Raman microspectrometry, FT-IR and inclusion characteristics of gem garnets from Tanzania and Madagascar     

Sang-konKim Maeng-eonPark Seung-gyunBaek Kyu-youlSung Sun-okKim Hee-yulPark 《东北亚地学研究》2004,7(2):125-135

Chemical composition, Raman microspectrometry, and Fourier transform infrared (FT-1R) and SEM-CL (Cathodluminescence) analyses are carried out for Tanzania and Madagascar garnets for locality identification. Inclusion study was sustained after electron probe microanalysis (EPMA). Needle-like illmenites, apatites and zircons were the most common solid inclusions in Tanzania garnets. Madagascar garnets revealed rutile needles and apatites were also observed, but differences in size, shape and distribution patterns were noticed compared to Tanzania garnets. Tanzania garnets exhibited all types of observable fluid inclusions such as ““ fingerprint““ pattern, called Type Ⅰ-A, liquid-only (L) single phase fluid inclusion, called Type Ⅰ-B and Type Ⅱ-A ( L S), Type Ⅱ-B ( L V) and Type Ⅲ-A (L Sylvite even if all examined garnets from three localities retained ““fingerprint““ features, so called, partially healed fractures, in common. Chemical composition, Raman microspectrometry and Fourier transform infrared (FT-IR) analysis taken turned out to be useful methods for the purpose of this study. Using consequences of SEM-CL and inclusion study, accordingly, the locality identification of gem-quality garnets is capable of being available in further application for other kinds of gemstones.  相似文献   

Fluid and source magma evolution of the Questa porphyry Mo deposit,New Mexico,USA   总被引：14，自引：1，他引：13  

Leonhard M. Klemm  Thomas Pettke  Christoph A. Heinrich 《Mineralium Deposita》2008,43(5):533-552

Combined fluid inclusion microthermometry and microanalysis by laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS) are used to constrain the hydrothermal processes forming a typical Climax-type porphyry Mo deposit. Molybdenum mineralisation at Questa occurred in two superimposed hydrothermal stages, a magmatic-hydrothermal breccia and later stockwork veining. In both stages, texturally earliest fluids were single-phase, of low salinity (~7 wt.% NaCl_equiv.) and intermediate-density. Upon decompression to ~300 bar, they boiled off a vapour phase, leaving behind a residual brine (up to 45 wt.% NaCl_equiv) at temperatures of ~420°C. The highest average Mo concentrations in this hot brine were ~500 μg/g, exceeding the Mo content of the intermediate-density input fluid by about an order of magnitude and reflecting pre-concentration of Mo by fluid phase separation prior to MoS₂ deposition from the brine. Molybdenum concentrations in brine inclusions, then, decrease down to 5 μg/g, recording Mo precipitation in response to cooling of the saline liquid to ~360°C. Molybdenite precipitation from a dense, residual and probably sulphide-depleted brine is proposed to explain the tabular shape of the ore body and the absence of Cu-Fe sulphides in contrast to the more common Cu-Mo deposits related to porphyry stocks. Cesium and Rb concentrations in the single-phase fluids of the breccia range from 2 to 8 and from 40 to 65 μg/g, respectively. In the stockwork veins, Cs and Rb concentrations are significantly higher (45–90 and 110–230 μg/g, respectively). Because Cs and Rb are incompatible and hydrothermally non-reactive elements, the systematic increase in their concentration requires two distinct pulses of fluid exsolution from a progressively more fractionated magma. By contrast, major element and ore metal concentrations of these two fluid pulses remain essentially constant. Mass balance calculations using fluid chemical data from LA-ICPMS suggest that at least 25 km³ of melt and 7 Gt of deep input fluid were necessary to provide the amount of Mo contained in the stockwork vein stage alone. While the absolute amounts of fluid and melt are uncertain, the well-constrained element ratios in the fluids together with empirical fluid/melt partition coefficients derived from the inclusion analyses suggest a high water content of the source melt of ~10%. In line with other circumstantial evidence, these results suggest that initial fluid exsolution may have occurred at a confining pressure exceeding 5 kbar. The source of the molybdenum-mineralising fluids probably was a particularly large magma chamber that crystallised and fractionated in the lower crust or at mid-crustal level, well below the shallow intrusions immediately underlying Questa and other porphyry molybdenum deposits. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

The sandstone-hosted stratiform copper mineralization at Mwitapile and its relation to the mineralization at Lufukwe, Lufilian foreland, Democratic Republic of Congo   总被引：2，自引：0，他引：2  

Hamdy A. El Desouky  Philippe Muchez  Roger Tyler 《Ore Geology Reviews》2008,34(4):561-579

