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1.
The amphibolite facies Puolankajärvi Formation (PjF) occupies the western margin of the Early Proterozoic Kainuu Schist Belt (KSB) of northern Finland. The lower and middle parts of the PjF consist of turbiditic psammites and pelites and tempestitic semipelites. This report concentrates on the pelitic lithologies which include quartz–two-mica–plagioclase schists with variable amounts of garnet, staurolite, andalusite and biotite porphyroblasts as well as sillimanite and cordierite segregations. The KSB forms a major north–south-trending synclinorium between two Archaean blocks. It contains both autochthonous and allochthonous units and is cut by faults and shear zones. The PjF lies on the western side of the KSB and is probably allochthonous. The formation has undergone six major deformation phases (D1, D2, D3a, D3b, D4 and D5). During D3a-D5 the maximum principal stress (σ1) changed in a clockwise direction from south-west to north-east. Between D2 and D3 the intermediate principal stress (σ2) changed from horizontal to vertical and the interval between D2 and D3 marks a transition from thrust to strike-slip tectonics. Relict structures in the porphyroblasts indicate the following mineral growth–deformation evolution in the PjF. (1) Throughout the PjF there was a successive crystallization of garnet (syn-D1), poryphyroblastic biotite (inter-D3/4) and staurolite (inter-D3/4) during the pre-D4 stage. (2) A syn-D4-inter-D4/5 crystallization of kyanite, sillimanite (fibrolite), porphyroblastic tourmaline, magnetite, rutile, cordierite and muscovite–biotite–plagioclase pseudomorphs after staurolite was most localized at and near D4 shear zones. (3) A syn- to post-D5 generation of andalusite, ilmenohematite and sheet silicates after staurolite and after cordierite occurred near D5 faults. The evolution outlined here permits the relative dating of the PjF parageneses, which is used in the second part of the study (Tuisku & Laajoki, 1990), and, together with the knowledge of the pressure–temperature conditions during various growth events, makes it possible to compile pressure–temperature–deformation paths for the PjF. 相似文献
2.
The source rock from which the sillimanite gneisses derive mainly was the biotite plagioclase gneiss in the Larsemann Hills. It is the deformation-metamorphism process under special pressure and temperature condition, not the original rock compositions, that controls the presence of sillimanite. To a great degree, the sillimanite gneiss was the mixture of the detaining materials of the migrating felsic melt from the bt-plagioclase gneiss that underwent partial melting and the relics when the melt was removed. In sillimanitization the original rock had been changed substantially in chemical composition. The related metamorphism process severely deviated from the isochemical series, the process was of, therefore, an open system. In addition, the Al2O3 contents of the original rock was an important, but not critical factor for the formation of sillimanite, i.e., the sillimanite-bearing rock need not be of aluminum rich in composition, and vise contrarily, the aluminum rock may not produce sillimanite. The authors of the present paper postulate that the source rock from which the aluminum rich rock derives need not be of aluminum rich, but sillimanitization is generally the Al2O3 increasing process. The aluminum rich sediments such as clay or shale need not correspond directly to sillimanite-rich gneisses. No argillaceous rock present equals to sillimanite-rich gneiss in chemical composition. The protoliths to the sillimanite gneisses from the Larsemann Hills, east Antarctica, and their adjacent area may be pelite, shale greywacke, sub-greywacke, quartz sandstone and quartz-tourmalinite. If correct, the conclusion will be of significant implication for the determination of the sillimanite gneiss formation process and the reconstruction of the protolith setting. 相似文献
3.
Quartz‐rich veins in metapelitic schists of the Sanandaj‐Sirjan belt, Hamadan region, Iran, commonly contain two Al2SiO5 polymorphs, and, more rarely, three coexisting Al2SiO5 polymorphs. In most andalusite and sillimanite schists, the types of polymorphs in veins correlate with Al2SiO5 polymorph(s) in the host rocks, although vein polymorphs are texturally and compositionally distinct from those in adjacent host rocks; e.g. vein andalusite is enriched in Fe2O3 relative to host rock andalusite. Low‐grade rocks contain andalusite + quartz veins, medium‐grade rocks contain andalusite + sillimanite + quartz ± plagioclase veins, and high‐grade rocks contain sillimanite + quartz + plagioclase veins/leucosomes. Although most andalusite and sillimanite‐bearing veins occur in host rocks that also contain Al2SiO5, kyanite‐quartz veins crosscut rocks that lack Al2SiO5 (e.g. staurolite schist, granite). A quartz vein containing andalusite + kyanite + sillimanite + staurolite + muscovite occurs in andalusite–sillimanite host rocks. Textural relationships in this vein indicate the crystallization sequence andalusite to kyanite to sillimanite. This crystallization sequence conflicts with the observation that kyanite‐quartz veins post‐date andalusite–sillimanite veins and at least one intrusive phase of a granite that produced a low‐pressure–high‐temperature contact aureole; these relationships imply a sequence of andalusite to sillimanite to kyanite. Varying crystallization sequences for rocks in a largely coherent metamorphic belt can be explained by P–T paths of different rocks passing near (slightly above, slightly below) the Al2SiO5 triple point, and by overprinting of multiple metamorphic events in a terrane that evolved from a continental arc to a collisional orogen. 相似文献
4.
