粉煤灰基地质聚合物水热原位转化NaP型沸石分子筛的研究     

仇秀梅  刘亚东  严春杰  董学林 《岩石矿物学杂志》2018,37(4):669-678

以固体废弃物粉煤灰基地质聚合物为基本骨架,通过水热合成法将其原位转化为自支撑Na P型沸石分子筛型体,并研究了水热过程中碱液浓度、碱液体积、水热温度和水热时间对NaP型沸石分子筛结晶程度、形貌和机械强度的影响,得到粉煤灰基地质聚合物原位转化Na P型沸石分子筛型体的适宜条件为水热温度100℃、NaOH浓度2.0mol/L、NaOH体积50 m L、水热时间24 h。所得Na P型沸石分子筛型体的抗压强度为23.21 MPa,BET比表面积为50.46 m~2/g,已达到工业生产P型沸石的水平。该法工艺简单,环境友好,可控成型。在此方法的基础上通过改变原料配比和反应条件,可以合成其他类型的沸石分子筛型体。  相似文献   

温度对沸石吸钾量检测的影响研究     

陈燕芳  刘清辉  郑存江 《岩矿测试》2014,33(5):670-673

沸石具有选择性吸附钾离子的特性,吸钾量是沸石应用中一项重要的物化性能,温度是影响吸钾量测量结果准确度的重要因素。在现有的吸钾量测试方法中,由于对测试温度的规定较为模糊,基本不作设定或只注明室温,而室温随季节变化较大,测试方法的准确度和精密度无法得到保证。为完善吸钾量的测试方法,本文研究了实际温度对沸石吸钾量的影响。结果表明,在试验的温度范围内(11.5~80℃),沸石样品的吸钾量与温度呈稳定且相对固定的负相关,由此提出了吸钾量计算公式:E20=Et+k(t-t20)。根据该定量关系,本文提出吸钾量测试方法中需要明确规定吸钾量的测试温度为20℃;如果是在非20℃的实际温度下测量得到的吸钾量,可根据温度校正系数(k)转换到20℃条件下的吸钾量。这种吸钾量测试方法可在实际室温下进行,操作简单,无需使用控温装置;又能消除因时间和地域差异导致的室温波动的影响,使吸钾量测试结果具有更好的精密度和准确度。  相似文献   

沸石强化过滤的中试及生产性试验研究   总被引：2，自引：0，他引：2  

丁磊  王萍 《矿物学报》2008,28(3)

对新型水处理材料沸石强化常规给水处理工艺进行了中试和生产性试验,并与石英砂滤料做了对比.中试结果表明粒径为0.80-1.20mm沸石对浊度、氨氮、有机物都表现出良好的去除效果,过滤时的水头损失、反冲洗强度明显小于石英砂,不仅能满足反冲洗要求,还可节省反冲洗水量,降低运行成本.在生产性试验条件下,沸石对浊度、氨氮、耗氧量的去除率分别为95%、83%和39%.因此,在当前水源水遭到污染的情况下,用沸石替代石英砂滤料可明显改善水质,在不增加处理构筑物的情况下,对给水处理工艺可起到强化作用  相似文献   

沸石基储能基元的研究     

杨玉山  董发勤  段涛 《矿物岩石》2008,28(1):13-16

以酸活化沸石为载体,十二醇为储能工质.制备沸石基储能基元,并采用X射线衍射、红外光谱和差示扫描量热等对沸石基储能基元进行表征.结果表明:储能基元在2θ=22.50时的衍射峰变强,相变储能材料十二醇和沸石栽体之间仅仅是简单的嵌合关系.储能基元的相变温度有一定的降低,并且熔融峰变宽.  相似文献   

Stability at high-pressure,elastic behaviour and pressure-induced structural evolution of CsAlSi<Subscript>5</Subscript>O<Subscript>12</Subscript>, a potential host for nuclear waste     