The Lufilian foreland is a triangular-shaped area located in the SE of the Democratic Republic of Congo and to the NE of the Lufilian arc, which hosts the well-known Central African Copperbelt. The Lufilian foreland recently became an interesting area with several vein-type (e.g., Dikulushi) and stratiform (e.g., Lufukwe and Mwitapile) copper occurrences. The Lufilian foreland stratiform Cu mineralization is, to date, observed in sandstone rock units belonging to the Nguba and Kundelungu Groups (Katanga Supergroup).The Mwitapile sandstone-hosted stratiform Cu prospect is located in the north eastern part of the Lufilian foreland. The host rock for the Cu mineralization is the Sonta Sandstone of the Ngule Subgroup (Kundelungu Group). A combined remote sensing, petrographic and fluid inclusion microthermometric analysis was performed at Mwitapile and compared with similar analysis previously carried out at Lufukwe to present a metallogenic model for the Mwitapile- and Lufukwe-type stratiform copper deposits. Interpretation of ETM+ satellite images for the Mwitapile prospect and the surrounding areas indicate the absence of NE–SW or ENE–WSW faults, similar to those observed controlling the mineralization at Lufukwe. Faults with these orientations are, however, present to the NW, W, SW and E of the Mwitapile prospect. At Mwitapile, the Sonta Sandstone host rock is intensely compacted, arkosic to calcareous with high silica cementation (first generation of authigenic quartz overgrowths). In the Sonta Sandstone, feldspar and calcite are present in disseminated, banded and nodular forms. Intense dissolution of these minerals caused the presence of disseminated rectangular, pipe-like and nodular dissolution cavities. Sulfide mineralization is mainly concentrated in these cavities. The hypogene sulfide minerals consist of two generations of pyrite, chalcopyrite, bornite and chalcocite, separated by a second generation of authigenic quartz overgrowth. The hypogene sulfide minerals are replaced by supergene digenite and covellite. Fluid inclusion microthermometry on the first authigenic quartz phase indicates silica precipitation from an H₂O–NaCl–CaCl₂ fluid with a minimum temperature between 111 and 182 °C and a salinity between 22.0 and 25.5 wt.% CaCl₂ equiv. Microthermometry on the second authigenic quartz overgrowths and in secondary trails related to the mineralization indicate that the mineralizing fluid is characterized by variable temperatures (Th = 120 to 280 °C) and salinities (2.4 to 19.8 wt.% NaCl equiv.) and by a general trend of increasing temperatures with increasing salinities.Comparison between Mwitapile and Lufukwe indicates that the stratiform Cu mineralization in the two deposits is controlled by similar sedimentary, diagenetic and structural factors and likely formed from a similar mineralizing fluid. A post-orogenic timing is proposed for the mineralization in both deposits. The main mineralization controlling factors are grain size, clay and pyrobitumen content, the amount and degree of feldspar and/or calcite dissolution and the presence of NE–SW to ENE–WSW faults. The data support a post-orogenic fluid-mixing model for the Mwitapile- and Lufukwe-type sandstone-hosted stratiform Cu deposits, in which the mineralization is related to the mixing between a Cu-rich hydrothermal fluid, with a temperature up to 280 °C and a maximum salinity of 19.8 wt.% NaCl equiv., with a colder low salinity reducing fluid present in the sandstone host rock. The mineralizing fluid likely migrated upwards to the sandstone source rocks along NE–SW to ENE–WSW orientated faults. At Lufukwe, the highest copper grades at surface outcrops and boreholes were found along and near to these faults. At Mwitapile, where such faults are 2 to 3 km away, the Cu grades are much lower than at Lufukwe. Copper precipitation was possibly promoted by reduction from pre-existing hydrocarbons and non-copper sulfides and by the decrease in fluid salinity and temperature during mixing. Based on this research, new Cu prospects were proposed at Lufukwe and Mwitapile and a set of recommendations for further Cu exploration in the Lufilian foreland is presented.  相似文献   

流体包裹体成分测定的低温相变和显微拉曼光谱分析技术研究进展   总被引：2，自引：1，他引：1  

葛云锦  陈勇  周瑶琪 《岩矿测试》2008,27(3):207-210

论述了包裹体低温分析技术的原理以及进展。传统的流体包裹体低温分析技术是以显微冷冻测温测定无机盐体系为主,目前已发展到应用低温原位拉曼光谱技术对包裹体中的阳离子和阴离子进行定量-半定量分析。油气包裹体原位低温分析技术也取得了较大的突破,对不同成分油气包裹体低温下的相变过程取得了一定的认识,据此对油气包裹体进行分类,推测其主要成分,为油气包裹体计算提供基础参数。  相似文献   

