and Cañada-Benatanduz anticlines shows typical geometries of salt-related rift basins, partly decoupled from basement faults. These structures could form a broader diapiric region still to be investigated. In this section, the Camarillas and Fortanete minibasins displayed well-developed bowl geometries at the onset of shortening. The most active period of diapiric growth in the Maestrat Basin occurred during the Early Cretaceous, which is also recorded in the Eastern Betics, Asturias and Basque-Cantabrian basins. This period coincides with the peak of eastward drift of the Iberian microplate, with speeds of 20 mm/year. The transtensional regime is interpreted to have played a role in diapiric development.  相似文献   

丹江断裂东段第四纪活动性及地震地质涵义     

雷东宁  乔岳强  胡庆  王秋良  林松  李雪 《吉林大学学报(地球科学版)》2019,49(5):1362-1375

丹江口地区地震地质因修建丹江水库而得到深入研究，但针对断裂进行的系统性研究较少。通过对丹江断裂东段进行1：1万大比例条带状活动断裂填图，综合采用地质地貌调查、岩样年龄测试、地质钻探、浅层地震勘探等多种手段进行研究，认为：1）丹江断裂东段第四纪以来累积左旋走滑量在250~500 m之间，上更新统地层垂直断距为10~20 m；2）断裂最新活动时代为晚更新世，活动性质以由NE向SW的逆冲为主，兼具有左旋走滑分量；3）断裂活动性由山地向盆地迁移。丹江断裂晚更新世以来活动表明，南襄盆地西缘活动性较强。该认识可为进一步评估丹江口地区乃至南襄盆地西缘的地震构造环境提供依据。  相似文献