G. Diego Gatta  Nicola Rotiroti  Martin Fisch  Milen Kadiyski  Thomas Armbruster 《Physics and Chemistry of Minerals》2008,35(9):521-533

The elastic and structural behaviour of the synthetic zeolite CsAlSi₅O₁₂ (a = 16.753(4), b = 13.797(3) and c = 5.0235(17) Å, space group Ama2, Z = 2) were investigated up to 8.5 GPa by in situ single-crystal X-ray diffraction with a diamond anvil cell under hydrostatic conditions. No phase-transition occurs within the P-range investigated. Fitting the volume data with a third-order Birch–Murnaghan equation-of-state gives: V ₀ = 1,155(4) ų, K _T0 = 20(1) GPa and K′ = 6.5(7). The “axial moduli” were calculated with a third-order “linearized” BM-EoS, substituting the cube of the individual lattice parameter (a ³, b ³, c ³) for the volume. The refined axial-EoS parameters are: a ₀ = 16.701(44) Å, K _T0a = 14(2) GPa (β_a = 0.024(3) GPa^?1), K′ _a = 6.2(8) for the a-axis; b ₀ = 13.778(20) Å, K _T0b = 21(3) GPa (β_b = 0.016(2) GPa^?1), K′ _b = 10(2) for the b-axis; c ₀ = 5.018(7) Å, K _T0c = 33(3) GPa (β_c = 0.010(1) GPa^?1), K′ _c = 3.2(8) for the c-axis (K _T0a:K _T0b:K _T0c = 1:1.50:2.36). The HP-crystal structure evolution was studied on the basis of several structural refinements at different pressures: 0.0001 GPa (with crystal in DAC without any pressure medium), 1.58(3), 1.75(4), 1.94(6), 3.25(4), 4.69(5), 7.36(6), 8.45(5) and 0.0001 GPa (after decompression). The main deformation mechanisms at high-pressure are basically driven by tetrahedral tilting, the tetrahedra behaving as rigid-units. A change in the compressional mechanisms was observed at P ≤ 2 GPa. The P-induced structural rearrangement up to 8.5 GPa is completely reversible. The high thermo-elastic stability of CsAlSi₅O_12, the immobility of Cs at HT/HP-conditions, the preservation of crystallinity at least up to 8.5 GPa and 1,000°C in elastic regime and the extremely low leaching rate of Cs from CsAlSi₅O₁₂ allow to consider this open-framework silicate as functional material potentially usable for fixation and deposition of Cs radioisotopes.  相似文献   

Effect of some additives on synthesis of zeolite from coal fly ash   总被引：3，自引：0，他引：3  

Deyi Wu  Bohua Zhang  Li Yan  Hainan Kong  Xinze Wang 《International Journal of Mineral Processing》2006,80(2-4):266-272

Hydrothermal conversion of fly ash into zeolites was conducted and the effects of the addition of sodium halide and waste solutions produced after zeolitization of fly ash, as well as the adjustment of the Si/Al ratio prior to synthesis process on the formation and cation exchange capacity (CEC) of zeolite product were evaluated. Both the addition of NaCl and NaF ameliorated the crystallinity and CEC of synthesized zeolite, but NaF had a better improvement effect. Na⁺ was considered to enhance the crystallization of zeolite, while F⁻ favored the dissolution of fly ash. The type of zeolite formed depended on the Si/Al ratio of the starting material prior to the nucleation and crystallization of zeolite. The adjustment of the Si/Al ratio of fly ash by addition of Na₂SiO₄ and Al(OH)₃ changed the type and CEC of zeolite. Waste solutions contained large amount of Si and little Al due to the formation of a zeolite named NaP1 in zeolite terminology with the Joint Committee of Powder Diffraction Standard (JCPDS) code of 39-0219. The alkalinity decreased largely. As a result, the CEC value of zeolite products synthesized with waste solution as alkali source decreased. The supplementation of new alkali to adjust the alkalinity of waste solution could enhance the CEC of synthesized product. It was concluded that: (1) addition of sodium halide and adjustment of the Si/Al ratio prior to synthesis can improve the quality of zeolite; (2) waste solutions produced following the zeolitization of fly ash can be reused as an alkali source in the activation of fly ash; zero-emission of waste solution in the synthesis of zeolite from fly ash is possible.  相似文献   