湖北徐家山锑矿床流体包裹体特征及其意义     

沈能平  彭建堂  袁顺达  张东亮  胡瑞忠  王国强 《矿床地质》2008,27(5):570-578

文章利用激光拉曼光谱和显微测温学方法,对湖北徐家山锑矿床成矿期的石英、重晶石和方解石中的流体包裹体进行了研究。研究表明,这些矿物中的流体包裹体主要有纯液体包裹体和液体包裹体(气相 液相)2类,其液体包裹体的气相成分为H2O±CO2±N2;石英、重晶石和方解石的均一温度分别为134~258℃、154~259℃和145~230℃,主要集中于150~200℃;流体的盐度w(NaCleq)和密度分别集中于3%~6%和0.90~0.96g/cm3。流体包裹体资料揭示出该矿床为典型的中低温热液锑矿床,其成矿流体为中低温、低盐度、中等密度热液。结合H、O、Sr、Pb同位素等研究结果,进一步推断该成矿热液主要是经深部循环演化的大气降水。  相似文献   

豫西前河构造蚀变岩型金矿成矿过程中的流体-岩石反应     

曹烨  李胜荣  申俊峰  要梅娟  李庆康  毛付龙 《矿床地质》2008,27(6):714-726

前河金矿区位于华北地台南缘,赋存在中元古界熊耳群安山岩和英安岩中,矿体受断裂破碎带控制。含矿热液在迁移过程中与围岩发生了广泛的流体-岩石反应而引起热液蚀变。本区石英中有4种类型的流体包裹体,均一温度范围为145～331℃,其中含CO2包裹体的完全均一温度主要分布在中-高温区。成矿流体的密度和压力变化范围分别是0.68～0.94g/cm3和(367.01～896.55)×105Pa。金大量沉淀成矿时的流体特征为:温度213～260℃、密度0.80～0.89g/cm3和压力(502.86～710.57)×105Pa。流体相为SO42->Na >Cl->K 型,CO2/H2O比值及N2、H2S、Ar、C2H6等挥发分的含量明显增高,f(CO2)、f(H2S)、f(CH4)和Eh值增大;f(O2)、f(H2O)和pH值减小。在青磐岩化安山岩的基础上发生的流体-岩石反应是造成本矿床金沉淀成矿的最主要原因。  相似文献   

In situ strength measurements on natural upper-mantle minerals   总被引：1，自引：0，他引：1  

Junji Yamamoto  Jun-ichi Ando  Hiroyuki Kagi  Toru Inoue  Akihiro Yamada  Daisuke Yamazaki  Tetsuo Irifune 《Physics and Chemistry of Minerals》2008,35(5):249-257

Using in situ strength measurements at pressures up to 10 GPa and at room temperature, 400, 600, and 700°C, we examined rheological properties of olivine, orthopyroxene, and chromian-spinel contained in a mantle-derived xenolith. Mineral strengths were estimated using widths of X-ray diffraction peaks as a function of pressure, temperature, and time. Differential stresses of all minerals increase with increasing pressure, but they decrease with increasing temperature because of elastic strain on compression and stress relaxation during heating. During compression at room temperature, all minerals deform plastically at differential stress of 4–6 GPa. During subsequent heating, thermally induced yielding is observed in olivine at 600°C. Neither orthopyroxene nor spinel shows complete stress relaxation, but both retain some stress even at 700°C. The strength of the minerals decreases in the order of chromian-spinel ≈ orthopyroxene > olivine for these conditions. This order of strength is consistent with the residual pressure of fluid inclusions in mantle xenoliths.  相似文献   