为了查明麻粒岩相变质高峰期的流体特征 ,对研究区太古宙孔兹岩系变质峰期特征矿物夕线石中具负晶形的碳质液相包裹体进行了冷热台显微测温和激光拉曼光谱成分测定。研究表明 ,该类包裹体xH2 O很低 (0mol%～ 17mol% ) ,碳质成分很高 (xCO2 +CH4=70mol %～ 90mol% ) ,密度为0 .94～ 1.0g/cm3 ,相应压力约为 0 .7GPa。流体氧逸度的lg fO2 在 - 14～ - 16之间。研究结果表明 ,丰富的碳质组分不是深部来源的 ,而可能是由孔兹岩系原岩中有机质氧化作用产生。 相似文献
5.
本文对丹凤西峡地区不同蓝晶石族矿床石榴子石进行了较系统的矿物学研究。从石榴子石的化学成分，晶体结构，红外吸收光谱特征及氧同位素组成与矿床成因类型，主变质相的相关关系，总结出了石榴子石的标型特征。 相似文献
6.
豫西南矽线石物相分析方法研究 总被引：2，自引：2，他引：2
以豫西南地区4个矿区的矿物组合为依据,建立了铝量法测定矽线石含量的物相分析方法。对比了不同方法制备的矽线石及其不同存在条件下溶解率的差异,确定了接近矿区实际的、准确合理的分析结果校正办法。 相似文献
7.
对我国鄂西及黑龙江省东部孔兹岩系的地质观察发现,含棱柱状夕线石的高铝夕线片岩类与含红柱石的云母片岩类岩石在区域上共生。系统的岩相学研究表明,这些夕线石系由叶蜡石直接转变所成。原岩恢复以及对变质作用过程中可能发生的变质反应的理论探讨和原始沉积物理想组分计算的结果都支持上述结论。认为孔兹岩系中的棱柱状夕线石和红柱石系低角闪岩相条件下在不同的原岩中经不同的变质反应形成。它们的形成主要受原岩的成分控制。这种由叶蜡石直接分解形成的夕线石,其初始形成温度较低,不能作为划分高角闪岩相的标志。 相似文献
8.
Abstract Muscovite-poor pelitic schists in the wallrocks of the Proterozoic Annex sulphide deposit, near Prieska, South Africa, contain peak metamorphic assemblages including Crd + Bt + Sil, St + Sil + Bt, Crd + St + Bt and, rarely, Ky + St ° Crd. All rocks include oligoclase, quartz and commonly Fe–Mn garnet, with or without muscovite. Peak assemblages, assigned to M2 regional metamorphism in the Gordonia Belt (Namaqua Province), are syn- to post-kinematic with respect to the main S2 fabric although larger staurolite grains contain S1 inclusion trails. Garnet–biotite thermometry, utilizing corrections for Fe3+, Mn, AlVI and Ti, yields peak temperatures of 571–624°C at pressures of 4.5–6.0 kbar. Consideration of the sympathetic variation of XMn in garnet with XMg in biotite and the preserved zoning patterns in prograde garnets, together with the inferred prograde transition from kyanite to sillimanite, indicates that heating occurred during mild decompression to the M2 metamorphic peak. Sillimanite and cordierite grew last in the prograde sequence, possibly related to a pulse of thermal metamorphism (M3) that is found along the margin of the Keimoes Suite batholith to the north. Retrograde assemblages, including Ms + Ky + Chl + Qtz (after Crd + Bt), Ky + Ms (after Sil) and Chl + Ms (after St) indicate a period of isobaric cooling (M4a) terminated by rehydration in the kyanite stability field at about 500°C. The size difference between prograde (1–2-mm) and retrograde (0.05–0.1-mm) mineral grains indicates substantial undercooling below equilibrium positions of relevant retrograde reactions prior to rehydration, and explains why cordierite that grew during M2 is almost completely destroyed. Post-M4a regrowth of staurolite and garnet (M4b) is spatially linked to sites of M4a rehydration. It reached temperatures of 510–530°C, remaining within the stability field of kyanite. A best fit of the observed textural history to the Namaqua orogenic cycle involves collision and heating (M2/D2) followed by granite intrusion (M3), rifting (M4a) and renewed heating due to crustal loading during volcanism (M4b). The P–T path for the Annex region is consistent with those derived from elsewhere in the Gordonia Belt and, with modification, to that published already for the nearby Prieska Copper Mines. 相似文献
9.