广西车田沸石及其开发利用研究进展     

申少华  付泽春  张欣  伍泽广 《矿产与地质》2007,21(5):589-593

文章在总结车田沸石的晶形及物理性质、化学成分特征、红外光谱、差热-热重、X射线衍射等矿物学特征，以及耐热稳定性、耐酸碱稳定性、离子吸附与交换性能等资源特性研究进展的基础上，重点介绍了车田沸石的开发利用研究新进展，即利用其在低温煅烧和低浓度酸处理后可使其成为无定形非晶态物质的特性制备A型、X型、Y型和P型分子筛；利用其吸附和离子交换性能制备水处理剂、沸石型化肥、无机抗菌剂、干燥剂；利用其化学成分和晶体结构特性制备沸石砖、橡胶和塑料的增强剂等。并对今后车田沸石及其开发利用的研究方向和研究前景进行了展望。  相似文献   

Implications of Analcime Hydrothermally Formed from Na-alumino-borosilicate Glasses Containing Cs and Sr for the Stability of High-level Radioactive Waste Form     

Wook Sohn    Tetsuya Shoji  Hiroaki Kaneda  Teruaki Ishii 《Resource Geology》2003,53(1):51-59

Abstract. In order to know the behaviors of radioactive elements such as cesium and strontium during a hydrothermal alteration of borosilicate glass of radioactive waste, some alumino-borosilicate glasses belonging to the systems Na₂O-Al₂O₃-B₂O₃-SiO₂-SrO, Na₂O-Al₂O₃-B₂O₃-SiO₂-Cs₂O and Na₂O-Al₂-O₃-B₂O₃-SiO₂-SrO-Cs₂O have been treated hydrothermally at 200C under a vapor pressure of 1.54 MPa. The result shows that all glasses are changed into crystalline phases with running time up to 60 days, and that analcime-type zeolite is formed as a major product. The formed zeolite is shown to contain cesium and/or strontium. Considering the fact that natural zeolite occurs in wide physicochemical conditions including hydrothermal one, the analcime-type zeolite is expected to fix stably the radioactive elements in the disposal site. Since aluminum is necessary for the formation of the analcime-type zeolite, the waste glass should have aluminum as one of major components.  相似文献   

Synthesis of zeolites using fly ash and their application in removing heavy metals from waters   总被引：1，自引：0，他引：1  

王焰新  郭永龙  杨志华  蔡鹤生  Xavier Querol 《中国科学D辑(英文版)》2003,46(9):967-976

Fly ash is the solid waste of thermal power plants where coal is used as fuel, and its management and utilization have been of environmental concern for decades. Since the technique of synthesizing zeolite from coal fly ash was introduced by Holler[1] (19…  相似文献   

利用高铁钾长石粉合成13X沸石分子筛的实验研究   总被引：6，自引：3，他引：6       下载免费PDF全文

章西焕  马鸿文杨静 肖万 《岩石矿物学杂志》2003,22(2):167-172

对江苏丰县的富钾页岩进行预处理，得到钾长石含量达76．4％的钾长石粉，其Fe2O3含量高达7．52％。以此钾长石粉为原料经过焙烧处理、水热合成实验，在铁含量较高情况下成功合成了13X沸石分子筛，并采用正交实验法确定了优化工艺参数。对实验产物的主要性能测试表明，合成的富铁沸石产品与13X沸石分子筛工业产品相似，吸附量达到国家化学工业产品标准，可用于对含重金属离子废水的吸附处理。  相似文献