邹平王家庄铜矿床成矿地球化学及成因探讨   总被引：2，自引：0，他引：2  

张军  徐兆文  李海勇  刘苏明  杨小男  陆现彩  李红超 《地质论评》2008,54(4):466-476

王家庄铜矿床的矿化脉石英中流体包裹体均一温度介于116 ~ 566 ℃之间,均值为 289 ℃;盐度介于7.2%～63.2% NaCleq,均值为21.1% NaCleq。流体的气相成分主要为H2O和CO2。在均一温度为240 ~ 440 ℃区间内,出现了富气相的两相水溶液包裹体、富液相的两相水溶液包裹体和含子晶的三相水溶液包裹体共存现象,以及加温后富气相包裹体均一到气相和同期富液相包裹体均一到液相的特征,表明成矿流体曾发生过沸腾作用;其中第一次发生于360 ~ 400 ℃,主要形成高温、高盐度含子晶的三相水溶液包裹体和高温、中盐度富液相的两相水溶液包裹体及高温、低盐度富气相的两相水溶液包裹体;第二次发生于240 ~ 320 ℃,主要形成高—中温、高盐度的含子晶的三相水溶液包裹体和高—中温、中盐度富液相的两相水溶液包裹体及高—中温、低盐度富气相的两相水溶液包裹体;之后主要形成富液相的两相水溶液包裹体,具有中低温和中盐度的特征。矿化脉石英中的δ18OH2O介于-1.14‰ ~ 1.79‰之间,均值为0.94‰;δD介于-63.70‰ ~ -56.50‰之间,均值为-59.8‰;说明王家庄铜矿床的成矿流体主要来源于岩浆,后期混入大气降水。矿石矿物的δ34S变化于-8.80‰ ~ -2.80‰之间,均值为-6.33‰。矿石矿物的n(206Pb)/n(204Pb)介于18.1684 ~ 18.3637之间,均值为18.2892;n(207Pb)/n(204Pb)介于155546 ~ 156342之间,均值为155777;n(208Pb)/n(204Pb)介于38.1286 ~ 38.4840之间,均值为38.2780。说明矿石具有贫重硫和富放射性成因铅的特征,硫、铅主要来源于深部,后期可能受到地壳物质或大气降水的混染。  相似文献   

黑龙江省金厂金矿床J0矿体流体地球化学研究   总被引：7，自引：6，他引：1  

张宇  赖勇  卿敏  王艳忠  徐佳佳 《岩石学报》2008,24(5)

黑龙江省东宁县金厂金矿床是最新发现的特大型金矿床,目前探获黄金资源量86吨,它位于中亚造山带东端的吉黑成矿带,是与中生代中酸性岩浆活动有关的复杂成矿系统,矿化类型可能包括了斑岩型、爆破角砾岩型、浅成低温热液型.研究表明,高丽沟J0号矿体为爆破角砾岩型,热液成矿过程经历了早、中、晚3个阶段,分别形成以石英-黄铁矿、多金属硫化物-石英和碳酸盐为代表的矿物组合,中阶段矿物含自然金最多,次为早阶段矿物.初始成矿流体系统为高温、高盐度、高氧逸度、富CO2的岩浆热液;经减压沸腾,CO2等挥发分大量逸出,流体温度、盐度和氧逸度下降,导致大量金属硫化物及自然金快速沉淀;大气降水混入导致晚阶段流体低温、低盐度、贫CO2,对成矿贡献甚微.总体而言,成矿流体盐度高(11.70%～37.81%NaCl.eq),成矿作用发生在中-高温(238.3～425.7℃)的浅成环境(深633m～2736m).岩浆-流体成矿系统富CO2应发育于大陆碰撞造山带的伸展构造背景,而非大洋板块俯冲诱发的岩浆弧背景.  相似文献   

河南洛宁段河金矿流体包裹体研究和矿床成因   总被引：2，自引：1，他引：1  

赖勇张宇高栏  李文博 《中国地质》2008,35(6):1206-1219

河南省洛宁县段河石英脉型金矿主要包括石寨沟和岭东两个矿区,分别由3～4条含金石英脉构成。矿化过程从早到晚包括石英-黄铁矿、石英-多金属硫化物和石英-碳酸盐等3个阶段．其中中阶段金矿化最强,次为早阶段。各阶段石英中流体包裹体以气液两相包裹体为主．次为纯液体包裹体。激光拉曼测试表明,气液两相包裹体的液相为H2O,气相主要为Ho和CO2混合、纯H2O,次为纯CO2;纯液体包裹体为纯H2O。石寨沟矿区包裹体均一温度从早到晚依次为240．9～315．9℃．188．7～304．5℃,137．3～259．3℃：流体盐度变化依次为（6．74～12．85）wt%NaCl．eq,（2．41～8．68）wt％NaCl．eq,（2．24-7．86）wt%NaCl．eq。岭东矿区均一温度从早到晚依次为303．7-343．1℃,251．8-325．4℃,305．7～355．0℃：流体盐度变化依次为（5．11～11．70）wt％NaCl．eq,（2．74-10．11）wt％NaCl．eq,（0．53-6．74）wt％NaCl．eq。两矿区主成矿期流体均为中温、低盐度,早阶段流体为改造热液和变质热液的混合体,含一定量CO2,且流体CO2含量和盐度从早到晚逐渐降低。石寨沟矿区包裹体均一温度逐渐降低,而岭东矿区包裹体均一温度先降后升,加之岭东矿区各阶段成矿温度均高于石寨沟矿区．表明成矿流体系统主要受岩浆热驱动,岭东矿区更靠近岩体,且在晚阶段又有脉动性的岩浆加热．段河金矿区南部存在隐伏岩体。  相似文献