Magnesian metapelites of probable Archaean age from Forefinger Point, SW Enderby Land, East Antarctica, contain very-high-temperature granulite facies mineral assemblages, which include orthopyroxene (8–9.5 wt% Al2 O3 )–sillimanite ± garnet ± quartz ± K-feldspar, that formed at 10 ± 1.5 kbar and 950 ± 50°C. These assemblages are overprinted by symplectite and corona reaction textures involving sapphirine, orthopyroxene (6–7 wt% Al2 O3 ), cordierite and sometimes spinel at the expense of porphyroblastic garnet or earlier orthopyroxene–sillimanite. These textures mainly pre-date the development of coarse biotite at the expense of initial mesoperthite, and the subsequent formation of orthopyroxene (4–6 wt% Al2 O3 )–cordierite–plagioclase rinds on late biotite.
The early reaction textures indicate a period of near-isothermal decompression at temperatures above 900°C. Decompression from 10 ± 1.5 kbar to 7–8 kbar was succeeded by biotite formation at significantly lower temperatures (800–850°C) and further decompression to 4.5 ± 1 kbar at 700–800°C.
The later parts of this P–T evolution can be ascribed to the overprinting and reworking of the Forefinger Point granulites by the Late-Proterozoic ( c . 1000 Ma) Rayner Complex metamorphism, but the age and timing of the early high-temperature decompression is not known. It is speculated that this initial decompression is of Archaean age and therefore records thinning of the crust of the Napier Complex following crustal thickening by tectonic or magmatic mechanisms and preceding the generally wellpreserved post-deformational near-isobaric cooling history of this terrain. 相似文献
The early reaction textures indicate a period of near-isothermal decompression at temperatures above 900°C. Decompression from 10 ± 1.5 kbar to 7–8 kbar was succeeded by biotite formation at significantly lower temperatures (800–850°C) and further decompression to 4.5 ± 1 kbar at 700–800°C.
The later parts of this P–T evolution can be ascribed to the overprinting and reworking of the Forefinger Point granulites by the Late-Proterozoic ( c . 1000 Ma) Rayner Complex metamorphism, but the age and timing of the early high-temperature decompression is not known. It is speculated that this initial decompression is of Archaean age and therefore records thinning of the crust of the Napier Complex following crustal thickening by tectonic or magmatic mechanisms and preceding the generally wellpreserved post-deformational near-isobaric cooling history of this terrain. 相似文献
10.
RALPH KRETZ 《Journal of Metamorphic Geology》1990,8(5):493-506
Garnet-biotite gneisses, some of which contain sillimanite or hornblende, are widespread within the Otter Lake terrain, a portion of the Grenville Province of the Canadian Shield. The metamorphic grade is upper amphibolite to, locally, lower granulite facies. The atomic ratio Fe2+/(Fe2++ Fe3+) in biotite ranges from 0.79 to 0.89 (ferrous iron determinations in 10 highly pure separates), with a mean of 0.86. Mg and Fe2+ atoms occupy 67–78% of the octahedral sites, the remainder are occupied by Fe3+, Ti, and Al, and some are vacant. Mg/(Mg + Fe2+), denoted X, in the analysed samples ranges from 0.32 to 0.65. Garnet contains 1–24% grossular, 1–12% spessartine and X ranges from 0.07 to 0.34. Compositional variation in biotite and garnet is examined in relation to three mineral equilibria: (I) biotite + sillimanite + quartz = garnet + K-feldspar + H2O; (II) pyrope + annite = almandine + phlogopite; (III) anorthite = grossular + sillimanite + quartz. Measurements of X (biotite) and X (garnet) are used to construct an illustrative model for equilibrium (I) which relates the observed variation in X to a temperature range of 70°C or a range in H2O activity of 0.6; the latter interpretation is preferred. In sillimanite-free gneisses, the distribution of Mg and Fe2+ between garnet (low in Ca and Mn) and biotite is adequately described by a distribution coefficient (KD) of 4.1 (equilibrium II). The observed increase in the distribution coefficient with increasing Ca in garnet is ln KD= 1.3 + 2.5 × 10?2 [Ca] where [Ca] = 100 Ca/(Mg + Fe2++ Mn + Ca). The distribution coefficient is apparently unaffected by the presence of up to 12% spessartine in garnet. In several specimens of garnet-sillimanite-plagioclase gneiss, the Ca contents of garnet and of plagioclase increase in unison, as required by equilibrium (III). The mean pressure calculated from these data (n= 17) is 5.9 kbar, and the 95% confidence limits are ±0.5 kbar. 相似文献