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LIU Rui LU Anhuai QIN Shan 《《地质学报》英文版》2006,80(2):175-179
Feldspar and Pb(NO3)2 were mixed and reacted at T=380℃ to synthesize Pb-feldspar. In the XRD (X-ray diffraction) pattern of the product, the d values (crystal lattice spacing) of the five peaks are 0.654, 0.342, 0.332, 0.327 and 0.257 nm. The XPS analysis results show that the binding energy of Pb 4f(7/2) in the feldspar was between 137.81-138.03 eV. Pb^2+ can replace alkali and alkali earth cations in the feldspar structure through ion exchange reaction to form Pb-feldspar. 相似文献
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Poly (n-octyl acrylate) with uniform polystyrene grafts (POA-g-PS) was obtained by radical copolymerization of n-octyl acrylate (OA) with PS macromer, in solution. The reactivity ratio and effects of copolymerization conditions on grafting efficiency were studied. The crude products were purified by extraction with cyclohexane and n-butanol successively. POA-g-PS exhibited a very good compatibilizing effect on the acrylic rubber/polystyrene blends. 2%-3% of the graft copolymer was enough for enhancing the tensile strength of the blends. DSC and SEM demonstrated the enhancement of compatibility in the presence of the graft copolymer. 相似文献
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微塑料因粒径小、比表面积大,可作为重金属、有机污染物以及病原微生物的载体。已有研究表明,微塑料表面附着的微生物主要以生物膜的形式存在。本研究以山东省海岸带环境中常见的两类软质塑料——发泡类聚苯乙烯(expanded polystyrene,EPS)和聚乙烯薄膜(polyethylene films,PE)为研究对象,比较了MP FastDNA®和MOBIO PowerSoil®两种DNA提取试剂盒对微塑料表面生物膜DNA的提取效果,探讨了不同的微塑料粒径和数量对DNA提取效果的影响。结果表明,MP FastDNA®试剂盒对两种软质微塑料表面生物膜DNA的提取浓度显著低于MOBIO PowerSoil®试剂盒(1.0~12.5倍)。采用MP FastDNA®试剂盒提取的PE表面DNA的浓度约为EPS的1.3~4.4倍。当微塑料数量不大于20片时,小粒径(1~3 mm)的EPS表面生物膜DNA浓度显著高于大粒径(3~5 mm) EPS,而对于PE薄膜则相反。对于两种粒径的EPS,微塑料表面DNA浓度均随着微塑料数量的增加而显著增加,但对于小粒径(1~3 mm)的PE薄膜,DNA浓度随微塑料数量的增加呈先增后减的趋势;而大粒径(3~5 mm)的PE薄膜表面DNA浓度随微塑料数量的增加而降低。微塑料的粒径和数量对其表面DNA提取效果影响的差异与微塑料的类型及其理化性质有关。本研究可为海洋与海岸环境中微塑料表面微生物群落组成与多样性研究提供方法支撑。 相似文献
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复合填料是以废铸砂、粉煤灰、聚苯乙烯颗粒(EPS)、水泥和水为原料,拌合后形成的一种轻质填筑材料。其中,EPS颗粒含量适当时,能减少或消除复合填料的冻胀和融沉,可作为季节性冻土区的路基填料。假设复合填料中除EPS颗粒外的骨料颗粒、孔隙冰为刚性介质,同时考虑EPS颗粒变形和填料孔隙变形对复合填料冻结过程的影响,在已有的冻土水热耦合分离冰模型的基础上,得到考虑EPS颗粒变形影响的饱和填料一维冻结水热耦合控制方程,进而预测填料的冻胀量。与室内模型试验结果对比表明,本文模型可用于该种具有弹性颗粒复合填料的冻胀量模拟,为工程中冻胀量预测提供依据。 相似文献
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